Corrosion inhibition efficiencies of holy basil on Al in HCl solution were studied by weight loss and thermometric methods in presence and in absence of stem extract of three different varieties of holy basil viz. ocimum basilicum ($E_B$), ocimum canum ($E_C$) and ocimum sanctum ($E_S$). Inhibition efficiency increases with the increasing concentration of stem extract and decreases with increases in acid strength. Results show that all varieties under study are good corrosion inhibitors, among which, $E_B$ is most effective. Maximum inhibition efficiency was found 97.09% in 0.5N HCl solution with 0.6% stem extract. The Langmuir adsorption isotherm indicates that surface coverage also increases with increasing in the concentration of extract of stem in HCl solution.

The corrosion inhibition of copper-nickel alloy by Ethylenediamine (EDA) and Diethylenetriamine (DETA) in 1.5M HCl has been investigated by weight loss technique at different temperatures. Maximum value of inhibitor efficiency was 75% at $35^{\circ}C$ and 0.2 M inhibitor concentration EDA, while the lower value was 4% at $35^{\circ}C$ and 0.01 M inhibitor concentration DETA. Two mathematical models were used to represent the corrosion rate data, second order polynomial model and exponential model respectively. Nonlinear regression analysis showed that the first model was better than the second model with high correlation coefficient. The reactivity of studied inhibitors was analyzed through theoretical calculations based on density functional theory (DFT). The results showed that the reactive sites were located on the nitrogen (N1, N2 and N4) atoms.

Using time domain reflectometry, the complex dielectric spectra between 10 MHz to 20 GHz has been measured in the whole composition range at 10, 20, 30 and $40^{\circ}C$ for the binary mixtures of ethylene glycol and dimethyl sulfoxide. For all the mixtures, only one dielectric loss peak was observed in this frequency range. The relaxation in these mixtures can be described by a single relaxation time using the Debye model. A systematic variation is observed in dielectric constant (${\varepsilon}_0$) and relaxation time (${\tau}$). The excess permittivity (${\varepsilon}^E$), excess inverse relaxation time $(1/{\tau})^E$, Kirkwood correlation factor (g) and thermodynamic parameters viz. enthalpy of activation (${\Delta}H$) and Gibbs free energy of activation (${\Delta}G$) have been determined, to confirm the formation of hydrogen bonded homogeneous and heterogeneous cooperative domains, the dynamics of solute - solute interaction and the hindrance to molecular rotation in the hydrogen bonded glass forming ethylene glycol - dimethyl sulphoxide system.

Densities, viscosities, refractive indices and speed of sounds of the binary mixtures of Acetophenone with Ethylchloroacetate were measured over the entire mole fractions at (303.15, 313.15 and 323.15) K. From these experimental results, excess molar volume $V^E$, viscosity deviation ${\Delta}{\eta}$, refractive index deviation ${\Delta}n_D$, deviations in speed of sound ${\Delta}u$, deviations in isentropic compressibility ${\Delta}k_s$ and excess intermolecular free length ${\Delta}L_f$ were calculated. The viscosity data have been correlated with the equations of Grunberg and Nissan, Hind et al., Tamura and Kurata, Katti and Chaudri, Sedgwick, Krishnan-Laddha and McAllister. The thermo physical properties under study were fit to the Jouyban-Acree model. The excess values were correlated using Redlich-Kister polynomial equation to obtain their coefficients and standard deviations. It was found that in all cases, the data obtained fitted with the values correlated by the corresponding models very well. The results are interpreted in terms of molecular interactions occurring in the solution.

Dissipative particle dynamics (DPD) was carried out to study the nucleation and crystal growth process of $CeO_2$ nanoparticles in different alcohol aqueous solutions. The results showed that the nucleation and crystal growth process of $CeO_2$ can be classified into three stages: nuclei growth, crystal stabilization and crystal aggregation except the initial induction stage, which could be reproduced by collecting simulation results after different simulation time. Properly selecting the sizes of $CeO_2$ and water bead was crucial in the simulation system. The influence of alcohol type and content in solutions, and precipitation temperature on the particle dimension were investigated in detail and compared with the experimental results. The consistency between simulation results and experimental data verify that the simulation can reproduce the macroscopic particle aggregation process. The effect of solvent on the nucleation and crystal growth of $CeO_2$ nanoparticles are different at three stages and can not be simply described by Derjaguin-Landau-Verwey-Overbeek (DLVO) theory or nucleation thermodynamics theory. Our work demonstrated that DPD methods can be applied to study nanoparticle forming process.

Heteroleptic complexes of zirconium (IV) derived from bulky Schiff base ligands containing a sulphur atom and oximes of heterocyclic ${\beta}$-diketones of the general formula ZrLL' (where $LH_2=RCNH(C_6H_4)SC:C(OH)N(C_6H_5)N:CCH_3$, $R=-C_6H_5$, $-C_6H_4Cl(p)$ and $L^{\prime}H_2=R^{\prime}C:(NOH)C:C(OH)N(C_6H_5)N:CCH_3$, $R^{\prime}=-CH_2CH_3$, $-C_6H_5$, $-C_6H_4Cl(p)$ were prepared by the reactions of zirconium tetrachloride with disodium salts of Schiff bases ($L\;Na_2$) and oximes of heterocyclic ${\beta}$-diketones ($L^{\prime}\;Na_2$) in 1:1:1 molar ratio in dry refluxing THF. The structures of these monomeric zirconium (IV) complexes were elucidated with the help of elemental analysis, molecular weight measurements, spectroscopic (IR, NMR and mass) studies. A distorted trigonal bipyramidal geometry may be suggested for these heteroleptic zirconium (IV) complexes. The ligands (bulky Schiff base ligands containing a sulphur atom and oximes of heterocyclic ${\beta}$-diketones) and their heteroleptic complexes of zirconium (IV) were screened against A. flavus, P. aeruginesa and E. coli.

In order to develop alloy resistance in aggressive sulphat ion, the corrosion behavior of metallic glasses $Ni_{92{\cdot}3}Si_{4.5}B_{32}$, $Ni_{82,3}Cr_7Fe_3Si_{4.5}B_{3.2}$ and $Ni_{75.5}Cr_{13}Fe_{4.2}Si_{4.5}B_{2.8}$ (at %) at different concentrations of $H_2SO_4$ solutions was examined by electrochemical methods and Scanning Electron Microscope (SEM) and X-ray Photoelectron Microscopy (XPS) analyses. The corrosion kinetics and passivation behavior was studied. A direct proportion was observed between the corrosion rate and acid concentration in the case of $Ni_{92{\cdot}3}Si_{4.5}B_{32}$ and $Ni_{75.5}Cr_{13}Fe_{4.2}Si_{4.5}B_{2.8}$ alloys. Critical concentration was observed in the case of $Ni_{82,3}Cr_7Fe_3Si_{4.5}B_{3.2}$ alloy. The influence of the alloying element is reflected in the increasing resistance of the protective film. XPS analysis confirms that the protection film on the $Ni_{92{\cdot}3}Si_{4.5}B_{32}$ alloy was NiS which is less protective than that formed on Cr containing alloys. The corrosion rate of $Ni_{82,3}Cr_7Fe_3Si_{4.5}B_{3.2}$ and $Ni_{75.5}Cr_{13}Fe_{4.2}Si_{4.5}B_{2.8}$. alloys containing 7% and 13% Cr are $7.90-26.1{\times}10^{-3}$ mm/y which is lower about 43-54 times of the alloy $Ni_{92{\cdot}3}Si_{4.5}B_{32}$ (free of Cr). The high resistance of $Ni_{75.5}Cr_{13}Fe_{4.2}Si_{4.5}B_{2.8}$ alloy at the very aggressive media may due to thicker passive film of $Cr_2O_3$ which hydrated to hydrated chromium oxyhydroxide.

8-Formyl-4-Methyl-7-Hydroxy Coumarin Derivatives were synthesized via Penchem condensation followed by Duffs reaction. Treatment of this with N,N-di substituted cyano acetamides in the presence of piperdine afforded New 8-Formyl-4-Methyl-7-Hydroxy Coumarin Derivatives (7a-o). Their structures were characterized by IR, $^1H$ and $^{13}C$ NMR and Mass spectral and elemental analysis data.

A novel chitosan derivative with double quaternary ammonium salt-2-pyridine-acetyl-N-trimethyl chitosan chloride (PATMCS) was synthesized and the antioxidant activity of PATMCS against hydroxyl radicals was assessed. The results indicated that PATMCS had potent hydroxyl scavenging activity. The $IC_{50}$ of PATMCS was 0.13 mg/mL. PATMCS showed 100% scavenging effect at a dose of 0.8 mg/mL which markedly better than that of N-trimethyl chitosan chloride (TMCS). It was confirmed that quaternary chitosan derivatives showed potent antioxidant activity. PATMCS has double quaternary ammonium salt structure in the molecules. Therefore, the antioxidant activity of PATMCS was better than TMCS. The above results are theoretically fundamental for further development and making use of chitosan resources to prepare new antioxidants.

마이크로웨이브를 이용한 가열 방법과 MeO-PEG-OMe를 용매로 사용하여, benzo-[1,4]-oxazinone의 효율적인 one-pot 합성방법을 개발하였으며, 개발한 합성방법을 이용하여, 8 가지의 benzo-[1,4]-oxazinone 화합물과 1H-pyrido[2,3-b][1,4]-oxazin-2-(3H)-one을 좋은 수율로 합성하였다.

The novel chitosan-based thermosensitive hydrogels were prepared as control-releasing drug carriers. N-carboxyethyl chitosan (ACS) was synthesized by microwave heating for 1 h through Michael addition of CS to acrylic acid in a grafting yield of 52.97%, which was proved to be a faster and more efficient way than ordinary methods. 5-Fu was modified with formaldehyde to synthesize N,N'-Bis(hydroxymethyl)-5-fluorouracil (5-Fu-OH). Then an esterification was performed using ACS and 5-Fu-OH to give 5-Fu-ACS. The new thermosensitive hydrogels were prepared by adding sodium glycerophosphate to the solution of compounds under a certain constant temperature. Simultaneously, the hydrogels' swelling rate, in vitro drug release rate and thermosensitive were studied, and found that the 5-Fu-ACS composite hydrogel had more excellent releasing effect, higher drug loading and better thermosensitive.

We successfully synthesized $Fe_3O_4/SiO_2$ nanoparticles with ultrathin silica layer of $1.0{\pm}0.5$ nm that was fine controlled by changing concentration of $Fe_3O_4$. Among various reaction conditions for silica coating, increasing concentration of $Fe_3O_4$ was more effective approach to decrease silica thickness compared to water-to-surfactant ratio control. Moreover, we found that concentration of the 1-octanol is also important factor to produce the homogeneous $Fe_3O_4/SiO_2$ nanoparticles. The present approach could be available to apply on preparation of other core/shell nanoparticles with ultrathin silica layer.

The tin (IV) oxide nanoparticles are prepared by controlled precipitation method and calcined at temperatures of $200-600^{\circ}C$. The prepared $SnO_2$ nanoparticles characterized by XRD patterns, TEM image, IR and UV-Vis spectra. The XRD patterns and TEM image show the tetragonal structure and spherical morphology for $SnO_2$ nanoparticles, respectively. The photocatalytic activity of the prepared $SnO_2$ nanoparticles studied in degradation reaction of methylene blue (MB). The results show the size of nanoparticles, band-gap energy and photocatalytic activity of $SnO_2$ depends on the calcinations temperature. The $SnO_2$ nanoparticles calcined at $500^{\circ}C$ indicated the highest photoreactivity. Also, the zero-valent tin (ZVT) nanoparticles with tetragonal structure are prepared by a reducing agent and used as a catalyst in degradation of MB. In basic pH of 11, the degradation >95% of MB at time 150 min obtained at presence of ZVT nanoparticles.

2009 개정 교육과정의 화학 I 교육과정에서의 교육목표를 교과서의 학습목표 및 평가 문항에서 얼마나 반영하였는지에 대하여 Klopfer의 분류틀을 이용하여 조사하였다. 연구대상은 2009 개정 화학과 교육과정, 해설서, 4종의 화학 I 교과서이었다. 연구결과는 다음과 같다. 첫째, 2009 개정 교육과정의 화학I 교육목표는 Klopfer의 과학목표 분류체계의 모든 영역을 포함하고 있다. 둘째, 화학 I 교과서의 학습목표에 기술된 행동목표는 지식과 이해가 높은 비중을 차지하고 있는 반면, 과학적 탐구과정, 과학 지식과 과학 방법의 적용, 조작적 기능, 태도와 흥미, 지향에 관한 목표는 상대적으로 소홀하게 다루어지고 있다. 셋째, 화학 I 교과서의 단원종합문항의 평가 행동목표의 빈도는 지식과 이해에 집중되어 있다. 따라서 교과서 집필 시 교육과정의 다양한 교육목표를 반영한 학습목표의 진술이 필요하다. 학습 목표 및 평가 문항이 인지적인 면에 편중되어 진술하고 있으므로 학생들의 창의적인 사고를 위해 학습목표의 진술을 다양화하는 노력이 필요하다. 또한 교과서 학습목표와 평가문항목표의 일관성이 요구된다.

이 연구의 목적은 다중 표상 수업이 고등학생들의 글쓰기에서 나타난 다중 표상의 내재성에 미치는 영향을 알아보기 위한 것이다. 이 연구는 광역시에 위치한 고등학교 자연계열 2학년 2개 학급 학생 74명을 대상으로 수행하였으며, 2개 학급 중 1개 학급 41명을 실험집단으로, 다른 1개 학급 33명을 비교집단으로 선정하였다. 실험집단에는 2차시의 다중 표상 수업과 7가지 주제에 대한 전통적인 방식의 수업을 처치하였고, 비교집단에는 다중 표상 수업을 제외하고 실험집단과 동일하게 수업을 진행하였다. 학생들이 작성한 Summary Writing의 분석 결과, 다중 표상의 내재성에 대한 실험집단의 평균이 비교집단에 비해 통계적으로 유의미하게 높은 것으로 나타났다.

이 연구에서는 2007 개정 교육과정에 의한 중학교 과학 교과서 27권의 삽화를 성역할 고정관념의 측면에서 분석하고, 그 결과를 7차 교육과정에 의한 중학교 과학 교과서와 비교하였다. 삽화의 유형을 분류한 후, 삽화에 등장하는 학생과 성인의 성별 등장 빈도, 활동 유형 및 행동 특성의 성별 빈도를 분석하였다. 7차 교육과정기에 비해 모든 분석 항목에서 성별에 따른 차이가 감소하였으나, 학생의 학습 활동과 학생 및 성인의 행동 특성을 제외한 모든 항목에서 여전히 성역할 고정관념이 나타났다. 남학생의 등장 빈도는 여학생보다 많았는데, 학생의 학습 활동에서는 성별 빈도가 균형을 이루고 있었으나 학습외 활동은 남학생을 중심으로 묘사되어 있었다. 성인의 경우에는 남성이 여성보다 많이 등장하였고, 가정 활동에서는 여성의 비율이, 가정외 활동에서는 남성의 비율이 우세하였다. 직업 활동에는 남성이 주로 묘사되어 있었다. 학생과 성인은 대부분 적극적 행동 특성을 보였고, 학생과 성인 모두 각 성별 내에서 행동 특성의 비율이 비교적 유사하였다.

이 연구에서는 중학교 '과학2' 교과서에 서술되어 있는 '원소', '주기율표', '원자'에 대한 내용이 요구하는 인지 요구도를 분석하였다. 우리나라는 2007년 개정 교육과정에 의하여 처음으로 주기율표 및 그와 관련 내용들을 중학교에서 다루게 되어있다. 분석에 활용한 6종 과학 교과서에 서술된 내용이 어떠한 인지 수준을 요구하는 지를 알아내는 분석틀은 영국에서 개발된 CAT(Curriculum Analysis Taxonomy)의 3종류 분석틀을 사용하였다. 이 3종류 분석틀에 의하여 분석한 '과학2' 교과서에 서술된 내용이 요구하는 인지 수준들은 다음과 같았다. '원소'에 대한 교과서 서술이 더 이상 간단한 물질로 분리될 수 없는 순물질임을 이해하는 내용으로 후기 형식적 조작 수준이었다. 그러나 '원소'는 한 가지 종류의 원자만으로 이루어진 물질이라고 서술된 초기 형식적 조작 수준도 있었다. '주기율표'에 대한 교과서 서술이 다양한 종류의 원소들을 원소 기호를 이용하여 특정 기준에 따라 몇 가지 그룹으로 분류될 수 있음을 이해해야 하고, 실체를 범주화하는데 있어서 여러 기준으로 분류해야 하는 내용으로 후기 구체적 조작 수준이었다. '주기율표'를 여러 족들의 집함임을 알고 이원 분류표로 이해해야 하는 내용으로 초기 형식적 조작수준이었다. '원자' 구조와 연결 짓는 복합적 분류 체계로 주기율표를 표현하는 후기 형식적 수준도 있었다. '원자'에 대한 교과서 서술이 원자가 구조를 가진다는 것 그리고 원자가 같은 종류도 있고 다른 종류도 있다는 서술은 초기 형식적 수준이었다.