As a new type of flame, tubular flame has attracted much attention from a fundamental viewpoint and many experimental and theoretical studies have been made on its characteristics. Recently, it is also recognized that the tubular flame has great potentials as practical combustor because its stability range is very wide in fuel concentration and also in injection velocity. Thus, tubular flame burners have been developed for various kinds of fuels. They are gaseous fuels of methane, propane, hydrogen, and by-product fuels gases in steel making processes including BFG (Blast Furnace Gas), LDG (LD Converter Gas), and COG (Cokes-Oven Gas), liquid fuels of kerosene, A-type and C-type heavy oils, and a solid fuel of biomass powder. In this paper, recent developments of the tubular flame burners have been briefly introduced.

Visualization has played an essential role in the development of our understanding of the complex unsteady flows associated with the initiation, propagation, and extinction of detonation waves. These methods and application to various aspects of detonation are illustrated by results obtained in my laboratory, particularly using combinations of the PLIF technique with other methods. Examples shown will include detonation initiation by projectiles, diffraction over ramps and steps, diffraction out of tubes, detonation implosion, and the cellular structure of detonation waves.

The meat consumption produces a lot of bone waste everyday. Dumping bone waste without treatment results into environmental hazards. Conventional treatment by pyrolysis is slow, inefficient and produces hazardous by-products. In the work, an investigation of bone waste incinerated using thermal plasma technology is presented. A high temperature arc plasma torch operated at 33 kW was employed for the experiments. Bone waste was incinerated to remove the infectious organic matter and to vitrify the inorganic matter using plasma torch. Bone waste was reduced its 2/3 weight after the treatment. The process was highly efficient, economical, convenient, and fuel free. This method could be used as an alternative method for disposal of bone waste, small infectious animals, hazardous hospital waste, etc.

본 연구는 Fuel-NOx 제어를 위한 암모니아 중 질소성분의 전환반응에 대한 실험 결과이다. 특히 열분해가스 촉매연소에서 NOx 생성을 줄이기 위한 제어 조건을 제시하였으며, Fuel-NOx 반응 메카니즘 연구의 기초자료를 제시하였다.

It has been observed in experiments that combustion instability of low frequency (${\sim}$ 10Hz) results form the modulation of equivalence ratio at fuel injection hole when a pressure fluctuation propagates upwards along the channel of the burner under an unchoked fuel flow condition. In this study, a commercial program was used to determine how the fuel flow rate changed with respect to the pressure, velocity of the fuel flow and the mass fraction in a choked and an unchoked condition. The calculation focus on the upstream of the dump plane to know how the forced pressure with the fuel injection conditions affects the modulation of the equivalence ratio. Therefore, it is found that pressure fluctuation leads to oscillation of mass flow rate and then results in equivalence ratio modulation under the unchoked fuel flow condition.

A simplified model of plastic layer and internal gas pressure In a coke oven is presented. We calculate internal gas pressure using presented model. And results are compared with calculated results using experimental data. Results show the difference of internal gas pressure by coal composition. The model is used to show that the permeability at the resolidification end of the plastic layer is a key determinant of the magnitude of the internal gas pressure.

A new and reusable energy source is water-treatment sludges. There is a significant need for understanding the characteristics of sludge combustion related to improving efficiency and ensuring the safety of this new energy source. Because sludges are composed of solids and gas mixture, the combustion of the mixture may become quite complex. Not only decomposition of conventional organic elements but also dust explosion may be important during the process of converting sludges into a new and safe form of energy. Sludge combustion mainly involves hydrogen, methane, hydro carbons, carbon, and organic particles. Dust explosion during the gasification stage may depend on the surrounding temperature and the composition of gases. The uncertainty in the explosive behavior of energetic source is noted in this work. We study the explosion characteristics of sludge combustion while the reusability of sewage sludges as a new form of energy is also investigated.

Extinction limits and combustion temperatures in heat-recirculating excess enthalpy reactors employing both gas-phase and catalytic reaction have been examined previously, with and emphasis Reynolds number (Re) effects and possible application to microscale combustion devices. However, Re is not the only parameter needed to characterize reactor operation. In particular, the use of a fixed reactor size implies that residence time and Re cannot be adjusted independently. To remedy this situation, in this work geometrically similar reactors of different physical sizes were tested with the aim of independently determining the effects of Re and Da. It is found that the difference between catalytic and non-catalytic combustion limits narrow as scale decreases. Moreover, to assess the importance of wall thermal conductivity, reactors of varying wall thickness were studied. From these results the effect of scale on microscale reactor performance and implications for practical microcombustion devices are discussed.

This study is measurement of radicals in gas & light oil diffusion flame focused on burner exit. The goal of this study is to analyse the relationship between flame chemiluminescence($OH^{\ast}$, $CH^{\ast}$, $C_2^{\ast}$) intensities and flame conditions. The investigation performed turbulent diffusion flame of commercial burner in varying the excess air ratio from 1.0 to 1.8. The optical emissions were measured by photomultiplier(PMT) using optical band pass filter and spectrometer system. The effects of excess air ratio and NOx emission characteristics on the radical emission intensities were investigated experimentally.

Propagation rates ($U_{edge}$) of various premixed, twin edge-flames were measured as a function of global strain rate ($\sigma$), mixture strength, and Lewis number (Le). Using a counterflow slot-jet burner with electrical heaters at each end, both advancing (positive $U_{edge}$) and retreating (negative $U_{edge}$) edge-flames can be studied as they propagate along the long dimension of the burner. Experimental results are presented for premixed methane/air twin flames in terms of the effects of $\sigma$ on $U_{edge}$. Both low-$\sigma$ and high-$\sigma$ extinction limits were discovered for all mixtures tested. As a result, the domain of edge-flame stability was obtained in terms of heat loss factor and normalized flame thickness, and comparison with the numerical result of other researchers was also made. For low ($CH_4/O_2/CO_2$) and high ($C_3H_8$/air) Lewis number cases, propagation rates clearly show a strong dependence on Le.

Experiments in methane-air low strain rate counterflow diffusion flames diluted with nitrogen have been conducted to study the behavior of flame extinction and edge flame oscillation in which flame length is less than the burner diameter and thus lateral conduction heat loss in addition to radiative heat loss could be remarkable at low global strain rates. Critical mole fraction at flame extinction is examined with velocity ratio and global strain rate. Onset conditions of edge flame oscillation and flame oscillation modes are also provided with global strain rate and added nitrogen mole fraction to fuel stream (fuel Lewis number). It is seen that flame length is closely relevant to lateral heat loss, and this affects flame extinction and edge flame oscillation considerably. Edge flame oscillations in low strain rate flames are experimentally described well and are categorized into three: a growing oscillation mode, a decaying oscillation mode, and a harmonic oscillation mode. The regime of flame oscillation is also provided at low strain rate flames. Important contribution of lateral heat loss even to edge flame oscillation is clarified.

The lifted oscillating flame has been studied using experiments of inverse diffusion flames that the air jet injected into a methane background. To find out the characteristics of inverse diffusion flames, fundamentally flame stabilized diagram is investigated with various air and fuel jet velocities. It has five regions - flame extinction, stable attached flame, anchored flame, liftoff flame and blow off region. In inverse diffusion flame, lifted flames were observed near the blow off region. As long as flames lift off, flames oscillate by periods. In this oscillating lifted flame region, the frequency of 1 and under were observed in various air and methane jet velocities. Characteristics of lifted flames are also examined by using the ICCD direct image. And intensity of flame chemiluminescence is very different in rising and falling period from photographs. For the present, it is predicted that the changes of flame structure are related with flame oscillation, but more experiments will be needed to make clear the phenomenon.

Radiative heat transfer is very important in many combustion systems since they are operated in high temperature. Fluid flows in most of the combustion systems are turbulent to promote fast mixing of the hydrocarbon fuel and oxidant. Major combustion products are $CO_2$ and $H_2O$. The turbulent flow is modeled by using the standard ${\kappa}-{\epsilon}$ model and the radiation transfer is modeled by using the discrete ordinates method where the radiative gas properties are calculated by using the weighted sum of gray gases model with a gray gas regrouping(WSGGM-RG). Effect of the radiation on the combustion characteristics in a three-dimensional rectangular enclosure is studied by changing the equivalence ratio. Results show that the radiation plays a significant role on the heat transfer in the combustion systems by resulting in a temperature drop of 16% as compared to that obtained without radiation. The equivalence ratio also affects the combustion by different contribution of the radiative transfer with different gas compositions.

This paper investigates the effects of acoustic forcing on NOx emissions and mixing process in the near field region of turbulent hydrogen nonpremixed flames. The resonance frequency was selected to force the coaxial air jet acoustically, because the resonance frequency is effective to amplify the forcing amplitude and reduce NOx emissions. When the resonance frequency is acoustically excited, a streamwise vortex is formed in the mixing layer between the coaxial air jet and coflowing air. As the vortex develops downstream, it entrains both ambient air and combustion products into the coaxial air jet to mix well. In addition, the strong vortex pulls the flame surface toward the coaxial air jet, causing intense chemical reaction. Acoustic excitation also causes velocity fluctuations of coaxial air jet as well as fuel jet but, the maximum value of centerline fuel velocity fluctuation occurs at the different phases of $\Phi$=$180^{\circ}$ for nonreacting case and $\Phi$=$0^{\circ}$ for reacting case. Since acoustic excitation enhances the mixing rate of fuel and air, the line of the stoichiometric mixture fraction becomes narrow. Finally, acoustic forcing at the resonance frequency reduces the normalized flame length by 15 % and EINOx by 25 %, compared to the flame without acoustic excitation.

This work forcus on the development of gas sensor that measure the concentrations of exhaust gas using diode laser. Each diode laser for exhaust gas measurement is set to work at near-IR using both DA and WMS methods. Also use of fiber-coupled optical elements makes such a sensor rugged and easy to align. On-line data acquisition and processing can be performed with a PC running LabVIEW software, and absorption signals are measured simultaneously by multiplexing method. Finally, It were experimentally compared WMS (Wavelength Modulation Spectroscopy) with DA (Direct Absorption) for the accuracy.

Improvements in internal combustion engine and aftertreatment technologies are needed to meet future environmental quality goals. Plasmatron fuel converters provide a rapid response, compact means to transform a wide range of hydrocarbon fuels (including gasoline, natural gas and diesel fuel) into hydrogen-rich gas. Hydrogen-rich gas can be used as an additive to provide NOx reductions of more than 80% in diesel engine vehicles by enabling very lean operation or heavy exhaust engine recirculation. For diesel engines, use of compact plasmatron reformers to produce hydrogen-rich gas for the regeneration of NOx absorber/absorbers and particulate traps for diesel engine exhaust after-treatment could provide significant advantages. Recent tests of conversion of diesel fuel to hydrogen-rich gas using a low current plasmatron fuel converter with non-equilibrium plasma features are described.

A new measurement technique based on a two-color pyrometry and modulated LII signals to measure local soot particle temperatures has been proposed and examined experimentally. The theoretical review suggests that modulated LII signals of soot particles is suitable for a two-color pyrometry as long as the temperature increase due to laser heating remains relatively small. The modulated LII signals from ethylene and propylene diffusion flames were simultaneously measured at 550 and 750 nm by a dual measurement system that consists of optical fibers, PMT and lock-in amps. The local soot particle temperatures of diffusion flames could be obtained using a two-color pyrometry and modulated LII signal based new technique.

Non-thermal plasma technology has many applications in various areas. One of the applications is regenerating diesel particulate filter (DPF). DPF is a widely applied device to control the particulate emission of diesel engines. But it needs periodic removal of clogged soot for the smooth running of engine. Conventional high-temperature removal processes easily leads to the breakage of DPF. Herein, low-temperature plasma formed in a dielectric barrier discharge (DBD) reactor was used to form active oxidants such as ozone and nitrogen dioxide. Experimentally, the effects of discharge power and frequency on the performance of DBD reactor were studied. Two oxidants, $O_3$ and $NO_2$, were synthesized and used for incinerating soot in the used DPF. Performances of the two oxidants on the reduction of soot were compared, and it was found that $NO_2$ is more effective than $O_3$ for getting rid of soot

The objective of this research is to determine generally applicable design principles for the development of Rapid mix burner. Details operating RMB(Rapid mix burner) is designed that thermal NOx and prompt NOx formation be reduced through control of low peak flame temperature, and nearly uniform flame temperature by rapid mixing at the ignition point. Results from RMB(Rapid mix burner) achieving lower than 43 ppm NOx emissions and nearly flame temperature uniform

Influence of changing combustor pressure on flame stabilization and nitrogen oxide (NOx) emission in the swirl-stabilized flame with secondary fuel injection was investigated. The combustor pressure was controlled by suction at combustor exit. Pressure index ($P{\ast}=P_{abs}/P_{atm}$), where $P_{abs}$ and $P_{atm}$ indicated the absolute pressure and atmosphere pressure, was controlled in the range of $0.7{\sim}1.3$ for each equivalence ratio conditions. The flammable limits of swirl flames were largely influenced by changing combustor pressure and they showed different tendency compared with laminar flames. Emission index showed maximum value near atmospheric condition and decreased with decreasing pressure index for overall equivalence ratio conditions. R.m.s of pressure fluctuations also showed similar tendency with nitric oxide emission. By injecting secondary fuel into flame zone, the flammable limits were extended significantly. Emission index of nitric oxide and r.m.s. of pressure fluctuations were also controlled by injecting secondary fuel. The swirl flames were somewhat lifted by secondary fuel with high momentum, hence low nitric oxide emission. This NOx reduction technology is applicable to industrial furnaces and air conditioning system by adopting secondary fuel injection.

Oil-fired power plants usually use several burners and the combustion air is supplied to each burner through the complicated duct which is called windbox. A windbox should be designed to supply combustion air to each burner evenly but, due to the complicated duct shape, flow distribution in the windbox is unbalanced and uneven supplies of combustion air to each burner are induced by these unbalanced flow distribution in the windbox. These flow patterns tend to make flame unstable, increase the formation of pollutants and lower the overall combustion efficiency. To prevent these disadvantages, flow patterns in the windbox should be investigated for the uniform flow distribution. In this study, computational simulation method was used to investigate the flow distribution in the windbox and measured the velocities at the exit of burners in the real windbox to compare with CFD results. The results show two significant flow patterns. One is that the flow rates of each burner are different from each other and this means that all burners operate in different conditions of air to fuel ratio. The other is that the flow distribution at the exit of each burner is not axi-symmetric although the burner shape is axi-symmetric and this increases the pollutant products like CO.

At the furnace top, the distribution of charging coke and ore is adjusted to control the reducing gas flow distribution in the furnace. It is necessary to predict operation condition of blast furnace according to the burden profile to judge whether charging is properly conducted In this study, We propose the model for predicting while layer structures whithin furnace when top burden profile was given. Layer structure of coke and ore could be predicted by top burden profile and solid velocity. Solid velocity is assumed as potential flow. Potential function distribution and timeline are also calculated using solid velocity field. The Calculation is conducted for different burden profile cases. As the result burden distribution and grid structure, which is deformed to match the layer structure in shaft and deadman profile. Gas flow was calculated using this grid, and calculated results are compared with each other.

The large amount of energy is consumed in a process for keeping the high temperature melting pool. For this reason, in addition to the wastes input to keep the high temperature melting pool, it is necessary for an auxiliary fuel and LOx to throw into the melting pool. So in this study, using a new melting furnace system, the experiments to keep the melting pool with minimal energy without throwing an auxiliary fuel and LOx was carried out. Also it is hoped that the results of the experiment will be available to analyze keeping a melting pool and behavior in a melting furnace.

Gasification and melting method is one of the most potential means for waste treatment process with low emission of fly ash or heavy metal, dioxin and high possibility of using slags as resources. Moisture contents influences directly a gasification characteristics of waste. So it is necessary to investigate the effect of moisture contents in gasification. But it is hard to consider the effect of moisture contents, using samples of powder form of Milligram's order in existing thermogravimetric analyser. Therefore, we made a thermogravimetric analysis device to applicate samples of Gram's order. Gasification characteristics are typically reported with result from thermogravimetric analysis date for wood and RDF samples along with changing moisture contents. It is discussed the way to apply these analysis results to gasification and melting furnace.

In this project, we studied more accurate and reliable sensing method for oxygen in reheating furnace, made the empirical model for NOx concentration based on oxygen and evaluate the stability of the Tuneable Diode Laser (Absorption) Spectroscopy(TDL(A)S). The tested oxygen monitoring system is installed at work-field reheating furnace on hot roll at POSCO and compared with the Zr sensor system which shows too sensitive because it measures oxygen concentration on a spot unlike TDLS sensor which is successfully applied at 13m-width reheating furnace to measures the line average along the Optical Path Line(OPL).

A pilot scale (200kg/hr) pyrolysis melting incineration system is designed and constructed in Korea Institute of Industrial Technology. The incineration process is composed of pyrolysis, gas combustion, ash melting, gas stabilization, waste heating boiler, and bag filter. For each unit process, experimental approaches have been conducted to find optimal design and operating conditions. Especially, a pyrolysis is very important process in that it is a way of energy recirculation and minimizing the waste products. This paper presents major results of the most efficient operating conditions in a pilot scale pyrolysis melting incinerator.

Flame surface area is a critical parameter determining turbulent flame speed. Three-dimensionaldirect numerical simulations (DNS) were conducted to figure out the evolution process of flame surface area. Fully compressible Navier-Stokes equations are solved to reproduce premixed flame embedded in isotropic decaying turbulent flow. The tangential straining and curvature of propagating surface affect development of flame area. In this study, four different turbulent intensity flows and three different Le number flames are investigated to force changes in straining and curvature effects. Consistent results are obtained for the probability density functions (PDF) of strain and curvature with previous researches. It is revealed that displacement speed, which is a speed of flame surface relative to unburnt flow, controls the balance between sink and source of flame surface area.

In this work, we introduce a newly constructed arc-jet device of 150 kW input power. The design of this device is a Huels type with a narrow downstream electrode. General features of this device are first described. From the measured values of electrical power input, heat discharged into cooling water, gas flow rate, and settling chamber pressure, average enthalpy was determined using the heat balance and sonic throat methods. Using the settling chamber pressure and average enthalpy values, the flow properties in the nozzle and the heat transfer rate to the stagnation point of a blunt body are calculated accounting for thermochemical nonequilibrium. The envelope of enthalpy, pressure, degree of dissociation, and heat transfer rate are presented. Stagnation temperature is predicted to be between 4630 to 6050 $^{\circ}K$, and the stagnation point heat transfer rate is predicted to be between 175 and 318 W/$cm^{2}$ for a blunt body of 3 mm nose radius. Degree of dissociation in the stagnation region of the blunt body exceeds 30%.

Silica(SiO2) nanoparticles are used as additives in plastics and rubbers to improve mechanical, electrical, magnetic properties and optical material. Silica nanoparticles were synthesized by the gas phase thermal oxidation of several kinds of precursors in many types of reactor. Diffusion flame reactor has some advantages compared with other types of reactors. In this study, we investigated the generation of silica nanoparticles on the effect of residence time by tetraethylothosilicate(TEOS) in a turbulent diffusion flame reactor controlled by providing reactant flowrate and reactor geometry affect particle morphology, particle size and particle size distribution. To determine the flame residence time, flame length should be determined which was examined by ICCD image. Particle size, distribution and morphology were performed with TEM.

The purpose of this research is to model numerically the turbulent gas-particle flows in a rectangular chamber using Eulerian-Eulerian Method. A computer code using the ${\kappa}-{\varepsilon}-Ap$ two-phase turbulence model is developed for the numerical study. This code and the Eulerian multiphase model in FLUENT were used for the numerical simulations of the two-phase flow in a rectangular chamber. The numerical results calculated by the two different turbulent gas-particle codes have shown that the ${\kappa}-{\varepsilon}-Ap$ model results in a stronger diffusion of the flow momentum in the gas-particle turbulence interaction than the Eulerian multiphase model in FLUENT.

The supersonic combustion experiments are carried out using T3 free-piston shock tunnel. Different shock tube fill pressures have various inflow conditions. $15^{\circ}$ inclined hydrogen fuel injection is located before the cavity. Oblique shock is generated at the trailing edge of the cavity and reflects off the top and bottom wall. For non-reacting flow, static pressures in low equivalence ratio are similar to those in no fuel injection. As equivalence ratio is increased, static pressures are increased in the duct. In the similar equivalence ratio, static pressures are increased when total enthalpy is decreased. For reacting flow, the flame is occurred near the cavity. The combustion is weak locally in the middle of the duct. The up and down pressure distribution in the duct means that the supersonic combustion is generated.

The effect of electric fields on the propagation speed of tribrachial flames has been investigated in a coflow jet by observing the transient flame propagation behavior after ignition. Without having electric fields, the propagation speed of tribrachial flame edges showed a typical behavior by having an inverse proportionality to the mixture fraction gradient at the flame edge. The behavior of flame propagation with the electric fields was investigated by applying high voltage to the central fuel nozzle and the enhancement of propagation speed has been observed by varying the applied voltage and frequency for AC electric fields. The propagation speed of tribrachial flame was also investigated by applying negative and positive DC voltages to the nozzle and similar improvements of the propagation speed were also observed. The propagation speeds of tribrachial flames in both the AC and DC electric fields were correlated well with the electric field intensity, defined by the electric voltage divided by the distance between the nozzle electrode and the edge of tribrachial flames.

The oxy-fuel combustion heating characteristics is investigated experimentally by measuring furnace and steel temperature variations for batch type furnace simulator with a specially designed low NOx oxy-fuel burner. Economics of using oxy-fuel combustion is confirmed and, the furnace and steel temperature variations for different heating conditions are compared to deduce optimal heating control pattern for energy savings and rapid uniform heating. High $CO_2$ concentration (> 80-90%), low NOx (< 40ppm) and CO (< 10ppm) are measured in the flue gas. Temperature differences (< $30^{circ}C$) inside the furnace and steel are reduced relatively by increasing the burner jet momentum.

Catalytic combustion is one of the suitable methods for micro power source due to high energy density and no flame quenching. Catalyst loading in the micro structured combustion chamber is one of the most important issues in the development of micro catalytic combustors. In this research, to coat catalyst on the chamber wall, two methods were investigated. First, $Al_2O_3$ was selected as a support of Pt and $Pt/Al_2O_3$ was synthesized through the alumina sol-gel procedure. To improve the coating thickness and adhesion between catalyst and substrate, heat resistant and water solvable organic-inorganic hybrid binder was used. Porous silicon was also investigated as a catalyst support for platinum. Through the parametric studies of current density and etching time, fabrication process of $1{\sim}2{\mu}m$ of diameter and about $25{\mu}m$ depth pores was confirmed. Coated substrates were test in the micro channel combustor which was fabricated by the wet etching and machining of SUS 304. Using $Pt/Al_2O_3$ coated substrate and Pt coated porous silicon substrate, conversion rate of fuel was over 95% for $H_2$/Air premixed gas.

The impacts of equivalence ratio on the flow structure and flame dynamics in a model gas turbine combustor are investigated using large eddy simulation(LES). Dynamic k-equation model and G-equation flamelet model are employed as LES subgrid model for flow and combustion, respectively. As a result of mean flow field for each equivalence ratio, the increase of equivalence ratio brings about the decrease of swirl intensity through the modification of thermal effect and viscosity, although the same swirl intensity is imposed at inlet. The changes of vortical structure and turbulent intensity etc. near flame surface are occurred consequently. That is, the decrease of equivalence ratio can leads to the increase of heat release fluctuation by the more increased turbulent intensity and fluctuation of recirculation flow. In addition, the effect of inner vortex generated from vortex breakdown on the heat release fluctuation is increased gradually with the decrease of equivalence ratio. Finally, it can be identified that the variations of vortical structure play an important role in combustion instability, even though the small change of equivalence ratio is occurred.

The effect of DC electric fields on the flame extinction was investigated experimentally in counterflow configurations for the methane/oxygen/nitrogen diffusion flame. The electric fields was applied by connecting the high voltage and ground terminals to the upper and lower burners, respectively. In case of having electric fields, several modes of flame extinction was observed according to the electric field intensity and strain rate defined by the exit velocity. To visualize and characterize the flame structure and intensity, planar LIF technique was adopted for OH radicals. Consequently, several length scales, including the flame width, thickness, and height from the burner tip, were introduced to explain the various flame behaviors and to characterize the flame extinctions. It was found that the variation of flame width and the chemical reaction are strongly related to a critical electric field intensity, thus the various modes of diffusion flame extinction could be observed due to the electric fields.

An experimental study on the catalytic reformer adopted in the auxiliary power unit system of solid oxide fuel cell was conducted. A 3-fluid nozzle, by which liquid fuel such as diesel, water and air are sprayed and uniformed mixed, was designed and used in this study. An electrically heated monolith inserted in the reformer was used for the vaporization of fuel and water in the transient state of reformer. The reformer uses the partial oxidizing reaction at the catalyst and the supply of water prevents the flame combustion in the spraying zone and lessens the deactivation of catalyst. The result showed that the reforming of liquid fuel can be started by the electrically heated monolith and the 3-fluid nozzle can give the uniform mixing of fuel, water and air. It was also found that the reformer fueled by n-hexadecane can make the reformate, at best, containing $H_2$ at 15.5% and CO at 11.5% that are used as fuel in the solid oxide fuel cell.

Characteristic of partial oxidation of methane using arc-jet plasma by AC power is investigated. Arc-jet reactor used in this work is slightly modified from typical arc jet reactor so that it can make and sustain stable state of plasma. Methane conversion, selectivity of chemicals such as hydrogen and hydrocarbon materials in the product are analyzed. Parametric approach on the performance of the reactor or detail on the partial oxidation process is carried with $O_2/C$ ratio as parameter. In addition to the results, SED and arc length is changed to understand the effect of current-voltage correlation on the reforming performance and relative role of thermal process.

Although fireside corrosion of heat transfer surfaces in coal fired steam generators has been a problem to some extent for a number of tears, with the advent of low NOx firing systems these surfaces can be exposed to conditions that will exacerbate wastage rates. Numerous reports of waterwall wastage in coal fired boilers have appeared in the literature. It is believed that wastage results both from gaseous phase attack of metal surfaces and from deposition of ash and unburned fuel. Gaseous phase attack is known to occur in the presence of reducing sulfur species such as $H_2S$ and in the presence of fuel chlorine. The highest wastage rates are thought to be due to deposition of unoxidized material and the presence of fuel chlorine. Localized wall and near wall conditions that may exacerbate wastage include reducing conditions, high temperatures, high heat fluxes, and a high fraction of unoxidized material deposited. So, this study is directed at developing an advanced corrosion model in coal-fired utility boilers.

Various kinds of coals are supplied for coal fired power plants as the coal market situations are fluctuated with the high prices of oil and coals over the world. The quality of coal is decreasing as coal consumption increased and some specifications of coals are out of boiler design criteria. It could make combustion troubles such as coal clogging, spontaneous combustion, coal firing in the coal handling equipments, ash slag and clinker issues, etc. This paper covers combustion troubles, issues and countermeasures in the biggest coal fired power plant in Korea.

There are many researches in progress on co-firing of coal and biomass to reduce carbon dioxide produced from the coal consumption. This study carried out 200 Kg/h combustion test furnace by mixing coal with timber. Coal was mixed with domestic and imported-wood around 10% to 20% based on input energy. For the mixed fuel, combustion temperature, unburned carbon and the composition of flue gas were analyzed. In addition, the tendency of slagging and fouling was examined using a probe. According to the result of the experiment, combustion temperature was depended on the kind of wood and mixing ratio. The unburned carbon loss was higher with increase of wood biomass mixing ratio, as a result, the total heat loss of furnace was slightly increased. The emission of NOx and SOx were decreased by $3{\sim}20%$ and $21{\sim}60%$ respectively. There are no difference of slagging and fouling tendency between biomass co-firing and coal burning only.

From the analysis of fly ash, which contains unburned carbon, collected from the coal-fired Yong Hung power station, most particles are turned out to be hollow cenosphere and agglomerated soot particles. The sooting potential from six coals used in the plant were investigated with CPD model. The results show that the higher potential presented to Peabody, Arthur, Shenhua coals rather than other coals. It is necessary to measure the coal flow rates at each coal feeding pipe for four burner levels since they affect the extent of mixing of soot with oxidant, in turn, the oxidation rate of soot particles. The unbalance in coal flow rate was found in several coal pipes. We successfully reduced unburned carbon in ash by increasing the excess air and changing the SOFA yaw angle.