• Journal of the Korean Crystal Growth and Crystal Technology
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• v.33 no.6
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• pp.261-267
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• 2023

Crystal structure, microstructure, and dielectric properties of the (Ca, Sr)(Zr, Ti)O₃ (CSZT) system has been studied as a function of sintering temperature and MgO addition for microwave applications. A single-phase CSZT powder with the orthorhombic crystal structure was obtained by the solid-state reaction method. The powder compacts were sintered at 1200℃, 1300℃, and 1400℃ respectively. All the sintered samples had a single-phase orthorhombic crystal structure and grain size increased with sintering temperature. In the case of 1 mol% MgO addition, the orthorhombic crystal structure was the main phase; however, a secondary phase appeared during sintering at 1400℃, as determined by EDS analysis. At 1400℃, the undoped and MgO-doped CSZT had almost similar grain size distribution and densification but the grain size distribution became slightly narrow. The MgO-doped CSZT showed excellent low-loss dielectric properties: ε_r = 34.14, tanδ = 0.00047, τ_ε = -3.58 ppm/℃ at 1 MHz.

• The Journal of Advanced Prosthodontics
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• v.16 no.1
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• pp.12-24
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• 2024

PURPOSE. This study aimed to evaluate the maximum vertical wear, volume wear, and surface characteristic of antagonist enamel, opposing monolithic zirconia or lithium disilicate crowns. MATERIALS AND METHODS. The study comprised 24 participants (n = 12), who were randomly allocated to receive either a 5 mol% Y-TZP or a lithium disilicate crown in positions which would oppose the natural first molar tooth. The contralateral first molar along with its antagonist was considered as the enamel opposing natural enamel control. Data collection was performed using an intraoral scanner and polyvinylsiloxane impression. The means of the maximum vertical loss and the volume loss at the occlusal contact areas of the crowns and the various natural antagonists were measured by 3D comparison software. A scanning electron microscope was subsequently used to assess the wear characteristics. RESULTS. The one-year results from 22 participants (n = 11) indicated no significant differences when comparing the zirconia crown's antagonist enamel (40.28 ± 9.11 ㎛, 0.04 ± 0.02 mm³) and the natural enamel wear (38.91 ± 7.09 ㎛, 0.04 ± 0.02 mm³) (P > .05). Also, there is no significant differences between lithium disilicate crown's antagonist enamel (47.81 ± 9.41 ㎛, 0.04 ± 0.02 mm³) and the natural enamel wear (39.11 ± 7.90 ㎛, 0.04 ± 0.02 mm³) (P > .05). CONCLUSION. While some studies suggested that monolithic zirconia caused less wear on opposing enamel than lithium disilicate, this study found similar wear levels to enamel for both materials compared to natural teeth.

• The Journal of the Acoustical Society of Korea
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• v.27 no.5
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• pp.215-220
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• 2008

The kerfs between arrayed piezoelectric elements in a medical ultrasonic transducer or a piezoelectric composite transducer are generally filled by polymeric materials. The boundary condition of the elements for lateral mode vibration is changed according to the kerf-filling materials, so that the resonance frequency for longitudinal mode of the transducer is also varied. In this study, to investigate the resonance frequency variation for an arrayed transducer experimentally, the piezoelectric vibration elements of $14mm{\times}0.22mm{\times}0.44mm$ were fabricated and those were linearly arrayed. And, the resonance frequencies were measured for three cases of kerf-filling condition, non-filling and two different kinds of epoxy filling. Conclusively, it is confirmed that the resonant frequency variation shows the similar tendency with the theoretical one for the longitudinal mode.

• Korean Journal of Materials Research
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• v.34 no.5
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• pp.254-260
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• 2024

This study is to manufacture a titanium dioxide (TiO₂) photocatalyst by recycling sludge generated using titanium tetrachloride (TiCl₄) as a coagulant. Compared to general sewage, a TiCl₄ coagulant was applied to dyeing wastewater containing a large amount of non-degradable organic compounds to evaluate its performance. Then the generated sludge was dried and fired to prepare a photocatalyst (TFS). Scanning electron microscope-energy dispersive X-ray spectroscopy (SEM-EDX), X-ray diffraction (XRD), and nitrogen oxide reduction experiments were conducted to analyze the surface properties and evaluate the photoactive ability of the prepared TFS. After using titanium tetrachloride (TiCl₄) as a coagulant in the dyeing wastewater, the water quality characteristics were measured at 84 mg/L of chemical oxygen demand (COD), 10 mg/L of T-N, and 0.9 mg/L of T-P to satisfy the discharge water quality standards. The surface properties of the TFS were investigated and the anatase crystal structure was observed. It was confirmed that the ratio of Ti and O, the main components of TiO₂, accounted for more than 90 %. As a result of the nitric oxide (NO) reduction experiment, 1.56 uMol of NO was reduced to confirm a removal rate of 20.60 %. This is judged to be a photocatalytic performance similar to that of the existing P-25. Therefore, by applying TiCl₄ to the dyeing wastewater, it is possible to solve the problems of the existing coagulant and to reduce the amount of carbon dioxide generated, using an eco-friendly sludge treatment method. In addition, it is believed that environmental and economic advantages can be obtained by manufacturing TiO₂ at an eco-friendly and lower cost than before.

• Journal of the Korean Geosynthetics Society
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• v.23 no.1
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• pp.1-7
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• 2024

In this study, a selecvively block barrier was developed to prevent the spread of contaminants (TPH, Phenol) in the ground only when contamination occurs. The materials were used Jumunjin sand, bentonite, polyolefin elastomer and spill hound marine. First, the properties and environmental hazards characteristics of materials were analyzed for evaluated their usability. Then, the possibility of use as a barrier material was confirmed by analyzing the water permeability characteristics that change after 24 hours of contact with contaminants. As a result of the analysis, the pH of each component was similar to the general groundwater pH range. In addition, the toxicity characteristics and the possibility of dissolution of hazardous substances, it was determined that there was no environmental hazard as the content was below the regulation value. Lastly, when comparing the permeability coefficient before and after contact with the contaminant, the permeability coefficient of approximately α × 10^-3cm/sec before contact was reduced to α × 10^-6cm/sec after contact with the contaminant.

• Transactions of Materials Processing
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• v.33 no.4
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• pp.270-276
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• 2024

In order to improve the performance of the PM (Particulate Matter) filter, the TPMS structure was used as a flow controller to control the flow entering the filter. Among various TPMS structures, a primitive structure that is easy to utilize 3D printing technique was selected and the effect of unit cell size was analyzed. In addition, numerical analysis was performed and swirl ratio was analyzed to confirm changes in filter inlet flow characteristics that affect changes in filter performance. Unit cell size is closely related to filter performance, and both PM collection efficiency and pressure drop increase as unit cell size decreases. Through quality factor (QF) comparison, which comprehensively evaluate collection efficiency and pressure drop, it was confirmed that when the unit cell size is 5 mm, PM collection efficiency increases, but the flow controller actually reduces filter performance. QF values are similar for unit cell sizes of 10 and 20 mm, and it is advantageous to select the unit cell size among these two considering collection efficiency and operating costs. The filter's collection performance increases due to the increase in swirl flow caused by the primitive structure, and the filter's collection efficiency increases due to the swirl flow that increases throughout the flow field as the unit cell size becomes smaller.

• Advances in materials Research
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• v.13 no.4
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• pp.269-283
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• 2024

Biocompositesmade up of starch and jute fibres are biodegradable and environmentally friendly materials for sustainable development. In this study, corn starch has been separately modified with 15% pine rosin and 40% glutaraldehyde, and 30% glycerol is used as a plasticizer. The composites have been prepared for three different volume proportions of matrix and jute fibre such as 60:40, 70:30 and 80:20 by using a hot compression moulding machine. The effects of pine rosin and glutaraldehyde on mechanical properties have been studied. Pine rosin modified starch jute composites have shown higher tensile and flexural properties as compared with glutaraldehyde modified starch jute composite. The highest tensile strength and modulus are found at 60:40 matrix and jute fibre volume proportion of pine rosin modified starch jute composite which are 13.97 MPa and 782.94 MPa respectively. Similar trends were found in flexural strength and modulus for pine rosin modified starch jute composite having matrix to jute fibre proportion 60:40 which are 29.18 MPa and 1107.76 MPa respectively. But, in case of impact strength, glutaraldehyde modified starch jute composite having matrix to jute fibre proportion 80:20 have shown highest impact strength that is 59.05 KJ/m². Starch-jute composite with glutaraldehyde shows 33% more water absorbency as compared to composite having pine rosin as cross linker. Highest FTIR graph indicates that the number of -OH group is much lower in case of pine rosin modified starch than glutatraldehyde modified starch which indicates that bonds formed by pine rosin are much stronger than the bonds formed by glutaraldehyde. The surface morphology of the composite was influenced by pine rosin and glutaraldehyde which is shown in the SEM image.

• International conference on construction engineering and project management
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• 2024.07a
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• pp.311-318
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• 2024

Quality control in construction projects necessitates the detection of defects during construction. Currently, this task is performed manually by site supervisors. This manual process is inefficient, labor-intensive, and prone to human error, potentially leading to decreased productivity. To address this issue, research has been conducted to automate defect detection using computer vision-based object detection technologies. However, these studies often suffer from a lack of data for training deep learning models, resulting in inadequate accuracy. This study proposes a method to improve the accuracy of deep learning models through the use of virtual image data. The target building is created as a 3D model and finished with materials similar to actual components. Subsequently, a virtual defect texture is produced by layering three types of images: defect information, area information, and material information images, to fabricate materials with defects. Images are generated by rendering the 3D model and the defect, and annotations are created for segmentation. This approach creates a hybrid dataset by combining virtual data with actual site image data, which is then used to train the deep learning model. This research was conducted on the tile process of finishing construction projects, focusing on cracks and falls as the target defects. The training results of the deep learning model show that the F1-Score increased by 12.08% for falls and cracks when using the hybrid dataset compared to the real image dataset alone, validating the hybrid data approach. This study contributes not only to unmanned and automated smart construction management but also to enhancing safety on construction sites. To establish an integrated smart quality management system, it is necessary to detect various defects simultaneously with high accuracy. Utilizing this method for automatic defect detection in other types of construction can potentially expand the possibilities for implementing an integrated smart quality management system.

• Advances in nano research
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• v.17 no.4
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• pp.323-334
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• 2024

This paper deals with the effect of non-linear volume fraction distribution of carbon nanotube in the FG-CNTRC beams on the critical buckling via a hyperbolic shear deformation theory. Here, different boundary condition was considered including hinged hinged, clamped clamped and clamped-free. Single-walled carbon nanotubes are aligned and distributed in the polymer matrix in different ways to reinforce it and the material properties of (CNTRC) beams are assumed to vary gradually along the thickness direction, following a new exponential power law distribution of (CNT). The effective material properties of nanocomposite beams are estimated using the rule of mixture. The governing equations of the mathematical models are obtained by applying Hamilton's principle. The results provided of mathematical models in this work are compared and validated with similar ones in the literature. The critical buckling loads of nanocomposite beams with different boundary conditions of linear and non-linear distribution of CNT volume fraction were obtained. The effects of several parameters, including the type of beam, the volume fraction of carbon nanotubes (CNTs), the exponent degree (n), and the aspect ratio, were investigated. The distribution non-linearity of CNT volume fraction in the beam has a significant impact on the mechanical properties, particularly in buckling behavior with different boundary conditions.

• Journal of the Korean Electrochemical Society
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• v.5 no.1
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• pp.30-38
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• 2002

Disordered carbon and boron-substituted disordered carbons $C_{l-x}B_x(x=0.05,\;0.10,\;0.20)$ were synthesized by Pyrolysis of LPG(liquid Propane gas)and $BCl_3$. Their electrochemical properties as anode materials for Li-ion secondary batteries were then investigated. When PVDF is added to the sample in a weight ratio 5 : 95, the disordered carbon with x=0.00 had the first discharge capacity 374 mAh/g. Its cycling performance was relatively good from the second cycle and it had the discharge capacity 258 mAh/g at the 10th cycle. When PVDF is added to the sample in a weight ratio 5 : 95, the sample with x=0.05 among the samples $C_{l-x}B_x(x=0.05,\;0.10,\;0.20)$ exhibited the largest first discharge capacity 860 mAh/g and discharge capacity 181 mAh/g at the 10th cycle. All the samples had similar cycling performances from the second cycle. The sample $C_{0.90}B_{0.10}$ showed the best electrochemical properties as a anode materials fur Li-ion secondary battery from the view points of the first discharge capacity(853 mAh/g when $10w1.\%$ PVDF is used), cycling performance, discharge capacity(400mAh/g at the 10th cycle when $10wt.\%$ PVDF is used). All the samples showed generally larger charge and discharge capacities when $10wt.\%$ PVDF ratter than $5wt.\%$ PVDF is used. The plateau region in the range of voltage lower than 1.25V becomes larger probably since the structure becomes less disordered by the addition of boron. When boron is added, the charge and discharge capacities decreased suddenly at the second cycle. This may be become only a part of Li are reversibly deintercalated and intercalated and a part of Li which are strongly combined with B are not deintercalated. The increases in charge and discharge capacities are considered to be resulted from the increase in the potential of Li in the boron-added carbons, caused by the strengthening of the chemical bond between the intercalated Li and the boron-carbon host since the boron acts as electron acceptor.