• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.187-187
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• 2012

In this report, the plasmonic nanopores of less than 5 nm diameter were fabricated on the apex of the pyramidal cavity array. The metallic pyramidal pit cavity can also utilized as the plasmonic bioreactor, and the fabricated Au or Al metallic nanopore can provide the controllable translocation speed down using the plasmonic optical force. Initially, the SiO2 nanopore on the pyramidal pit cavity were fabricated using conventional microfabrication techniques. Then, the metallic thin film was sputter-deposited, followed by surface modification of the nanometer thick membrane using FESEM, TEM and EPMA. The huge electron intensity of FESEM with ~microsecond scan speed can provide the rapid solid phase surface transformation. However, the moderate electron beam intensity from the normal TEM without high speed scanning can only provide the liquid phase surface modification. After metal deposition, the 100 nm diameter aperture using FIB beam drilling was obtained in order to obtain the uniform nano-aperture. Then, the nanometer size aperture was reduced down to ~50 nm using electron beam surface modification using high speed scanning FESEM. The followed EPMA electron beam exposure without high speed scanning presents the reduction of the nanosize aperture down to 10 nm. During these processes, the widening or the shrinking of the nanometer pore was observed depending upon the electron beam intensity. Finally, using 200 keV TEM, the diameter of the nanopore was successively down from 10 nm down to 1.5 nm.

• Journal of the Korean Geotechnical Society
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• v.21 no.3
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• pp.119-131
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• 2005

Seepage analysis through unsaturated zone based on the theory of unsaturated flow is commonly performed to evaluate dam safety. However, the concepts of unsaturated soil behavior have not been transferred into the hands of practicing geotechnical engineers since the problems involving unsaturated soils often have the appearances of being extremely complex. The behavior of dam such as seepage rate and the pore water pressure distribution is different according to the unsaturated hydraulic properties, but nevertheless simply assumed properties have been used due to insufficient data from domestic soils. In this paper, the effect of unsaturated hydraulic properties on the behavior of dam was studied through a series of numerical analyses, and then the results were discussed. It is observed that water table moves at a (aster rate, as the values of unsaturated soil parameter a and n increase. The value of m showed opposite trend. The sensitivity calculated using the approximation form showed maximum values near the water table. And the value of n that is related to the slope of soil water characteristic curve gives greatest influence on the change of sensitivity with time.

• Journal of the Korean Geotechnical Society
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• v.21 no.3
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• pp.133-140
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• 2005

In order to accelerate the rate of consolidation settlement and gain a required shear strength for a given soft clay deposit, vertical drain method combined with a preloading technique has been widely applied. In this paper, a theory of axisymmetric nonlinear consolidation fer drainage-installed deposit, which considers secondary compression (or creep) during primary consolidation, as well as the variations of compressibility and permeability during the consolidation process, has been developed. A computer program named AXICON based on Hypothesis B fur the analysis of axisymmetric nonlinear consolidation was developed by adopting finite difference method. The results of AS(ICON were compared with Hansbo's solution based on Hypothesis A, as well as in-situ settlements and pore pressures measured in test embankment of Ska-Edeby. The results indicated that Hypothesis A usually underestimated the in-situ settlement and Hypothesis B was considered to be logically correct. It was also shown that one may able to appropriately predict the real in-situ behaviors using the proposed program.

• Journal of the Korean Geotechnical Society
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• v.21 no.4
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• pp.135-143
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• 2005

This paper presents a case history of a geosynthetics-reinforced segmental retaining wall, which collapsed during a severe rainfall immediately after the completion of the wall construction. In an attempt to identify possible causes for the collapse, a comprehensive investigation was carried out including physical and strength tests on the backfill, stability analyses on the as-built design based on the current design approaches, and slope stability analyses with pore pressure consideration. The investigation revealed that the inappropriate as-built design and the bad-quality backfill were mainly responsible for the collapse. This paper describes the site condition including wall design, details of the results of investigation and finally, lessons learned. Practical significance of the findings from this study is also discussed.

• Applied Chemistry for Engineering
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• v.28 no.4
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• pp.473-478
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• 2017

In this study, the guanidine compound, 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) was impregnated to three kinds of silica to prepare $CO_2$ adsorbents, and the $CO_2$ adsorption and physicochemical properties of the resulting adsorbents were investigated. The TBD amount of impregnation was changed and its effect on adsorption capacity and characteristics were studied. The physicochemical properties of TBD-impregnated silica were evaluated with $N_2$ adsorption/desorption, FT-IR, elemental analysis, and thermogravimetric analysis. The TBD-impregnated silica lowered the surface area and pore volume, and the increased impregnation amount of TBD made them further decrease. When TBD was 6 mmol/g, the $CO_2$ adsorption capacity was the highest at 7.3 wt%, and the adsorption capacity decreased due to the blocking phenomenon when the TBD amount increased.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.17 no.1
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• pp.21-30
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• 2007

To establish the Fourier-transform infra-red spectrophotometry (FTIR) direct-on-filter(DOF) technique as a useful analytical method for quartz in respirable dust samples, influence of the interference should be corrected. This study was designed to compare three methods of correction for cristobalite when quantifying the content of quartz, including the least square, the optimum choice and the spectral subtraction methods. Respirable dust, created in a dust chamber containing the standard material of quartz, cristobalite was collected using a cyclone equipped with a 25 mm, $0.8{\mu}m$ pore size DM filter as a collection medium. The quartz weights overestimated about 100% when mixed of cristobalite by measure using 799 cm-1 absorption peak of quartz. The quartz weights appeared over estimated by optimum choice, spectral subtraction and least square method in mixtures of 33% cristobalite were 90.3%, 60.1% and about 4.3%, respectively. The least square method have been adopted to correction methods of cristobalite and satisfactory results have been obtained. The results of this study suggest that, when correcting for effect of cristobalite on quantitative analysis of quartz in respirable dust by FTIR direct-on-filter method, the least square method produce the most unbiased results compared with those of other correction methods.

• Membrane Journal
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• v.21 no.2
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• pp.171-176
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• 2011

Membrane fouling is formed due to pore blocking and cake formation by suspended material or contaminant in the membrane boundary layer. Membrane fouling is main obstacle for the wider application of industrial water treatment. The objective of this paper is to study the direct monitoring technique for the measuring the membrane fouling in real time. We investigated the extracted image of R, G, and B by visible light irradiation of 360 nm wavelength to measure the membrane fouling in real time by transparent foulant. The intensity of B of 400~499 nm wavelength range was stronger than that of R and G. The fluorescence image extraction analysis appeared to be a very attractive technique for monitoring the membrane fouling in real time.

• Journal of Korean Tunnelling and Underground Space Association
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• v.7 no.2
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• pp.97-108
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• 2005

This paper presents the effect of tunneling and groundwater interaction on tunnel behavior. As part of this study, design issuses for tunneling situations similar to that considered in this study are first identified. A parametric study is then conducted on tunneling situations frequently encountered in Seoul area using a 3D stress-pore presure coupled finite-element model with emphasis on the effects of ground and lining permeabilities. The results indicate that tunneling in water bearing ground results in a deeper and wider settlement trough, increased axial thrusts in shotcrete lining than those without the groundwater. Also revealed is that the axial thrusts in shotcrete lining are governed by the relative permeability between the ground and the lining. Design implications of the findings from this study are discussed.

• Journal of Powder Materials
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• v.20 no.5
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• pp.350-354
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• 2013

In this study, porous titanium samples were manufactured by space holder methods using two kinds of urea and sodium chloride space holders. Three-dimensional pore structures were obtained by a computed-tomography (CT) technique and utilized for finite element analysis in order to investigate the mechanical properties. The CT-based finite element analyses were in better agreement with the experimental results than unit cell model-based analyses. Both the experimental and CT-based results showed the same tendency that the elastic modulus decreased with increasing the porosities. The total porosity of the bulk body plays a key role in determining the elastic modulus of porous materials.

• Journal of the Korean Geotechnical Society
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• v.31 no.5
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• pp.67-74
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• 2015

Unlike the primary consolidation settlement, the settlement of ground water lowering is not considered separately because of relatively small residual settlement. But the allowed residual settlement (30 mm) of the concrete track in the high-speed railway may be exceeded due to unexpected excessive ground water lowering. This study analyzed the effect of the settlement according to the ground water level change using finite element analysis of stress-pore pressure coupling model, and compared the analysis results with the measured data. As a result, the range of elasticity modulus satisfying the allowable settlement was proposed, and it is suggested that settlement due to ground water level changes should be reflected in the design.