• Title/Summary/Keyword: 가속열화

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Accelerated Degradation Test and Failure Analysis of Rapid Curing Epoxy Resin for Restoration of Cultural Heritage (문화재 복원용 속(速)경화형 Epoxy계 수지의 가속열화시험 및 고장분석 연구)

  • Nam, Byeong Jik;Jang, Sung Yoon
    • Journal of Conservation Science
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    • v.33 no.6
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    • pp.467-483
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    • 2017
  • In this study, the degradation properties by temperature stress of $Araldite^{(R)}$ rapid-curing epoxy resin used for inorganic cultural heritages, was identified. The tensile and tensile shear strength of durability decreased for 12,624 hours at temperatures of $40{\sim}60^{\circ}C$. In terms of stability of external stress and temperature, the slow-curing epoxy was superior to the rapid-curing epoxy, and cultural heritage conservation plans should therefore consider the strength and stress properties of restoration materials. Color differences increased for 12,624 hours at temperatures of $40{\sim}60^{\circ}C$, and glossiness decreased. Both color and gloss stability were weak, which necessitates the improvement of optical properties. Thermal properties (weight loss, decomposition temperature, and glass transition temperature) of adhesives are linked to mechanical properties. Interfacial properties of the adherend and water vapor transmission rates of adhesives are linked to performance variation. For porous media (ceramics, brick, and stone), isothermal and isohumid environments are important. For outdoor artifacts on display in museums, changes in physical properties by exposure to varying environmental conditions need to be minimized. These results can be used as baseline data in the study of the degradation velocity and lifetime prediction of rapid-curing epoxy resin for the restoration of cultural heritages.

Reducing the Test Time for Chemical/Mechanical Durability of Polymer Electrolyte Membrane Fuel Cells (고분자연료전지의 화학적/기계적 내구성 평가 시간 단축)

  • Sohyeong Oh;Donggeun Yoo;Kim Myeonghwan;Park Jiyong;Choi Yeongjin;Kwonpil Park
    • Korean Chemical Engineering Research
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    • v.61 no.4
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    • pp.517-522
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    • 2023
  • A chemical/mechanical durability test of polymer membrane evaluation method is used in which air and hydrogen are supplied to the proton exchange membrane fuel cell (PEMFC) and wet/dry is repeated in the open circuit voltage (OCV) state. In this protocol, when wet/dry is repeated, voltage increase/decrease is repeated, resulting in electrode degradation. When the membrane durability is excellent, the number of voltage changes increases and the evaluation is terminated due to electrode degradation, which may cause a problem that the original purpose of membrane durability evaluation cannot be performed. In this study, the same protocol as the department of energy (DOE) was used, but oxygen was used instead of air as the cathode gas, and the wet/dry time and flow rate were also increased to increase the chemical/mechanical degradation rate of the membrane, thereby shortening the durability evaluation time of the membrane to improve these problems. The durability test of the Nafion 211 membrane electrode assembly (MEA) was completed after 2,300 cycles by increasing the acceleration by 2.6 times using oxygen instead of air. This protocol also accelerated degradation of the membrane and accelerated degradation of the electrode catalyst, which also had the advantage of simultaneously evaluating the durability of the membrane and the electrode.

Planning Accelerated Degradation Tests: the Case of Gamma Degradation Process (열화가 감마과정을 따르는 경우 가속열화시험의 최적 계획)

  • Lim, Heonsang;Lim, Dae-Eun
    • Journal of Korean Society for Quality Management
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    • v.43 no.2
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    • pp.169-184
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    • 2015
  • Purpose: This paper is concerned with optimally designing accelerated degradation test (ADT) plans based on a gamma process for the degradation model. Methods: By minimizing the asymptotic variance of the MLE of the q-th quantile of the lifetime distribution at the use condition, the test stress levels and the proportion of test units allocated to each stress level are optimally determined. Results: The optimal plans of ADT are developed for various combination of parameters. In addition, a method for determining the sample size is developed, and sensitivity analysis procedures are illustrated with an example. Conclusion: It is important to optimally design ADT based on a gamma process under the condition that a degradation process should be always nonnegative and strictly increasing over time.

열가속 열화에 따른 NBR의 산화반응과 기계적 특성

  • Kim, Ki-Yup;Kang, Hyun-Gu;Ryu, Boo-Hyung;Lee, Chung;Im, Ki-Jo
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2003.05a
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    • pp.434-439
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    • 2003
  • 원전 계통에서는 gas circulator, fuel handling system 등에 수 천여 개의 봉합(seal) 부위가 존재하며, 그 형상 또한 5 mm 에서부터 600 mm로 다양하다. 이러한 sealing 재료는 사용온도가 유리전이온도 이상인 열가소성 수지이며, 유연성 있는 segment의 조합으로 자유운동을 가지게 되는데 이러한 구조는 비교적 낮은 방사선 선량에 대해 취약하며, 원전계통에서는 NBR 및 ethylene-propylene 계열의 높은 내방사선 특성을 가지는 O-ring이 주로 사용되어지며, 10년을 교체시기로 주기적으로 교체하는 실정이다[2]. 이러한 seal 부위는 공정 전체에 걸쳐 다양한 열화요인에 노출되며, 최대 20$0^{\circ}C$의 온도, 압력 40 bar, 연간 1Gy~1MGy의 방사선에 노출된다.(중략)

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Planning of Accelerated Degradation Tests: In the Case Where the Performance Degradation Characteristic Follows the Lognormal Distribution (성능특성치의 열화가 대수정규분포를 따를 때의 가속열화시험 모형 개발)

  • Lim, Heonsang;Sung, Si-Il
    • Journal of Applied Reliability
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    • v.18 no.1
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    • pp.80-86
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    • 2018
  • Purpose: This article provides a mathematical model for the accelerated degradation test when the performance degradation characteristic follows the lognormal distribution. Method: For developing test plans, the total number of test units and the test time are determined based on the minimization of the asymptotic variance of the q-th quantile of the lifetime distribution at the use condition. Results: The mathematical model for the accelerated degradation test is provided. Conclusion: Accelerated degradation test method is widely used to evaluate the product lifetime within a resonable amount of cost and time. In this article. a mathematical model for the accelerated degradation test method is newly developed for this purposes.

Optimal Design of Accelerated Degradation Tests under the Constraint of Total Experimental Cost in the Case that the Degradation Characteristic Follows a Wiener Process (열화가 Wiener process를 따르는 경우의 비용을 고려한 가속열화시험 계획)

  • Lim, Heon-Sang
    • Journal of Korean Society for Quality Management
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    • v.40 no.2
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    • pp.117-125
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    • 2012
  • For the highly reliable products, an accelerated degradation test (ADT) is a useful tool which has been employed in industry to obtain reliability-related information within an affordable amount of time and cost. In an ADT, as all other reliability tests, it is important to carefully design the ADT beforehand to obtain estimates of the quantities of interest as precisely as possible. In this paper, optimal ADTs are developed assuming that the constant-stress loading method is employed and the degradation characteristic follows a Wiener process. Under the constraint that the total cost does not exceed a pre-specified budget, the stress levels, the number of test units allocated to each stress level and the number of measurement (termination time) are determined such that the asymptotic variance of the maximum likelihood estimator of the q-th quantile of the lifetime distribution at the use condition is minimized.

Optimal Design of Accelerated Degradation Tests with Two Stress Variables in the Case that the Degradation Characteristic Follows Weibull Distribution (열화특성치가 와이블분포를 따르는 경우 두 가지 스트레스 변수를 고려한 가속열화시험의 최적 설계)

  • Lim, Heonsang;Kim, Yong Soo
    • Journal of Applied Reliability
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    • v.13 no.2
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    • pp.87-98
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    • 2013
  • Accelerated degradation tests (ADTs) measuring failure-related degradation characteristic at the accelerated condition are widely used to assess the reliability of highly reliable products. Often, however, little degradation could be observed even in single-stress ADTs due to the high reliability of test unit, and as a result poor estimate of the reliability may be obtained. ADTs with multiple stress variables can be employed to overcome such difficulties. In this paper, optimal ADT plans with two stress variables are developed assuming that the degradation characteristic follows Weibull distribution by determining the stress levels, the proportion of test units allocated to each stress level such that the asymptotic variance of the maximum likelihood estimator of the q-th quantile of the lifetime distribution at the use condition is minimized.

Development of Reliability Acceptance Sampling Plan for the Case where the Degradation Quantity of the Performance Characteristic follows Weibull Distribution based on the Accelerated Degradation Test (성능특성치의 열화가 와이블 분포를 따를 때 가속열화시험을 활용한 신뢰성 샘플링검사계획의 개발)

  • Lim, Heonsang;Park, Jaehun;Sung, Si-Il
    • Journal of Applied Reliability
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    • v.18 no.2
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    • pp.122-129
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    • 2018
  • Purpose: This article develops an optimal reliability acceptance sampling plan for the case where the degradation quantity of the performance characteristic follows Weibull distribution. Method: For developing reliability acceptance sampling plans, the sample size and the acceptance constant are determined based on the accelerated characteristic of the test condition and the product. Results: The sample size and the acceptance constant are provided such that the constraints of the producer and the consumer risks are satisfied. Conclusion: Reliability acceptance sampling plans based on the accelerated degradation test method can be used for the quality control within a resonable amount of cost and time. In this article. an optimal reliability sampling plans are newly developed for this purpose.

A Study on the Electrical Characteristics by Accelerating Degradation for Traction Motor in Urban Transit EMU (전동차용 견인전동기의 가속열화에 의한 전기적 특성 연구)

  • Park, H.J.;Kim, G.D.;Jang, D.U.;Choi, J.S.;Kim, J.S.
    • Proceedings of the KIEE Conference
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    • 2002.07b
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    • pp.1235-1237
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    • 2002
  • Insulation system(200 class} for stator coil is designed for traction motor with VVVF inverter. Sample coils for stator of the traction motor were tested by accelerative thermal degradation which composed of heat, vibration, moisture, and overvoltage apply. Reliability and expected life were evaluated on the insulation system for 200 class traction motor. After aging of 10 cycles, tan ${\delta}$ increased with voltage. This result is due to increase of internal defects and change of insulation structure.

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Analysis of Influence for High Frequency voltage Accelerated Aging of XLPE Cable (고주파 전압이 XLPE cable의 가속열화에 미치는 영향 분석)

  • Kim, We-Young;Hu, Jong-Chul;Yun, Dae-Hyuk;Park, Tae-Gone
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.1670-1672
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    • 2004
  • XLPE compound have used for insulation of 22.9kV power cable. XLPE insulation is aged for use long time in distribution line. The cause of aging is water tree is happening and growth. Accelerated water tree test method are Accelerated volatge aging method and high frequency aging method. In this paper, high frequency accelerated water tree was performed. And the result was analysed AC breakdown voltage and size and number of water trees.

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