• Journal of the Korean Applied Science and Technology
• /
• v.34 no.4
• /
• pp.799-806
• /
• 2017

The potential use of modified clays in the adsorption of vapor phase benzene and toluene was investigated. The modified clays OC-CPC, IOC, and Al-PILC were prepared for comparative purposes and were characterized using infrared spectroscopy, thermogravimetric analysis, and X-ray diffraction. It was confirmed the intercalation of the aluminium pillar in IOC and Al-PILC, as well as the introduction of cetylpyridinium. The adsorption studies showed a great affinity of benzene and toluene for OC-CPC due to the hydrophobic character that resulted and also to the increase in the interlaminar distance. IOC showed a lower affinity for the benzene and toluene, followed by Al-PILC. Natual clay had no affinity for benzene and toluene due to its hydrophilic nature. Clay materials having a laminar structure can be chemically modified, changing their physiochemical characteristics, such as interlaminar distance, surface area, pore size, and chemical affinity. In this study, it was focused on obtaining modified clays to be used for the adsorption of volatile organic chemicals.

• Journal of the Mineralogical Society of Korea
• /
• v.32 no.3
• /
• pp.185-200
• /
• 2019

This study aimed to liberate gold from invisible gold concentrate (Au = 1,840.00 g/t) through microwave nitric acid leaching experiments. For the purpose, this study conducted microwave-nitric acid leaching experiments and examined nitric acid concentration effect, microwave leaching time effect and sample addition effect. The results of the experiments were as follows: Au (gold) contents were not detected in all of the microwave leaching conditions. In the insoluble-residue, weight loss rate tended to decrease as the nitric acid concentration, microwave leaching time and sample addition increased. In an XRD analysis with solid-residue, it was suggested that gypsum and anglesite were formed due to dissolution of calcite and galena by nitric acid solution. When a fire assay was carried out with insoluble-residue, it was discovered that gold contents of the solid-residue were 1.3 (Au = 2,464.70 g/t) and 28.8 (52,952.80 g/t) times more than those of concentrate. But in the gold contents recovered, a severe gold nugget effect appeared. It is expected that the gold nugget effect will decrease if a sampling method of concentrate is improved in the microwave-nitric acid leaching experiments and filtering paper with smaller pore size is used for leaching solution and burned filter paper is used for sampling in lead-fire assay.

• Membrane Journal
• /
• v.29 no.1
• /
• pp.51-60
• /
• 2019

In order to improve gas separation properties of polymeric membranes which have been widely applied in the industry field, aluminosilicate hollow nanoparticles named as allophanes were synthesized by sol-gel method and formulated in Poly(dimethylsiloxane) (PDMS) matrix to investigate the gas separation properties of PDMS membrane. Transmission electron microscope (TEM), Energy dispersive X-ray analysis (EDX), X-ray diffractometer (XRD), Surface area and pore size analyzer (BET) and Fourier transform infrared spectrophotometer (FTIR) were carried out to characterize the synthetic allophanes. Then the PDMS mixed matrix membranes were prepared by adding different volume fraction of allophanes. To examine the effect of allophanes addition in PDMS matrix using unmodified allophane and modified ones, the gas permeation experiments were performed using oxygen, nitrogen, methane and carbon dioxide. As the volume fraction of modified allophane increased up to 4.05 Vol% the permeability of four test gases through PDMS mixed matrix membranes increased. Also, the selectivity of $O_2/N_2$ and $CO_2/CH_4$ increased with the contents of the modified allophane. Further improvement of gas separation properties of PDMS mixed matrix membranes containing higher volume percent of allophanes can be expected as long as well dispersion of allophanes in PDMS matrix can be achieved for better PDMS membranes.

• Journal of Electrochemical Science and Technology
• /
• v.9 no.4
• /
• pp.282-291
• /
• 2018

The pristine fluorine-doped $SnO_2$ (abbreviated as FTO) inverse opal (IO) was developed using a 410 nm polystyrene bead template. The nanolayered copper tungsten oxide ($CuWO_4$) was decorated on the FTO IO film using a facile electrochemical deposition, subsequently followed by annealing at $500^{\circ}C$ for 90 min. The morphologies, crystalline structure, optical properties and photoelectrochemical characteristics of the FTO and $CuWO_4$-decorated FTO (briefly denoted as $FTO/CuWO_4$) IO film were investigated by field emission scanning electron microscopy, X-ray diffraction, UV-vis spectroscopy and electrochemical impedance spectroscopy, showing FTO IO in the hexagonally closed-pack arrangement with a pore diameter and wall thickness of about 300 nm and 20 nm, respectively. Above this film, the $CuWO_4$ was electrodeposited by controlling the cycling number in cyclic voltammetry, suggesting that the $CuWO_4$ formed during 4 cycles (abbreviated as $CuWO_4$(4 cycles)) on FTO IO film exhibited partial distribution of $CuWO_4$ nanoparticles. Additional distribution of $CuWO_4$ nanoparticles was observed in the case of $FTO/CuWO_4$(8 cycles) IO film. The $CuWO_4$ layer exhibits triclinic structure with an indirect band gap of approximately 2.5 eV and shows the enhanced visible light absorption. The photoelectrochemical (PEC) behavior was evaluated in the 0.5 M $Na_2SO_4$ solution under solar illumination, suggesting that the $FTO/CuWO_4$(4 cycles) IO films exhibit a photocurrent density ($J_{sc}$) of $0.42mA/cm^2$ at 1.23 V vs. reversible hydrogen electrode (RHE, denoted as $V_{RHE}$), while the FTO IO and $FTO/CuWO_4$(8 cycles) IO films exhibited a $J_{sc}$ of 0.14 and $0.24mA/cm^2$ at $1.23V_{RHE}$, respectively. This difference can be explained by the increased visible light absorption by the $CuWO_4$ layer and the favorable charge separation/transfer event in the cascading band alignment between FTO and $CuWO_4$ layer, enhancing the overall PEC performance.

• Tunnel and Underground Space
• /
• v.29 no.4
• /
• pp.262-279
• /
• 2019

In the engineering barriers of high-level radioactive waste disposal, gases could be generated through a number of processes. If the gas production rate exceeds the gas diffusion rate, the pressure of the gas increases and gases could migrate through the bentonite buffer. Because people and the environment can be exposed to radioactivity, it is very important to clarify gas migration in terms of long-term integrity of the engineered barrier system. In particular, it is necessary to identify the hydro-mechanical mechanism for the dilation flow, which is a very important gas flow phenomenon only in medium containing large amounts of clay materials such as bentonite buffer, and to develop and validate new numerical approach for the quantitative evaluation of the gas migration phenomenon. Therefore, in this study, we developed a two-phase flow model considering the mechanical damage model in order to simulate the gas migration in the engineered barrier system, and validated with 1D gas flow modelling through saturated bentonite under constant volume boundary conditions. As a result of numerical analysis, the rapid increase in pore water pressure, stress, and gas outflow could be simulated when the dilation flow was occurred.

• Journal of Convergence for Information Technology
• /
• v.11 no.3
• /
• pp.220-228
• /
• 2021

In this study, 20 middle-aged women aged from 35 to 55 were studied from October 12, 2020 to November 15, 2020 to find out the effects of improvement of facial skin of Jinyeosoo Clean Mist. Among the 20 participants, 10 were divided into experimental group and 10 control group. The Janus facial skin scope system (PSI Co.) used on the skin to measure pore, wrinkles, elasticity, UV pigmentation, and skin tone observed depending the difference in light sources. The facial examination took place 10 minutes after cleansing to stabilize and a total of 4 examinations were carried out after every week of using Jinyeosoo Clean Mist for 4 weeks. For statistical processing, SPSS statistics program 21.0 was utilized to compare the mean averages of pre-experimental and post-experimental data from the above two groups - the experimental group that used Jinyeosoo Clean Mist (hydrogen ion mist) 1 and 2 and the control group that did not use the subject products - and the corresponding sample t-test was used. As a result of the analysis, the group that used Jinyeosoo Clean Mist showed difference in pores (t=3.280, p<.05), wrinkles (t=4.353, p<.01) and elasticity (t=3.003, p<.05), skin tone(t=3.280, p<.01) under the statistical significance level.

• Economic and Environmental Geology
• /
• v.54 no.1
• /
• pp.69-76
• /
• 2021

This study is to identify the mineralogical properties of caprock samples from drilling cores of the Pohang basin, which is the research area for the demonstration-scale CO2 storage project in Korea. The interaction of water-rock-gas that can occur due to CO2 injection was identified using geochemical modeling. Results of mineralogical studies, together with petrographic data of caprock and data on the physicochemical parameters of pore water were used for geochemical modeling. Modelling was carried out using the The Geochemist's Workbench 14.0.1 geochemical simulator. Two steps of modeling enabled prediction of immediate changes in the caprocks impacted by the first stage of CO2 injection and the assessment of long-term effects of sequestration. Results of minerlaogical analysis showed that the caprock samples are mainly composed of quartz, K-feldspar, plagioclase and a small amount of pyrite, calcite, kaolinite and montmollonite. After the injection of carbon dioxide, the porosity of the caprock increased due to the dissolution of calcite, and dawsonite and chalcedony were precipitated as a result of the dissolution of albite and k-feldspar. In the second step after the injection was completed, the precipitation of dawsonite and chalcedony occurred as a result of dissolution of calcite and albite, and the pH was increased due to this reaction. Results of these studies are expected to be used as data to quantitatively evaluate the efficiency of mineral trapping capture in long-term storage of carbon dioxide.

• Applied Chemistry for Engineering
• /
• v.22 no.2
• /
• pp.167-172
• /
• 2011

In this work, the effect of surface treatment on mesoporous carbons (MCs) supports was investigated by analyzing surface functional groups. MCs were prepared by a conventional templating method using mesoporous silica (SBA-15) for using catalyst supports in direct methanol fuel cells (DMFCs). The MCs were treated with different phosphoric acid ($H_3PO_4$) concentrations i.e., 0, 1, 3, 4, and 5 M at 343 K for 6 h. And then Pt-Ru was deposited onto surface treated MCs (H-MCs) by chemical reduction method. The characteristics of Pt-Ru catalysts deposited onto H-MCs were determined by specific surface area and pore size analyzer, X-ray diffraction, X-ray photoelectron, transmission electron microscopy, and inductive coupled plasma-mass spectrometer. The electrochemical properties of Pt-Ru/H-MCs catalysts were also analyzed by cyclic voltammetry experiments. From the results of surface analysis, an oxygen functional group was introduced to the surface of carbon supports. From the results, the H4M-MCs carbon supports surface treated with 4 M $H_3PO_4$ led to uniform dispersion of Pt-Ru onto H4M-MCs, resulting in enhancing the electro-catalytic activity of Pt-Ru catalysts.

• Journal of the Korean Geotechnical Society
• /
• v.37 no.11
• /
• pp.71-81
• /
• 2021

The purpose of this study is liquefaction phenomenon was simulated using the 1g shaking table test. Analysis of liquefaction and Re-liquefaction behavior according to the ground conditions was analyzed when an embankment exists above the ground. The soil used in the experiment was silica sand and the ground composition was a liquefied layer of 50cm (Case 1), a non-liquefied layer of 17.5cm and a liquefied layer of 32.5cm (Case 2). The embankment was formed by fixing the height of 10cm and the slope of the slope at a ratio of 1:1.8. For seismic waves, excitation of a 5Hz sine wave was performed for 8 seconds, and a total of 5 case excitations were performed. In Case 1, it was confirmed that liquefaction occurred at all depths during the first vibration excitation at the free-field and that liquefaction did not occur at all depths except 5cm at the third vibration excitation. At the center of the embankment, liquefaction occurred up to a depth of 20cm during the first vibration excitation, and it was confirmed that liquefaction did not occur at all depths except for a depth of 5cm during the second vibration excitation.

• Journal of the Korean Geotechnical Society
• /
• v.37 no.12
• /
• pp.47-56
• /
• 2021

The cryosuction (negative pore pressure) in freezing soils causes groundwater migration from the frozen fringe to freezing front for ice lens formation. Frost heave and heaving pressure by ice lens cause damage to ground infrastructure. In order to prevent damage by the frost heave, various frost susceptibility criteria have been proposed. The SP (Segregation Potential) is the most widely used classification criterion for frost susceptibility in cold regions. The expansion of the ice lens by the migration of the groundwater is a key role in frost heave mechanism, and thus it is necessary to evaluate the hydraulic conductivity. In this paper, soil mixtures of coarse-fines (sand-silt) were prepared in various weight fractions and used for frost heave and column permeability test. For each case, the SP and the hydraulic conductivity were derived and correlations were analyzed. As a results, the transition threshold of the SP and the hydraulic conductivity were shown at 20% and 50% of the silt weight fraction, respectively. Although there are difference between these transition thresholds, these two coefficients show a specific correlation. In the future, additional study should be conducted for detailed analysis of the threshold transition values between SP and hydraulic conductivity.