• Title/Summary/Keyword: Phase change behavior

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Rapid thermal annealing temperature effects on the ohmic behavior of the Pd/Ge-based contact to n-type InGaAs (n형 InGaAs에 형성된 Pd/Ge계 오믹 접촉 특성에 미치는 급속 열처리 온도의 영향)

  • 김일호;박성호;김좌연;이종민;이태우;박문평
    • Journal of the Korean Vacuum Society
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    • v.7 no.1
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    • pp.24-28
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    • 1998
  • Pd/Ge ohmic contact system on n-type InGaAs was studied. A good ohmic begavior by rapid thermal annealing was shown up to $400^{\circ}C$, and the specific contact resistance was reduced to low-$10^-6\Omega\textrm{cm}^2$EX>. However, above $425^{\circ}C$ it was deteriorated by intermixing and phase reaction of ohmic metals and InGaAs substrate. No remarkable phase change was observed below $350^{\circ}C$, but the reaction was initiated at ~$375^{\circ}C$ and considerable phase change was found above $425^{\circ}C$. Non-spiking and planar interfaces were observed even when annealed at $425^{\circ}C$, and smooth and shiny surface was kept up to $400^{\circ}C$.

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Numerical Study on the Effects of Gravity Direction and Hydrogen Filling Rate on BOG in the Liquefied Hydrogen Storage Tank (액체수소 저장 탱크의 중력 방향 및 수소 충전율이 BOG에 미치는 영향에 관한 수치적 연구)

  • YOUNG MIN SEO;HYUN WOO NOH;DONG WOO HA;TAE HYUNG KOO;ROCK KIL KO
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.4
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    • pp.342-349
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    • 2023
  • In this study, a numerical simulations were conducted to analyze the phase change behavior of a liquid hydrogen storage container. The effects of gravity direction and hydrogen filling rate on boil-off gas (BOG) in the storage container were investigated. The study employed the volume of fluid, which is the phase change analysis model provided by ANSYS Fluent (ANSYS, Canonsburg, PA, USA), to investigate the sloshing phenomenon inside the liquefied hydrogen fuel tank. Considering the transient analysis time, two-dimensional simulation were carried out to examine the characteristics of the flow and thermal fields. The results indicated that the thermal flow characteristics and BOG phenomena inside the two-dimensional liquefied hydrogen storage container were significantly influenced by changes in gravity direction and hydrogen filling rate.

Morphogenetic Behavior of Tropical Marine Yeast Yarrowia lipolytica in Response to Hydrophobic Substrates

  • Zinjarde, Smita S.;Kale, Bhagyashree V.;Vishwasrao, Paresh V.;Kumar, Ameeta R.
    • Journal of Microbiology and Biotechnology
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    • v.18 no.9
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    • pp.1522-1528
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    • 2008
  • The morphogenetic behavior of a tropical marine Yarrowia lipolytica strain on hydrophobic substrates was studied. Media containing coconut oil or palm kernel oil (rich in lauric and myristic acids) prepared in distilled water or seawater at a neutral pH supported 95% of the cells to undergo a transition from the yeast form to the mycelium form. With potassium laurate, 51 % of the cells were in the mycelium form, whereas with myristate, 32% were in the mycelium form. However, combinations of these two fatty acids in proportions that are present in coconut oil or palm kernel oil enhanced the mycelium formation to 65%. The culture also produced extracellular lipases during the morphogenetic change. The yeast cells were found to attach to the large droplets of the hydrophobic substrates during the transition, while the mycelia were associated with the aqueous phase. The alkane-grown yeast partitioned more efficiently in the hydrophobic phases when compared with the coconut oil-grown mycelia. A fatty acid analysis of the mycelial form revealed the presence of lauric acid in addition to the long-chain saturated and unsaturated fatty acids observed in the yeast form. The mycelia underwent a rapid transition to the yeast form with n-dodecane, a medium-chain aliphatic hydrocarbon. Thus, the fungus displayed a differential behavior towards the two types of saturated hydrophobic substrates.

Deformation Behavior of Corrosion-Resistant Fe-Cr Alloy

  • Era, Hidenori;Kono, Yusuke;Sasabuchi, Ryota;Miyoshi, Noriko;Tokunaga, Tatsuya;Shinozaki, Nobuya;Lee, Je-Hyun;Shimozaki, Toshitada
    • Applied Microscopy
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    • v.46 no.1
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    • pp.45-50
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    • 2016
  • Iron containing a high amount of chromium is known to be inferior to ductility due to ${\sigma}$ phase formation so that it is generally difficult to apply the plastic deformation process although the alloy possesses a superior characteristics of an excellent corrosion resistance. In this study, Fe-50mass%Cr alloy was melted using high purity powder and the deformation behavior has been investigated by cold rolling and tensile test. The tensile test yielded that the alloy revealed a serration at an early stage of tensile deformation and then the serrated flow vanished to change to a normal work hardening flow at the later stage. The former was governed by twin formation process, the latter by dislocation multiplication one, bringing about a high ductility of 20% or over. The reduction ratio in cold rolling was attained as high as 90%, thus the high corrosion-resistant alloy is able to possess a high ductility.

Mechanical behavior of Beishan granite samples with different slenderness ratios at high temperature

  • Zhang, Qiang;Li, Yanjing;Min, Ming;Jiang, Binsong
    • Geomechanics and Engineering
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    • v.24 no.2
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    • pp.157-166
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    • 2021
  • This paper aims at the temperature and slenderness ratio effects on physical and mechanical properties of Beishan granite. A series of uniaxial compression tests with various slenderness ratios and temperatures were carried out, and the acoustic emission signal was also collected. As the temperature increases, the fracture aperture of intercrystalline cracks gradually increases, and obvious transcrystalline cracks occurs when T > 600℃. The failure patterns change from tensile failure mode to ductile failure mode with the increasing temperature. The elastic modulus decreases with the temperature and increases with slenderness ratio, then tends to be a constant value when T = 1000℃. However, the peak strain has the opposite evolution as the elastic modulus under the effects of temperature and slenderness ratio. The uniaxial compression strength (UCS) changes a little for the low-temperature specimens of T < 400℃, but a significant decrease happens when T = 400℃ and 800℃ due to phase transitions of mineral. The evolution denotes that the critical brittle-ductile transition temperature increases with slenderness ratio, and the critical slenderness ratio corresponding to the characteristic mechanical behavior tends to be smaller with the increasing temperature. Additionally, the AE quantity also increases with temperature in an exponential function.

Work Softening Behavior of Zn-15%Al alloy (Zn-15%Al 합금의 가공연화 거동)

  • Jun, Joong-Hwan;Seong, Ki-Duk;Kim, Jeong-Min;Kim, Ki-Tae;Jung, Woon-Jae
    • Journal of the Korean Society for Heat Treatment
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    • v.18 no.1
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    • pp.18-23
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    • 2005
  • Effect of cold rolling on microstructural changes has been investigated for a Zn-15%Al alloy to elucidate the reason for its work softening behavior. Fully annealed microstructure of the Zn-15%Al alloy is characterized by ${\eta}$ grains and (${\eta}+{\alpha}$) lamellar colonies, where ${\eta}$ and ${\alpha}$ are Zn-rich HCP and Al-rich FCC phases, respectively. The hardness decreases continuously with increasing cold rolling degree, exhibiting work softening behavior. It is revealed that during the cold rolling, (${\eta}+{\alpha}$) lamellar colonies gradually change into equiaxed ${\eta}$ and ${\alpha}$ grains due to dynamic recrystallization at room temperature, while pre-existing ${\eta}$ grains are only deformed without recrystallization. Furthermore, cold rolling causes the precipitation of dissolved Al solutes in ${\eta}$ grains. In view of these results, change of (${\eta}+{\alpha}$) phases from lamellar to equiaxed morphology, which results in structural softness and increase in equiaxed ${\eta}/{\alpha}$ grain boundaries with higher mobility, and deterioration of solution hardening by precipitation of Al solutes from ${\eta}$ grains, are thought to contribute to the work softening of Zn-15%Al alloy.

PATTERN OF PHYSICAL, PSYCHOLOGICAL SYMPTOMS IN THE MENSTRUAL CYCLE OF ADOLESCENTS - FOCUSED ON THE MEAN DAILY PATTERN OF SYMPTOM CHANGES BY DAILY RATING FORM - (청소년에서의 월경주기에 따른 신체적, 심리적 변화양상 - 매일평가서에 의한 증상변화양상을 중심으로 -)

  • Joe, Sook-Haeng;Nam, Min;Lee, Hyeon-Soo;Song, Soo-Shic
    • Journal of the Korean Academy of Child and Adolescent Psychiatry
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    • v.7 no.1
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    • pp.52-60
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    • 1996
  • Premenstrual symptoms can begin at anytime after menache and usually remit with menopause. Numerous studies of the premenstrual symptoms have been reported, based on mature woman and clinic patients. As yet, however, no prospective study has specially examined the extent or nature of PMS in adolescents. The authors investigated the pattern of mood, behavior and physical symptom changes in the menstrual cycle for 230 high school students who reported premenstrual symptoms by using Baily Rating form(DRF), The scores on 21 symptoms of DRF were recorded daily for at least one menstrual cycle. The results as follows : 1) 1.7%(4/230) of the subjects who reported premenstrual symptoms met criteria for premenstrual dysphoric disorder(PMDD) by 30% change criteria. 2) The pattern of symptom changes in the menstrual cycle showed a clear increase in mean daily symptom score at premenstrual -1,-2 day. and reaching a maximum scores at the first day, rapidly decreased at day 4 during menstruation. 3) The mean daily symptom score in the menstrual phase was significantly higher than those in the premenstrual and postmenstrual phase, and significantly higher in the premenstrual phase than that in postmenstrual phase. 4) The scores of the subjects with longer duration of menstrual bleeding were higher than those of the subjects with the shorter duration. Particularly in the menstrual phase, there was a significant difference on the mean scores of physical symptom duster between the longer and shorter group. These results demonstrated that the mean daily pattern of symptom changes in the menstrual cycle for the subjects was similar pattern of change for the PMDD group, except high level of symptom scores if premenstrual phase. The adolescents might experienced more physical discomfort than the other symptoms in the menstrual phase Especially the subject with longer duration of mense flow were more likely to report more discomfort than that of shorter duration.

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A Study on the Hydriding Reaction Characteristics and the Change of the Hydriding Reaction Rates of MmNi4.5Al0.5 during Temperature-Induced Cycling (MmNi4.5Al0.5의 수소화 반응특성 및 Temperature-Induced Cycling에 따른 수소화 반응속도의 변화에 관한 연구)

  • Kim, Soo-Ryoung;Lee, Jai-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.1 no.1
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    • pp.1-8
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    • 1989
  • The hydriding kinetic mechanism and the change of the hydriding reaction rate of $MmNi_{4.5}Al_{0.5}$ during the thermally induced hydrogen absorption-desorption cycling are investigated. Comparison of the reaction rate data which are obtained by the pressure sweep method with the theoretical rate equations suggests that the hydriding rate controlling step has changed from the dissociative chemisorption of hydrogen molecules at the surface to the hydrogen diffusion through the hydride phase with the increase of the hydriding fraction. These hydriding kinetic mechanism is not changed during the cycling. However, the intrinsic hydriding reaction rate of $MmNi_{4.5}Al_{0.5}$ after 5500 cycles increases significantly comparing with the activated one. It is suggested that the change of the hydriding kinetic behavior due to intrinsic degradation of $MmNi_{4.5}Al_{0.5}$ can be interpreted as follows ; the formation of nickel cluster at the surface of the sample and the host metal atom exchange in bulk by thermal cycling.

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The Stress -Strain Behavior of Asan Marine Soil (아산만 해성토의 응력 -변형률 거동)

  • Hong, Chang-Su;Jeong, Sang-Seom;Kim, Su-Il
    • Geotechnical Engineering
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    • v.12 no.5
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    • pp.17-26
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    • 1996
  • The undrained behavior of Asan marine soil was investigated by using an automated triaxial testing device. The stress-strain behavior at the preand postfailure state of marine soil under undrained compression and eatension conditions was compared with the behavior of pure silt, pure clay and the overall behavior of Asan marine soil was predicted with the modified Camflay model and the bounding surface model. The marine soil sampled in Asan bay area was clayey silts with 70oA silt-30% clay content and the testing samples were prepared in both undisturbed and remolded conditions. All samples are normally consolidated with 400 kPa of effective mean confining pressure and each sample is unloaded to 200, 100, 67 kPa, respectively. And then the shear test was performed with different confining pressure. According to experimental results, there exists an unique failure line whose slope is lower than silt's and higher than clay's. It is identified that the undrained shear strength of normally consolidated samples increases after crossing the phase transformation line because of volume dilation tendency which is not seen in clay. Overconsolidated samples show different soil behavior compared with pure silt due to its tendency of change in volume. It is also found that the overall behavior of Asan marine soil cannot be predicted precisely with the modified Cam-clay model and the bounding surface model.

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Study on the rheological, thermal and mechanical properties of thermoplastic starch plasticized by glycerol (열가소성 녹말의 유변학 성질, 열적 성질 및 기계적 성질에 관한 연구)

  • Bui, Duc Nhat;Son, Younggon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.6
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    • pp.21-26
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    • 2018
  • Thermoplastic starch (TPS) was prepared by mixing starch with glycerol as a plasticizer. The glycerol content ranged from 20 to 35 wt. % and TPS was prepared in a twin screw extruder. The shear viscosity, thermal and mechanical properties of the TPS were investigated. The viscosity of TPS exhibited typical shear thinning behavior: decreasing viscosity with increasing shear rate. The power index, n, increased with increasing glycerol content. This is because as the content of glycerol, a Newtonian fluid, increases, the viscosity behavior of the TPS becomes closer to that of a Newtonian fluid. The thermal behavior of TPS showed that starch and glycerol are miscible. In addition, when TPS was aged for more than one day at room temperature, TPS showed a partially miscible phase structure. The moisture absorbed into the TPS was assumed to change the phase behavior. The mechanical properties of TPS were found to be strongly dependent on the content of the plasticizer. Both the toughness and stiffness increased with increasing plasticizer content. DSC showed that this unusual result was due to the combined effect of humidity and the high amylose content in starch.