• Title/Summary/Keyword: hydrogen vent

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Optimization of Vent Logic for Cascade Type Fuel Cell Module (캐스캐이드형 연료전지 모듈 벤트 로직 최적화)

  • Lim, Jongkoo;Park, Jongcheol;Kwon, Kiwook;Shin, Hyun Khil
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.87.2-87.2
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    • 2011
  • Many type of fuel cell stacks have been developed to improve the efficiency of reactants usage. The cascade type fuel cell stack using dead end operation is able to attain above 99% usage of hydrogen and oxygen. It is sectionalized to several parts and the residual reactants which are used previous parts would be supplied again to next parts which have less number of cells in dead end operation stack. The oversupply of reactants which is usually 120%~150% of the theoretical amount to generate current for preventing the flooding effect could be provided to each part except the last one. The final section which is called monitoring cells is supposed to be supplied insufficient the fuel or oxidant that would have some accumulated inert gas from former parts. It makes some voltage drop in the part and the fresh reactants must be supplied to the part for recovering it by venting the residual gas. So the usage of fuel and oxidant is depend on the time and frequency of opening valves for venting of residual gas and it is important to optimize the vent logic for achieving higher usage of hydrogen and oxygen. In this research, many experiments are performed to find optimal condition by evaluating the effect of time and frequency under several power conditions using over 100kW class fuel cell module. And the characteristics of the monitoring cells are studied to know the proper cell voltage which decide the condition of opening the vent valve for stable performance of the cascade type fuel cell module.

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Forced Ignition Characteristics with a Plasma Jet Torch in Supersonic Flow (초음속 유동장 내 플라즈마 토치를 사용한 강제 점화 특성)

  • Kim, Chae-Hyoung;Jeung, In-Secuk;Choi, Byoung-Il;Kouchi, Toshinori;Masuya, Goro
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.04a
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    • pp.363-366
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    • 2011
  • Mixing and combustion experiments with a vent slot mixer were performed in Mach 2 supersonic wind tunnel. Helium and hydrogen gases each were used for the mixing and the combustion experiment with a plasma jet (PJ) torch. The vent slot mixer holds plenty of fuel in the downstream mixing region, even though the fuel is transversely injected. In case of the combustion, the injected fuel is ignited by the PJ torch, and then unburned mixture is burned by shock-induced combustion downstream. Thermal choking in the combustor leads to shock trains in the isolator, causing the unstable combustion.

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A Study on the Safety Improvement of Carbon Black Manufacturing Process (카본블랙 제조공정의 안전성 향상에 관한 연구)

  • Joo, Jong-Yul;Jeong Phil-Hoon;Sung-Eun, Lee
    • Journal of the Korea Safety Management & Science
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    • v.25 no.4
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    • pp.153-161
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    • 2023
  • Carbon black is a material in the form of fine black powder obtained by incomplete combustion or pyrolysis of hydrocarbons, and is composed of 90-99% carbon, and the rest is composed of hydrogen and oxygen. In the event of an emergency during the manufacture of carbon black, the generated tail gas should be safely discharged through an emergency line to prevent fire, explosion, and environmental pollution accidents caused by the tail gas. If the pressure continues to rise, the pressure control valve shall operate and the rupture plate shall be ruptured sequentially and the tail gas shall be discharged to the vent stack through the emergency line. As an emergency emission system, even if some untreated substances in the tail gas are released into the atmosphere, they are lighter than air, so it is safe to discharge them to a safe place through the Vent Stack. If the gas pressure is rising or worse, it is discharged from the Vent Stackine, and discharging fuel.

A Study on the Safety of Carbon Manufacturing By-product Gas Emissions (카본제조 부생가스 배출 안전성에 관한 연구)

  • Joo, Jong-Yul;Jeong Phil-Hoon;Kim, Sang-Gil;Sung-Eun, Lee
    • Journal of the Korea Safety Management & Science
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    • v.26 no.1
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    • pp.99-106
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    • 2024
  • In the event of an emergency such as facility shutdown during process operation, the by-product gas must be urgently discharged to the vent stack to prevent leakage, fire, and explosion. At this time, the explosion drop value of the released by-product gas is calculated using ISO 10156 formula, which is 27.7 vol%. Therefore, it does not correspond to flammable gas because it is less than 13% of the explosion drop value, which is the standard for flammable gas defined by the Occupational Safety and Health Act, and since the explosion drop value is high, it can be seen that the risk of fire explosion is low even if it is discharged urgently with the vent stock. As a result of calculating the range of explosion hazard sites for hydrogen gas discharged to the Bent Stack according to KS C IEC 60079-10-1, 23 meters were calculated. Since hydrogen is lighter than air, electromechanical devices should not be installed within 23 meters of the upper portion of the Bent Stack, and if it is not possible, an explosion-proof electromechanical device suitable for type 1 of dangerous place should be installed. In addition, the height of the stack should be at least 5 meters so that the diffusion of by-product gas is facilitated in case of emergency discharge, and it should be installed so that there are no obstacles around it.

Thermococcus onnurineus sp. nov., a Hyperthermophilic Archaeon Isolated from a Deep-Sea Hydrothermal Vent Area at the PACMANUS Field

  • Bae, Seung-Seob;Kim, Yun-Jae;Yang, Sung-Hyun;Lim, Jae-Kyu;Jeon, Jeong-Ho;Lee, Hyn-Sook;Kang, Sung-Gyun;Kim, Sang-Jin;Lee, Jung-Hyun
    • Journal of Microbiology and Biotechnology
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    • v.16 no.11
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    • pp.1826-1831
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    • 2006
  • A novel hyperthermophilic, anaerobic, heterotrophic archaeon, designated strain $NA1^T$, was isolated from a deep-sea hydrothermal vent area (depth, 1,650 m) within the Papua New Guinea-Australia-Canada-Manus (PACMANUS) field. Cells of this strain were motile by means of polar flagella, coccoid-shaped with a diameter of approximately $0.5-1.0{\mu}m$, and occurred as single cells. Optimal temperature, pH, and NaCl concentration for growth were $80^{\circ}C$, 8.5, and 3.5%, respectively. The new isolate was an obligate heterotroph that utilized yeast extract, beef extract, tryptone, peptone, casein, and starch as carbon and energy sources. Elemental sulfur was required for growth and was reduced to hydrogen sulfide. The G+C content of the genomic DNA was 52.0 mol%. Phylogenetic analysis of the 16S rRNA gene indicated that strain $NA1^T$ belongs to the genus Thermococcus, and the organism is most closely related to T. gorgonarius, T. peptonophilus, and T. celer; however, no significant homology was observed among species by DNA-DNA hybridization. Strain $NA1^T$ therefore represents a novel species for which the name Thermococcus onnurineus sp. novo is proposed. The type strain is $NA1^T$ (=KCTC 10859, =JCM 13517).

$SO_2/O_2$ Separation Process with EMIm[$EtSO_4$] in SI Cycle for the Hydrogen Production by Water Splitting (물분해 수소제조를 위한 SI cycle에서의 EMIm[$EtSO_4$]를 이용한 $SO_2/O_2$ 분리공정)

  • Lee, Ki-Yong;Kim, Hong-Gon;Jung, Kwang-Deog;Kim, Chang-Soo
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.1
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    • pp.13-20
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    • 2011
  • $SO_2$ has been absorbed and separated selectively by an ionic liquid from $SO_2/O_2$ mixture decomposed from sulfuric acid during the thermochemical SI cycle for the water splitting. In order to design and operate high pressure $SO_2/O_2$ separation system, the solubility of $SO_2$ in [EMIm]$EtSO_4$ (1-ethyl-3-methylimidazolium ethylsulfate) has been measured by Magnetic Suspension Balance at high pressure and temperature. Based on the measured solubility, a pressurized separation system was set up and operated. 194 L/h of $SO_2$($SO_2:O_2$=0.65:1) has been separated with 99.85% of $O_2$ at the vent of absorption tower, which is 22.7% of the theoretically ideal capacity of the system. This discrepancy results from the reduced contact between the gaseous $SO_2$ and the ionic liquid. Increased $SO_2$ supply, scale-up of the absorption column, and a faster ionic liquid circulation speed were suggested to improve the separation capacity.

The Exploration Methodology of Seafloor Massive Sulfide Deposit by Use of Marine Geophysical Investigation (해양 지구물리 탐사를 이용한 해저열수광상 부존지역 탐지 방법)

  • Kim, Hyun-Sub;Jung, Mee-Sook;Kim, Chang-Hwan;Kim, Jong-Uk;Lee, Kyeong-Yong
    • Geophysics and Geophysical Exploration
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    • v.11 no.3
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    • pp.167-176
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    • 2008
  • Lau basin of the south Pacific, as an active back arc basin, is promising area bearing seafloor massive hydrothermal deposit that is located in a subduction zone between the Pacific ocean plate and Indo-Australian continental plate. We performed multi-beam bathymetry survey in the Lau basin using EM120, to find out high hydrothermal activity Bone. Fonualei Rift and Spreading Center (FRSC) and Mangatolou Triple Junction (MTJ) area were selected for precise site survey through seafloor morphology investigation. The result of surface and deep-tow magnetometer survey showed that Central Anomaly Magnetization High (CAMH) recorded which is associated with active ridge in FRSC-2 and revealed very low magnetic anomalies that can be connected to past or present high hydrothermal activity in MTJ-1 seamount area. Moreover, the physical and chemical tracers of hydrothermal vent flume, i.e., transmission, hydrogen ion concentration (pH), adenosine triphosphate (ATP), methane (CH4) by use of CTD system, showed significant anomalies in those areas. From positive vent flume results, we could conclude that these areas were or are experiencing very active volcanic activities. The acquired chimney and hydrothermal altered bed rock samples gave us confidence of the existence of massive hydrothermal deposit. Even though not to use visual exploration equipment such as ROV, DTSSS, etc., traditional marine geophysical investigation approach might be a truly cost-effective tool for exploring seafloor hydrothermal massive deposit.

Preliminary Study on Factor Technology of Selective Catalytic Reduction System in Marine Diesel Engine (선박용 디젤엔진 SCR 시스템 요소 기술에 관한 기초 연구)

  • Park, Yoon-Yong;Song, Ha-Cheol;Ahn, Gi-Ju;Shim, Chun-Sik
    • Journal of Navigation and Port Research
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    • v.40 no.4
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    • pp.173-181
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    • 2016
  • From 2016, controls on reduction of NOx and SOx emissions from the vessels that are operated in the emission control area were tightened. The selectivity catalytic reduction system of the denitrification equipment which NOx among the above controlled materials is very effective and used commercially very much. But it has the disadvantage that CSR is activated at high temperatures. Therefore, the SCR and SCR activation instrument that can react even at low temperatures by using micro-nano bubbles so that the above problems can be minimized were developed. And the computational fluid dynamics technique was used by ANSYS-CFX package to prepare the plan that improves the SCR system's efficiency. Simulation for the viscous flow analysis of the SCR system was executed by applying the Navier-Stokes equation to it as a governing equation. For the SCR system's shape, 3D modeling was done by using CATIA V5. SCR jet nozzle's position was checked by changing it to the intervals of 1/3, 1/2, and 2/3 from the inlet of the vent pipe to compare the SCR system's efficiency. And the number of nozzles was compared and analyzed by simulating 4, 6, and 8 holes to check an effect of the number on the SCR system's efficiency. The simulation result has found that the closer nozzles are to the inlet of the vent pipe and the more nozzles are, the more efficiency is improved.

Evidence for Hydrothermal Plume in Manus Basin, SW Pacific: Distribution of Transparency and Hydrogen Sulfide (남서태평양 마누스분지 해역의 열수 plume 증거: 투명도 및 황화수소 분포)

  • Lee, Kyeong-Yong;Park, Yong-Chul;Son, Seung-Kyu
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.5 no.4
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    • pp.363-373
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    • 2000
  • To understand and investigate chemical characteristics of thermal environment in the southwestern Paciflc, we have measured hydrological and chemical parameters such as temperature, salinity, transparency, pH, nutrients and hydrogen sulfide (H$_2$S). Samples were collected with CTD-casting at 12 station, in Manus Basin including PACMANUS, DESMOS and Susu Knolls, Hydrothermal systems consist of circulation zones where seawater interacts with rock, thereby changing chemical and physical characteristics of both the seawater and the rock. The altered seawater, called hydrothermal fluid, is injected back into the ocean from the hydrothermal vent fields and forms hydrothermal plumes. Consequently, we detected hydrothermal plume with transparency and sulfide anomalies at PACMANUS and Susu Knolls. Sulfide, as geochemical tracer of hydrothermal plume, ranged 0-3.31 ${\mu}$M, and averaged 0.63 ${\mu}$M in the study area. The height, flux and activity of the plume are affected by circulations in the deep water and the spread of plume follows along the isopycnal surface. Therefore the observed H$_2$S anomaly can provide important clue for the source location and it appears that the targestsource in the PACMANUS is aligned in the north-south direction.

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Optimal Operation of Gas Engine for Biogas Plant in Sewage Treatment Plant (하수처리장 바이오가스 플랜트의 가스엔진 최적 운영 방안)

  • Kim, Gill Jung;Kim, Lae Hyun
    • Journal of Energy Engineering
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    • v.28 no.2
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    • pp.18-35
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    • 2019
  • The Korea District Heating Corporation operates a gas engine generator with a capacity of $4500m^3 /day$ of biogas generated from the sewage treatment plant of the Nanji Water Recycling Center and 1,500 kW. However, the actual operation experience of the biogas power plant is insufficient, and due to lack of accumulated technology and know-how, frequent breakdown and stoppage of the gas engine causes a lot of economic loss. Therefore, it is necessary to prepare technical fundamental measures for stable operation of the power plant In this study, a series of process problems of the gas engine plant using the biogas generated in the sewage treatment plant of the Nanji Water Recovery Center were identified and the optimization of the actual operation was made by minimizing the problems in each step. In order to purify the gas, which is the main cause of the failure stop, the conditions for establishing the quality standard of the adsorption capacity of the activated carbon were established through the analysis of the components and the adsorption test for the active carbon being used at present. In addition, the system was applied to actual operation by applying standards for replacement cycle of activated carbon to minimize impurities, strengthening measurement period of hydrogen sulfide, localization of activated carbon, and strengthening and improving the operation standards of the plant. As a result, the operating performance of gas engine # 1 was increased by 530% and the operation of the second engine was increased by 250%. In addition, improvement of vent line equipment has reduced work process and increased normal operation time and operation rate. In terms of economic efficiency, it also showed a sales increase of KRW 77,000 / year. By applying the strengthening and improvement measures of operating standards, it is possible to reduce the stoppage of the biogas plant, increase the utilization rate, It is judged to be an operational plan.