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Effect of graphite oxide on photodegradation behavior of poly(vinyl alcohol)/graphite oxide composite hydrogels

  • Moon, Young-E;Yun, Ju-Mi;Kim, Hyung-Il;Lee, Young-Seak
    • Carbon letters
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    • v.12 no.3
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    • pp.138-142
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    • 2011
  • Poly(vinyl alcohol) (PVA) composites with various graphite oxide (GO) contents (0 to 10 wt%) were prepared by sonicating the mixture of PVA and GO, followed by crosslinking with glutaraldehyde. GO was pre-treated with oxyfluorination ($O_2:F_2$ = 8:2) in order to modify the surface of GO to allow it to carry hydrophilic functional groups. PVA/GO composite hydrogels were characterized by scanning electron microscopy and Fourier-transform infrared spectrometer (FT-IR). The morphology of the PVA/GO composite hydrogels and the variations in soluble gel portion were investigated under various GO contents and UV irradiation doses. The variation in the chemical structure of photo degraded PVA/GO composite hydrogels was studied by FT-IR. The photochemical stability of PVA/GO composite hydrogels under UV irradiation was found to improve noticeably with increasing content of uniformly dispersed GO.

Time-to-go Polynomial Guidance Law for Target Observability Enhancement (표적 가관측성 향상을 위한 Time-to-go 다항식 유도법칙)

  • Kim, Tae-Hun;Lee, Chang-Hun;Tahk, Min-Jea
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.39 no.1
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    • pp.16-24
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    • 2011
  • In this paper, we propose a new guidance law for target observability enhancement, which can control both terminal impact angle and acceleration. The proposed guidance law is simple form, combined conventional time-to-go polynomial guidance and a additional bias term which consists of relative position and proportional gain. The guidance law provides oscillatory flight trajectory and it maintains the conventional time-to-go polynomial guidance performance. To investigate the characteristics of the guidance law, we derive the closed-form solution, and various simulations are performed for proving the validity of the proposed guidance.

The Study on Common Factors of Typical CFIT Accident with Go-around Failure and Go-around Gate Operation of Foreign Carriers (An Analysis of Korean CFIT Accidents through TEM) (복행실패로 발생한 CFIT사고의 공통요인 및 외항사 복행게이트 운영 실태에 대한 연구 (한국 대표적 CFIT사고의 TEM 분석을 중심으로))

  • Choi, Jin-Kook
    • Journal of the Korean Society for Aviation and Aeronautics
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    • v.22 no.3
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    • pp.15-23
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    • 2014
  • There have been CFIT(Controlled Flight Into Terrain) accidents that can be prevented if the crew executed go-around. This study is to analyse the common factors of three typical CFIT accidents of Korea in TEM(threat and error management) frame, and the examples of go-around gate and the countermeasures of eight airlines through the survey facilitating go-around to prevent CFIT. The common factors found in three typical CFIT accidents occurred in Korea or by Korean carriers turned out to be in mountainous terrain, in bad weather while in non-precision approach or circling approach by captain as PF(Pilot Flying) when crew make monitoring errors and communication errors. It also turned out that the crew in all three typical tragic CFIT accidents did not execute go-around in unstabilized approaches. The captains did not respond immediately when first officers advised them to go-around until it is too late. Seven out of eight Airlines answered that they use stabilized approach height as 1,000 feet to be stabilized earlier to have more safety margin by enhancing go-around gate regardless of the weather to prevent CFIT in the survey.

Dual-Mode Type Stop-and-Go Adaptive Blind Equalization Algorithm (이중모드 형태의 Stop-and-Go 적응 블라인드 등화 알고리즘)

  • 정영화;진용옥
    • The Journal of the Acoustical Society of Korea
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    • v.17 no.2
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    • pp.11-17
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    • 1998
  • 본 논문에서는 빠른 수렴 속도를 가지면서 정상 상태에서 작은 오차 레벨을 유지하 는 이중모드 형태의 Stop-and-Go 알고리즘을 제안한다. 제안된 알고리즘은 특별한 결정 영 역을 설정하여 등화기 출력 레벨이 어느 영역에 속하느냐에 따라 MCMA와 판정지향 알고 리즘을 결합한 변형된 Stop-and-Go 알고리즘과 기존의 Stop-and-Go 알고리즘의 동작을 자동 전환한다. 컴퓨터 모의실험 결과, 제안한 알고리즘이 CMA, MCMA 및 Stop-and-Go 알고리즘등과 같은 기존의 적응 블라인드 등화 알고리즘들에 비해 잔류 심볼간 간섭과 정상 상태로의 수렵 속도면에서 모두 우수한 성능을 가짐을 확인하였다.

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Photocatalytic Degradation of Methylene Blue in Presence of Graphene Oxide/TiO2 Nanocomposites

  • Kim, Sung Phil;Choi, Hyun Chul
    • Bulletin of the Korean Chemical Society
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    • v.35 no.9
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    • pp.2660-2664
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    • 2014
  • A simple method of depositing titanium dioxide ($TiO_2$) nanoparticles onto graphene oxide (GO) as a catalytic support was devised for photocatalytic degradation of methylene blue (MB). Thiol groups were utilized as linkers to secure the $TiO_2$ nanoparticles. The resultant GO-supported $TiO_2$ (GO-$TiO_2$) sample was characterized by transmission electron microscopy (TEM), near-edge X-ray absorption fine structure (NEXAFS), and X-ray photoelectron spectroscopy (XPS) measurements, revealing that the anatase $TiO_2$ nanoparticles had effectively anchored to the GO surface. In the photodegradation of MB, GO-$TiO_2$ exhibited remarkably enhanced photocatalytic efficiency compared with thiolated GO and pure $TiO_2$ nanoparticles. Moreover, after five-cycle photodegradation experiment, no obvious deactivation was observed. The overall results showed that thiolated GO provides a good support substrate and, thereby, enhances the photodegradation effectiveness of the composite photocatalyst.

ZnO on Thiolated Graphene Oxide as Efficient Photocatalyst for Degradation of Methylene Blue

  • Kim, Yu Hyun;Choi, Hyun Chul
    • Bulletin of the Korean Chemical Society
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    • v.34 no.12
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    • pp.3586-3590
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    • 2013
  • We present here an efficient and simple method for preparation of highly active heterogeneous ZnO photocatalyst (graphene oxide-zinc oxide: GO-ZnO), specifically by deposition of ZnO nanoparticles onto thiolated GOs. The resultant GO-ZnO sample was characterized by TEM, XRD, Auger, XPS, and Raman measurements, revealing that the size-similar and quasi-spherical ZnO nanoparticles were anchored to the thiolated GO surfaces. The average particle diameter was about 2.5 nm. In the photodegradation of methylene blue (MB) under ultraviolet (UV) light, GO-ZnO exhibited remarkably enhanced photocatalytic efficiency compared with thiolated GO and pure ZnO particles. This strong photocatalytic performance of GO-ZnO can be attributed to the suppression of electron recombination and the enhancement of mass transportation. The results showed that thiolated GO is the preferable supporting material.

Modulation of Rit Activation by the Alpha Subunit of Go

  • Yang, Chul-Min;Ghil, Sung-Ho
    • Biomedical Science Letters
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    • v.15 no.4
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    • pp.327-333
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    • 2009
  • Heterotrimeric GTP binding proteins, G-proteins, mediate signal transduction generated by neurotransmitters and hormones. Among G-proteins, Go proteins are the most abundant in brain and classified as a member of Gi family. Ras-like protein in all tissues (Rit), one of the small GTPases, is a member of a Ras superfamily and identified as an important regulator of neuronal differentiation and cell transformation. Recently, we have reported that Rit functioned as a candidate downstream effector for alpha subunit of Go proteins ($Go{\alpha}$) and regulated neurite outgrowth triggered by $Go{\alpha}$ activation. In this study, we showed that the GTPase domain of $Go{\alpha}$ contributed to the direct interaction with Rit. We also demonstrated that $Go{\alpha}$ could lead to an increase of Rit activity suggesting that Rit play a role as a downstream effector of $Go{\alpha}$.

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A Study on the performance Improvement of the Adaptive Blind Equalizer Using the Soft Decision-Directed Stop-and-Go Algorithm (연판정지향 Stop-and-Go 알고리즘을 이용한 적응 블라인드 등화기의 성능 향상에 관한 연구)

  • 정영화
    • The Journal of Information Technology
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    • v.2 no.1
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    • pp.103-113
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    • 1999
  • In this paper, we propose th soft decision-directed sto-and-go algorithm combining a concept of the stop-and-go algorithm with soft decision-directed algorithm. The proposed algorithm has an enhanced equalization performance according to using the more confidential error signal than two algorithms. By computer simulation, it is confirmed that the proposed algorithm has the performance superiority in terms of residual ISI and convergence speed compared with the adaptive blind equalization algorithm of CMA, Modified CMA(MCMA), Stop-and Go algorithm and simplified 50ft decision-directed algorithm.

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Characterization of few-layered reduced graphene oxide (rGO) for standardization (소수의 층을 갖는 환원 graphene oxide(rGO) 표준화를 위한 물성분석)

  • Ahn, Hae Jun;Huh, Seung Hun;Jee, Youngho;Lee, Byeong Woo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.6
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    • pp.239-245
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    • 2022
  • Reduced graphene oxide (rGO) has attracted many attention and applications due to its excellent electrochemical ability. Therefore, standardization of rGO through structural and thermal analysis facilitates quality improvement and management, enabling users to increase efficiency and reduce relevant costs. For rGO and graphene-related materials, it is very important to determine the number of layers and define the resulting difference in physical properties. In this study, 3~4 layers of rGO-1 and 9~10 layers of rGO-2 were obtained from graphene oxide (GO) through a hydrazine reduction process. For the prepared rGOs, X-ray diffraction (XRD) pattern obtained a diffraction peak at 2θ≈25° related to (002) reflection was used to calculate the layer numbers by determining interlayer distance and FWHM value. To reduce the angular uncertainty, XRD data analysis was performed with angle correction using standard reference materials for X-ray powder diffraction analysis. Precise interlayer distance and number of layers were determined using OriginLab and open-source XRD diffraction analysis programs using the angle-corrected diffraction data. TG-DSC thermal analysis was performed to further standardize the physical properties of rGO samples.