• Title/Summary/Keyword: Corrosion Product

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Development of Moving Alternating Magnetic Filter Using Permanent Magnet for Removal of Radioactive Corrosion Product from Nuclear Power Plant

  • M. C. Song;Kim, S. I.;Lee, K. J.
    • Nuclear Engineering and Technology
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    • v.34 no.5
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    • pp.494-501
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    • 2002
  • Radioactive Corrosion Products (CRUD) which are generated by the neutron activation of general corrosion products at the nuclear power plant are the major source of occupational radiation exposure. Most of the CRUD has a characteristic of showing strong ferrimagnetisms. Along with the new development and production of permanent magnet (rare earth magnet) which generates much stronger magnetic field than the conventional magnet, new type of magnetic filter that can separate CRUD efficiently and eventually reduce radiation exposure of personnel at nuclear power plant is suggested. This separator consists of inner and outer magnet assemblies, coolant channel and container surrounding the outer magnet assembly. The rotational motion of the inner and outer permanent magnet assemblies surrounding the coolant channel by driving motor system produces moving alternating magnetic fields in the coolant channel. The CRUD can be separated from the coolant by the moving alternating magnetic field. This study describes the results of preliminary experiment performed with the different flow rates of coolant and rotation velocities of magnet assemblies. This new magnetic filter shows better performance results of filtering the magnetite at coolant (water). How rates, rotating velocities of magnet assemblies and particle sizes turn out to be very important design parameters.

The Research and Application of Protective Coating for PCCP

  • Lin, Zhu;Xu, Cuizhu;Zhang, Li;Fan, Yunpeng;Zhang, Qibin
    • Corrosion Science and Technology
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    • v.7 no.5
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    • pp.265-268
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    • 2008
  • Prestressed Concrete Cylinder Pipe(PCCP) had became one of the dominating kinds of pipes substituting for steel pipes because of its unique feature (high intensity, high pressure and high leakproofness). PCCP was produced firstly by Bonna company in France. By the end of 20th century, there were over 19000 km of this product installed in America. PCCP was introduced from Ameron company by Shandong Eletric Power Pipeline Engineering Company in 1988. As the statistical data in 2002, 700 km of PCCP had been applied in China, and the application trended towards rapid increase.Since prestressing wire would be corroded in environment, Several accidents due to the breakdown of pipe had happened. Consequently the external wall of pipe should be covered with protective coatings. There was a lack of technical study in corrosion and control of PCCP, because PCCP had been applied for a short time in China. in order to ensure the service life of PCCP, we have developed a kind of protective coating for concrete pipe, which had high intensity and anti-corrosive property with convenient applicability. The physical and chemical properties, painting technology and field application of this coating was introduced in the paper, at the same time, the future of external protective coating for PCCP was looked into.

Synthesis and Properties of Fatty Ester Type Cationic Gemini Surfactants (고급지방산 에스테르형 양이온 제미니 계면활성제의 합성 및 특성)

  • Park, Jong-Kwon;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.2
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    • pp.140-145
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    • 2011
  • Cationic gemini-surfactant, namely 1,4-butane-bis(N-alkanoyloxyethyl-N,Ndimethyl)-diammonium bromide was synthesized and their inhibition effect on corrosion of mild steel in 1 M HCl solution was tested by weight loss method. The synthesized product was confirmed by FT-IR and $^1H-NMR$ spectroscopy. Surface tensions were measured by surface tensiometer Sigma 70. Their c.m.c. values evaluated by surface tension method was $4.1{\times}10^{-5}{\sim}5.4{\times}10^{-5}$ mol/L. The Krafft point of the these surfactants were <0~$10.7^{\circ}C$. The emulsifying properties of synthesized cationic gemini surfactants and sodium dodecyl sulfate (SDS), tetradecyl trimethyl ammonium bromide (TTAB) was investigated. Of these, 1,4-butane-bis(N-lauroyloxyethyl-N,N-dimethyl)- diammonium bromide, CGL 14-4-14 has been confirmed as a good emulsifier. The inhibition efficiency increases by increasing cationic gemini surfactant concentration. As a result, these surfactants are expected to be applied as corrosion inhibitors.

Investigation of Pellet-Clad Mechanical Interaction in Failed Spent PWR Fuel

  • Jung, Yang Hong;Baik, Seung Je
    • Corrosion Science and Technology
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    • v.18 no.5
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    • pp.175-181
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    • 2019
  • A failed spent fuel rod with 53,000 MWd/tU from a nuclear power plant was characterized, and the fission products and oxygen layer in the pellet-clad mechanical interaction region were observed using an EPMA (Electron Probe Micro-Analyzer). A sound fuel rod burned under similar conditions was used to compare and analyze, the results of the failed fuel rod. In the failed fuel rod, the oxide layer represented $10{\mu}m$ of the boundary of the cladding, and $35{\mu}m$ of the region outside the cladding. By comparison, in the sound fuel rod, the oxide layer was $8{\mu}m$, observed in the cladding boundary region. The cladding inner surface corrosion and the resulting fuel-cladding bonding were investigated using an EPMA. Zirconium existed in the bonding layer of the (U, Zr)O compound beyond the pellet cladding interaction gap of $20{\mu}m$, and composition of UZr2O3 was observed in the failed fuel rod. This paper presents the results of the EPMA examination of a spent fuel specimen, and a technique to analyze fission products in the pellet-clad mechanical interaction region.

A Study on Improvement of Scaling Factor Prediction Using Artificial Neural Network

  • Lee, Sang-Chul;Hwang, Ki-Ha;Kang, Sang-Hee;Lee, Kun-Jai
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.534-538
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    • 2003
  • Final disposal of radioactive waste generated from Nuclear Power Plant (NPP) requires the detailed knowledge of the natures and quantities of radionuclides in waste package. Many of these radionuclides are difficult to measure and expensive to assay. Thus it is suggested to the Indirect method by which the concentrations of DTM (Difficult-to-Measure) nuclide is decided using the relation of concentrations (Scaling Factor) between Key (Easy-to-Measure) nuclide and DTM nuclide with measured concentrations of Key nuclide. In general, scaling factor is determined by using of log mean average (LMA) and regression. These methods are adequate to apply most corrosion product nuclides. But in case of fission product nuclides and some corrosion product nuclides, the predicted values aren't well matched with the original values. In this study, the models using artificial neural network (ANN) for C-14 and Sr-90 are compared with those using LMA and regression. The assessment of models is executed in the two parts divided by a training part and a validation part. For all of two nuclides in the training part, the predicted values using ANN are well matched with the measured values compared with those using LMA and regression. In the validation part, the accuracy of the predicted values using ANN is better than that using LMA and is similar to or better than that using regression. It is concluded that the predicted values using ANN model are better than those using conventional model in some nuclides and ANN model can be used as the complement of LMA and regression model.

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Nondestructive Analysis on Miniature Pagoda of Sarira Reliquary (Treasure No. 259-2) from Sujong-sa Temple (수종사(水鍾寺) 석조(石造) 부도내(浮屠內) 금동제구층탑(金銅製九層塔)(보물(寶物) 제(第)259-2호(號))의 비파괴(非破壞) 분석조사(分析調査))

  • Kwon, Hyuknam;Yu, Heisun;Kang, Hyungtae
    • Conservation Science in Museum
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    • v.4
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    • pp.57-61
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    • 2003
  • From the stupa of Sujongsa-Temple, located in Yangpyeong, Gyeonggi-do province, was excavated a celadon jar with lid, a gilt-bronze nine-storied miniature pagoda and a silver-plate hexagonal miniature shrine, etc. Among them, the gilt-bronze miniature pagoda has been known as a gilt-bronze product since most of its surface has copper tint and the base part has bronze corrosion. Its formal title registered on the Cultural Properties Administration also begins with "a gilt-bronze". However, it was supposed to be a gold product in many aspects: the color and status of the surface, degree of the bronze corrosion creation and the metal thread joining the wind bell. So the necessity to prove its material by a scientific analysis was raised. We examined it with nondestructive method. The results were traces of open-working on many parts of the surface, but no traces of gilding. Moreover, as we perform an XRF analysis, the main component were gold and silver(16%) and some impurities such as copper and iron were found. Therefore, it could be inferred that this miniature pagoda is a gold product.

Empirical study on inhibition effect of scale and rust in tap-water line by zinc ionization device (아연 이온화 장치에 의한 상수배관 내 스케일 및 녹 생성 억제효과 실증 연구)

  • Yum, Kyung-Taek;Choi, Jung-Wook;Yang, Sung-Bong;Shim, Hak-Sup;Yu, Mee-Seon
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.6
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    • pp.465-476
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    • 2021
  • Scale and rust generation in water pipes is a common phenomenon when cast iron water pipes have been used for a long time. A physical water treatment device is known among various means for suppressing rust in a water pipe, and a zinc ionization device for putting zinc metal into a pipe and emitting the zinc cation into water is one of such devices. This research measured the amount of zinc ion generated, which is known to exhibit an effect of inhibiting rust and scale generation in a pipe, and examined the scale and rust inhibition effect of the ionization device installed for ground or building water supply. In the case of distilled water, the concentration of zinc ion increased by circulating water in the ionization device several times, and it was verified to be hundreds of ㎍/L, and in the case of discharging ground or tap water, it was verified to be tens of ㎍/L. In addition, a verification pipe was installed to confirm the change inside the pipe before and after installation of the zinc ionization device, and the internal condition of the pipe was observed 3 months to several years after installation. It was confirmed that the corrosion area of the surface of the pipe was no longer increased by installing a corrosion inhibitor, and if the pipe was already filled with corrosion products, the amount of corrosion products gradually decreased every year after installation. The phenomenon of fewer corrosion products could be interpreted as expanding the space in the pipe due to the corrosion product as Fe2O3 adhered to the inner surface of the pipe and turned into a smaller black Fe3O4. In addition, we found that scale such as CaCO3 together in the corrosion by-products gradually decreased with the attachment of the ionization device.

A study on shearing die design for window roller housing and die manufacture (창호용 롤러 하우징의 전단금형 설계 및 제작에 관한 연구)

  • Kim, Sei-hwan;Choi, Kye-kwang
    • Design & Manufacturing
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    • v.8 no.1
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    • pp.35-39
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    • 2014
  • Window roller housings are durable because high-quality source materials such as stainless steel is used in making them. After a series of precise structure analysis, their design is optimized. They are subject to repetitive driving tests of more 100,000 times, durability tests, impact resistance tests, corrosion tests and others. For a long time, gaps often occur in press molded products owing to serious squareness deformation and flatness deformation of them. Severe burrs in press molded products require frequent grinding, which leads to short life cycle and rough or unreliable movement of assembled roller housing, which, in turn, causes product defects. This study focuses on developing measures to resolve existing defects and to improve lifespan of dies by designing and making a window roller shearing die.

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A Study on the Development of Al Alloy for the Vehicle Connecting Rod Using Hot Forging (열간단조공법을 이용한 컨로드용 Al 합금의 개발에 관한 연구)

  • Kim, S.H.;Hwang, T.M.
    • Journal of Power System Engineering
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    • v.12 no.1
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    • pp.66-71
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    • 2008
  • Alumium alloys hot forging process are gaining increased acceptance in the automotive and electronic industries and hot forging is one of the most efficient manufacturing method for mass product parts. It has been investigated the microstructures and mechanical properties of Al-11.7Si-0.5Mg (KNT40-T6)alloy fabricated by hot forging process for development of connecting rod in this study. The microstructure of hot forged specimen was composed of eutectic structure of alumimum solid solution and $Mg_2Si$ precipitates. The tensile strength of solutionized Al-11.7Si-0.5Mg alloy was 217MPa. This alloy showed a good corrosion resistance using electrochemical polarization test.

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Root Cause Analysis on Failure Mode of Calorifier for Vessel (선박용 calorifier의 고장모드에 대한 근본원인분석)

  • Lee D.B.;Kim J.H.;Kang S.K.;Kang Y.B.;Kim H.S.
    • Journal of Applied Reliability
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    • v.6 no.1
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    • pp.93-103
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    • 2006
  • Basic function of calorifier system is to supply warm water to the vessel. The heater used in the calorifier system plays a very important role in its reliability. The failure mechanism of heater are compared with accelerated life test. The main cause of failed heater is pitting corrosion occurred between the surface of heater and spacer. To prevent the corrosion failure from heater, material of spacer replaces metal(SUS 304) with polymer (Acryl). The life of redesigned heater can guarantee 2.47years of B10 life under the worst condition.

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