• 제목/요약/키워드: reaction diffusion system

검색결과 168건 처리시간 0.024초

Pattern Formations with Turing and Hopf Oscillating Pattern in a Discrete Reaction-Diffusion System

  • 이일희;조웅인
    • Bulletin of the Korean Chemical Society
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    • 제21권12호
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    • pp.1213-1216
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    • 2000
  • Localized structures with fronts connecting a Turing patterns and Hopf oscillations are found in discrete reaction-diffusion system. The Chorite-Iodide-Malonic Acid (CIMA) reaction model is used for a reaction scheme. Localized structures in discrete reaction-diffusion system have more diverse and interesting features than ones in continuous system. Various localized structures can be obtained when a single perturbation is applied with variation of coupling strength of two intermediates. Roles of perturbations are not so simple that perturbations are sources of both Turing patterns and Hopf oscillating domains, and spatial distribution of them is determined by strength of a perturbation applied initially.

ROBUST BOUNDARY CONTROL OF CHEMOTAXIS REACTION DIFFUSION SYSTEM

  • Ryu, Sang-Uk;Kang, Yong Han
    • Korean Journal of Mathematics
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    • 제16권4호
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    • pp.457-470
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    • 2008
  • This paper is concerned with the robust boundary control of the chemotaxis reaction diffusion system. That is, we show that the existence of the saddle point for the robust control problem when the control and the disturbance are given by the boundary condition.

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Estimating Diffusion-Controlled Reaction Parameters in Photoinitiated Polymerization of Dimethacrylate Macromonomers

  • Choe, Youngson
    • Macromolecular Research
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    • 제11권5호
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    • pp.311-316
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    • 2003
  • The kinetics of photoinitiated polymerization of dimethacrylate macromonomers have been studied to determine the diffusion-controlled reaction parameters using attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR). A predicted kinetic rate expression with a diffusion control factor was employed to estimate an effective rate constant and to define the reaction-controlled and diffusion-controlled regimes in the photopolymerization. An effective rate constant, k$_{e}$, can be obtained from the predicted kinetic rate expression. At the earlier stages of polymerization, the average values of kinetic rate constants do not vary during the reaction time. As the reaction conversion, $\alpha$, reaches the critical conversion, $\alpha$$_{c}$, in the predicted kinetic expression, the reaction becomes to be controlled by diffusion due to the restricted mobility of dimethacrylate macromonomers. A drop in value of effective rate constant causes a drastic decrease of reaction rate at the later stages of polymerization. By determining the effective rate constants, the reaction-controlled and diffusion-controlled regimes were properly defined even in the photopolymerization reaction system.m.m.

Hyperbolic Reaction-Diffusion Equation for a Reversible Brusselator: Solution by a Spectral Method

  • 이일희;김광연;조웅인
    • Bulletin of the Korean Chemical Society
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    • 제20권1호
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    • pp.35-41
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    • 1999
  • Stability characteristics of hyperbolic reaction-diffusion equations with a reversible Brusselator model are investigated as an extension of the previous work. Intensive stability analysis is performed for three important parameters, Nrd, β and Dx, where Nrd is the reaction-diffusion number which is a measure of hyperbolicity, β is a measure of reversibility of autocatalytic reaction and Dx is a diffusion coefficient of intermediate X. Especially, the dependence on Nrd of stability exhibits some interesting features, such as hyperbolicity in the small Nrd region and parabolicity in the large Nrd region. The hyperbolic reaction-diffusion equations are solved numerically by a spectral method which is modified and adjusted to hyperbolic partial differential equations. The numerical method gives good accuracy and efficiency even in a stiff region in the case of small Nrd, and it can be extended to a two-dimensional system. Four types of solution, spatially homogeneous, spatially oscillatory, spatio-temporally oscillatory and chaotic can be obtained. Entropy productions for reaction are also calculated to get some crucial information related to the bifurcation of the system. At the bifurcation point, entropy production changes discontinuously and it shows that different structures of the system have different modes in the dissipative process required to maintain the structure of the system. But it appears that magnitude of entropy production in each structure give no important information related for states of system itself.

GLOBAL COUPLING EFFECTS ON A FREE BOUNDARY PROBLEM FOR THREE-COMPONENT REACTION-DIFFUSION SYSTEM

  • Ham, Yoon-Mee
    • 대한수학회지
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    • 제43권3호
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    • pp.659-676
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    • 2006
  • In this paper, we consider three-component reaction-diffusion system. With an integral condition and a global coupling, this system gives us an interesting free boundary problem. We shall examine the occurrence of a Hopf bifurcation and the stability of solutions as the global coupling constant varies. The main result is that a Hopf bifurcation occurs for global coupling and this motion is transferred to the stable motion for strong global coupling.

NEW BLOW-UP CRITERIA FOR A NONLOCAL REACTION-DIFFUSION SYSTEM

  • Kim, Eun-Seok
    • 호남수학학술지
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    • 제43권4호
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    • pp.667-678
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    • 2021
  • Blow-up phenomena for a nonlocal reaction-diffusion system with time-dependent coefficients are investigated under null Dirichlet boundary conditions. Using Kaplan's method with the comparison principle, we establish new blow-up criteria and obtain the upper bounds for the blow-up time of the solution under suitable measure sense in the whole-dimensional space.

BaCO3-TiO2계의 고상반응에 관한 연구 (A Study on Solid Reaction of BaCO3-TiO2 System)

  • 이응상;황성연;임대영
    • 한국세라믹학회지
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    • 제24권5호
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    • pp.484-490
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    • 1987
  • Diffusion coupling experiment was done to study expansion of body and soild reaction in BaCO3-TiO2 system. Specimen of BaCO3 and TiO2 was formed with Pt-mark's method. Each specimen was fired at interval of 25℃ from 900℃ to 1000℃ for 2hrs. After that, specimen was fixed with resin and polished. Product layers of specimen were observed with SEM and EDS. The result were following; 1. Diffusion component is Ba2+, which diffuse toward TiO2. 2. Large crack between layer of BaCO3 and Ba2TiO4 was generated because of difference of thermal expansion coefficient. 3. Ba2TiO4 is formed to TiO2 body by the reaction of BaTiO3 and BaO and its structure is very porous. 4. BaTiO3 changes immediately to Ba2TiO4 by the reaction of BaO. But BaTiO3 which formed by the reaction of TiO2 and Ba2TiO4 exsists as layer because the diffusion distance of Ba2+ is far.

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The well posedness of a parabolic double free boundary problem

  • Ham, Yoon-Mee
    • 대한수학회지
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    • 제32권3호
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    • pp.389-399
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    • 1995
  • We consider the reaction-diffusion system of two-component model in one-dimensional space described by $$ (1) u_s = d_1 u_{xx} + f(u, \upsilon) \upsilon_t = d_2\upsilon_{xx} + \gammag(u, \upsilon) $$ where $d_1$ and $d_2$ are the diffusion rates of u and $\upsilon$, and $\gamma$ is the ration of reaction rates. It is interesting the case of that there are differences in the diffusion and reaction rates of u and $\upsilon$.

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