• Title/Summary/Keyword: polymer's surface

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Flexural and Interfacial Bond Properties of Hybrid Steel/Glass Fiber Reinforced Polymer Composites Panel Gate with Steel Gate Surface Deformation for Improved Movable Weir (개량형 가동보에 적용하기 위한 하이브리드 강판/GFRP 패널 게이트의 강판게이트 표면형상에 따른 휨 및 계면 부착 특성 평가)

  • Kim, Ki Won;Kwon, Hyung Joong;Kim, Phil Sik;Park, Chan Gi
    • Journal of The Korean Society of Agricultural Engineers
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    • v.57 no.2
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    • pp.57-66
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    • 2015
  • The purpose of this study was to improved the durability of a improved movable weir by replacing the improved movable weir's metal gate with a hybrid steel/glass fiber reinforced polymer composites panel gate. Because the metal gate of a improved movable weir is always in contact with water, its service life is shortened by corrosion. This study made four type of hybrid steel/glass fiber reinforced polymer composites panel gate with different steel gate surface deformation (control, sand blast, scratch and hole), flexural. Fracture properties tests were performed depending on the steel gate surface deformation. According to the test results, the flexural behavior, flexural strength and fracture properties of hybrid steel/glass fiber reinforced polymer composites panel gate was affected by the steel panel gate surface deformation. Also, the sand blast type hybrid steel/glass fiber reinforced polymer composites panel gate shows vastly superior flexural and fracture performance compared to other types.

Relationship between the pretilt angle generation and the polarization component with oblique polarized UV light irradiation on polyimide surface. (폴링미드표면에 편광된 UV광을 경사조사시의 프리틸트각의 발생과 편광성분의 상호관계)

  • 서대식;박두석
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.12 no.1
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    • pp.75-80
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    • 1999
  • In this study, we have investigated the relationship between the generation of pretilt angle and the polarization component in cells with UV light irradiation on polyimide (PI) surface. It was found that the generated pretilt angle is about $1.4^{\circ}$ with S-polarized UV light irradiation of $75^{\circ}$ on PI surface; it may be attributed to the asymmetry triangular of polymer surface with oblique S-polarized UV light irradiation on PI surface. Also, we measured that the generated pretilt angle is about $2.0^{\circ}$ with oblique P polarized UV light irradiation of $75^{\circ}$ on PI surface. Consequently, we suggest that the generated pretilt angle of the NLC is attributed to the interaction between the LC molecules and the polymer surface with oblique polarized UV light irradiation on PI surface.

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Deposition of Plasma Polymerized Films on Silicon Substrates Using Plasma Assisted CVD Method For Low Dielectric Application

  • Kim, M.C.;S.H. Cho;J.H. Boo;Lee, S.B.;J.G. Han;B.Y. Hong;S.H. Yang
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2001.06a
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    • pp.72-72
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    • 2001
  • Plasma polymerized thin films have been deposited on Si(lOO) substrates at $25-400^{\circ}C$ using thiophene ($C_4H_4S$) precursor by plasma assisted chemical vapor deposition (PACVD) method for low-dielectric device application. In order to compare physical properties of the as-grown thin films, the effects of the plasma power, gas flow ratio and deposition temperature on the dielectric constant and thermal stability were mainly studied. XRD and TED studies revealed that the as-grown thin films have highly oriented amorphous polymer structure. XPS data showed that the polymerized thin films that grown under different RF power and deposition temperature as well as different gas ratio of $Ar:H_2$ have different stoichiometric ratio of C and S compared with that of monomer, indicating a formation of mixture polymers. Moreover, we also realized that oxygen free and thermally stable polymer thin films could be grown at even $400^{\circ}C$. The results of SEM, AFM and TEM showed that the polymer films with smooth surface and sharp interface could be grown under various deposition conditions. From the electrical property measurements such as I-V and C-V characteristics, the minimum dielectric constant and the best leakage current were obtained to be about 3.22 and $10-11{\;}A/\textrm{cm}^2$, respectively.

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Surface Characteristics of Functional Polymer Film by Ion Beam Irradiation (이온빔 조사에 의한 기능성 고분자 필름의 표면 특성)

  • Kim, Young Jun;Hong, Seong Min;Noh, Yong Oh
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.431-436
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    • 2013
  • Polycarbonate (PC) films have been irradiated with various kinds of ions according to energy and dose. Change of the optical transmittance and chemical characteristics were confirmed by UV-VIS and FTIR (ATR) spectroscopy respectively. These UV-A block in 400 nm was variable from 10 to 100% according to energy and doses. Surface electrical resistance of PC film irradiated by ion beam was $10^6-10^{13}{\Omega}/cm^2$, which reveal variation of conduction. Contact angle of film irradiated by ion beam was decreased than the pristine film. Polymer surface morphology was examined by means of atomic force microscopy (AFM). As expected, degradation of polymer film was higher after irradiation with heavier Xe ions but the roughness in the polymer surface morphology were more pronounced for Ar ions. This observed effect can be explained by stronger compaction of polymer surface layer in the case of Xe irradiation, connected with a reduction of free volume available.

A Study of Corona Discharge in Polymer Insulators by Artificial UV Radiation (인위적인 자외선 조사량에 따른 폴리머애자에서의 코로나 방전 특성)

  • Kim, Y.S.;Choi, M.I.;Kim, C.M.;Bang, S.B.;Shong, K.M.;Kwag, D.S.
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.62 no.5
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    • pp.643-648
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    • 2013
  • In this study, degradation was observed by irradiating UV rays to the polymer insulators which have been widely used in outdoor electric power facilities. For an indoor accelerated UV test, 0.55 w/m2 of UV rays were applied using a xenon-arc method. A UV detection system with 65 ${\phi}mm$ in diameter, 100 mm in length and 1.0 of brightness (F/#) has been designed. Even though efflorescence on the surface of polymer insulators wasn't observed according to the accelerated UV test. UV rays were detected at around 50% and 40% of insulation breakdown in EPDM and silicone-type insulators respectively. As degradation continued because of an indoor accelerated UV test, breakdown voltage with which UV rays can be detected in an early stage decreased as well. A silicone polymer insulator would be severer than EPDM polymer insulator in terms of surface degradation because of UV strength against $V_m/V_{BD}$ was high in silicone polymer insulators. UV strength in silicone-type insulators increased at 1,000 $kJ/m^2$ because contact angle at the intial stage sharply decreased to from $113^{\circ}$ to $92.1^{\circ}$.

Polymer brush: a promising grafting approach to scaffolds for tissue engineering

  • Kim, Woonjung;Jung, Jongjin
    • BMB Reports
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    • v.49 no.12
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    • pp.655-661
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    • 2016
  • Polymer brush is a soft material unit tethered covalently on the surface of scaffolds. It can induce functional and structural modification of a substrate's properties. Such surface coating approach has attracted special attentions in the fields of stem cell biology, tissue engineering, and regenerative medicine due to facile fabrication, usability of various polymers, extracellular matrix (ECM)-like structural features, and in vivo stability. Here, we summarized polymer brush-based grafting approaches comparing self-assembled monolayer (SAM)-based coating method, in addition to physico-chemical characterization techniques for surfaces such as wettability, stiffness/elasticity, roughness, and chemical composition that can affect cell adhesion, differentiation, and proliferation. We also reviewed recent advancements in cell biological applications of polymer brushes by focusing on stem cell differentiation and 3D supports/implants for tissue formation. Understanding cell behaviors on polymer brushes in the scale of nanometer length can contribute to systematic understandings of cellular responses at the interface of polymers and scaffolds and their simultaneous effects on cell behaviors for promising platform designs.

Development of Debris-free Process using Erasable Ink for Polymer Ablation (폴리머의 어블레이션 시 소거성 잉크를 이용한 잔유물 제거공정 개발)

  • Shin, D.S.;Lee, J.H.;Suh, J.;Kim, T.H.
    • Laser Solutions
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    • v.8 no.2
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    • pp.21-32
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    • 2005
  • The excimer laser ablation of a polymer occurs by the excitation of chemical bonds to energy levels that are above the dissociation energy. In this process, however, fragmented debris is finally ejected explosively by the scission of bonds and accumulates on the material surface. In the present work, a process for eliminating surface debris contamination generated by the laser ablation of a polymer is developed. The proposed approach for removing surface debris utilizes an erasable ink pasted on a polymide. The ink pasted polyimide is ablated by KrF excimer laser. The surface debris ejected from the polyimide is then combined with the ink layer on the polymer. Finally, both the surface debris and the ink layer are removed using adhesive tape or alcohol solvent. The results suggest that the erasable ink method is a simple, low cost, and extremely effective debris eliminating process.

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Introduction of Chromophores on the Activated Surface of Poly(2-trialkylstannylthioethyl acrylate) Films (Poly(2-trialkylstannylthioethyl acrylate) 필름의 표면 활성화를 통한 발색단 도입)

  • Yun, Jong Chul;Do, Jung Yun
    • Polymer(Korea)
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    • v.36 no.6
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    • pp.795-802
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    • 2012
  • Surface modification of a hydrophobic acrylic polymer film has been performed through simple chemical treatment to give a reactive surface. 2-Triphenylstannylthioethyl acrylate was polymerized under UV-illumination with various contents of a comonomer. When the polymer film was treated with fluoride ion, thiol functional group (SH) was generated on the film surface, which was observed through infrared absorption spectroscopy. The surface was functionalized by thiol addition reaction to acrylic chromophores. The SH content on the surface was controlled with a comonomer, tris(hydroxymethyl)ethane triacrylate, and examined with UV-Vis absorbance of the chromophore attached film. Similarly, a polymer film from 2-tributylstannylthioethyl acrylate was prepared. Destannylation from the triphenylstannyl and tributylstannyl surface completed after 30 and 5 min, respectively. The SH-exposed surface was modified with an isocyanate attached chromophore within 10 min, while acrylic chromophore required 24 h.