한국신재생에너지학회:학술대회논문집

Korean Society for New and Renewable Energy (한국신·재생에너지학회)
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Development of an Catalyst for Hydrolysis of Aqueous Sodium Borohydride Solution

$NaBH_4$ 수용액 분해 수소 발생용 최적 촉매 개발

  • 양태현 (한국에너지기술연구원 고분자연료전지연구단) ;
  • ;
  • 이원용 (한국에너지기술연구원 고분자연료전지연구단) ;
  • 김창수 (한국에너지기술연구원 고분자연료전지연구단)
  • Published : 2005.06.01
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Abstract

Hydrogen generation by the hydrolysis of aqueous sodium borohydride $(NaBH_4)$ solutions was studied using IRA-400 anion resin dispersed Pt. Ru catalysts and Lithium Cobalt oxide $(LiCoO_2)$ supported Pt, Ru and PtRu catalysts. The performance of the $LiCoO_2$ supported catalysts is better than the ion exchange resin dispersed catalysts. There is a marked concentration dependence on the performance of the $LiCoO_2$ supported catalysts and the hydrogen generation rate goes down if the borohydride concentration is increased beyond $10\%$. The efficiency of PtRu- $LiCoO_2$ is almost double that of either Ru-$LiCoO_2$ or Pt-$LiCoO_2$ for $NaBH_4$ concentrations up to $10\%$.

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