한국신재생에너지학회:학술대회논문집
Korean Society for New and Renewable Energy (KSNRE)
- Semi Annual
Domain
- Energy/Resources > New and Renewable Energy
2005.06a
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This paper aims to introduce the Daegwallyeong wind turbine test site which is the first official wind turbine test site in Korea. The current status of test site, the characteristics, the projects performed and future plan of this test site are described. The results of wind condition measurements and monitoring system established by the Kangwon National University are presented. The importance of field test is also commented.
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In this paper. we offer a new monitoring system that controls all of the windfar. it can also apply use general wind turbine systems and real meteorological tower. We propose a hierarchical releiable monitoring system connected by wireless communication channels between monitoring host computer and modular slave measuring subsystems. Our system has two hierarchical subsystems: slave measuring systems, and supervisory host computer. We design and implement that the slave measuring subsystems is placed in meteorological tower and wind turbines, and the supervisory host computer in safety zone, The micro-controller in slave measuring system is duplicated using cold-standby method for reliability. The host computer and slave system constructs a feedback system, with wireless communication channel between them. For monitoring and command function, the supervisory computer is implemented with a Personal Computer using graphic user interface. Consequently. we can get a reliable but economic system.
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본 연구는 발전용 풍력설비의 안정적인 전원공급 및 계통운영에 필요한 기술기준 및 규정을 제정하는 것으로 전기사업법 제67조(기술기준)에 따라 전기설비의 안전관리를 위하여 운영중인 기술기준 중 현재 제정되어 있지 않은
$\ulcorner$ 발전용 풍력설비기술기준$\lrcorner$ 과 법정 기술기준을 구체화하여 설비의 설계, 제작, 시공, 운영, 검사 및 보수시에 기술지침으로 활용할 수 있는$\ulcorner$ 풍력발전규정$\lrcorner$ 을 신규로 개발하는 것이다. 현재 기술기준은 전기사업법 제67조(기술기준) 및 동 법 시행령 제43조(기술기준의 제정)에 따라 전기설비기술기준, 발전용 화력설비기술기준, 발전용 수력설비기술기준 및 발전설비 용접기술기준 등 4개가 고시로 운영중이다. 그러나 국내 풍력발전기 설비용량은 약 22MW이고, 다수가 건설중 이거나 계획 중에 있으나 설치허가 및 검사기준이 되어야 할 기술기준이 없는 상황이다. 따라서, 본 연구를 통하여 풍력발전설비에 대한 국내기술의 안정적인 전원공급 및 계통운영에 필요한 기술기준(안) 및 규정(안)등을 실현하였다. -
This paper presents an overview analysis on the observed wind shear at Pohang Steel Works, focusing on diurnal patterns and the frequency of high nighttime shear at the site in case of land breeze. In addition, this paper discusses the importance of accurate shear estimates for reliable evaluation of wind energy density. In order for a long-term correlation of the site, three Measure-Correlate-Predict methods were tested with Pohang wind data and it was shown that the linear MCP gives poor estimation due to the geographic characteristics of complex terrain where the severe transformation of wind direction was accompanied.
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This study explains the procedure that should be taken to develop a successful wind park project. It Provide guideline for activities and studies to be done step by step solution. This study follow a chronological flow through the development process. They cover Technical consideration, Assessment of Wind Energy Resource, Wind park siting and Energy yield calculation. It's build on the experience gained by the Youngduk Wind Park project and give the playa role in the development of wind energy projects. It is important to understand all theses issues if a new project is to be successfully completed.
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The aerodynamic loads at the blade hub and the drive shaft for 1MW horizontal axis wind turbine are calculated numerically. The geometric shape of the blade such as chord length and twist angle can be obtained fran the aerodynamic optimization procedure. Various airfoil data, that is thick airfoils at hub side and thin airfoils at tip side, are distributed along the spanwise direction of the rotor blade. Under the wind data fulfilling design load cases based on the IEC61400-1, all of the shear forces, bending moments at the hub and the low speed shaft of the drive train are obtained by using the FAST code. It shows that shear forces and bending moments have a periodic. trend. These oscillating aerodynamic loads will lead to the fatigue problem at both of the hub and drive train From the load analysis the maximum shear forces and bending moments are generated when wind turbine generator system operates in the case of the extreme speed wind condition.
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A critical issue in the field of the rotor aerodynamics is the treatment of the wake. The wake is of primary importance in determining overall aerodynamic behavior, especially, a wind turbine blade includes the unsteady air loads problem. In this study, the wake generated by blades are depicted by a free wake model to analyse unsteady loading on blade and a new free wake model named Finite Vortex Element(FVE hereafter) is devised in order to include a wake-tower interact ion. In this new free wake model, blade-wake-tower interaction is described by cutting a vortex filament when the filament collides with a tower. This FVE model is compared with a conventional free wake model and verified by a comparison with NREL and SNU wind tunnel model. A comparison with NREL and SNU data shows validity and effectiveness of devised FVE free wake model and an efficient.
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Kwon, Sei-Jin;Son, Yoon-Gyu;Suh, Jae-Hak;Lee, Woul-Woo;Jang, Sung-Duk;Oh, Jong-Seok;Whang, Jin-Su;Kang, Sin-Il;Kwon, O-Jung;Chung, Chin-Wha;Han, Kyung-Seop;Chun, Chung-Wan 37
풍력을 이용한 풍력발전기의 전력변환 시스템을 개발하기 위해서는 바람의 특성을 정확히 분석하고 이를 대치할 수 있는 모의시험 장치인 시뮬레이터가 필수적이다. 모의시험 장치는 풍향 풍속등의 인자들을 입력받아 회전자 블레이드의 토오크를 전동기가 대신해서 발전기에 공급하게 된다 본 논문에서는 풍력발전 모의시험 장치를 이용하여 750-kW gearless형 풍력발전기의 축소모델인 20-kW 모델 발전기와 고효율의 전력변환 장치 설계 및 인버터 특성을 위한 시험용 지그에서의 시험한 결과를 보이고자 한다. -
In spite of fast growing of prediction codes, there is still not negligible uncertainty in their results. This uncertainty affects on the turbine structural design and power production prediction. With the growing size of wind turbine, reducing this uncertainty is becoming one of critical issues for high performance and efficient wind turbine design. In this respect, there are international efforts to evaluate and tune prediction codes of wind turbine. As the reference data for this purpose, field test data is not appropriate because of its uncontrollable wind characteristics and its inherent uncertainty. Wind tunnel can provide controllable wind. For this reason, NREL has done the full scale test of the 10m turbine at NASA-Ames. With this reference data, a blind comparison has been done with participation of 18 organizations with 19 modeling tools. The results were not favorable. In Europe, a similar project is going on. Nine organizations from five countries are participating in the MEXICO project to do full scale wind tunnel tests and calculation with prediction codes. In this study. these two projects were reviewed in respect of wind tunnel test and its contribution. As a conclusion, it is suggested that scale model wind tunnel tests can be a complementary tool to calculation codes which were evaluated worse than expected.
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본 연구의 목적은 차세대 대체에너지로 각광받는 풍력발전 중에서 육상발전보다 여러 가지 이점이 있는 해상에서의 한국형 풍력터빈 블레이드의 최적 형상을 위 한 알고리즘을 구현하는 것이다. 풍력터빈 블레이드에서 깃익형의 공기 역학적 특성은 매우 중요한 사항이다. 이를 위해서 익형 성능예측에 층류에서 난류로의 천이과정을 포함하는 XFOIL을 이용하여 블레이드 익형 단면의 양력과 항력 분포를 해석하였다. 첫 번째 수준의 설계변수는 운용범위내의 바람의 속도와 블레이드 지름, 축 회전수이며, 각 단면에서의 비틀림각과 시위길이는 두 번째 수준의 설계 변수이다. 운용범위 내의 각 설계점에서 익형의 공력 변수들과 최소에 너지손실 조건을 이용하여 시위길이와 피치각 분포를 최적화하였다. 각각의 설계점에서 결과를 바탕으로 풍력발전의 설계 운용범위에서 반응면을 구성하고 구배최적화 기법을 통해 요구동력의 제약함수를 만족하고 효율을 최대로 하는 블레이드 형상을 구현하였다. 최적형상에 대해 탈설계점 해석을 수행하여 그 성능을 구하였다.
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Generator efficiency optimization is important for economic saving and environmental pollution reduction. In general, the machine loss can be reduced by the decreasing the flux level, resulting in the significant reduction of the core loss. This paper proposesan model-based controller is used to decrement the excitation current component on the basis of measured stator current and machine parameters and the q-axis current component controls the generator torque, by which the speed of the induction generator iscontrolled according to the variation of the wind speed in order to produce the maximum output power. The generator reference speed is adjusted according to the optimum tip-speed ratio. The generated power flows into the utility grid through the back-to-back PWM converter. The grid-side converter controls the dc link voltage and the line-side power factor by the q-axis and the d-axis current control, respectively. Experimental results are shown to verify the validity of the proposed scheme.
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풍력발전기에 있어서 보호 및 제어 시스템은 그 효율, 성능, 안전 및 수명까지도 영향을 미칠 수 있는 중요한 구성요소이다 따라서 제어 시스템은 풍력발전기의 최대 효율 및 가동률을 확보하여야 하며 풍력발전기에 문제가 발생할 경우 즉시 가동을 정지할 수 있도록 안전성을 확보할 수 있도록 설계되어야 한다. 본 연구에서는 "750kw급 Gearless형 풍력발전시스템 개발" 과제의 일환으로 수행되었던 풍력발전기용 제어시스템의 설계 및 제작 과정과 상용제품으로서의 본 제어 시스템을 소개하고자 한다.
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Son, Yoon-Gyu;Suh, Jae-Hak;Kwon, Sei-Jin;Jang-Seung-Duck;Oh, Jong-Seok;Hwang-Jin-Su;Kang, Sin-Il;Park, Ga-Woo;Kwon, O-Jung;Chung-Chin-Hwa;Han-Kyung-Seop;Chun-Chung-Hwan 59
The 800-kW PM (permanent magnet) synchronous generator is developed as a wind power generator. The matching converter is designed to control the torque and power depending on the wind speed regime. The generator starts to generate the power at the speed of 9 rpm and the rated output is generated at the speed of 25 rpm. The rated output power of an inverter is 750 kW when the PM synchronous generator is delivering 800 kW to the inverter. The inverter is specially designed to perform the maximum power point tracking (MPPT) at the low wind speed regime that is typical wind environment in Korea. The inverter test was done with a 2 MW M-G system at KERI (Korea Electric Research Institute). The M-G set has a 2 MW motor driver and a 38:1 gear to match the speed between the motor and the PM generator. The torque simulating the wind is applied to the PM generator by a DC motor. The test results show the inverter efficiency of$94.3\%$ at the rated power generating condition. The measured values show that the MPPT algorithm is working well. Overall reliability will be verified through the long-term site test. -
A vibration monitoring system for a small size wind turbine (WIT) is established and operated. The monitoring system consists of monolithic integrated chip accelerometer for vibration monitoring, anemometers for wind data acquisition and auxiliary sensors for atmospheric data. Using the monitoring system, vibration response of a 6kW stand alone WIT generator is investigated. Acceleration data of the WIT tower under various operation condition is acquired in real time using LabVIEW and the data are remotely transferred from the test site to the laboratory in school by internet. Vibration response characteristics of the tower structure are diagnosed in the aspect of stability of W/T. Wind data and electrical power performance are also investigated with the stability problem.
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In the case of wind turbine design, Optimization of tower structure is very important because tower generally takes about
$20\%$ of overall turbine cost. In this paper, we calculated wind loads considering vortex shedding, and optimized tower flange using the calculation results. For optimization, we used FEM to analyze structural strength of the flange and blade momentum theory to calculate wind loads. -
Recently, as the global warming by fossil fuels become social issues. the interest of renewable energy producing system is increasing rapidly. Among these, wind turbines are most highlighted because of its economic competitiveness. The tower occupying about
$20\%$ of overall turbine costs, is one of the main components of wind turbine. Tower access door located to base part of the tower, is used to enter the tower. This is the main structural weak point because of door hole, weldment, etc. In this study, by FEM, we retrieved the maximum van Mises stress at door location and carried out fatigue analysis using stresses at weld toe locations of tower access door part. -
Lee H. G.;Kim D. E.;Suh H. S.;Han H. S.;Jung Y. G.;Lee W. W.;Park K. H.;Chung C. W.;Lim M. S.;Oh M. S. 76
포항풍력에너지연구소와 (주)보국전기는 에너지 관리공단의 지원으로 2002년부터 직접구동형 풍력터빈( KBP-750D) 에 사용될 발전기 개발을 시작하여 2005년 3월 개발을 완료하였다. KBP-750D에 사용되는 발전기는 증속을 위한 gearbox를 사용하지 않는 직접 구동형이고, 영구자석을 사용하여 여자하는 형식이다. 이런 특징은 풍력발전에서 요구하는 주요 요구조건인 고 효율, 고 신뢰성을 만족시키기 위해서 매우 중요하다. 개발된 발전기는 25 rpm 에서 800 kW의 정격을 가지도록 설계되었다. 공극 직경은 3,320mm 이며, stator의 길이는 705mm, 공극은 4.5mm 이고, 극수는 84이다. 또한 전체 중량은 약 22 ton이다. 이 논문에서는 발전기의 물리설계, 공학설계, 제작 및 시험결과에 관해서 기술한다. -
Kang Yongcheol;Lee Byungeun;Kim Eunsuk;Hwang Taekeun;Lee Jihoon;Cha Sunhee;Park Jongmin;Jung Taeyoung 80
Distributed generation (IX;) plays an important role in the power system nowadays. Over-current relay, widely used in the DG protection, causes a wide outage section and long time delay. This paper proposes a DG protection technique to minimize the outage section. The proposed method uses three directional over-current relays with delay, which are connected to the point of common coupling. The method can minimize the outage section. -
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A rear contact solar cell has a potential merit of efficiency improvement by a low shading loss in front surface. a simplified module assembly. and a higher packing density. Among the rear contact solar cells. MWT. metallizationl wrap through MWT solar cells that have the bus bars on the back side and the front side metallization is connected to the back through metal filled laser fired holes in the silicon wafer. This approach has the advantages of a much more uniform appearance. The first fabrication of MWT using a multicrystalline silicon modules in our group showed
$12.28\%$ on$125mm{\times}125mm$ active area. -
For the fabrication of poly-crystalline silicon ingot, CCCC (Cold Crucible Continuous Casting) method under a high frequency alternating magnetic field, was utilized in order to prevent crucible consumption and ingot contamination and to increase production rate. In order to effectively and continuously melt and cast silicon, which has a high radiation heat loss due to the high melting temperature and a low induction heating efficiency due to a low electric conductivity, Joule and pinch effects were optimized. Throughout the present investigation, poly-crystalline Si ingot was successfully produced at the casting speed of above 1.5 mm/min under a non-contact condition.
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변환 효율이
$16\%$ 에 근접하는 다결정 실리콘 태양전지를 위한 열처리 공정에 대한 연구를 수행하였다. 고속 열처리 공정이 가능한 RTP 를 사용하여 다결정 실리콘 태양전지의 효율 향상에 요구되는 PECVD$SiN_x$ 반사방지막을 이용한 결정 결함의 수소화 효과를 극대화하는 동시에 양산 가능한 screen-printed contacts 의 특성 (FF >0.76) 올 최적화함으로써 다결정 실리콘 태양전지의 변환 효율을$15.9\%$ 까지 향상시킬 수 있었다. -
We have developed highly stabilized (p-i-n)-type protocrystalline silicon (pc-Si:H) multilayer solar cells. To achieve a high conversion efficiency, we applied a double-layer p-type amorphous silicon-carbon alloy
$(p-a-Si_{1-x}C_x:H)$ structure to the pc-Si:H multilayer solar cells. The less pronounced initial short wavelength quantum efficiency variation as a function of bias voltage proves that the double$(p-a-Si_{1-x}C_x:H)$ layer structure successfully reduces recombination at the p/i interface. It was found that a natural hydrogen treatment involving an etch of the defective undiluted p-a-SiC:H window layer before the hydrogen-diluted p-a-SiC:H buffer layer deposition and an improvement of the order in the window layer. Thus, we achieved a highly stabilized efficiency of$9.0\%$ without any back reflector. -
Cu계
$I-III-VI_2$ 화합물은 직접천이형 반도체로 광흡수계수가 매우 높아 박막형 태양전지 제조에 매우 유리하다 또한 화학적으로 안정하며 Ga, A1등을 첨가하면 에너지 금지대폭을 조절할 수 있어 Wide Bandgap 태양전지 및 탠덤구조 태양전지를 제조하기에도 용이하다.$CuInSe_2(CIS)$ 물질에서 In을$20-30\%$ 정도 치환한$Cu(In,\;Ga)Se_2(CIGS)$ 태양전지의 경우$19.5\%$ 의 세계 최고 효율을 보고하고 있으며 이는 다결정 실리콘 태양전지의 효율과 비슷한 수준이다. 본 연구에서는 동시 진공증발법을 이용하여 증착한 CIGS 박막 및$CuGaSe_2(CGS)$ 박막을 이용하여 태양전지를 제조하였다. 공정의 재현성 및 결정립계가 큰 광흡수층 제조를 위하여 실시간 기판 온도 모니터링 시스템을 도입하였으며 버퍼층으로는 용액성장한 CdS 박막을 사용하였다. SLG/MO/CIGS(CGS)/CdS/ZnO/Al구조의 태양전지를 제조하여 면적$0.5cm^2$ 에서 각각$15\%$ (CIGS)와$7\%(CGS)$ 의 효율을 얻었다. -
Lee, Jeong-Chul;Lim, Chung-Hyun;Ahn, Sae-Jin;Yun, Jae-Ho;Kim, Seok-Ki;Kim, Dong-Seop;Yang, Sumi;Kang, Hee-Bok;Lee, Bo-young;Yi, Junsij;Son, Jinsoo;Yoon, Kyung-Hoon 113
In this paper, silicon thin-film solar cells(Si- TFSC) and a-Si/c-Si heterojunction solar cells(HJ-cell) are investigated. The Si-TFSC was prepared on glass substrate by depositing$1-3{\mu}m$ thin-film silicons by glow discharge method. The$a-Si:H/{\mu}c-Si:H$ tandem solar cells on textured ZnO:A1 TCO (transparent conducting oxide) showed improved Jsc in top and bottom cells than that on$SnO_2:F$ TCO. This enhancement of jsc resulted from improved light trapping effect by front textured ZnO:A1. The a-Si/c-Si HJ-cells with simple structure without high efficiency features are suffering from low Voc and Jsc. The improvement of front nip and back interface properties by adopting high quality silicon-films at low temperature should be done both for increasing device performances and production cost. -
This paper proposes an inverter for the grid-connected photovoltaic system based on the transformer-less inverter. This system consists of a high frequency converter bridge, high frequency transformer, diode bridge rectifiers, a DC filter, a low frequency inverter bridge, and an AC filter. The high frequency converter bridge switching at 20kHz is used to generate bipolar PWM pulse, and the high frequency transformer raise its voltage twice, which is subsequently rectified by diode bridge rectifiers to result in a full-wave rectified sine wave. Finally, it is unfolded by a low frequency inverter bridge to result in a 60Hz sine wave power output. Even though the high frequency link system needs more power semiconductors, a reduced size, light weight, and saved parts cost make this system more comparative than the other systems due to elimination of 60Hz transformer.
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Recently, because of the depletion of fossil fuels and the environmental pollution by using fossil fuels and harmfulness of atomic power plants. the interests concerning new and renewable energy resources are rising increasingly. And of all new and renewable energy sources the PV generation systems are recognized as the most useful and desirable renewable energy source in allowance for installation conditions. In this development, the 3kWp photovoltaic power generation system is realized to verify the performance of the 3kWp PCS developed by Hyundai Heavy Industries Co. (HHI). The photovoltaic array used in this system is composed of 60 modules of 50Wp capacity. The developed system is tested as procedures and items of test regulation recognized by governmen and the experimental results show the excellent electrical characteristics. Now, the 3kWp PCS developed is installed in the PV model house built in HHI plant and is being tested for practical use commercialization.
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The paper addresses modeling and analysis of a grid-connected photovoltaic generation system (PV system). PSCAD/EMIDC. an industry standard simulation tool for studying the transient behavior of electric power system and apparatus. is used to conduct all aspects of model implementation and to carry out extensive simulation study. An equivalent circuit model of a solar cell has been used for modeling solar array. A PWM voltage source inverter (VSI) and its current control scheme have been implemented. A maximum power point tracking (MPPT) technique is employed for drawing the maximum available energy from the PV array. Comprehensive simulation results are presented to examine PV array behaviors and PV system control performance in response to irradiation changes. In addition, dynamic responses of PV array and system to network fault conditions are simulated and analysed
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A modular photovoltaic PCS with high-frequency isolation is proposed. The proposed system consists of a SEPIC converter and a full-bridge inverter. Using the power slope versus voltage of the PV array, the MPPT controller is proposed that produces a smooth transition to the maximum power point. The disturbance of the line voltage is detected using a fast sensing technique. Experimental results obtained on a 500W prototype show high performance such as almost unity power factor,
$90\%$ power efficiency,$3.6\%$ THD. -
The application of photovoltaics into building as integrated building components has been paid more attention worldwide. Photovoltaics or solar electric modules are solid state devices, directly converting solar radiation into electricity; the process does not require fuel and any moving parts, and produce no pollutants. So, the purpose of this research is to present how to get PVIB which can be applied building facade and how to apply it. From the basis of these results this study will intend to develop an integrated for optimal design of PV System.
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Standards are increasing of importance for photovoltaics. The rapid growth of production is one reason for this but standards are equally important in ensuring the quality and reliability of installed PV systems. which have a propound impact on acceptance of the technology in the expanding marketplace. Korea government (Korean Agency for Technology and Standards. KATS)make and implement a five year plans for promotion of international standardization of this field from 2004. Through these works and harmonization of PV Korea standards with international standards(international electrotechnical commission. IEC). KATS leads the technology innovations and eventually increases the international Competitiveness. Strategic collaboration with other countries is also strengthened through Korea's participation in IECEE(IEC system for conformity and certification of electrical equipment) on standards and conformity assessment. One of the major goals of the Plan is to facilitate trade between Korea and its trading partners by emphasizing harmonization of its national conformity assessment system with international norms
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Synthesis of
$TiO_2$ nanoparticle paste is one of the important technologies in dye-sensitized solar cells (DSSC). Performances of the DSSCs from synthesized$TiO_2$ nanoparticle paste was similar or better than those from commercial sources. In addition. cell efficiency was further improved by using large scattering$TiO_2$ particles. Those results was utilized in manufacturing high efficiency DSSC modules. -
반도체성 고분자인 poly(3-hexylthiophene) (P3HT)과
$C_{60}$ 유도체인 PCBM의 복합재를 이용하여 유기태양전지를 제작하였다. 열처리 온도론 중심으로 다양한 제조조건 하에서의 태양전지 특성을 조사하였다. 열처리 온도를 높임에 따라, P3HT/PCBM 복합재 박막은 뚜렷한 색변화와 함께 가시광 영역에서의 광흡수가 증가됨이 관찰되었고, 소자 성능도 크게 향상되었다. 결과적으로, 본 P3HT/PCBM bulk 이종접합형 구조의 유기 태양전지는 최적화된 제조 조건에서$2.8\%$ 의 에너지 전환 효율을 나타내었다($100mW/cm^2$ , 백색광). -
Low RF power density was used for preparing transparent conducting AI-doped ZnO (AZO) thin films by RF Magnetron Sputtering on Corning 1737 glass. The dependence of films' structural, optical and electrical properties on sputtering gas, film's thickness and substrate temperature were investigated. Low percent of incorporated H2 in Ar sputtering gas has proven to reduce film's resistivity and sheet resistance as low as
$4.1\times10^{-3}{\Omega}.cm$ . It also formed new preferred peaks orientation of (101) and (100) which indicated that the c-axis of AZO films was parallel to the substrate. From UN-VIS-NIR Spectrophotometer analysis, it further showed high optical transmittance at about$\~ 90\%$ at visible light spectra (400-700nm). -
This paper proposes a simple MPPT control scheme of a Current-Control-Loop Error system Based that can be obtains a lot of advantage to compare with another digital control method, P&O and IncCond algorithm, that is applied mostly a PV system. An existent method is needed an expensive processor such as DSP that calculated to change the measure power of a using current and voltage sensor at the once. Therefore, it is applied a small home power generation system that required many expenses. But, a proposed method is easy to solve the cost reduction and power unbalance problems that it is used by control scheme to limit error of a current control of common sensor. This proposed algorithm had verified through a simulation and an experiment on battery charger using PIC that is the microprocessor of a low price.
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Diethnao lamine(DEA)을 함유한 수용액을 ultrasonic irradiation에 의하여 CdSe 반도체 양자점을 제조하였고 제조된 양자점의 광학적 성질을 조사하였다. CdSe 양자점 제조시 카드뮴을 제공하는 물질로는
$CdCl_2{\cdot}2.5H_2O$ 를, 셀레늄을 제공하는 물질로는 Se powders를$Na_2SO_3$ 수용액에서$90^{\circ}C$ , 1시간 reflux 한$Na_2SeSO_3$ 를 사용하였다. 상온에서 고출력의 초음파 조사 (20kHz,$60Wcm^{-2}$ )에 의한 CdSe반도체 양자점을 얻기 위하여 초음파 시간을 각각 변화시켰고 XRD, UV-Vis, PL, TEM, XPS론 사용하여 CdSe 나노 입자의 특성을 분석하였다. CdSe흡수스펙트럼을 분석한 결과 450-640nm범위에서 양자점 형성에 의한 엑시톤 흡수 봉우리가 관찰되었음을 확인할 수 있었다. 또한 초음파 조사시간을 5분, 15분, 30분으로 증가시킴에 따라 505nm, 525nm, 545nm로서 엑시톤의 흡수 파장이 장파장 쪽으로 이동함을 확인함으로써 초음파 조사시간에 따라 CdSe 양자점의 크기를 변화시킬 수 있음을 알 수 있었다. -
Thickness optimization of heavily doped p-type seeding layer was studied to improve performance of thin film silicon solar cell. We used liquid phase epitaxy (LPE) to grow active layer of
$25{\MU}m$ thickness on p+ seeding layer. The cells with p+ seeding layer of$10{\mu}m\;to\;50{\mu}m$ thickness were fabricated. The highest efficiency of a cell is$12.95\%$ , with Voc=633mV,$Jsc=26.5mA/cm^2,\;FF=77.15\%$ . The$P^+$ seeding layer of the cell is$20{\mu}m$ , thick. As thicker seeding layer than$20{\mu}m$ , the performance of the cell was degraded. The results demonstrate that the part of the recombination current is due to the heavily doped seeding layer. Thickness of heavily doped p-type seeding layer was optimized to$20{\mu}m$ . The performance of solar cell is expected to improve with the incorporation of light trapping as texturing and AR coating. -
Phase Lacked Loop(PLL)은 분산전원을 계통연계시 동기설정을 위해 중요한 장비이다. 이러한 동기설정은 Point of Common Coupling(PCC)에서 계통 전압을 검출하여 크기와 위상을 동일하게 설정하여 전력변환장치에서 전력을 출력한다. 일반적으로 PCC에서 계통전압을 검출하였을 때 고조파, 상간불평형은 전력변환장치 출력 왜곡을 야기 시킨다. 본 논문에서는 이러한 출력왜곡을 감소시키기 위한 3상 PLL을 모델링하여, 그 제어 성능을 시뮬레이션을 통해 확인하였다.
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본 연구에서는 염료 감응형 태양전지의 효율 향상을 위한 유리 기판 및 전극 패턴에 따른 특성 변화와 대면적화 모듈을 위한 금속 그리드의 특성을 보여준다. 단위 셀 단위의 기본적인 재료와 기존의 제조 방법에 의해 제조된 염료 감응형 태양전지(DSC)는 높은 내부 저항으로 인하여 대면적 셀의 변환 효율은 치명적으로 저하된다. 또한 증가하는 내부 저항 감소를 위해서 외부적인 제조 공정이 추가되지 않고서는 불가능하다. 따라서 본 논문에서는 TCO(ITO) 식각,
$TiO_2$ 식각,$50mm{\times}50mm$ 셀과$100mm{\times}30mm$ 셀의 특성 비교 실험을 통해서 변환 효율 상승효과를 얻었고 광전류 포집 향상을 기대하기 위해 Pt 그리드를 이용해 current correcting line을 증착시켰다. -
Operating conditions of photovoltaic power generator is very sensitive to the PV modules. The PV module's control is an importance issue in the removing DC ripple noise. In this paper, the phase-shifted-carrier technique, which is a new three-step dc-dc power multi-converter schemes, is applied to solar generator system to improve the output current waveform. The novel type of three-step dc-dc converter presented has many features such as the good output waveform, high efficiency, low switching losses, low acoustic noise. The circuit configuration is constructed by the conventional full-bridge type converter circuit using the isolated DC power supply for which the solar cell is very suitable. In the end, a circuit design for understanding three-step dc-dc converter and new solar power system were presented
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나노 입자 분무 기법을 이용한
$Cu(In,\;Ga)Se_2$ (CIGS) 광흡수층 제조 기법은 고진공 장치를 사용하지 않는다는 점에서 대면적 저가형 CIGS 태양전지 양산에 적합한 차세대 기술로 인식되고 있다. 그러나 일반적으로 스프레이 된 상태의 CIGS충 자체는 태양전지 제조에 적합하지 않은데 이는 스프레이 막의 다공성 구조 때문이다. 본 연구에서는 나노입자 분무 기법을 이용하여 증착한 CIGS 광흡수층막을 질소 또는 셀레늄 분위기에서 열처리함으로써 태양전지 제조에 적합한 치밀한 구조의 CIGS 광흡수충을 제조하고자 하였다. 실험 결과, 질소 분위기$500^{\circ}C$ 의 온도에서 1시간 열처리하여도 CIGS 나노 입자의 성장은 거의 일어나지 않는 것으로 나타났다. 반면 셀레늄 분위기$500^{\circ}C$ 의 온도에서 30분 열처리시 입자 크기가$1{\mu}m$ 이상인 치밀한 광흡수층을 얻을 수 있었다. 본 결과는 CIGS 나노 입자의 입자 성장 반응에서 열에너지 단독에 의한 표면 에너지 감소 효과는 미미하며 셀레늄 증기의 역할이 더욱 크다는 것을 의미하는 것이다. -
태양전지 분야에서 최근 크게 주목받고 있는 염료감응형 태양전지(DSC)의 효율 및 대면적화에 대한 연구는 지속적으로 이루어지고 있다. 그러나 염료감응형 태양전지의 대면적화로 인한 셀 내부의 전자 흐름에 관한 셀 특성의 고찰은 이루어지고 있지 않다. 따라서 본 연구에서는 염료감응형 태양전지의 대면적화에 앞서 염료감응형 태양전지의 대면적화에 따른 셀 특성을 알아보았다. 본 실험에서는 대면적화의 하나의 변수로서 셀의 가로 폭을 선택하였고, 가로 폭의 변화에 따른 각 샘플 셀의 전기특성을 확인하였다. 그 결과 셀의 폭이 증가할수록 표면저항이 커져 염료에서 발생된 광전자가 표면저항으로 인해 포집이 잘 이루어지지 않게 되어 전자의 흐름이 원활하지 않게 됨을 알 수 있었다. 궁극적으로 셀의 대면적화는 표면저항의 증가로 이어져 셀 특성에 나쁜 영향을 미치게 됨을 확인 할 수 있었다.
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Jeon Sang Won;Lee Jeong Chul;Ahn Sae Jin;Yun Jae Ho;Kim Seok Ki;Park Byung Ok;Song Jinsoo;Yoon Kyung Hoon 192
The silicon thin film solar cells were fabricated by 13.56 MHz PECVD (Plasma-Enhanced Chemical-Vapor Deposition) and 60 MHz VHF PECVD (Very High-Frequency Plasma-Enhanced Chemical-Vapor Deposition). We focus on textured ZnO:Al films prepared by RF sputtering and post deposition wet chemical etching and studied the surface morphology and optical properties. These films were optimized the light scattering properties of the textured ZnO:Al after wet chemical etching. Finally, the textured ZnO:Al films were successfully applied as substrates for silicon thin films solar cells. The efficiency of tandem solar cells with$0.25 cm^2$ area was$11.8\%$ under$100mW/cm^2$ light intensity. The electrical properties of tandem solar cells were measured with solar simulator (AM 1.5,$100 mW/cm^2)$ and spectral response measurements. -
Lim, Chung-Hyun;Lee, Jeong-Chul;Jeon, Sang-Won;Kim, Sang-Kyun;Kim, Seok-Ki;Kim, Dong-Seop;Yang-Sumi;Kang-Hee-Bok;Lee, Bo-young;Song-Jinsoo;Yoon-Kyung-Hoon 196
In this work, we investigated simple Aㅣ/TCO/a-Si:H(n)/c-Si(p)/Al hetero-junction solar cells prepared by low temperature processes, unlike conventional thermal diffused c-Si solar cells. a-Si:H/c-Si hetero-junction solar cells are processed by low temperature deposition of n-type hydrogenated amorphous silicon (a-Si:H) films by plasma-enhanced chemical vapor deposition on textured and flat p-type silicon substrate. A detailed investigation was carried out to acquire optimization and compatibility of amorphous layer, TCO (ZnO:Al) layer depositions by changing the plasma process parameters. As front TCO and back contact, ZnO:Al and AI were deposited by rf magnetron sputtering and e-beam evaporation, respectively. The photovoltaic conversion efficiency under AMI.5 and the quantum efficiency on$1cm^2$ sample have been reported. An efficiency of$12.5\%$ is achieved on hetero-structure solar cells based on p-type crystalline silicon. -
In this research, we have studied the development of dc-dc converter suitable for the driving of mobile instruments by using a dye-sensitized solar cell(DSC). We also have designed a interlocking circuit. The circuit makes power from DSC be saved in one battery and concurrently be discharged in the other battery. As this application, mobile devices like MP3, cellular phone are drived by using power from DSC during the daytime and they can be drived by using the saving energy of the daytime during the night. Besides, we designed dc-dc converter circuit to drive low power instruments by using NMOS switch and PMOS rectifier.
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Kim Sang-Kyun;Lee Jeong Chul;Jeon Sang Won;Lim Chung Hyun;Ahn Sae Jin;Yun Jae Ho;Kim Seok Ki;Song Jinsoo;Park S-J;Yoon Kyung Hoon 205
최근 열선 화학 기상 증착법(HWCVD)은 낮은 온도에서 TFT용 Poly Si 중착을 할 수 있다는 점과 실리콘 박막을 빠른 속도로 증착할 수 있다는 점에서 각광을 받고 있다. 본 연구에서는 HWCVD를 이용하여 태양전지를 제조하고 그 특성을 평가하였다. 조건에 따른 실리콘 박막의 특성 변화를 알기 위해 corning glass 및 실리콘 wafer에 다양한 조건에서 단위 박막(intrinsic layer)을 증착하였고 이 결과를 바탕으로 p/i/n 구조의 태양전지를 제조하였다. Ta 열선 온도는 1700-2000도였고 가스 원료인$SiH_4$ 와 수소의 비율을 조절하면서 그 영향을 관찰하였다. 태양전지의 경우 p충과 n충은 PECVD로 증착하였으며 단위박막 및 태양전지 i충 증착시 기판과 열선간의 거리는 7cm, 기판 온도는$200^{\circ}C$ 와$250^{\circ}C$ 로 고정하였고 작업압력은 30mTorr였다. 단위 박막 특성 평가를 위해 암/광 전도도, SEM, Raman Scattering, FT-IR등을 사용하였으며 태양전지 특성 평가를 위해 I-V 및 Spectral response를 측정하였다. 열선 온도가 증가함에 따라 증착속도 및 결정화 분율은 증가하였다. 특히 비정질에서 결정질로 전이되는 구간은 매우 좁았으며 여러 분석 방법에서 일치되는 결과를 보였다.$SiH_4$ 유량이 늘어날수록 비정질이 결정질로 바뀌는 열선 온도가 증가하였으며 기판 온도가 낮을 경우 또한 결정으로 바뀌는 열선 온도가 증가하였다. 태양전지의 경우 열선 온도가 증가함에 따라$V_{oc}$ 및 W가 낮아졌으며$J_{sc}$ , 는 증가하는 경향을 보였으며 결정질 비율이 증가하는 것을 관찰할 수 있었다. 이러한 경향은 quantum efficiency 결과에서도 확인할 수 있었다.용을 반복하면서 석재 내부와 외부의 암석 및 결정에 균열과 미세열극 등이 생성되어 석재 자체의 구조적 안정성에 영향을 주고 있다. 따라서 감은사지 석탑은 지리적 환경 차이로 인해 일반적인 환경의 석조물들과는 다른 형태의 풍화양상을 보이고 있어서 풍화양상 및 풍화형태에 대한 정확한 연구와 이해를 바탕으로 보존대책이 마련되어야 한다.되었다. 이런 모든 시편들을 각 탈염방법에 따라 탈염처리한 후 XRD와 SEM-EDS으로 분석한 결과 인철광과 침철광은 어떠한 변화도 보이지 않았고, 다만 적금광으로 동정된 시편만이 잔존하지 않았다. 철기 제작별$Cl^-$ 이온 추출량과 탈염효과에 대한 비교 실험은 이온 크로마토그래피 분석 결과와 마찬가지로 단조 철제유물이 주조 철제보다$Cl^-$ 이온을 많이 가지고 있었으며, 탈염 처리 후에는$Cl^-$ 이온은 전혀 발견되지 않았다. 이상의 결과$K_2CO_3$ 와 Sodium 용액은 탈염처리에서 가장 적합한 탈염처리 용액으로 알수가 있었으며 특히 어떠한 탈염 용액으로 유물을 처리한다 해도 철제유물에 생성된 부식물은 제거되지 않는다는 것을 알게 되었다. 따라서 보존처리자는 유물 표면의 부식 상태만을 보고 처리하기 보다는 철기제작물로 고려하여 처리하는 것이 필요하다. 또한 금속에 부식을 야기시키는$Cl^-$ 이온과 부식물을 완전하게 제거하여 탈염처리를 하는 것이 유물 부식을 최대한 지연시킬 수 있는 것이라 생각된다.TEX>$88\%$)였다.(P=0.063). 결론: 본 연구에서는 MTHFR C/T & T/T 유전자 다형성이 위암의 발생과 그 위치에 대해 관련이 있는 것으로 여겨지고, 흡연력, 음주력과는 관련이 없는 것으로 여겨진다.험이 커지는 경향을 보였으나, 나이 및 병기, 종양의 크기, MD-BED$Gy_{10}$ 등의 예후 인자를 보정한 다변 -
태양광 주택 보급을 위해서는 기존에 고가의 실리콘 기판을 이용한 고효율 달성을 위한 연구중심의 태양전지 개발연구가 주축을 이루어왔다. 이는 개발에 성공하더라도 고가, 고난도, 복잡한 다단계 공정기술을 이용하는 단점 때문에 보급활성화를 촉진하기 위해서는 저가의 다결정 실리콘 기판을 이용한 중 상급 태양전지 상용화 기술개발로 전환할 필요로 인하여 본 연구에서는 차세대전력용 태양광발전시스템의 요소소자인 다결정태양전지 고효율화의 열쇠가 되는 기술력 확보를 통한 저가, 대면적, 고효율, 고수율 제품 대량생산 상용화에 중점을 두었다.
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For
$CO_2-free$ hydrogen production and better utilization of the produced carbon, catalytic decomposition of methane over rubber-grade carbon blacks manufactured from coal tar was carried out. The catalytic activities of several domestic carbon blacks were compared. A pelletized carbon black exhibited considerably lower activity and activation energy than the fluffy( loose) carbon black of the same grade. This difference is considered due to the binder that was added during pelletization. For pelletized carbon blacks, a tendency was observed that the activity per unit mass of catalyst increased with the specific surface area of the carbon black. Another tendency was also observed that the activation energy increased with the primary particle size or decrease of the specific surface area. -
There is a worldwide interest In the development and commercialization of PEMFCs for vehicular and stationary applications. The major problem in the practical use of PEMFCs is the deactivation of the Pt anode electrocatalyst by the adsorption of carbon monoxide. Therefore, intensive work has been devoted to finding electrocatalysts that are tolerant to CO in hydrogen at operating temperatures bellow
$100^{\circ}C$ . Also, DMFC is considered to be one of the most promising technologies for energy generation. But, the most important problem associated with the DMFC is the slow reaction rate of methanol oxidation and the second major problem is fuel crossover. So, the performance of a state-of-the-art DMFC is considerably lower than that of hydrogen-fuelled PEMFC. In this research, the preparation and characterization of electrode materials will be introduced. Also, some electrochemical techniques for the characterization of PEMFCs will be presented. -
수소 기반의 에너지 사회는 중소규모 분산 발전과 연료 전지 자동차에서 시작될 거라는 예측이 지배적이다. 가정용 고분자 연료전지 시스템은 상업화에 가장 가까운 소규모 분산 발전 시스템중의 하나이며, 에너지기술연구위원에서는 가정용 고분자 연료전지에 수소를 공급하기 위한 천연가스 수증기 개질시스템의 개발을 진행해 왔다. 효율 향상과 제작의 용이성, 그리고 소형화에 초점을 맞추어 개발된 prototype-I은
$2.0Nm^3/hr$ 의 순수 수소 생산 용량을 가지고 있으며, 수증기 개질기와 수성가스 전이 반응기 수중기 생성 장치, 그리고 반응열 공급에 필요한 버너 등을 이중 동심원관에 통합한 형태이다. 수중기 개질과 수성가스 전이 반응을 거쳐 나오는 개질 가스의 조성은$72.3\%\;H_2,\;4.8\%\;CH_4,\;0.7\%\;CO,\;22.2\%\;CO_2$ 이며, 이때 S/C 비율은 2.5였다. 고분자 연료 전지 공급 시 요구되는 CO 농도가 10ppm 이하이기 때문에, 본 시스템에는 선택적 산화 반응기를 2단으로 설치하여 CO. 농도를 10ppm 이하로 낮추어주었다. 전체 시스템의 열효율은 LHV 기준으로$68\%$ . Prototype-I의 운전을 통해 설계 개선안을 도출하였으며, 이를 적용해 제작한 prototype-II가 시험 운전 중이다,. 통합된 개질 시스템에서는 각 단위 반응기사이의 열교환을 최적화하여 단위 반응들이 적정 온도 범위에서 일어나도록 유도하는 것이 중요하다. Prototype-II는 수증기 개질 반응기와 WGS 반응기, 수증기 생성 장치 사이의 열교환율을 향상시켜 농도를$2.5\%$ 로 감소시키면서 CO의 농도는$1\%$ 이하로 유지하였다. 이 결과를 바탕으로 얻어진 메탄 전환율은$87\%$ 이고, 열효율은 LHV 기준으로$75\%$ 이다. 아울러 개선점을 적용한 선택적 산화 반응기를 제작하였다. 개질 가스와 산소의 혼합을 유도하고, 반응기 온도의 제어를 통해 선택적 산화 반응의 속도와 선택성을 향상시키고자 한다. 시스템의 운전을 통해 메탄 전환율과 열효율의 개선을 진행할 예정이다. -
Sulfonated poly(ether sulfone) copolymers (PESs) were synthesized using hydroquinone 2-potassium sulfonate (HPS) with other monomers (bisphenol A and 4-fluorophenyl sulfone). PESs with different
$mole\%$ of hydrophilic group were prepared by changing the mole ratio of HPS in the polymerization reaction. The chemical structure and the thermal stability of these polymers were characterized by using$^1H-NMR$ , FT-IR and TGA techniques. The PES 60 membrane, which has$60 mole\%$ of HPS unit in the polymer backbone, has a proton conductivity of 0.091 S/cm and good insolubility in boiling water. The TGA showed that PES 60 was stable up to$272^{\circ}C$ with a char yield of about$29\%\;at\;900^{\circ}C\;under\;N_2$ atmosphere. To investigate the single cell performance, the catalyst coated PES 60 membrane was used and a single cell test was carried out using$H_2/O_2$ gases as fuel and oxidant at various temperatures. We observed that the cell performance was enhanced by increasing the cell temperature. A current density of$1400 mA/cm^2$ at 0.60 V was obtained at$70^{\circ}C$ . -
고분자 전해질형 연료전지에서는 수소이온의 이온전도성 저하를 방지하기 위하여 외부에서 가습하여 주는 방식이 일반적이지만, 가습에 소요되는 부품을 일부라도 제거할 경우 연료전지의 효율은 높이고 제작단가도 경감할 수 있다. 이를 위하여 저가습 및 무가습 실험을 수행하였으며, 정확한 data의 수집과 시험장비의 자동제어를 위하여 National Instrument사의 compact field point (cFP)를 사용하였다. 무가습 실험 중 stack의 안정성 측면을 고려하기 위하여 수소연료가 부족하거나 갑작스런 voltage drop이 발생할 경우 LabVIEW logic에 의한 stack 보호용 자동차단 시스템을 구현하였다. Humidifier와 heater의 온도를 조절하여 공급유체의 상대습도 및 온도를 각각 조절하였으며, 이에 필요한 이론적 온도는 Antoine equation을 사용하여 산정하였다. Anode와 cathode 양측
$100\%$ 가습 경우를 기준으로 가습량을 조절하면서 실험을 수행하였으며 성능 차이를 그래프로 도시하여 양측의 변화에 대한 영향을 볼 수 있도록 하였다. Stack의 온도가$70^{\circ}C$ 이고 양측 무가습일 경우에 성능 측정이 불가능하여 stack의 온도를 저온에서부터 변화시키면서 무가습 성능을 실시간으로 측정하여 보았다 일반적으로 hydronium ion은 anode측에서 cathode측으로 계속 이동하여야 전기를 생성할 수 있으므로 cathode측 무가습이 anode측 무가습보다 성능이 더 잘 나오는 것으로 예측하였으나 이와 반대되는 경향의 실험 결과를 얻었다. Anode측 무가습과 cathode측 무가습의 standard deviation은 anode 무가습일 경우가 크게 발생하였고 양측 무가습일 경우는 stack의 온도가 높을수록 크게 관찰되었다. 이와 같은 현상은 공기중의 상대습도와 back diffusion등에 영향을 받을 수 있으므로 각종 변수들의 영향을 분리하여 관찰할 수 있는 실험을 수행중에 있다. -
This paper describes an on-going national R&D program for the development of a gas turbine/fuel cell hybrid power generation system and related R&D activities. The final goal of this program is to develop a 200kW-c1ass gas turbine/fuel cell hybrid power generation system and achieve high efficiency over
$60\%$ (AC/LHV). In the first phase of the development, a sub-scaled 60kW-class hybrid system based on the 50kW-class microturbine and the 5kW SOFC will be developed for the purpose of concept proof of the hybrid system. Core components such as the microturbine and the SOFC system are being developed and parallel preparation for system integration is being carried out. Before the core components are assembled in the final system. operating characteristics of a hybrid system are investigated from a simulated system where a turbocharger (microturbine simulator) and a modified fuel cell burner test facility (fuel cell simulator) are employed. The 60kW demonstration unit will be built up and operated to provide the valuable information for the preparation of the final full scale 200kW hybrid system. -
Graphite reinforced conductive polymer composites for PEMFC bipolar plates were fabricated by the compression molding technique. Graphite powder was mixed with an phenol resin to impart electrical property in composites. In this study, conductive polymer composites with high filler
$loadings(>60wt.\%)$ were manufactured to accomplish high electrical conductivity above 100S/cm. The level of compaction is important because graphite powder increase electrical conductivity of composites by direct physical contact between particles. The optimum molding pressure according to filler was proposed experimentally. Various tests(electrical conductivity, flexural strength, compressive strength, leach test, etc) were carried out to verify the performance of fabricated composites for PEMFC bipolar plates. Fabricated composites have good electrical conductivity and mechanical strength. The results of leach test and contact angle measurement showed similar characteristics compared with commercial bipolar plates. -
The effort to realize the concept of stratospheric airship, which can fly at about 20km altitude, has been persevered since late 1980's. Referring to the feasibility study of ensuring the flight duration of the airship over 1year, total weight is about 30 tons, the length is about 200m. There are lots of key technologies to be solved to develop the system, and one of the essential prerequisite technologies is regenerative fuel cell system. In this paper, design requirement of regenerative fuel cell system is introduced with the feasibility study results of the challenging stratospheric airship.
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본 연구에서는 기존 니켈 활성성분만의 알루미나담지 촉매에 비해 고온에서의 수소를 사용한 환원 전처리 과정을 거치지 않고도 높은 반응활성을 나타내며, 반응 중 탄소침적에 대한 촉매 저항성에서도 우수한 결과를 나타낸 루테늄-니켈 촉매에 대해보고 하고자 한다. 메탄 수증기 개질 반응을 통해, 루테늄을 최종적으로 담지한 알루미나 담지니켈계 촉매는 별도의 전처리과정 없이
$650^{\circ}C$ 에서부터 높은 반응성을 보였으며, 루테늄과 니켈을 동시에 담지한 경우보다 더 우수한 활성을 나타내었다. Ru의 담지량을 달리한 실험에서는$RU(0.5)/Ni(20)/Al_2O_3$ 촉매가 가장 높은 활성을 보였다.$H_2-TPR$ 분석 결과,$Ru(0.5)/Ni(20)/A1_2O_3$ 촉매의 경우 세 가지 환원 피크가 나타났으며,$Ni(20)/A1_2O_3$ 촉매와 비교해 볼 때, 저온(<$130^{\circ}C)$ 에서 환원가능한$RUO_2$ 의 존재를 확인할 수 있었다. 담지된 RU은 분산도가 높아, XRD분석 결과에서 Ru이나$RuO_2$ 의 특성 피크가 존재하지 않았다. 또한$650^{\circ}C$ 에서 10시간 개질반응 후 얻어진 촉매에 대해$O_2-TGA$ 를 분석한 결과,$Ni(20)/Al_2O_3$ 촉매는$-7.2wt\%$ 정도의 큰 무게 감소를 보였으며, 이는 촉매 표면에 생성된 carbon tube에 의한 것임을 SEM 분석을 통해 알 수 있었다 이에 반해,$Ru(0.5)/Ni(20)/Al_2O_$ 촉매는$O_2-TGA$ 시$0.3wt\%$ 정도 무게 증가에 그쳤으며, SEM 분석상 carbon tube의 생성이 크게 억제되었음을 알 수 있었다. -
NUMERICAL STUDY ON THE FLOW CHARACTERISTICS OF MANIFOLD FEED-STREAM IN POLYMER ELECTROLYTE FUEL CELLThe effects of internal manifold designs the reactant feed-stream in Polymer Electrolyte Fuel Cells (PEFCs) is studied to figure out mass flow-distribution patterns over an entire fuel cell stack domain. Reactants flows are modeled either laminar or turbulent depending on regions and the open channels in the bipolar plates are simulated by porous media where permeability should be pre-determined for computational analysis. In this work, numerical models for reactant feed-stream in the PEFC manifolds are classified into two major flow patterns: Z-shape and U-shape. Several types of manifold geometries are analyzed to find the optimal manifold configurations. The effect of heat generation in PEFC on the flow distribution is also investigated applying a simplified heat transfer model in the stack level (i.e. multi-cell electrochemical power-generation unit). This modeling technique is well suited for many large scale problems and this scheme can be used not only to account for the manifold flow pattern but also to obtain information on the optimal design and operation of a PEMC system.
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수소의 소규모 분산 생산 기술은 본격적 인 수소 인프라가 도입되기 전에 연료전지 자동차의 수소 충 전용이나 분산 발전형 연료전지의 수소 공급을 위해 필요하다. 생산 용량은 수소 기준으로
$10\~100 Nm^3/hr$ 정도로 현재로선 천연가스의 수증기 개질법이 가장 경제적인 공정으로 알려져 있다. 소규모 생산에 따른 열효율 저하를 줄이 기 위해 단위 공정들이 통합된 컴팩트 개질 시스템의 개발이 필요하다. 핵심 기술인 컴팩트 리포머의 국산화 기술 확보를 위하여$20 Nm^3/hr$ 용량의 동심관형 리포머를 설계, 제작하였다. 내부구조는 제작의 단순화를 고려하여 중첩된 동심관이 배열되었고 압력 손실과 열웅력 발생을 억제하도록 유로를 배치하였다. 수증기개질 반응에 필요한 반응열은 리포머 본체에 부착된 버너를 이용하여 공급하였다. 성능 측정을 위한 부속 기기로 상온 흡착식 탈황기, 폐열 회수형 수증기 발생기, 반응물 예열을 위한 열교환기, 생성 가스 응축기를 설계 제작하여 전체 리포밍 시스템을 구성하였다. 반응 온도$680\~720^{\circ}C$ , 탄소 대 수중기 비(S/C ratio)$2.7\~3.2$ 조건에서 수증기 개질 반응을 수행하였다. 해당 반응 조건에서 메탄 전환율$89\%$ 이상, 저위 발열량 기준 개질 열효율$70\%$ 이상을 달성하였고 개질 생성가스 내 수소의 최대 유량은$23.4Nm^3/h$ 였다. 개발된 리포밍 시스템은 고순도 수소 생산이 필요한 경우, 수소 수율 향상을 위한 고온 수성 가스 전화 반응기를 통합 가능하도록 열교환기 구성을 조정할 수 있으며 용융 탄산염 연료전지와 같이 고온형 연료전지의 경우$550^{\circ}C$ 이상으로 개질 생성 가스를 공급하도록 구성할 수도 있다. 향후 리포머 본체의 개질 효율 향상 및 장치 소형화, 부속 기기의 최적화를 통한 전체 리포밍 시스템 개선, 스케일 업 설계를 위한 엔지니어링 설계 패키지 구성을 계획하고 있다. -
현재 국내 수소 관련 연구는 생산, 운반, 저장 등 공급과정의 기술과 발전, 수송 등 이용기술을 중심으로 이루어지고 있다. 본 연구에서는 현재 개발 중인 MCFC 발전설비에 대한 기술 및 비용 특성을 이용하여 LEAP모형시스템 기반의 ROK2003-H2 모형을 구축하고 정부의 '제2차 신재생에너지 기술개발 및 이용보급 기본계획
$(2003\~2012)$ '의 계획에 따른 수소에너지(연료전지) 보급의 에너지/환경부문 파급효과를 분석한다. 분석 대상이 되는 기술은 Molten Carbonate 연료전지를 이용한 2MW급 발전기술로, 2008년 70MW가 설치되기 시작하여 2011년까지 매년 100MW증설되어 2011년 전체 설비가 370MW에 이르는 것으로 시나리오를 구축한다. 설비의 에너지효율성은 연료전지 발전설비가 처음 도입된 2008년에는$45\%$ 로 가정하고 2009년-2011년 간에$5\%$ 씩 상승되어 2011년에는$60\%$ 에 이를 것으로 전망한다. 분석결과에 의하면 2011년에 연료전지의 발전설비를 370MW로 확대하는 경우에 CO를 비롯한 대부분의 대기오염배출량이 감소하며, 온실가스 배출량 역시 35,433백만tC로 약 295백만tC가 감소한다. -
Performance analysis of a solid oxide fuel cell/micro gas turbine hybrid system is conducted at design-point and part-load conditions and its results are discussed in this study. With detailed considerations of the heat and mass transfer phenomena along various flow streams of the SOFC, the analysis based on a quasi-2D model reasonably predicts its performance at the design-point operating conditions. In case of part-load operations, performance of the hybrid system to three different operation modes(fuel only control, speed control, and VIGV control) is compared. It is found that the simultaneous control of both supplied fuel and air to the system with a variable MGT rotational speed mode is the optimum choice for the high performance operation. And then, the dynamic characteristics of a solid oxide fuel cell are briefly introduced.
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SOHN Young-Jun;PARK Gu-Gon;UM Sukkee;YIM Sung-Dae;Yang Tae-Hyun;YOON Young-Gi;LEE Won-Yong;KIM Chang-Soo 277
Air-breathing polymer electrolyte membrane fuel cells (PEMFC) are highly promising particularly for small-power applications up to tens watts class. A distinctive feature of the air-breathing PEMFC is its simple system configuration in which axial fans operate for dual purposes, supplying both oxidant and coolant in a single manner. In the present study, a nominal SOW air-breathing PEMFC system is developed and investigated to determine the optimal operating strategy through parametric studies (i.e., reactant humidity, and fan-blowing flow rate). The cell voltage distributions are examined as a function of time to evaluate the system performance under various operating conditions. -
Park Gu-Gon;Lim Nam-Yun;Sohn Young-Jun;Park Jin-Soo;Lee Won-Yong;Kim Sae-Hoon;Lim Tae-Won;Kim Chang-Soo 281
Water management in polymer electrolyte membrane fuel cells(PEMFCs) is one of the most challenging issues. Freeze start-up in the automotive applications is also important research topic in the PEMFC field. Transportation of proton and separation of reactant gases are main roles of polymer electrolyte membranes. It has been known that water in the membrane conducts as a vehicle for the proton transportation. At sub-zero temperature, the frozen water blocks the access of reactant gases to the active sites of electrode as well as occurs the physical destruction of fuel cell structures. In this study, property changes of electrolyte membranes in the freeze conditions$(at\;-25^{\circ}C)$ were investigated. For the various amount of water contained membranes, the property changes, especially for the proton conductivity, were observed after several times of freeze/thaw$(-25\~80^{\circ}C)$ cycle. -
A fluidized bed reactor made of quartz with 0.055 m I.D. and 1.0 m in height was employed for the thermocatalytic decomposition of methane to produce
$CO_2 - free$ hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. The methane decomposition rate with the carbon black N330 catalyst was quickly reached a quasi-steady state rate and remained for several hour. The methane decomposition reaction was carried out at the temperature range of$850-925^{\circ}C$ , methane gas velocity of$1.0U_{mf}\;3.0U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature, gas velocity on the reaction rates was investigated. The produced carbon by the methane decomposition was deposited on the surfaces of carbon catalysts and the morphology was observed by SEM image. -
고분자전해질 연료전지는 자동차, 분산전원 및 이동전원 등에 대한 차세대 에너지원으로 채택 가능성이 높아지고 있다. 고분자전해질 연료전지 시스템의 상용화를 위한 가장 큰 걸림돌 중 한 가지로 가격문제를 들 수 있는데, 연료전지 스택이 전체 가격의 약
$50\%$ 를 차지하고 있다. 또한 스택을 구성하는 요소 중 분리판의 가격 비중은 약$30\%$ 를 차지하고 있어, 분리판의 생산단가 저감은 연료전지의 상용화를 위해 반드시 해결해야 될 문제이다. 본 연구에서는 탄소를 재료로 하는 분리판에 대한 연구를 수행하였으며, 압축성형방식으로 제작된 다양한 복합재료 분리판 및 흑연 분리판에 대한 기계적 강도, 물리적 특성, 화학적 안정성을 조사하였으며, 가흑 운전 시 분리판내에 함유되어있는 고분자 성분의 침출에 의한 연료전지의 성능변화가 발생하는지 확인하였으며 이에 대한 단위전지의 성능평가를 수행하였다. 이러한 결과를 토대로 최적의 압축성형 복합체 분리판 제작 방향을 제시하고, 보다 신뢰성 있는 분리판 성능평가 기준을 확립하고자 하였다. -
The PEMFC behavior is quite complex and is influenced by several factors, including composition and structure of electrodes and membrane type. Fabrication of MFA is important factor for proton exchange membrane fuel cell. MFA of PEMFC with hot pressing and direct coating method were prepared, and performances were evaluated and compared each other. The effect of MEA preparation methods, hot pressing methods and direct coating methods, on the cell performance was analyzed by impedance spectroscopy and SEM. The performance of PEMFC wi th direct coat ing method was better than wi th hot pressing method because membrane internal resistance and membrane-:-interfacial resistance were reduced by elimination of hot pressing process in MEA fabrication. In addition the micro structure of MEA with direct coating method reveals uniform interface between membrane and catalyst layer.
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Hydrogen generation by the hydrolysis of aqueous sodium borohydride
$(NaBH_4)$ solutions was studied using IRA-400 anion resin dispersed Pt. Ru catalysts and Lithium Cobalt oxide$(LiCoO_2)$ supported Pt, Ru and PtRu catalysts. The performance of the$LiCoO_2$ supported catalysts is better than the ion exchange resin dispersed catalysts. There is a marked concentration dependence on the performance of the$LiCoO_2$ supported catalysts and the hydrogen generation rate goes down if the borohydride concentration is increased beyond$10\%$ . The efficiency of PtRu-$LiCoO_2$ is almost double that of either Ru-$LiCoO_2$ or Pt-$LiCoO_2$ for$NaBH_4$ concentrations up to$10\%$ . -
Direct Borohydride Fuel Cell은 알칼리 붕소 수소화물의 수용액을 이용하는 연료전지로 연료의 직접 산화반응을 통해 기존의 DMFC(직접 메탄을 연료전지)보다 높은 전류밀도와 OUV(Open Circuit Voltage)를 나타낸다. 또한 액체 연료를 사용하므로 장치 구성이 간단하며, 사용하는 연료가 반응성이 높은 알칼리 붕소 수소화물로 이루어져 있기 때문에 탄화수소 계열의 액체 연료와 달리 전기화학 반응이 비귀금속 전극에서도 쉽게 이루어질 수 있다는 장점을 가지고 있다 하지만 강알칼리 조건에서 전기화학 반응이 진행되므로 이에 적합한 재료로 장치를 구성해야 하며, 액체 상태의 연료가 전해질을 투과하는 현상인 크로스오버 문제를 해결해야 하고, 생성물인
$BO_2$ -가 침적되어 전지효율을 떨어뜨리는 것을 방지해야 하는 문제점이 있다. 또한 알칼리 붕소 수소화물이 물과 반응하여 수소를 발생시키는 hydrolysis 반응을 억제하여야 하고 직접 산화반응만이 진행될 수 있도록 전지를 구성해야 연료효율을 높일 수 있다. 따라서 본 연구에서는 수소 생성반응일 hydrolysis 반응은 억제하고 연료의 직접 산화반응만을 진행시키기 위한 전극촉매에 대하여 연구하였다. 일반적인 저온형 연료전지의 전극촉매로 사용하는 Pt등의 귀금속 촉매와, 귀금속 촉매를 대체할 수 있는 Ni등의 비귀금속 촉매를 그 연구 대상으로 하였으며, 평가 방법으로는 unit cell station을 이용한 단위전지 성능측정 실험과 Potentiostat/Galvanostat을 이용한 half cell 실험을 병행하여 수행하였다. -
Lee Sang-Heon;Yim Sung-Dae;Park Gu-Gon;Yu Sang-Phil;Yoon Young-Gi;Kim Chang-Soo;Park Seung-Bin 303
현재 인류가 직면하고 있는 에너지 및 환경 문제를 해결할 수 있는 최선의 대안으로서 수소 에너지 및 연료전지 기술에 대한 연구가 활발히 진행 중이다. 본 연구에서는 디메틸 에테르를 이용한 수소 생산 기술에 대한 연구를 수행하였다 디메틸 에테르(BATE)는 안정한 화합물로서 비 활성적이고 부식성이 없으며 발암성 및 마취성이 얼어 인체에 무해한 청청 연료로서 각광을 받고 있으며 특히 기존의 LPG 인프라를 그대로 사용할 수 있는 장점 등으로 수소 스테이션 및 소형 연료전지용 수소 발생기 등에의 적용을 위한 연구가 활발히 진행 중이다. 본 연구에서는 이러한 응용을 위한 수소 발생기용 DME 개질 반응기의 개발을 위하여 본 반응에 대한 촉매 종류의 영향, 공간속도의 최적화, 반응 메카니즘에 따른 촉매 선정, 반응온도 등의 다양한 반웅 조건에 대한 영향을 확인하고 실제 소형 연료전지를 위한 수소공급 장치로서 적용코자 마이크로채널 반응기에 적용하여 마이크로채널 DME 개질반응기의 컴팩트한 수소공급 장치로서의 적용 가능성을 평가하였다. -
Park Byung-Tak;Yoon Sung Pil;Kim Hyun Jae;Nam Suk Woo;Han Jonghee;Lim Tae-Hoon;Hong Seong-Ahn;Lee Dokyol 306
One of the most critical issues in sol id oxide fuel cell (SOFC)running on hydrocarbon fuels is the risk of carbon formation from the fuel gas. The simple method to reduce the risk of carbon formation from the reactions is to add steam to the fuel stream, leading to the carbon gasification react ion. However, the addition of steam to fuel is not appropriate for the auxiliary power unit (APU) and potable power generation (PPG) systems due to an increase of complexity and bulkiness. In this regard, many researchers have focused on so-called 'direct methane' operation of SOFC, which works with dry methane without coking. However, coking can be suppressed only by the operation with a high current density, which may be a drawback especially for the APU and PPG systems. The single chamber fuel cell (SC-SOFC) is a novel simplification of the conventional SOFC into which a premixed fuel/air mixture is introduced. It relies on the selectivity of the anode and cathode catalysts to generate a chemical potential gradient across the cell. Moreover it allows compact and seal-free stack design. In this study, we fabricated honeycomb type mixed-gas fuel cell (MGFC) which has advantages of stacking to the axial direction and increasing volume power density. Honeycomb-structured SOFC with four channels was prepared by dry pressing method. Two alternative channels were coated with electrolyte and cathode slurry in order to make cathodic reaction sites. We will discuss that the anode supported honeycomb type cell running on mixed gas condition. -
Lee Dong Hyun;Shin Moon Kwon;Kim Eun Mi;Son Seong Yong;Park Byung Sub;Han Gui Young;Yoon Ki June 310
The conical fluidizing system of a binary mixture of Geldart C powders and Geldart A particles was defined as the conical powder-particle fluidized bed. We used a cold conical powder-particle fluidized bed model having a 0.104m-I.D. and 0.6m-high with an apex angle of$10^{\circ}$ for fluidization of a binary powder-particle mixture of 50$vol\%$ fine carbon black powders (HI-900L, Korea Carbon Black Co.) and coarse alumina particles$(90{\mu}m)$ under different superficial gas velocities (0-0.1 m/s). The differential bed pressure drop increases with increasing gas velocity, and it goes from zero to a maximum value with increasing or decreasing gas velocity. In the conical fluidized beds of fine powders, demarcation velocities of the partial fluidization, full fluidization, partial defluidization was not observed. -
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Bipolar plate is the main part with MEA in automotive PEMFC. It must have a good electrical conductivity and excellent corrosion resistance, be cost effective. Therefore, stainless steels have been studied by many researchers because of its corrosion resistance and cost benefits. But their properties are not sufficient for the application to bipolar plate for automotive PEMFC. In this work, we have performed stamping using various commercial stainless steels to select candidate material for biploar plate and to derive design parameters for stamping simulation. The results showed that a small curvature at the corner of flow field is more favorable due to easier a plastic deformation. Stamping process was simulated by changing surface condition, and the size and angle of channel. The optimum shape and spring back phenomena were evaluated. Surface coating was applied to increase the corrosion resistance and electrical conductivity of stainless steel. The electrical interfacial resistance was 10 to
$15m{\Omega}cm^2$ under clamping force of 150psi. But corrosion resistance of coating on the stainless steel was not good due to the unstableness of microstructure. -
Proton exchange membrane (PEM) should be sufficiently hydrated with proper water management to maintain a good ionic conductivity and performance of a PEM fuel cell. However. cathode flooding resulting from excess water can impede the transport of reactants and hence deteriorate the fuel cell performance. For the PEM fuel cell to be commercially viable as vehicle or portable applications, the flooding on the cathode side should be minimized during the fuel cell operation. In this study, visualization technique was applied to understand the cathode flooding phenomena on the cathode side of a PEM fuel cell. To this end. a transparent PEM unit fuel cell wi th an act ive area of
$25cm^2$ was designed and manufactured to allow for the visualization of cathode channel with performance characteristics. Two-phase flow resulting from the electro-chemical reaction of fuel cell was investigated experimentally. The images photographed by CCD camera with cell operating temperatures$(30\~50^{\circ}C)$ were presented. Results indicated that the flooding on the cathode side first occurs near the exit of cathode channel. As the operating temperature of fuel cell increases. it was found that liquid water droplets tend to evaporate easily and it can have an influence on lowering the flooding level. It is expected that this study can effectively contribute to the detailed researches on modeling water transport of an operating PEM fuel cell including two-phase flow phenomena. -
고분자 전해질막 연료전지는 운전시 정상적인 성능을 발현하기 이해서 전지 본체 조립 후 초기 활성화 운전이 필요하다. 이러한 활성화 운전을 통해 전해질 사이의 수소이온이동 통로, 반응가스가 반응할 수 있는 촉매까지의 이동 통로, 촉매층내의 전기적 연속성을 확보함으로 연료전지는 최적의 성능을 나타낼 수 있다. 본 연구를 통해 연료전지 활성화에 영향을 미치는 요인을 찾았고, 이를 통해 효과적이고 빠른 활성화 절차에 관한 연구를 수행하였다.
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Starting with the development of environmentally friendly electric controlled engine, sensors have played an increasing role in automotive technology. Electric power steering (EPS) systems are more and more replacing hydraulic systems. To improve fuel economy, the power assistance is provided by an electric drive. In this paper, development of a unique torque sensor for EPS is introduced. A capacitive type torque sensor is concluded to be suitable for EPS because its output is accurate, linear and robust against the variance of temperature, and patents have not applied so much.
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A PEMFC system model for FCEV was constructed and simulated numerically to examine the heat/water flow of the system and air/fuel humidification process for various operation conditions (ambient pressure /temperature/humidity, operating temperature, power load). We modeled PEMFC stack which can generate maximum electricity of about 80 kW. This stack consists of 400 unit cells and each unit cell has
$250cm^2$ reacting area. Uniform current density and uniform operating voltage per each cell was assumed. The results show the flow characteristics of heat and water at each component of PEMFC system in macro-scale. The capacity shortage of the radiator occurred when the ambient was hot$(over\;40^{\circ}C)$ and power level was high (over 50 kW). In spite of some heat release by evaporation of water in stack, heat unbalance reached to 20kW approximately in such a severe operating condition. This heat unbalance could be recovered by auxiliary radiators or high speed cooling fan with additional cost. In cold environment, the capacity of radiator exceeded the net heat generation to be released, which may cause a problem to drop the operating temperature of stack. We dealt with this problem by regulating mass flow rate of coolant and radiator fan speed. Finally, water balance was not easily broken when we retrieved condensed and/or unused water. -
본 개발의 목적은 연료전지차량에 탑재되는 연료전지 시스템에 장착될 공기공급기를 개발하는 것이었다. 개발된 공기공급기의 형태는 공급해야 할 공기의 유량과 압력 범위, 소음 및 향후 양산성 등을 고려하여 원심형 블로어를 선택하였으며, 차량 부하에 따른 공기공급량을 제어하기 위한 제어기도 적용되었다. 또한 차량에 적용될 경우, 예상되는 가혹한 사용환경에서 안정적인 성능을 발휘하고, 내구성을 할 수 있도록 설계되었으며, 특히, 외기온도
$45^{\circ}C$ 에서도 충분한 방열성능을 갖도록 모터 및 모터 방열구조를 설계하였다. 이를 위하여 공급되는 공기로 직접 모터를 냉각하는 개념을 적용하였다. 개발된 터보블로어의 응답성을 포함한 성능평가를 수행하였으며, 설계점에서 600시간 연속운전을 통하여 기본 내구평가를 완료하였다. -
The energy management of an HEV using optimal control and global optimization is thought to be closest to the best operation of the system. However, there are some controversies on the ways of defining the optimization problems and constituting the optimal control simulators. Here, we presented a simulator which adopts the concept of equivalent fuel economy and leads the vehicle to run in a more efficient way. In order to realize the optimal operation of the HEV and check the validity of the control logics, we also developed a forward-facing simulator. The simulator was developed with the Cruise and MATLAB co-simulation interface. Especially, neural network controller was used for the hybrid control module in the simulator. With the simulator, the optimal operation could be converted into hybrid control rules and the validity of the operation was verified.
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We developed a dynamic model of PEM fuel cell system which can analyze its transient response to dynamic load current. System components such as compressor, air cooler, humidifier, and stack were modeled based on their dynamic equations and performance maps by using Matlab Simulink platform. Through this simulation model, dynamic characteristics of fuel cell system including oxygen excess rat io, stack voltage, and system efficiency were shown. In addition to that, we briefly analyzed the humidity effect on cathode pressure and system efficiency, expecting that this model can be further used to optimize fuel cell system parameters just like operating pressure and temperature, humidity and oxygen excess ratio.
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Hyundai Motor Company developed the second generation of fuel cell hybrid electric vehicle based on Tucson SUV in 2004. This vehicle has cold start capability below -10C and its driving performances including maximum speed and accelerating time are almost similar to conventional Tucson SUV's performances without any sacrifice in terms of cabin space. Especially. the cold start capability was realized by utilizing only internal power sources such as fuel cell power and high voltage lithium ion polymer battery. In this paper, we will briefly introduce specifications of Tucson FCEV and its driving performances based on field test and simulations.
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Since the fuel cell uses the hydrogen for its fuel. it has no emission and higher efficiency than an internal combustion engine. Also fuel cell is much quieter than engine generator and generates heat much less than engine generator. So it has advantage of Army's 'si lent watch' capability and the ability to operate undetected by the enemy. The fuel cell hybrid system combines a fuel cell power system with an ESS. The ESS (e.g., batteries or ultracapacitors) reduces the fuel cell's peak power and transient response requirements. It allows the fuel cell to operate more efficiently and recovery of vehicle energy during deceleration. The battery has high energy density, so it has the advantage regarding driving distance. However, it has a disadvantage considering dynamic characteristic because of low power density. One other hand. the ultracapacitor has higher power density, so it can handle sudden change or discharge of required power. Yet. it has lower energy density. so it will be bigger and heavier than the battery when it has the same energy. This paper proposes the power management strategy for multi-power source fuel cell hybrid system. which is applied with the merits of both battery and ultra capacitor by using both of them simultaneous.
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최근 환경 및 에너지 문제가 자동차 산업의 중요한 이슈로 인식되면서 하이브리드 자동차(Hybrid Electric Vehicle) 기술과 연료 전지 자동차(Fuel Cell Vehicle)등이 주목받고 있다. 특히 하이브리드 자동차는 요구되는 동력과 생성되는 동력의 차이 때문에 순시 동력 저장 장치 (peak power buffer)가 필요한데, 반복적인 충/방전 싸이클에서 용량의 감소 없이 높은 단위 질량당의 동력과 에너지를 가지며 부피, 효율, 수명 면에서도 우수한 플라이 휠 에너지 저장장치가 이러한 동력 저장 장치로 적합하다. 본 논문은 하이브리드 자동차를 위한 플라이 휠 에너지 저장 장치의 현 상태 (state of art)를 기술한다. 첫번째로, 플라이 휠 에너지 저장장치의 기원과 배경을 설명한다. 두 번째로 하이브리드 자동차를 위한 플라이 휠 에너지 저장 장치의 세부 사항을 요약하고, 플라이 휠 에너지 저장을 이용한 하이브리드 자동차의 예와 플라이 휠 에너지 저장장치의 설계 쟁점과 자동차에 적용시키기 위한 최근 기술적 진보를 논의한다. 마지막으로, 플라이 휠 에너지 저장장치의 파급 효과와 다른 적용 예를 소개한다.
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In this research, we presented the regenerative braking algorithms considering fuel economy and charging oftenness, and also analyzed these algorithms. The first algorithm was the regenerative braking algorithm for the ideal recovery of kinetic energy. The HEV using this algorithm had high fuel economy, on the other hand frequent charging was occurred. The second algorithm was the regenerative braking algorithm for reduction of the charging oftenness. Using this algorithm, the HEV had the low charging oftenness and small loss of fuel economy.
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Hyundai motor company has designed a above 50kW-class PEMFC stack for Fuelcell vehicle based on SUV. Hyundai increased the power density of the stack through the optimized flowfield of bipolar plate, manifold structure, and improvement of sealing, etc. Also, Gas to Gas humidifier was adopted in fuelcell system to reduce the system humidification load, it had been proven by short stack test. Components of stack, bilpolar plate, manifold, were analyzed through the computer simulation, so temperature and pressure distribution in the components and system were improved. This stack tested in Bread Board which was organized similar to real vehicle system.
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This experimental study presents the results of the cooling performance test of a
$CO_2$ heat pump system for fuel cell vehicles. The experimental facility provides the cool ing and heating environment for cabin and heat releasing component. The test loop is designed to target the cooling capacity of 5kW and its coefficient of performance (COP) of 2.2. The cooling performance of the heat pump system is strongly dependent on the refrigerant charge and the degree of superheat. We carried out basic experiments to obtain optimum refrigerant charge and the degree of superheat level at the internal heat exchanger outlet. The heat pump system for fuel cell vehicles is different from that of engine-driven vehicles, where the former has an electricity-driven compressor and the latter has the belt-driven (engine-driven) compressor. In the fuel cell vehicle, the compressor speed is an independent operating parameter and it is controlled to meet the cooling/heating loads. Experiments were carried out at cooling mode with respect to the compressor speed and the incoming outdoor air speed. The results obtained in this study can provide the fundamental cool ing performance data using the$CO_2$ heat pump system for fuel cell vehicles. -
Fuel cell has been well known as a clean alternative power for vehicles. Recently, an experimental technique has been developed measurement of species and distributions by using gas chromatograph. In this study, cathode channel oxygen distributions as various conditions were investigated using gas chromatograph and cell visualization. And discussed relation between flooding and oxygen concentrations. As a result of experiment, oxygen consumpt ion is affected wi th flooding. Flooding is observed in channel near hydrogen inlet, and oxygen consumption is low at that region.
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In this paper, Cell voltage monitoring method is studied for fault detection of PEMFC(Proton Exchange Membrane Fuel Cell) for FCEV(fuel cell electric vehicle). To measuring several hundred of cells in fuel cell stack, The demanded feature of hardware and software is studied and several types are analysed. Finally,
$3.26\%$ maximum measuring error is acquired and verified experimentally. -
Photovoltaic (PV) module can generate electricity using sunlight without causing any environmental degradation. Due to higher fossil fuel prices and environmental awareness, PV applications are becoming more popular as clean source of electricity generation. PV output is sensitive to the operating temperature and can be drastically affected in Building Integrated PV (BIPV) systems. PV Solarwall (SWPV) combination and PV systems have been evaluated in this study for improvement in electrical output and system costs. PV modules under forced ventilation. A 75W polycrystalline silicon PV module was fixed on SW in front of the ventilation fan as it was indicated to be the coolest position on the SW in phoenix simulations. The effectiveness of cooling by means of the forced ventilating air stream has been studied experimentally. The results indicate that there appears to be significant difference in temperature as well as electricity output comparing the SWPV and BIPV options. Electrical output power recovered is about
$4\%$ during the typical day of the month of February. RETScreen(R) analysis of a 3kW PV system hypothetically located at Taegu has shown that with typical temperature reduction of$15^{{\circ}C$ , it is possible to reduce the simple payback periods by one year. The work described in this paper may be viewed as an appraisal of a SWPV system based on its improved electrical and financial performances due to its ability to operate at relatively lower temperatures. -
Objective of the research is to demonstrate solar thermal space and ground heating system which is integrated to a greenhouse culture facility for reducing heating cost, increasing the value of product by environment control, and developing advanced culture technology by deploying solar thermal system. Field test for the demonstration was carried out in horticulture complex in Jeju Island. Medium scale solar hot water system was installed in a ground heating culture facility. Reliability and economic aspect of the system which was operated complementary with thermal storage and solar hot water generation were analyzed by investigating collector efficiency, operation performance, and control features. Short term day test on element performance and Long term test of the whole system were carried out. Optimum operating condition and its characteristics were closely investigated by changing the control condition based on the temperature difference which is the most important operating parameter. For establishing more reliable and optimal design data regarding system scale and operation condition, continuous operation and monitoring on the system need to be further carried out. However, it is expected that, in high-insolation areas where large-scale ground storage is adaptable, solar system demonstrated in the research could be economically competitive and promisingly disseminate over various application areas.
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Solar fuel production technology using high-temperature solar furnace was briefly reviewed in this paper. 'Hydrogen' which is known to be the most promising energy carrier in the near future is to be generated environment-friendly from non-carbon resources. Combination of solar furnace operated by concentrated solar energy and high-temperature thermal reactions could be one of the most efficient ways to fulfill this need eventually. Various reaction mechanisms are feasible within a wide spectrum of solar fuel production technology, but intensive research efforts in related key areas need to be taken for successful development and commercialization of the technology.
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Solar thermal power generation is one of promising and well-proven ways to convert solar energy to electricity. Though it requires high initial cost for system construction and continuous efforts for maintainment. it is more positive in terms of efficiency than other solar power generation technologies. Moreover, solar thermal power generation allows additional benefits of cheap thermal storage and easy hybridization with other fossil fuel-driven power generation. Owing to these benefits, large scale solar thermal power generation technology is expected to be competitive to other commercial technologies in the near future. In this paper an overview on the solar thermal hybrid power generation technology and the state of the art in Korea were briefly introduced.
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Most of solar system dissemination has been focused on domestic hot water system of which utilization to a building is relatively simple and safe than solar heating system. Through the survey on a cause of solar house dissemination failure in Korea, we conclude that design integration and systematic approach method for technology application are the most important element for a successful solar house. KIER(Korea Institute of Energy Research) and Hanbat National University have started new project on a development of Zero energy Solar House, called ZeSH which can be sustained just by natural energy without the support of existing fossil fuel. This is the 1st phase research of 10 years long-term ZeSH plan which develops a low-cost and
$100\%$ self sufficient ZeSH. The goal of 1st phase ZeSH research is to get a$70\%$ self sufficiency only in thermal loads. Actual demonstration house, named KIER ZeSH I was designed and constructed as a result of 1st phase research work in the end of 2002. Various innovative technologies such as super insulation, high performance window, passive and active solar systems, ventilation heat recovery system are applied and evaluated to the KIER ZeSH I. A lot of computer simulations had been conducted for the optimal design and system integration in every design steps. Considering all the results from detailed hourly computer simulation, it is expected that at least$70\%$ self-sufficiency in thermal loads which is 1st phase target value can be excessively achieved in actual demonstration house. Besides, many valuable findings from the design and analysis to construction could be established such as collaboration method among the participants, practical design and construction techniques for system integration and the others. The purpose of this paper is to introduce the main findings through the development of KIER ZeSH I project. Practical guidelines in every design step for new low- or zero- energy solar house is proposed as result. -
This experimental study represents the results of an analysis on the characteristics of flux density distribution in the focal region of solar concentrator. The characteristics of flux density distributions are investigated to optimally design and position a cavity receiver. This was deemed very useful to find and correct various errors associated with a dish concentrator. We estimated the flux density distribution on the target placed along with focal lengths from the dish vertex to experimentally determine the focal length. It is observed that the actual focal point exists when the focal length is 2.17m. The total integrated power and percent power was 2467W and
$85.8\%$ , respectively, in the case of small dish, and also 2095W and$79\%$ , respectively, in the case of KIERDISH II. As a result of the percent power within radius, approximately$90\%$ of the incident radiation is intercepted by about 0.06 m radius. The minimum radius of receiver in KIERDISH II is found to be 0.15m and approximately$90\%$ of the incident radiation is intercepted by receiver aperture. -
This study treats the advantage of in situ line source method measuring the heat transfer capacity of a borehole, using mobile equipment, to determine the thermal properties of the entire borehole system such as thermal conductivity, diffusiveity. volumetric heat capacity, and borehole thermal resistance. The results from the response test include not only the thermal properties of the ground and the borehole, but also conditions that are difficult to estimate, e,g. natural convection in the boreholes, asymmetry in the construction, etc. In this study, 1) theoretical in situ methods for assessing working fluid temperature variation in V-type PE tube have been introduced, and 2) TRTE(Thermal Response Test Equipment) has been built based on these kinds of theoretical in situ methods. Basically TRTE consists of a pump, a heater and temperature sensors for measuring the inlet and outlet temperatures of the borehole. In order to make equipment easily transportable it is set up on a small trailer. Since the response test takes above two days to execute, the test was fully automatic in recording measured data using Labview DAS(Data acquisition system) program. The test was demonstrated in the course of intensive research in this field through the one site at Ulsan city in Korea. From this kind of thermal properties test of borehole systems in situ, the design of the borehole system can be optimized regarding the total geological, hydro-geological and technical conditions at the location.
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This study was carried out the design and analysis of solar thermal system with preheating of returning district heating water for the Chung-ju district heating and cooling system. Two different types of solar collectors are used for this system. TRNSYS simulation program was used for the analysis. As a results, the solar system efficiency is
$35.8\%$ for the plate type and$45.1\%$ for the evacuated type solar collector in the case of$50^{\circ}C$ for the returning district heating water temperature. The returning district heating water temperature is on of the very important factors that is influence on the system efficiency. So the effect of the returning district heating water temperature on the system efficiency is analyzed in this study. -
The Kaplan turbine model has been tested and analyzed. The blade angle and the guide vane opening of the turbine model were designed to be varied according to the best combination of guide vane and runner blade opening. When the changes in head and output were comparatively large, the efficiency drop were small, so the efficiency characteristics and stability of the entire operating condition were maintained in good condition. These results showed that the developed model in this study will be suitable for small hydro power stations with large changes in head and load.
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This paper presents the methodology to analyze flow duration characteristics and performance prediction for small hydro power(SHP) plants and its application. The flow duration curvecan be decided by using monthly rainfall data at the most of the SHP sites with no useful hydrological data. It was proved that the monthly rainfall data can be characterized by using the cumulative density function of Weibull distribution and Thiessen method were adopted to decide flow duration curve at SHP plants. And, the performance prediction has been studied and development. One SHP plant was selected and performance characteristics was analyzed by using the developed technique. Primary design specfications such as design flowrate, plant capacity, operational rate and annual electricity production for the SHP plant were estimated. It was found that the methodology developed in this study can be a useful tool to predict the performance of SHP plants and candidate sites in Korea.
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We have studied the prearranged plan and the economy of a candidate site for the development of small hydro power. And also we have confirmed its economy by suggesting the technology of the unmanned operation and the selection of the water turbine generator which has a great efficiency. working rate and suitability to the topographical characteristics of various development sites, for example, irrigation reservoirs, water works pipes, sewage systems and cool ing water of a steam power stat ion. Besides we give more examples of the select ion of Francis, propeller turbine and induction generator which can achieve a maximum of power production at a minimum construction cost. With a water turbine which runs at the low head we are able to suggest many programs to boost a development of small hydro power more economically.
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삼천포 보령 당진 등 국내 대형 기력발전단지에서 냉각수로 사용되고 방류되는 해수는 약 150cms로 (100Mwe당 약 5cms) 약 3,000kW 이상의 수력에너지를 보유하고 있으나, 현재 활용되지 못하고 그대로 해양으로 방류되고 있어 이 소수력에너지의 개발 방안을 검토하였다. 발전소 온배수의 원활한 배수를 위한 설계 낙차와 함께 남서해안의 조위변화에 따른 낙차를 이용하는 것으로 소수력 발전 방식과 조력 발전 방식의 특징을 동시에 활용하는 것이다. 국내의 기력발전소 가운데 삼천포, 보령, 하동화력발전소에 대하여 소수력에너지 개발방안을 검토하였으며, 배수로에 댐을 축조하여 방류수 전량을 발전에 이용하는 댐식, 배수로 중간에서 방류수 일부를 취수하는 수로식, 배수로의 빠른 유속을 이용하는 조류식 발전 방안을 중심으로 각 발전소의 구체적 적용여건에 따라 다양한 대안을 검토하여 기술적 가능성 및 경제성이 충분함을 입증하였다.
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As the distributed generation becomes more reliable and economically feasible, it is expected that a higher application of the distributed generation units would be interconnected to the existing grids. This new generation technology is linked to a large number of factors like economics and performance, safety and reliability, market regulations, environmental issues, or grid connection constrains. KEPOD (Korea Electric Power Corporation) is performing the project to develope the Distributed Micro Gas Turbine (MGT) technologies by using Swine BID-ENERGY. This paper describes the plans and strategies for the renewable energy of MGT on actual grid-connection under Korean situations. KEPOD also, has a research plan on bio-gas pretreatment system applicable to our domestic swine renewable resources and is performing concept design of pilot plant to test grid operation. In addition, this testing will be conducted in order to respond to a wide variety of needs for application and economic evaluation in the field of On-site generation.
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지구온난화 현상과 화석연료의 고갈에 대한 두려움 때문에 재생에너지에 대한 관심이 지속적으로 증가하고 있다. 이에 따라 대체에너지, 합성가스, 화학 원료, 오일 등으로 전환할 수 있는 바이오매스 활용에 대한 연구도 활발히 진행되고 있다. 바이오매스의 열화학적 전환 공정에는 열분해, 연소, 가스화 등이 이용되고 있다. 특히 열분해는 syringol, levoglucosan, guaiacol등의 고부가가치 물질들을 생산하기에 적합한 기술로 인정받고 있다. 본 연구에서는 국내에서 쉽게 구할 수 있는 톱밥, 폐목재 등의 바이오매스의 열화학적 전환 특성을 분석하였다. 사용된 바이오매스의 열분해 특성은 열중량 분석기 및 열천칭 반응기를 통해 분석하였으며 이를 통해 유동충 반응기(지름 0.2m, 높이 2m)를 설계 및 제작하였다. 반응온도 및 산소 농도가 증가할수록 levoglucosan 등의 고부가가치 물질들의 수율이 낮아지며 페놀류가 급격히 증가함을 알 수 있었다. 회재 성분이 높은 왕겨의 바이오오일 수율은 톱밥보다
$30\%$ 이상 낮게 나타났다 -
Genenrally, biogas contained methane contents of
$40-75\%$ , was made in anaerobic compost facilities, landfill site, etc. And it is very useful for gas engine as a fuel. So, many imported biogas engines for electrical generation, are installed and operating now at landfill sites and anaerobic compost facilites. And KIMM has studied on and developed biogas engines with the aids of engine maker and parts companies for several years. Some results are shown here. -
2004년말 현재 국내에서 발생되는 음식물쓰레기의 재활용량은 전체 발생량의
$87.7\%$ 인 10,015톤/일이며, 전체 재활용량의$6.47\%$ 인 640톤/일 정도가 혐기성소화 방법에 의해 처리 및 자원화 되고 있다. 국내에서 적용되고 있는 음식물쓰레기 혐기성소화 기술의 대부분은 습식소화(Wet digestion) 공법이며, 처리 방법별로 2상 혐기성소화(Two-phase anaerobic digestion)와 하수슬러지 흑은 축산분뇨와 함께 혼합처리 하는 통합소화(Co-digestion) 공정으로 구분되고 있다. 음식물쓰레기의 자원화 방법에 있어 혐기성소화는 사료화, 퇴비화에 비하여 폐기물의 효과적인 감량화와 자원화 효과뿐만 아니라 유용 에너지원인 메탄가스의 회수가 가능하기에 최근에 주목을 받는 biotechnology중의 하나로 자리매김 하고 있으며, 또한 유기성폐기물의 자원순환형 관리 시스템 구현에 있어 적절한 대안으로 고려되고 있다. -
Total forest growing stock and growing stock per ha in Korea are
$470\times10^6m^3\;and\;73m^3$ , respectively. Those figures mean that forest growing stock was increased 4.7 times more during last 30 years. The annual production of forest biomass comes from forest tending executed by Korea Forest Service was estimated about$1.07\times10^6m^3$ M/T, which was equivalent to$0.45\%$ of total imported crude oil of Korea at 2002. The production is expected to increase and reach up to$1.9\times10^6 M/T$ till 2008. The analysis of economic feasibility showed that the production cost of wood chip(134,786Won/T) was about 30,389 Won/T higher than heat value of wood chip, 104,397 Won/T estimated from that of kerosene. For the promotion of forest bioenergy utilization, more efforts need to be given for the education and public relations to induce publicity a willingness-to-pay for the environment friendly fuels under the good understanding for the use of bioenergy. In addition, we need to provide a community-based biomass utilization program by region to allocate the role of each participant and to increase the profitability of bioenergy. -
재생 가능한 자원인 동식물성 기름으로부터 만들어지는 수송용 연료 바이오디젤은 낮은 대기오염물질 배출과
$CO_2$ Neutral 특성으로 환경친화적인 연료로 인정올 받으며 전세계적으로 그 생산량이 급격히 증가하고 있다 한국에서는 년간 20만톤의 폐식용유가 배출되며 이중 약 10만톤이 회수 가능한 것으로 추산된다. 폐식용유의 무단 폐기로 인한 수질오염과 폐기물의 자원 재활용 및 에너지 생산 관점에서 폐식용유를 바이오디젤 원료로 사용하는 연구가 많이 진행되었다. 높은 함량의 유리지방산을 함유한 폐식용유를 효율적으로 전이에스테르화(methanolysis) 하기 위해서는 먼저 산 촉매를 이용한 유리지방산의 전환 제거가 필요하다 본 연구에서는 다양한 종류의 강산성 이온교환 수지를 폐식용유의 전처리(pre-esterification)용 고체 산 촉매로 회분식 반응기에서 테스트하였으며 그 결과 Amberlyst-15가 유리지방산의 에스테르화 반응에 가장 적합한 것으로 나타났다. 회분식 반응기에서 도출된 최적 전처리 반응조건을 적용한 200시간 이상의 연속 전처리 운전결과 폐식용유에 함유된$5\%$ 의 유리지방산이$90\%$ 이상 전환제거 되었다 전처리 반응 후의 폐식용유를 균질계 염기촉매(KOH) 존재하에 메탄올과 전이에스테르화 반응을 시킨 결과 바이오디젤로 불리는 지방산메틸에스테르(Fatty Acid Methyl Ester, FAME)의 생산 수율은$85\%$ 로 얻어졌으며 국내 바이오디젤 표준 규격에 따른 연료특성 분석 결과 FAME의 농도 규격을 제외한 모든 항목이 국내 규격을 만족하였다 폐식용유 바이오디젤의 FAME 농도가$94.3\%$ 로 국내 규격$96.5\%$ 에 미달하는 문제는 식물성 원료유로 제조한 고순도 바이오디젤과 혼합 사용하거나 감압 증류 공정을 통해 고농도의 폐식용유 바이오디젤을 제조하여 해결 가능하다. 대전시 신성동 소재의 음식점에서 수거한 폐식용유를 원료로 하여 생산한 바이오디젤의 차량 배출가스 실증 테스트 결과 경유 차량의 주 오염물질인 PM과 Soot 및 기타 오염물질의 배출량은 감소하였으나 NOx의 배출량은 약간 증가하는 것으로 나타났다 -
엄청난 자원의 매장고, 국가간의 대규모 교역을 가능케 한 항로, 어족자원의 공급원등으로서 인류의 생존과 번영에 일익을 담당하고 있는 바다는 인간의 증가하는 에너지 수요를 지속적으로 감당할 수 있는 무공해에너지의 보고로도 다가오고 있다. 그러나, 에너지 밀도가 타 에너지에 비하여 상대적으로 낮아 큰 규모의 에너지추출장치가 필요하다는 단점에도 불구하고, 대부분의 바다에서 하루에 두 번 씩 발생하는 조석현상을 이용하는 조력발전은 조석의 반복적이고 주기적인 특성 , 태양계가 존속하는 한 영구히 발생한다는 영속성, 현대과학과 관련기술의 진보 등으로 전 세계적으로 그 개발에 인류의 관심이 높아져 있다. 현재 조력발전소가 건설 중인 시화호는 포화상태에 있는 수도권에 공업용지를 공급하고 우량농지 조성으로 경쟁력 있는 농업을 육성하기 위하여 담수호로 조성되었으나,하수처리장 등 기초환경시설이 미비한 상태에서 인근지역으로부터 오염물질이 유입되어 수질이 악화되자 정부는 수질개선을 위하여 시화호를 해수호로 용도를 변경하였다. 본 논문에서는 조수간만의 차를 이용하여 무공해 전력을 생산하는 조력발전의 원리 및 최적발전량 산정기법과 높은 조수간만의 차로 조력개발적지로 유망한 서해안에 건설하게 될 시화호 조력발전소의 사업 및 기후변화협약 이행 시 기대효과 등에 대하여 논하고자 한다.
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삼천포 등 국내 대형 화력발전단지에서 냉각수로 사용되고 방류되는 해수는 약 150 cms로 (100 MWe당 약 5 cms) 약 3,000 kW 이상의 수력에너지를 보유하고 있으나, 현재 활용되지 못하고 그대로 해양으로 방류되고 있어 이 수력에너지의 개발을 추진하고 있다 온배수를 이용한 수력 개발시에는 기존 발전소의 배수로를 변경하여 이용하는 것으로 기존 발전소에 미치는 영향을 최소화하는 것이 중요하다. 본 검토에서는 삼천포화력에 댐식 수력발전소를 건설할 경우 기존 배수로의 수리특성 변화를 3차원 유동해석 프로그램인 FLOW-3D를 이용하여 해석한 결과를 소개하였다. 수치해석 결과를 이용하여 수력에너지의 최적 개발을 도모하였고, 다양한 운전조건을 설계에 반영할 수 있었다.
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2003년 11월과 2004년 4월의 2회에 걸쳐 상용조류발전소 건설 예정지인 울돌목에서 발전소 건설로 인해 야기될 주변생태환경의 변화를 파악하기 위해 4개 지점의 주변 암반조간대에 형성된 기존의 부착생물상 조사가 수행됐다. 울돌목 주변의 암반조간대에 형성된 부착생물상은 서식 형태에 따라 크게 대형해조류(Macroalgae)를 포함한 고착생물, 소 이동성 부착동물, 이동성 소형 무척추동물 등으로 구분된다 부착생물상은 서식양상에 있어 각각의 정점별 특이성이 관찰되었으며, 이는 각기 다른 비생물학적 요인에 따라 지역 특유의 서식환경이 조성되어 있음을 시사하는 간접적인 결과로 간주된다. 이같은 지역 간 생물상 차이는 조위에 따른 수직분포 분석결과 주로 중부조간대를 중심으로 형성된 생물상에 따라 대별되고 있음이 발견되었다.
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울돌목은 조류발전의 세계적인 최적지로 꼽히고 있으며 서해와 남해의 점이 지대로서 조류에 의해 해양 생물 군집의 대량 이동이 빈번한 곳이라 할 수 있다. 조류 발전 시설인 터빈의 가동은 물리적인 충격에 의해 해양 생물의 생태-생리 반응에 영향을 미칠 가능성이 있다. 네트를 이용한 1차 조사에서 터빈 가동에 의한 동물플랑크톤의 순 사망률은
$44.3\%$ 로 나타났다. 1차 조사 이 후 다이아프램 펌프를 이용한 조사 결과 중 출현 개체수가 높았던 조사에서 전체 동물플랑크톤의 순 사망률은 각각$7.3\%,\;5.8\%$ 를 나타내었고, 요각류는 각각$4.4\%,\;5.2\%$ 를 나타냈다. 물리적인 충격을 인위적으로 가한 실험에서 스트레스를 받은 요각류 Acartia hongi의 알 생산은 스트레스를 받지 않은 것보다$1.8\~2.3$ 배 낮은 경향을 보였다. 본 조사에서 동물플랑크톤이 낮은 사망률을 보골 이유는 작은 크기의 생물이 우점하였기 때문이며 조사 결과에서 몸체가 비교적 단단하고 크기가 작은 요각류는 상대적으로 약한 부유유생보다 높은 생존율을 보였다. 울돌목 조사 해역에서 출현한 동물플랑크톤은 크기가 작아 터빈의 물리적인 충격에 의한 사망률은 낮을 수 있으나 순간적으로 강한 스트레스를 받는다면 재생산을 포함한 생리활동이 저하될 수 있음을 보였다. 네트 및 펌프를 이용한 조사 결과에서 네트에 의한 채집은 터빈의 영향뿐만 아니라 빠른 유속으로 인하여 네트가 받는 압력에 의해 생물체가 손상되는 양상이 높아 사망률이 높았던 것으로 보인다. 그러나 다이아프램 펌프는 생물 채집 시 오류를 최소화하는 장점은 있으나 채집의 장시간에 비해 매우 적은 생물량이 채집되는 단점을 보였다TEX>$96.5\%$에 미달하는 문제는 식물성 원료유로 제조한 고순도 바이오디젤과 혼합 사용하거나 감압 증류 공정을 통해 고농도의 폐식용유 바이오디젤을 제조하여 해결 가능하다. 대전시 신성동 소재의 음식점에서 수거한 폐식용유를 원료로 하여 생산한 바이오디젤의 차량 배출가스 실증 테스트 결과 경유 차량의 주 오염물질인 PM과 Soot 및 기타 오염물질의 배출량은 감소하였으나 NOx의 배출량은 약간 증가하는 것으로 나타났다구와 이해를 바탕으로 보존대책이 마련되어야 한다.되었다. 이런 모든 시편들을 각 탈염방법에 따라 탈염처리한 후 XRD와 SEM-EDS으로 분석한 결과 인철광과 침철광은 어떠한 변화도 보이지 않았고, 다만 적금광으로 동정된 시편만이 잔존하지 않았다. 철기 제작별$Cl^-$ 이온 추출량과 탈염효과에 대한 비교 실험은 이온 크로마토그래피 분석 결과와 마찬가지로 단조 철제유물이 주조 철제보다$Cl^-$ 이온을 많이 가지고 있었으며, 탈염 처리 후에는$Cl^-$ 이온은 전혀 발견되지 않았다. 이상의 결과$K_2CO_3$ 와 Sodium 용액은 탈염처리에서 가장 적합한 탈염처리 용액으로 알수가 있었으며 특히 어떠한 탈염 용액으로 유물을 처리한다 해도 철제유물에 생성된 부식물은 제거되지 않는다는 것을 알게 되었다. 따라서 보존처리자는 유물 표면의 부식 상태만을 보고 처리하기 보다는 철기제작물로 고려하여 처리하는 것이 필요하다. 또한 금속에 부식을 야기시키는$Cl^-$ 이온과 부식물을 완전하게 제거하여 탈염처리를 하는 것이 유물 부식을 최대한 지연시킬 수 있는 것이라 생각된다.TEX>$88\%$)였다.(P=0.063). 결론: 본 -
Lee Kwang-Soo;Yum Ki-Dai;Park Jin Soon;Kang Sok Kuh;Park Woo-Sun;Han Sang-Hun;Jung Gong-Il;Park Jung Woo 512
The Korean peninsula has a number of coastal sites where the rhythmic rising and lowering of water surface due to tides result in strong tidal current. The kinetic energy of these currents can be efficiently exploited by using tidal current turbines. The pilot tidal current power plant is to be constructed at the Uldolmok between Chindo and Haenam. Extensive coastal engineer ing research works have been carried out. This paper describes some observation results of field campaign, design of the supporting structure of a pilot plant of 1,000kW and a future tidal current power plant and so on. -
The pilot tidal current power plant is to be constructed at the Uldolmok between Chindo and Haenam, during next year. and extensive coastal engineering research works have been carried out. In this paper we describes some observation results of the tide and tidal current. as well as modeling work in order to investigate the tide and tidal current regime change in relation to the tidal current power plant (TCPP) construction. The special modeling skill in order to consider the turbine operation in the TCPP is developed and applied to the estimation for the flow regime change by the simple layout of the tidal current power plant.
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국내에서 대체에너지 공급 비율을 보면 청정에너지로 분류할 수 있는 태양열에너지, 태양 광 에너지, 풍력에너지를 모두 합하여 대체에너지의
$10\%$ 이하이며, 대체에너지 비율의$90\%$ 이상을 폐기물로부터 얻은 에너지가 차지하고 있는 실정이다. 신재생에너지원에는 여러 종류가 있지만 해양에너지원에 대해 대상을 설정하고 이에 대한 부존량을 살펴보면 진도 주변의 해역에서 조류발전 부존량이 약 362만 kW가 되며, 시화호와 새만금 등지에서의 조력발전 부존량이 650만 kW, 동해안 후포 연안을 비롯한 파력발전 부존량이 20만kW가 되는 것으로 알려져 있다. 이에 따라 해양에너지를 실용화하기 위한 연구가 국내외에서 연구되고 있다. 본 논문은 권선형유도발전기를 갖는 조류발전 시스템을 대상으로 연구한 결과로 권선형유도발전기를 제어하기 위한 전력변환장치 개발과 관련한 내용이다. 신재생에너지원이 발전 단가 측면에서 경제성을 갖기 위해서 발전기 용량은 5MW 급까지 대용량화되어 있는 단계이지만 국내에서는 아직 MW급 이상이 되는 권선형 유도발전기와 권선형 유도발전기를 제어하는 전력변환장치에 대한 연구 실적이 없는 상황이다 이에 본 논문에서는 1MW급의 권선형유도발전기에 대한 개발 사례를 소개하면서 유효전력제어, 역률제어, 계통연계방법, 그리고 운전 속도에 따라 변동되는 회전자측에서의 피상전력 특성 등을 제시하고자 한다. -
A railway catenary system which supplies a train with electric power is an important system in determining the maximum speed of an electric train. However, a pantograph could be separated from a contact wire because of reciprocal action between a pantograph with constant upward force and a catenary system. The contact loss of a pantograph-catenary system is mainly affected by the dynamic characteristics of damping and wave propagation velocity of contact wire. For increasing speed of an electrical train, it is necessary to establish the techniques to identify the modal parameter of a catenary system through experiment. However, it is difficult to decouple each mode and to extract respect ive damping rat io since a catenary system has an extremely high modal density. For this reason, mode decoupling process to identify modal parameters is a principal technique in analyzing a catenary system. In this paper, the damping extract ion method for a catenary system using the continuous wavelet transform is discussed.
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Free Vibration Analysis using Non-dimensional Dynamic Influence Function (NDIF) is extended to arbitrarily shaped plates including polygonal plates. Since the corners of polygonal plates have indefinite normal directions and additional boundary conditions related to a twisting moment at a corner along with moment and shear force zero conditions, it is not easy to apply the NDIF method to polygonal plates wi th the free boundary condition. Moreover, owing to the fact that the local polar coordinate system, which has been introduced for free plates with smoothly varying edges, cannot be employed for the straight edges of the polygonal plates, a new coordinate system is required for the polygonal plates. These problems are solved by developing the new method of modifying a corner into a circular arc and setting the normal direction at the corner to an average value of normal direct ions of two edges adjacent to the corner. Some case studies for plates with various shapes show that the proposed method gives credible natural frequencies and mode shapes for various polygons that agree well with those by an exact method or FEM (ANSYS).
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In tapping mode atomic force microscopy(TM-AFM). the vibro-contact response of a resonating tip is used to measure the nanoscale topology and other properties of a sample surface. However, the nonlinear tip-surface interact ions can affect the tip response and destabilize the tapping mode control. Especially it is difficult to obtain a good scanned image of high adhesion surfaces such as polymers and biomoleculars using conventional tapping mode control. In this study, theoretical and experimental investigations are made on the nonlinear dynamics and control of TM-AFM. To analyze the complex dynamics and control of the tapping tip, the classical contact models are adopted due to the surface adhesion. Also we report the surface adhesion is an additional important parameter to determine the control stability of TM-AFM. In addition, we prove that it is more adequate to use Johnson-Kendall-Roberts (JKR) contact model to obtain a reasonable tapping response in AFM for the soft and high adhesion samples.
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This paper is concerned wi th the generation of the Lamb waves in a nonferromagnetic plate by a recently-developed orientation-adjustable patch-type magnetostrictive transducer (OPMT) and the dispersion analysis from the measured Lamb waves. OPMT is capable of adjusting wave-propagation orientation only with a single installation on a plate. The mechanics behind the wave generation and measurement by the magnetostrictive phenomenon, the working principle of OPMT is explained and the actual generation and measurement of the Lamb waves were conducted in a 3 mm-thick aluminum plate. For the accurate analysis of the dispersion characteristics of the measured Lamb waves, a modified version of the short-time Fourier transform, known as the dispersion-based short-time Fourier transform, was employed. The results presented in this work would serve as the underlying research for an advanced non-destructive evaluation based on ultrasonic waves.
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Micro EDM milling using deionized water as dielectric fluid was investigated. After machining micro grooves using deionized water with different voltage. capacitance. and resistivity of deionized water, machining characteristics were investigated. The wear of a tool electrode and the machining time can be reduced by using deionized water instead of kerosene. Micro hemispheres were machined in deionized water and kerosene and their machining characteristics were compared.
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Pyrolysis of polyethylene was carried out in the stainless steel reactor of internal volume of
$40cm^3$ . Pyrolysis reactions were performed at temperature$390-450^{\circ}C$ and the pyrolysis product were collected separately as reaction products and gas products. The molecular weight distributions(MWDs) of each liquid product were determined by GC-SIMDIS. Molecular weight of each product were decreased wi th increase of react ion temperature and time. -
Production, utilization and related regulation of refuse derived fuel in Korea have been discussed in this paper. Also, the expected future of RDF has been discussed. Although the interest about RDF has been increased continuously , there are many things that must be solved for the development of RDF industry. Compared with other developed country, inadequacy of regulation about RDF and the lack of possible utilization facility make the limitation for the development of RDF industry.
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Gasification has been regarded as a very important technology to decrease environmental pollution and to obtain higher efficiency. The gasification process converts carbon containing feedstock into a synthesis gas, composed primarily of CO and
$H_2$ . And the synthesis gas can be used as a source for power generation or chemical material production. Through more than nine years, IAE developed and upgraded several gasification/melting pilot plant system, and obtained a good quality synthesis gas. This paper illustrates the gasification characteristics and operation results of two 3 ton/day synthesis gas production facilities. One is entrained-bed slagging type coal gasifier system which is normally operated in the temperature range of$1,400\~1,450^{\circ}C,\;8\~10$ bar pressure. And the other is fixed-bed type gasification/melting furnace system using MSW and industrial wastes as a feedstock. -
신
$\cdot$ 재생에너지는 환경친화적이면서 무한하게 공급되므로 지속가능한 미래 에너지원으로 각광받고 있으나 선행투자와 시장전망의 불확실성 때문에 정부 주도의 개발이 필요하다. 정부는 이러한 여건에 있는 신$\cdot$ 재생에너지 사업의 활성화를 위하여 공공기관 신축 건물에 대해 신$\cdot$ 재생에너지의 이용을 의무화하는 법령을 만들고, RPS제도를 도입하는 것을 검토하는 둥의 노력을 하고 있다. 이러한 정책수립 과정에서 국민들의 의견을 수렴하여 충분히 반영해야 신규 정책에 대한 타당성이 뒷받침되게 된다. 이에 일반 국민의 신$\cdot$ 재생에너지에 대한 관심과 선호도에 대한 인식을 분석하기 위해 일반 국민에게 가장 보편적으로 알려져 있거나 이용 중인 특정 신$\cdot$ 재생에너지의 종류를 알아보고, 아울러 가장 도움을 주거나 우리나라 여건에 적절하다고 국민들이 기대하는 종류가 무엇인지 조사하였다. 또 거주지역에 신$\cdot$ 재생에너지 생산기지가 건설되는 것에 대한 찬반 의견을 물어 일반 혐오시설 건설에 대한 의견과 비교하고, 응답이 각 계층별로 어떠한 양상을 띠는지 조사하였다. 이를 통해 정부의 신·재생에너지 정책에 대한 국민들의 입장과 수용여부를 분석하고자 한다. 응답자 중 대부분이 태양열과 풍력 에너지라는 용어를 경험한 것으로 드러난 반면, 소수력과 바이오매스 에너지는 생소하게 느끼고 있었다 일반적으로 친숙한 용어의 신$\cdot$ 재생에너지의 종류에 대해 기대를 갖고 있는 반면, 생소한 신·재생에너지에 대해서는 기대 수준이 낮은 것으로 나타나 신·재생에너지 관련 교육의 필요성을 보여주고 있다. 또 여성보다는 남성이, 그리고 신$\cdot$ 재생에너지에 대한 사전지식이 많을수록 거주지역에 신$\cdot$ 재생에너지 생산기지를 건설하는 것에 대해 호의적이었다. -
대표적인 신
$\cdot$ 재생에너지의 시장확대 정책으로 RPS와 기준가격의무구매제가 주요 선진국에서 실시되고 있으며 자국의 자원부존과 경제사회여건에 맞춰 적합한 정책수단을 선택하고 있음. RPS 실시국가에서 RPS는 특별법으로 제정되어 실시효과를 극대화하고 있으며, 신$\cdot$ 재생에너지발전 인중서의 거래를 포함시켜 시너지효과를 거두고 있음. RPS의 단일의 최적모델은 존재하지 않으며 기본설계와 세부사항은 각 국의 고유의 자원부존 여건 및 경제사회적 특징에 따라 달라짐. RPS의 국내도입이 전력시장과 국민경제에 미치는 영향은 그리 크지 않으며 외부효과를 감하면 편익을 초래함. 또한 수요조사결과 RPS에 대한 선호도가 비교적 높게 나타나며 산$\cdot$ 재생에너지발전의 시장확대 수단으로 높은 점수를 매기고 있음 그러나 RPS의 기본설계를 신중히 가져가야 할 것이며, 법제도 정비에 임해서는 기존에 실시되고 있는 기준가격우선구매제도(발전차액보전)의 고려해야 함. -
There are many activities involved in promoting renewable energy technologies. These include governments, the renewable energy manufacturing and service industries, energy supply companies, investors, researchers, non-government organizations and customers. For a sustainable renewable energy market, finding a promising industry is essential. The industry has made significant progress in recent years, considering the fact that today's renewable energy market is relatively small. This paper analyses the technology market of renewable energy, focusing on photovoltaic system, fuel cell, wind system. It appears that there has been remarkable progress in renewable energy systems. Besides, developed countries are effectively increasing the share of niche market and promoting renewable energy worldwide.
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우리나라는 에너지의 안정적 공급과 에너지이용 과정에서 발생하는 환경적, 안보적 외부성을 최소화하는 에너지수급 구조를 마련하기 위해 2003년 12월 '제2차 신재생에너지 기술개발 및 이용보급 기본계획(2003-2012)'을 발표하였다. 이 계획에서는 2011년까지 전체 TPES의
$5\%$ 를 신재생에너지로 공급하는 것을 정책목표로 수립하고 수소, 태양광 그리고 풍력기술을 중점적으로 추진하기로 하였다. 특히 수소부문에서는 주택 및 건물용, 발전용, 수송용 연료전지의 개발을 중심으로 개발하여 세계 기술시장의$20\%$ 를 확보한다는 계획을 발표하였다. 이러한 기술 잠재력을 기반으로 우리 정부도 미국이나 일본과 같이 수소경제로의 전환을 준비하고 있으며 2020년대 이후 우리나라의 에너지부문은 새로운 국면에 접어들 것으로 전망된다. 에너지나 환경기술의 효과적 인 개발을 위해서는 이들 기술의 직접적인 비용측면에 대한 분석 즉 경제성 평가와 새로운 기술변화로 인한 중장기적인 사회경제적 영향평가가 선행되어야 한다. 이러한 평가는 대상 기술의 사회경제적 파급효과가 광범위할수록 더욱 복잡한 분석이 요구된다. 본 연구의 주제인 수소에너지기술은 지금까지 이용되던 것과는 전혀 새로운 에너지캐리어(carrier)를 개발하는 것으로 에너지부문 및 여타 다른 산업부문이 공유하고 있는 에너지 관련 인프라의 전면적인 조정이 요구되며 에너지 이용과 관련된 사회경제적 측면의 급속한 변화를 수반한다. 본 연구는 수소경제로의 이행에 대한 사회경제적 영향평가의 방법론적 요소들과 기법을 제시한다."중등도 독성"으로 나타났다 이상의 결과는 전기도금을 이용하여 교정용 선재의 직경을 증가시키는 방법이 임상에 적용되기 위해서는 세포독성을 줄이기 위한 추가의 연구가 필요함을 시사하였다.의하게 가장 낮은 정지. 운동 마찰력을 보였고 브라켓-호선 각도가 증가함에 따라 유의하게 정지, 운동 마찰력도 증가하였다 (P<0.001)%$ 낮추지만(p value=0.260) 평균$D_{max}$ 는 거의동일 하여($0.3\%$ 감소, p value=0.867), 전통적인 방법보다 우수성이 크게는 없는 것으로 평가되었다. 그러나 환자의 체곡선이 보상체와 잘 일치하는 경우에는 DII가$18\%$ 까지 감소하였다. 결론 : Multistatic field 방법은 모든 환자에 대하여 선량분포의 균일성을 전반적으로 향상시키는 효과적인 방법으로 평가되는 반면 공용보상체의 사용은 보상체의 크기가 환자의 체 윤곽과 잘 일치하는 경우만 효과적으로, 적용의 범위에는 한계가 있는 방법으로 평가되었다.비교하여 계통에 따르는 차이가 있음을 알 수 있었다. 그러므로 가임기 여성의 방사선 진단 및 치료시 Rugh의 10일 법칙을 적용하여 착상전기 방사선 조사로 인한 부작용들을 적극적으로 예방하는 것이 매우 중요하다고 생각한다.equirements of the prematured infants during the early weeks of life. 모든 치근단 수준에서 비표준화 medium 크기 master cone 사용군이 ISO 표준화 규격의 master cone 사용군에 비해 -
Renewable energy technology development has been carrying out in 11 different areas so far. Many technologies are being applied to the required areas according to its own characteristics. Before launching the development, these technologies have been evaluated by their commercial effect and contribution to energy supply. In this paper, the impact factors enhancing the distribution of renewable energy were developed to select appropriate diffusion regulations for each technology area. In addition, AHP methodology was introduced to investigate priorities of the regulations along with weights of impact factors.
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U.S. National Research Council proposed benefits framework for energy R&D project as economic benefits, environmental benefits, security benefits and knowledge benefits. Following this framework, U.S. National Renewable Energy Laboratory evaluated the projected benefits of Federal Energy Efficiency and Renewable Energy Programs in the indicators of energy-expenditure savings, energy system cost savings,
$CO_2$ emissions reductions. oil savings, natural gas saving and avoided additions to central conventional power. As this result, geothermal energy have predominant position in the energy-expenditure savings, natural gas saving and avoided addi t ions to central conventional power to FY2050. The projected benefits, in monetary value, of the whole supply-potential of geothermal energy in Korea were evaluated as 480.2 billion Won, 43.1 billion Won and 135.8 billion Won for the private energy-cost savings, social environmental-cost savings, and import energy-cost saving, respectively. -
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Gas hydrates are ice-l ike sol id compounds that are composed of water and natural gas. All common gas hydrates belong to the three crystal structures that are composed of five polyhedral cavities formed by hydrogen bonded water molecules and stable in specific high pressure and low temperature conditions. Gas hydrates contain large amounts of organic carbon and widely occur in deep oceans and permafrost regions, and they may therefore represent a potential energy resource in the future. United States and Japan perform the national R&D programs for the commercial production of gas hydrates in 2010's. The study on gas hydrates are also important for exploration and development of natural gas in the regions where gas hydrates are accumulated and could be formed. Although their global abundance is debated, they play an important role in global climate change since methane is a 50 times more effect ive greenhouse gas than carbon dioxide. Natural gas hydrates also form a possible natural hazard if rapidly dissociated and can cause slides and slumps and in the marine environment associated tsunamis.
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[
$^{13}C$ ] NMR spectra were obtained for pure$CH_4$ hydrate in order to identify hydrate structure and cage occupancy of guest molecule. The NMR technique can provide both qualitative and quantitative hydrate characteristics. The moles of methane captured into pure$CH_4$ hydrate per mole of water were found to be similar to the full occupancy value. The overall results drawn from this study can be usefully applied to storage and transportation of natural gas. -
In this study, the phenomena of hydrate formation and inhibition were investigated according to varying the concentrations using methanol and ethylene glycol as chemical additives. The results reveal that the used additives display better inhibition effects compared to pure water by decreasing the formation temperature and the inhibition performance of methanol is superior to that of ethylene glycol. As a conclusion, the plugging phenomena of flowline in natural gas product ion. subsea and frozen field pipelines can be predicted by examining the hydrate formation and inhibition conditions. Specifically, the results of this study can be applied to the selection of the prevention criteria and method of hydrate formation.
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Kim Ji-Hoon;Park Myong-Ho;Ryu Byong-Jae;Lee Young-Joo;Han Hyun-Chul;Cheong Tae-Jin;Oh Jae-Ho;Chang Ho-Wan 622
본 연구의 목적은 동해 울릉분지 천부퇴적층의 공극수와 메탄의 특징 및 상호작용을 규명하는데 있다. 울릉분지에서 채취한 코어에서 공극수를 추출하여 분석한 결과, 공극수의 황산염 농도가 퇴적물의 심도가 증가할수록 감소하며, 감소하는 경향은 크게 세 가지 (직선성, concave down, upward kink)로 나뉨을 알 수 있었다. 이는 모든 코어에서 황산염 환원작용이 일어나고 있음을 지시한다 황산염 농도의 수직적 구배를 이용하여 SMI (sulfate-methane interface) 심도를 계산하면, 남부울릉분지가 북부울릉분지보다 낮은 값을 갖는다. 반면에 메탄 농도는 퇴적물의 심도가 증가할수록 전반적으로 증가하며, 공간적으로는 남부 울릉분지가 북부울릉보지보다 높다. 또한 남부울릉분지에서 메탄가스 농도는 SMI 심도 아래에서 급격히 증가한다 메탄가스의 탄소 안정동위원소$(\delta^{13}C)$ 분석 값들은 대부분$-60\%_{\circ}$ 이하로서 이는 메탄가스가 열기원 보다는 박테리아기원임을 지시해준다 또한 남부 울릉분지에서 메탄의 탄소 안정동위원소 분석 값들은 메탄농도가 증가할수록 낮은 값을 보여 주는 데 이러한 결과들은 남부 울릉분지에서 무산소 메탄 산화작용이 일어나고 있음을 지시하고, 메탄의 상향 분산 (diffusion)량이 북부 울릉분지보다 많이 일어난다는 것을 의미한다. 공극수내 황산염 이온 농도 구배와 메탄가스 농도를 종합적으로 고려할 때, 울릉분지에서 가스하이드레이트의 부존가능성은 북부 울룽분지보다 남부 울릉분지가 높은 것으로 추정된다. -
새로운 에너지 자원으로 활용 가능성을 포함하고 있는 가스 하이드레이트를 조사하기 위해 한국지질자원연구원에서는 동해일원에서 탄성파탐사를 실시하고 있다. 탄성파 반사자료로부터 가스 하이드레이트 부존여부를 확인하는 방법은 해저면과 평행하면서 위상이 반대로 나타나는 고진폭 반사파 BSR (Bottom Simulating Reflect ion)과 BSR 상부에서의 진폭감소, 하부에서 진폭증가와 구간속도 감소 등을 들 수 있다. 그러나 고진폭 반사파는 free gas 또는 실리카를 포함하는 퇴적층에서도 발생하므로 이를 구별할 수 있는 방법이 필요하다. 여기에서는 가스 하이드레이트 탐사자료에 대한 일반자료처리와 함께 가스층 존재 유무를 확인하는 방법으로 많이 이용되는 탄성파 복소분석법을 적응하였다. 가스 하이드레이트 부존 유망지역에 대해 순간진폭, 순간진폭에 대한 1차, 2차 미분, 순간위상, 순간주파수 단면도를 제작하여 중합단면도와 비교하였으며 그 결과 순간진폭단면도의 경우 강한 BSR이 나타나는 지층경계면에서 순간진폭변화 차이를 강하게 보였으며, 순간주파수 단면도의 경우 BSR지역에서 고주파에서 저주파수로 변화함을 확인할 수 있었다.
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Some gases can be formed into hydrate by physical combination with water under appropriate temperature and pressure condition. Besides them, it was found that the pore size of the sediments can affect the formation and dissociation of hydrate. In this study, formation temperatures of carbon dioxide and methane hydrate have been measured using isobaric method to investigate the effects of flow rates of gases on formation condition of hydrate in porous rock samples. The flow rates of gases were controlled using a mass flow controller. To minimize Memory effect, system temperature increased for the dissociation of gas hydrates and re-established the initial saturation. The results show that the formation temperature of hydrate decreases with increasing the injection flow rate of gas. This indicates that the velocity of gas in porous media may act as kinds of inhibitor for the formation of hydrate.
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Multichannel seismic data acquired in Ulleung Basin of East Sea for gas hydrate exploration. The seismic sections of this area show strong BSR(bottom simulating reflections) associated with methane hydrate occurrence in deep marine sediments. Very limited information is available from deep sea drilling as the risk of heating and destabilizing the initial hydrate conditions during the processing of drilling is considerably high. Not so many advanced status of gas hydrate exploration in Korea, the most of information of gas hydrate characteristics and properties are inferred from seismic reflection data. In this study, The AVO analysis using the long offset seismic data acquired in Ulleung Basin used to explain the characteristics and structure of gas hydrate. It is used primarily P-wave velocity accessible from seismic data. To make a good quality of AVO analysis input data, seismic preprocessing including 'true gain correction', 'source signature deconvolution', twice velocity analysis and some kinds of multiple rejection and enhancing the signal to noise ratio processes is carried out very carefully. The results of AVO analysis, the eight kinds of AVO attributes are estimated basically and some others of AVO attributes are evaluated for interpretation of AVO analysis additionally. The impedance variation at the boundary of gas hydrate and free gas is estimated for investing the BSR characteristics and properties. The complex analysis is performed also to verifying the amplitude variation and phase shift occurrence at BSR. Type III AVO anomaly appearance at saturated free gas area is detected on BSR. It can be an important evidence of gas hydrate deposition upper the BSR.
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For gas hydrate exploration, long offset multichannel seismic data acquired using by the 4km streamer length in Ulleung basin of the East Sea. The dataset was processed to define the BSRs (Bottom Simulating Reflectors) and to estimate the amount of gas hydrates. Confirmation of the presence of Bottom Simulating reflectors (BSR) and investigation of its physical properties from seismic section are important for gas hydrate detection. Specially, faster interval velocity overlying slower interval velocity indicates the likely presences of gas hydrate above BSR and free gas underneath BSR. In consequence, estimation of correct interval velocities and analysis of their spatial variations are critical processes for gas hydrate detection using seismic reflection data. Using Dix's equation, Root Mean Square (RMS) velocities can be converted into interval velocities. However, it is not a proper way to investigate interval velocities above and below BSR considering the fact that RMS velocities have poor resolution and correctness and the assumption that interval velocities increase along the depth. Therefore, we incorporated Migration Velocity Analysis (MVA) software produced by Landmark CO. to estimate correct interval velocities in detail. MVA is a process to yield velocities of sediments between layers using Common Mid Point (CMP) gathered seismic data. The CMP gathered data for MVA should be produced after basic processing steps to enhance the signal to noise ratio of the first reflections. Prestack depth migrated section is produced using interval velocities and interval velocities are key parameters governing qualities of prestack depth migration section. Correctness of interval velocities can be examined by the presence of Residual Move Out (RMO) on CMP gathered data. If there is no RMO, peaks of primary reflection events are flat in horizontal direction for all offsets of Common Reflection Point (CRP) gathers and it proves that prestack depth migration is done with correct velocity field. Used method in this study, Tomographic inversion needs two initial input data. One is the dataset obtained from the results of preprocessing by removing multiples and noise and stacked partially. The other is the depth domain velocity model build by smoothing and editing the interval velocity converted from RMS velocity. After the three times iteration of tomography inversion, Optimum interval velocity field can be fixed. The conclusion of this study as follow, the final Interval velocity around the BSR decreased to 1400 m/s from 2500 m/s abruptly. BSR is showed about 200m depth under the seabottom
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The gas hydrate exploration using seismic reflection data, the detection of BSR(Bottom Simulating Reflector) on the seismic section is the most important work flow because the BSR have been interpreted as being formed at the base of a gas hydrate zone. Usually, BSR has some dominant qualitative characteristics on seismic section i.e. Wavelet phase reversal compare to sea bottom signal, Parallel layer with sea bottom, Strong amplitude, Masking phenomenon above the BSR, Cross bedding with other geological layer. Even though a BSR can be selected on seismic section with these guidance, it is not enough to conform as being true BSR. Some other available methods for verifying the BSR with reliable analysis quantitatively i.e. Interval velocity analysis, AVO(Amplitude Variation with Offset)analysis etc. Usually, AVO analysis can be divided by three main parts. The first part is AVO analysis, the second is AVO modeling and the last is AVO inversion. AVO analysis is unique method for detecting the free gas zone on seismic section directly. Therefore it can be a kind of useful analysis method for discriminating true BSR, which might arise from an Possion ratio contrast between high velocity layer, partially hydrated sediment and low velocity layer, water saturated gas sediment. During the AVO interpretation, as the AVO response can be changed depend upon the water saturation ratio, it is confused to discriminate the AVO response of gas layer from dry layer. In that case, the AVO modeling is necessary to generate synthetic seismogram comparing with real data. It can be available to make conclusions from correspondence or lack of correspondence between the two seismograms. AVO inversion process is the method for driving a geological model by iterative operation that the result ing synthetic seismogram matches to real data seismogram wi thin some tolerance level. AVO inversion is a topic of current research and for now there is no general consensus on how the process should be done or even whether is valid for standard seismic data. Unfortunately, there are no well log data acquired from gas hydrate exploration area in Korea. Instead of that data, well log data and seismic data acquired from gas sand area located nearby the gas hydrate exploration area is used to AVO analysis, As the results of AVO modeling, type III AVO anomaly confirmed on the gas sand layer. The Castagna's equation constant value for estimating the S-wave velocity are evaluated as A=0.86190, B=-3845.14431 respectively and water saturation ratio is
$50\%$ . To calculate the reflection coefficient of synthetic seismogram, the Zoeppritz equation is used. For AVO inversion process, the dataset provided by Hampson-Rushell CO. is used. -
Gas hydrates draw great at tent ion recently as a new clean energy resources substituting conventional oil and gas hydrate its presumed huge amount of volume reaching 10 trillion tons of gas and environmentally friendly characteristics. Gas hydrate can contribute to the rapidly increasing consumption of natural gas in Korea and achieve the self support target by 2010 which is
$30\%$ of total natural gas demand. This paper shows the importance and benefit of Gas hydrate comparing with new & renewable energy in Korea -
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Considering the fact that more than
$97\%$ of fossil energy resources such as oil and natural gas needed in Korea rely on import, primary concern of the national economy is to secure future energy sources. Gas hydrates. which is non-conventional types of natural gas, distribute worldwide, especially in marine and permafrost Gas hydrates draw great attention recently as a new clean energy resources substituting conventional oil gas due to its presumed huge amount of volume reaching 10 trillion tons of gas and environmentally friendly characteristics. Results of preliminary survey by Korea Gas Corporation (KOGAS) and Korea Institute of Geoscience and Mineral Resources (KIGAM) showed that gas hydrates can be present in deep sea over 1,000m water depth in the East Sea. Gas hydrates can contribute to the rapidly increasing consumption of natural gas in Korea and achieve the self-support target by 2010 with$30\%$ of total natural gas demand. This study presents the potentialities and development prospects of gas hydrate as a future energy source. -
his paper develops the systematic and quantitative priority-determining method for national investment using the framework of evaluating R&D. This study proposes multi criteria for evaluating the R&D of New & Renewable Energy through analysing the attribute of 11 types of energy. The framework is constituted by 4 criteria, the political urgency, economic impact, regional constraint. and technological attribute and the each criteria has 3 or 4 sub-criteria. These sub-criteria are weighted using AHP.
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본 연구에서는 미 인근 해저에서 ODP로 확인된 부존 하이드레이트 샘플을 다양한 분광학 및 실험적 분석 방법을 통해 시료의 물성 및 특성을 파악하여 부존된 하이드레이트 자원의 성분 파악을 목적으로 하고 있다. 일반적으로 가스 하이드레이트 연구에 있어서 X-ray diffractometer, NMR stectrometer, Raman spectrometer 등 분광학적 분석기기를 이용하여 가스 하이드레이트의 구조 및 성분을 규명한다. 본 연구에서는 실험실에서 인위적으로 만들어진 메탄 하이드레이트와 심해저 천연가스 하이드레이트 층에서 채취된 샘플의 비교 분석을 통하여 심해에 매장되어 있는 천연가스 하이드레이트의 구조 및 성분을 규명하였다 XRD 결과로부터 천연가스 하이드레이트는 sI의 구조를 가지며 NMR 및 Raman 결과에 의하면 하이드레이트 내에 포집되어 있는 가스의 주 성분은 메탄인 것으로 밝혀졌다. 또한 천연가스 하이드레이트를 이용한 이산화탄소의 치환 실험을 통하여 심해저 천연가스 하이드레이트 층의 이산화탄소 저장 매체로의 활용 가능성을 조사하였다.
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Gas hydrates are ice-like compounds that form at the low temperature and high pressure conditions common in shallow marine sediments at water depths greater than 300-500 m when concentrations of methane and other hydrocarbon gases exceed saturation. Estimates of the total mass of methane carbon that resides in this reservoir vary widely. While there is general agreement that gas hydrate is a significant component of the global near-surface carbon budget, there is considerable controversy about whether it has the potential to be a major source of fossil fuel in the future and whether periods of global climate change in the past can be attributed to destabilization of this reservoir. Also essentially unknown is the interaction between gas hydrate and the subsurface biosphere. ODP Leg 204 was designed to address these questions by determining the distribution, amount and rate of formation of gas hydrate within an accretionary ridge and adjacent basin and the sources of gas for forming hydrate. Additional objectives included identification of geologic proxies for past gas hydrate occurrence and calibration of remote sensing techniques to quantify the in situ amount of gas hydrate that can be used to improve estimates where no boreholes exist. Leg 204 also provided an opportunity to test several new techniques for sampling, preserving and measuring gas hydrates. During ODP Leg 204, nine sites were drilled and cored on southern Hydrate Ridge, a topographic high in the accretionary complex of the Cascadia subduction zone, located approximately 80km west of Newport, Oregon. Previous studies of southern Hydrate Ridge had documented the presence of seafloor gas vents, outcrops of massive gas hydrate, and a pinnacle' of authigenic carbonate near the summit. Deep-towed sidescan data show an approximately
$300\times500m$ area of relatively high acoustic backscatter that indicates the extent of seafloor venting. Elsewhere on southern Hydrate Ridge, the seafloor is covered with low reflectivity sediment, but the presence of a regional bottom-simulating seismic reflection (BSR) suggests that gas hydrate is widespread. The sites that were drilled and cored during ODP Leg 204 can be grouped into three end-member environments basedon the seismic data. Sites 1244 through 1247 characterize the flanks of southern Hydrate Ridge. Sites 1248-1250 characterize the summit in the region of active seafloor venting. Sites 1251 and 1252 characterize the slope basin east of Hydrate Ridge, which is a region of rapid sedimentation, in contrast to the erosional environment of Hydrate Ridge. Site 1252 was located on the flank of a secondary anticline and is the only site where no BSR is observed. -
World geothermal resources potential is estimated to supply 189 EJ annually, which can take charge approximately a half of annual world energy consumpt ion, from considering identified resources and supplies in USA and Iceland. Present annual use of geothermal energy, on the other hand, is only
$0.1\%$ of its potential, but still has$70\%$ share among total new renewables. World-wide installed capacity of geothermal power generation reaches 8,900 MWe and 27,825 MWt for direct uses in 2005 which is almost two-fold increase over 2000. This increase is mainly due to exploding expansion of geothermal heat pump utilization: USA and western European countries lead these trends. Although geothermal heat pump distribution in Korea is still in its starting phase, comparing to Swiss achievement in terms of areal utilization sense, we expect to come up with national supply of over 600,000 toe in near future. -
The characteristics of geothermal resources in Korea was roughly estimated using hot springs, 580 geothermal gradients and 338 heat flow data. In the aspect of hot springs with geologic structure, location of hot springs coincide with fault zone, especially younger age of Cretaceous to Tertiary. In the aspect of geothermal gradients, Pohang area shows the highest geothermal gradient anomaly, which is covered with unconsol idated rock of low thermal conductivity preserving the residual heat from igneous activity or radioactivity elements decay. In the aspect of heat flow density, high anomaly can be found along the zone connecting Uljin-Pohang-Busan on the southeastern part of Korean peninsula at which big fault zone as Yangsan fault is well developed.
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Korea is utilizing geothermal resources mainly in the bathing and swimming facilities with very few applications for industrial processes or space heating. It is estimated that geothermal capacity and annual utilization are 36.2MWt and 761TJ/year as compared to global capacity and annual utilization of 15,145MWt and 190,699 TJ/year. RETScreen software is a user's friendly tool for analyzing the technical and financial pre-feasibility of potential Renewable Energy (RE) projects that promotes the use of RE applications through the capacity building of planners, decision-makers and industries for successful implementation of RE projects. Strong ties between Canada and Korean organizations such as Korean Solar Energy Society (KSES) and the Korea Institute of Energy Research (KIER) exist for knowledge transfer about RETScreen. In this paper, an overview of RETScreen and its ground source heat pump (GSHP) model with a practical example of an existing project of a community hall in Canada are described to illustrate effectiveness of RETScreenin the implementation of RE technologies. The same community hall project is then evaluated hypothetically considering its location at Kangnyng, Korea. The main objective is to demonstrate how RETScreen GSHP model can also be utilized effectively for GSHP applications in Korea.
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Ground source heat pump systems are used for heating, ventilating and air-conditioning systems in commercial buildings, schools, and factories because of low operating and maintenance costs. These systems use the earth as a heat source in heating mode and a heat sink in cooling mode. Ground heat exchangers are classified by a horizontal type and vertical type according to the installation method. A horizontal type means that a heat exchanger is laid in the trench bored in 1.2 to 1.8 m depth. The solar heat and the rainwater are affected by the performance of heat exchanger and causes mutual influence among heat exchangers. In this study, to evaluate the performance of straight type, slinky type, and spiral type of horizontal ground heat exchangers designed on 1 RT scale, test sections are buried on the earth and experimental apparatus is installed. Therefore the performance of these is estimated.
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Importance of substitute energy has been increasing due to environmental issues and lack of fossil fuels. In addition, heating cost that occupies from 30 to
$40\%$ of the total production cost in Korean protected cultivation needs to be reduced for profitability and global competition. But, studying on substitute energy to solve these problems has not been activated for Korean protected cultivation. Therefore, this study was conducted to develop a geothermal heat pump system for cool ing and heat ing of greenhouses at a lower cost than conventional hot air heater and air conditioner. Fundamental test of heat transfer characteristics in soil was conducted by computer simulation and controlled tests for its verification. Based on the results of the theoretical and empirical investigations, an optimum heat pump system was developed and the performance was evaluated for practical use in a greenhouse at the Pusan Horticultural Experiment Station. The system was compared with a conventional hot air heating system through a cucumber growing test and economic feasibility analysis. Results of the application test of the geothermal heat pump showed that with an initial setting of$15^{\circ}C$ the inside temperature of the greenhouse could be maintained between 15 and$17^{\circ}C$ . Results of the cucumber growing test showed that there were no significant differences in average height, leaf length, leaf width, number of nods, leaf area, dry weight and yield between the plots wi th the geothermal heat pump system and a conventional hot air heater. Economic feasibility analysis indicated that the variable cost of the hot air heater could be saved$81.2\%$ using the geothermal heat pump system. It was concluded that the geothermal heat pump system might be a pertinent heating and cooling system for greenhouses because of the low operating cost and the use of environment-friendly geothermal energy. -
KIGAM (Korea Institute of Geoscience and Mineral Resources) launched a new project to develop the low-temperature geothermal water in the area showing high geothermal anomaly, north of Pohang city, for large-scale space heating. Surface geologic and geophysical surveys including Landsat 1M image analysis, gravity, magnetic, Magnetotelluric (MT) and controlled-source audio-frequency MT (CSAMT), and self-potential (SP) methods have been conducted and the possible fracture zone was found that would serve as deeply connected geothermal water conduit. In 2004, two test wells of 1.1km and 1.5km depths have been drilled and various kinds of borehole survey including geophysical logging, pumping test, SP monitoring, core logging and sample analysis have followed. Temperature of geothermal water at the bottom of 1.5km borehole reached over
$70^{\circ}C$ and the pumping test showed that the reservoir contained huge amount of geothermal water. Drilling for the production well of 2 km depth is on going. After test utilization and the feasibility study, geothermal water developed from the production well is going to be provided to nearby apartments. -
Aquifer Thermal Energy Storage (ATES) system can be very cost-effective and renewable energy sources, depending on site-specific parameters and load characteristics. In order to develop an ATES system which has certain hydrogeological characteristics, understanding of the thermo hydraulic processes of an aquifer is necessary for a proper design of an aquifer heat storage system under given conditions. The thermo hydraulic transfer for heat storage is simulated using FEFLOW according to two sets of pumping and waste water reinjection scenarios of heat pump operation in a two layered confined aquifer. In the first set of model, the movement of the thermal front and groundwater level are simulated by changing the locations of injection and pumping well in seasonal cycle. However, in the second set of model the simulation is performed in the state of fixing the locations of pumping and injection well. After 365 days simulation period, the temperature distribution is dominated by injected water temperature and the distance from injection well. The small temperature change is appears on the surface compared to other slices of depth because the first layer has very low porosity and the transfer of thermal energy are sensitive at the porosity of each layer. The groundwater levels and temperature changes in injection and pumping wells are monitored to validate the effectiveness of the used heat pump operation method and the thermal interference between wells is analyzed.
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Aquifer Thermal Energy Storage (ATES) can be a cost-effective and renewable geothermal energy source, depending on site-specific and thermohydraulic conditions. To design an effective ATES system having influenced by groundwater movement, understanding of thermo hydraulic processes is necessary. The heat transfer phenomena for an aquifer heat storage are simulated using FEFLOW with the scenario of heat pump operation with pumping and waste water reinjection in a two layered confined aquifer model. Temperature distribution of the aquifer model is generated, and hydraulic heads and temperature variations are monitored at the both wells during 365 days. The average groundwater velocities are determined with two hydraulic gradient sets according to boundary conditions, and the effect of groundwater flow are shown at the generated thermal distributions of three different depth slices. The generated temperature contour lines at the hydraulic gradient of 0.00 1 are shaped circular, and the center is moved less than 5m to the groundwater flow direction in 365 days simulation period. However at the hydraulic gradient of 0.01, the contour center of the temperature are moved to the end of boundary at each slice and the largest movement is at bottom slice. By the analysis of thermal interference data between two wells the efficiency of the heat pump system model is validated, and the variation of heads is monitored at injection, pumping and no operation mode.
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For the development of geothermal energy, many different kind of geoscientific data including both surface geological data and underground geomechanical data, are acquired. Integration of such data itself for better understanding of underground condition is not a simple process due to complexity of the data, i.e. mixture of 20 and 3D data, mixture of geological data, geochemical data, geomechanical data and hydrogeological data. This paper reports a preliminary suggestion of GIS modeling for such specific purpose. Data used for GIS modeling mainly came from British case studies. The modeling is much more focused on the design of database for 3D underground geotechnical data in this study.