In this study, the experiment of the measuring of four different types of flooring materials' thermal characteristics was conducted and examined during the summer. The experimental materials were arranged on the existing slab of the roof, and then its thermal characteristics were examined from the point of view of thermal radiation analysis. The aim of this study is ultimately to draw the fundamental data for improvements in a building's thermal function and reduce the urban heat island phenomena through optimizing the thermal characteristics of the surface covering materials of a building. The results from this study are as follows; 1) Each experimental material's albedo was calculated as 0.83 on the aluminum panel, 0.40 on the rock block, 0.37 on the wood deck and 0.21 on the concrete. It shows that the concrete material, which has the lowest short wave reflective rate, absorbed the most radiation energy and the aluminium panel has absorbed the lowest radiation energy. 2) From the each experimental object's value of the long wave radiation, the concrete material measured the highest, at $628W/m^2$, and the aluminium panel measured the lowest at $412W/m^2$. Therefore, it verifies that the experimental objects' own radiation rate determines the amount of the long wave radiation. 3) The degree of energy absorbency of a building's surface covering materials is greatly influenced by its own albedo and radiation rate, Therefore, it needs to be considered for the improvements in a building's thermal function and reducing the urban heat island phenomena. 4) According to the evaluation result of the each experimental object's overall heat transmission screening function on the roof of a building, the wooden deck is proven to be an excellent material for excluding the outside temperature differences effectively with its characteristic of low heat capacity and conduction. Also its surface temperature on the roof slab and the temperature difference during the day were both measured at low.