• 기계와재료
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• v.23 no.2
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• pp.68-79
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• 2011

전고체 리튬 이차전지는 기존 리튬 이차전지의 구성요소 가운데 액체 전해질을 고체 전해질로 대체한 것을 말한다. 전지의 폭발이나 화재의 위험성이 업소 제조공정이 단순화되며 고 에너지 밀도화 가능성에서 기존 리튬 이차전지보다 유리한 전고체 리튬이차전지는 차세대 이차전지로 주목받고 있다. 본고에서는 전고체 리튬 이차전지의 핵심 요소기술인 세라믹 고체 전해질과 용량 및 에너지 밀도 향상을 위한 전고체 이차전지 구조 등에 대해 연구개발 현황을 조사하였다.

• Journal of the Korean Applied Science and Technology
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• v.36 no.4
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• pp.1253-1258
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• 2019

The solid-state electrolyte based on polymer is applicable to various electrochemical devices including supercapacitor, battery, sensor, actuator and has great attention to develop its ionic conductivity from conventional polymer electrolyte by uisng wide range of ionic liquids. The research about ion gel as a solid state electrolyte with the ionic liquid has focused on the wearable and flexible electronic device to use as the high electrical and electrochemical performances, mechanical strength of polymer. In this work, we have investigated and developed solid-state electrolyte based on the ionic liquid and polymer with enhanced ionic conductivity and stability.

• Applied Chemistry for Engineering
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• v.33 no.3
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• pp.289-295
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• 2022

In this study, we intend to fabricate an all solid polymer battery with a reduced interfacial resistance between the solid electrolyte and the electrode by applying thiophene based polymers as both electrode and electrolyte materials. In order to minimize the interfacial resistance with the poly(3,4-ethylenedioxy thiophene) (PEDOT) based electrode, 3,4-ethylenedioxy thiophene (EDOT) oligomer was introduced into the solid electrolyte. Also, to improve the lithium salt dissociation ability of the EDOT oligomer [oligo(EDOT)] electrolyte, it was blended with poly(vinylidene fluoride) (PVdF). As a result, the ionic conductivity of the solid polymer electrolyte increased by introducing PVdF into the oligo (EDOT). From the result of evaluating the electrochemical properties of an all solid polymer battery, the interfacial resistance significantly decreased by introducing a thiophene based polymer to the electrode and electrolyte.

• Journal of the Korean Electrochemical Society
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• v.22 no.3
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• pp.87-103
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• 2019

Nonaqueous organic electrolyte solution in commercially available lithium-ion batteries, due to its flammability, corrosiveness, high volatility, and thermal instability, is demanding to be substituted by safer solid electrolyte with higher cycle stability, which will be utilized effectively in large-scale power sources such as electric vehicles and energy storage system. Of various types of solid electrolytes, composite solid electrolytes with polymer matrix and active inorganic fillers are now most promising in achieving higher ionic conductivity and excellent interface contact. In this review, some kinds and brief history of solid electrolyte are at first introduced and consequent explanations of polymer solid electrolytes and inorganic solid electrolytes (including active and inactive fillers) are comprehensively carried out. Composite solid electrolytes including these polymer and inorganic materials are also described with their electrochemical properties in terms of filler shapes, such as particle (0D), fiber (1D), plane (2D), and solid body (3D). In particular, in all-solid-state lithium batteries using lithium metal anode, the interface characteristics are discussed in terms of cathode-electrolyte interface, anode-electrolyte interface, and interparticle interface. Finally, current requisites and future perspectives for the composite solid electrolytes are suggested by help of some decent reviews recently reported.

• Journal of the Korean Applied Science and Technology
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• v.37 no.6
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• pp.1591-1596
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• 2020

The solid-state electrolyte based on polymer has great attention to develop its ionic conductivity from conventional polymer electrolyte by using wide range of ionic liquids with remarkable processability, flexibility and is applicable to various electrochemical devices including batteries, supercapacitor. Polymer electrolyte based on Ionic liquid with high conductivity, wide electrochemical stability, thermal stability is used in various electronic devices. In this work, we have investigated and developed solid-state electrolyte based on ionic liquid and polymer with enhanced ionic conductivity and electrochemical performances to conduct to various electronic devices including secondary battery. The ionic conductivity of polymer based solid state electrolyte with optimized ratio of the ionic liquid was 1.46-2 S/cm. The ionic liquid and polymer based electrolyte with enhanced ionic conductivity is promising candidates to utilize in wide range of secondary batteries.

• Journal of the Korean Electrochemical Society
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• v.24 no.4
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• pp.100-105
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• 2021

Recently, all-solid-state batteries have attracted much attention to improve safety of rechargeable lithium batteries, but the solid-state batteries of conductive ceramics or solid polymer electrolytes show poor electrochemical properties because of several problems such as high interfacial resistance and undesired reactions. To solve the problems of the reported all-solid-state batteries, a hybrid solid electrolyte is suggested, in this study, NASICON-type nanoparticle Li_1.5Al_0.5Ti_1.5P₃O₁₂ (LATP) conductive ceramic, PVdF-HFP, and a carbonate-based liquid electrolyte were composited to prepare a quasi-solid electrolyte. The hybrid solid electrolyte has a high voltage stability of 5.6 V and shows an suppress effect of lithium dendrite growth in the stripping-plating test. The LiNi_0.83Co_0.11Mn_0.06O₂ (NCM811)-based battery with the hybrid solid electrolyte exhibits a high discharge capacity of 241.5 mAh/g at a high charge-cut-off voltage of 4.8V and stable electrochemical reaction. The NCM811-based battery also shows 139.4 mAh/g discharge capacity without short circuit or explosion at 90℃. Therefore, the LATP-based hybrid solid electrolyte can be an effective solution to improve the safety and electrochemical properties of rechargeable lithium batteries.

• Journal of IKEEE
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• v.27 no.1
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• pp.25-29
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• 2023

Effect of the processes of polysilazane solid electrolyte layer and silver (Ag) active electrode on the electrical characteristics of memristor was investigated. The memristor with the solid electrolyte annealed at higher temperature exhibited the higher set voltage and better memory retention characteristics than that annealed at lower temperature. The increase in the set voltage and the improvement of the memory retention characteristic at high annealing temperature were attributed to a reduction in the void density and an increase in the void uniformity inside the solid electrolyte, respectively. In the case where the polysilazane solution's concentration is high, the memristor exhibited rapid degradation of low resistive state even annealed at high temperature. Lastly, it was shown that the memristor with the solution-processed Ag active electrode showed WORM property unlike that with the vacuum-processed Ag active electrode. The WORM property was possibly due to morphological defects present in the solution-processed Ag active electrode.

• Journal of the Korean Vacuum Society
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• v.17 no.4
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• pp.253-261
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• 2008

Programmable metallizaton cell (PMC) memory device has been known as one of the next generation non-volatile memory devices, because it includes non-volatility, high speed and high ON/OFF resistance ratio. This paper reviews the operation principle of the device. Besides, the recent research results of professor Kozicki who firstly invented the device and investigated it for the memory applications, NEC corporation which studied it for the FPGA (field programmable gate array) switch applications, ETRI and chungnam national university which examined Te-based devices are introduced.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.127.1-127.1
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• 2010

고체산화물연료전지는 고효율 및 무공해의 전기화학 에너지 변환장치로서, 최근 국내외에서 활발한 연구개발이 수행되고 있다. 특히, 고체산화물 연료전지 시스템의 조기 상용화를 위해 시스템의 작동온도를 약 $800^{\circ}C$ 이하로 낮추고 저가로 생산 할 수 있는 제조공정 개발에 대한 연구를 적극적으로 수행하고 있다. 본 연구에서는 고체산화물연료전지의 단위셀를 구성하는 연료극지지체 및 박막 전해질에 대해서 저가 양산의 테이프케스팅법 및 동시소성 공정, 그리고 연료극 지지체 전해질(anode-supported electrolyte)에 대한 공기극 페이스트 프린팅 제조공정에 대해 소개한다. 또한 고체산 화물연료전지의 제조공정 및 시간을 단축하기 위해 방전플라즈마 소결공법(SPS)에 의한 연료극 지지체 제조 공정, 단위셀의 성능 최적화를 위한 나노 스케일의 고성능 전해질 소재 분말합성 공정(crystallite size: 5~10nm, surface area : $100m^2/g$ 이상) 그리고 테이프케스팅에 의한 박막 전해질 제조 공정(thin film : $10{\mu}m$ 이하) 등 주요 단위셀 소재 및 부품의 제조공정 특성 그리고 단위셀의 전기화학적 특성(max. power density : 1.0 W/$cm^2$)에 대해 소개하며, 최종적으로 평판형 대면적 고체산화물연료전지(max. $20cm{\times}15cm$)의 단위셀 상용화 제조 기술 및 성능평가 기술에 대해서도 소개 할 예정이다.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1993.05a
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• pp.96-100
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• 1993

상용 모사기인 ASPEN PLUS를 이용하여 메탄올을 원료로 한 고체 고분자 전해질 연료전지 발전 시스템의 정상상태 전산 모사를 실시하여 최적의 설계를 시도하였다. 연료전지 본체의 모사를 위하여 USER block과 FORTRAN block을 작성하였으며, 다른 공정은 ASPEN PLUS에서 제공되는 모델을 사용하였다. 모사 결과, 실제 경우와 근사한 값을 얻었으며, 이를 근거로 하여 조업조건에 따른 출력의 변화를 살펴봄으로써 효율을 최대로 하는 각 단위공정의 최적 조업조건을 찾아내었다. 이로부터 향후 실용화될 국내의 고체 고분자 전해질 연료전지 발전 시스템에 대한 기본 자료를 제시할 수 있으며, 개발되는 공정은 고온으로 조작되는 개질기의 열을 효율적으로 회수하여 이용함으로써 공정의 에너지 효율을 높이도록 하여야 한다.