• Journal of the Computational Structural Engineering Institute of Korea
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• v.19 no.1 s.71
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• pp.15-25
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• 2006

The researches on the early-aged concrete hydration process and the techniques for the early-aged concrete crack control mainly have been focused and developed on the massive concretes in both experimental and numerical studies. However, those researches for relatively thin members such as the upper slab of the reinforced concrete rahmen bridge have nearly been attempted. In this study, a designing technique for crack controlling in the thin members of the early-aged reinforced concrete rahmen bridges based on measured temperature history, strength revelation model and sinkage model is proposed. A method of calculating the reinforcing bar area for crack controlling is also proposed and it is found that the distributing bars under the design loads become the main reinforcing bars in the temperature stress analysis of the early-aged reinforced concrete rahmen bridges. It is shown that the proposed analysis technique is able to use the design of crack control for the early-aged reinforced concrete rahmen bridge.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.981-984
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• 2008

The super tall building above 100 floors is required that each floor's height is more than 4 meters, and each core wall's thickness is more than 60cm. Therefore, for the successive accomplishment of super tall building, the full scale mock-up test was required. The test results are as follows; Real strength of core wall was satisfied with design strength at 28 days regardless of types of strength, and according to the consolidation effect, lower part's strength was a little higher than upper part's strength. Lateral force of HSC was evaluated with max. $4.5ton/m^2$, and hydration temperature of mock-up test was evaluated that maximun heat of central part revealed about $80^{\circ}C$ at 70MPa and $65^{\circ}C$ at 50MPa, and, the difference between inner and outter part revealed about $30^{\circ}C$ at 70MPa and $12^{\circ}C$ at 50MPa. Also, no crack by hydration temperature was not shown on the surface.

• Journal of the Korean Recycled Construction Resources Institute
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• v.2 no.3
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• pp.239-246
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• 2014

High volume slag concrete is attracting new attention and are thought to have promising potential for industrial applications, partly due to the climate debate, but especially due to their very low heat of hydration and their good durability in chemically aggressive environments. However, High volume slag concretes tend to have slower strength development especially. In this study, the effect of anhydrite ($CaSO_4$) on the mechanical and durability performance of high volume slag concrete were investigated. The main variables were anhydrite contents (0, 4, 6, 8, 10%). Test results show that 4~8% anhydrite concrete have improved engineering properties (hydration, compressive strength, shrinkage, creep, carbonation) as control concrete at early ages.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.661-664
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• 2008

As architectures have recently become high-risers and megastructured, stable high strength products have been ensured. Accordingly, use of precast concrete accouplement has been increased in order to facilitate air compression and rationalize construction. Since not only external heating but also internal temperature rise caused by the accumulation of cement hydration heat in manufacturing process, precast concrete members with large cross-section used for high-rise mega-structure's columns and beams may exhibit different temperature history compared to the precast concrete members for wall and sub-floor with relatively small cross-sections. Therefore, this study aims to elucidate the characteristics of temperature history of mass concrete members cast with high-strength concrete for precast concrete application. In this study, large cross-sectional precast concrete mock-up, unit cement quantity, and temperature histories in manufacturing precast concrete member under different curing condition were inclusively investigated.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1999.05a
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• pp.185-191
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• 1999

An air-conditioning system based on the chemical heat storage principle was considered. $H_2O$ was chosen as the reaction gas and the working fluid as well. Na$_2$S, CaCl$_2$, MnCl$_2$, BaCl$_2$, MgCl$_2$, Fe$_2$(SO$_4$)$_3$ and MnSO$_4$ were tested as the solid reactants by using Cahn pressure balance. Na$_2$S was superior to other salts in respect of high capability of absorption of water gas, 5 moles of $H_2O$ per unit mole of Na$_2$S, and adequate temperature of adsorption, $65^{\circ}C$ at 7torr, and of desorption, 13$0^{\circ}C$ at 76torr. Clausius-Clapeyron diagram of Na$_2$S was obtained via adsorption experiments at several vapor pressures of water gas. To enhance heat and mass transfer characteristics, usually below 1W/m K, of the reactor bed of general adsorption systems, expanded graphite block was adapted as the support of Na$_2$S salt. Expanded graphite blocks had thermal conductivity values of 20~80W/mK with respect to 100~400kg/㎥ of block bulk density. Permeability values of expanded graphite blocks were 10$^{-13}$ ~ 10$^{-14}$ $m^2$ with respect to 100~300kg/㎥ of block bulk density showing highly decreasing values of permeability, below 10$^{-l4}$$m^2$, in the range of above 150kg/㎥ of block bulk density.y.

• Journal of the Korea Concrete Institute
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• v.26 no.6
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• pp.723-730
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• 2014

The usage of Ground Granulated Blast Furnance Slag (GGBFS) has been increased recently. Studies on the cement hydration model incorporating GGBFS as well as the properties of cement paste done with GGBFS such as compressive strength, hydration products and hydration heat have been the subjects of many researches. However, studies on the reaction degree of GGBFS that affect the properties of cement paste incorporating GGBFS are lacking globally and specially in Korea. Thus, in this study, the reaction degree of GGBFS using the method if selective dissolution, compressive strength, the amount of chemical bound water and $Ca(OH)_2$ were measured and analysed in accordance with water-binder ratio, replacement ratio of GGBFS, and curing temperature. The results show that the reaction degree of GGBFS, the amount of chemical bound water and $Ca(OH)_2$ in cement paste with GGBFS were higher in conditions where the replacement ratio of GGBFS was low and both water-binder ratio and curing temperature were high. Finally, the reaction degree of GGBFS was achieved at a value between 0.3~0.4.

• Resources Recycling
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• v.19 no.3
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• pp.33-44
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• 2010

In this study, the possibility of utilizing carbide lime waste, obtained from the generation of acetylene process, as a alkali activator of blast furnace slag cement was investigated. The physical and chemical analysis of the carbide lime waste was studied and three types lime waste in order to investigate behaviour as alkali activator were used. Lime wastes were added 0, 10, 20 and 30 wt.% in blast furnace slag and blast furnace slag containing lime waste were added 0, 10, 30 and 50 wt.% in OPC. As a result of analysis of hydration properties, in the case of calcium hydroxide rehydrated after heat treatment at $800^{\circ}C$, it was higher hydration rate than other specimens. For the results of compressive strength test, when lime waste passed 325 mesh sieve and rehydrated calcium hydroxide were used, it was higher compressive strength than OPC from hydration 7days. At OPC50 wt.%-BFS45 wt.%-AA5 wt.% system using lime waste of 325 mesh under, the highest compressive strength appeared.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.24 no.5
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• pp.531-542
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• 2011

The time-dependent temperature distribution across the section in bridges is determined on the basis of the three-dimensional finite element analyses and numerical time integration in this study. The material properties which change with time and thermal stress of concrete are taken into account to effectively trace the early-age structural responses. Since the temperature distribution is nonlinear and depends upon many material constants such as the thermal conductivity, specific heat, hydration heat of concrete, heat transfer coefficients and solar radiation, three representative influencing factors of the construction season, wind velocity and bridge pavement are considered at the parametric studies. The validity of the introduced numerical model is established by comparing the analytical predictions with results from previous analytical studies. On the basis of parametric studies for four different bridge sections, it is found that the creep deformation in concrete bridges must be considered to reach more reasonable design results and the temperature distribution proposed in the Korean bridge design specification need to be improved.

• Journal of the Korean Recycled Construction Resources Institute
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• v.1 no.1
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• pp.81-88
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• 2005

The fly ash has been widely used in the latest to complement the performance and economical efficiency of the concrete which uses only a normal portland cement, the pulp ash gained through the incineration of paper sludge is possible to be used as the material of concrete because it contains the properties similar to the previous fly ash in ingredients and physical characteristics. Therefore, this research has tested physical characteristics by replacing 20% of fly ash used with the paper ash to solve the problem which lowers the early strength caused when the fly ash was used. As a result, it showed that the fluidity becomes lower and the compressive strength becomes increased by using paper ash. In addition, after mixing the paper ash with the fly ash, it showed that time and heating amount of the 2nd peak of the minor heat of hydration affecting the revelation of strength was equivalent to the combination for normal portland cement, and also indicated that the compressive strength for 3 days is superior to the combination of the fly ash. Therefore, if the paper ash having a regular fineness is used, it was effective in improving the early strength of concrete used the fly ash.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.23 no.3
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• pp.124-128
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• 2013

In this research, cubic zirconia is synthesized with a refined CaO from shells as a stabilizer through Skull melting method. The proper process time and concentration are defined by Hydration reaction to produce the refined CaO after two different treatments using 0.1 mol% of HCl respectively with Cockle shell. The highest purity of CaO is reached when the shell is immersed in 1 mol% HCl. In Hydration reaction step, the pure $Ca(OH)_2$ is produced at $45^{\circ}C$ for 24 hours. The highest purity of CaO is measured when the $Ca(OH)_2$ is treated by heat at $1200^{\circ}C$ for 5 hours. The single crystals are grown through Skull melting method by adding the different contents of the refined CaO from 10 mol% to 30 mol% into $ZrO_2$. The frequency of High-frequency oscillator used for Skull melting method is 3.4 MHz. The descending speed of the single crystal is 3 mm/hour. The grown length of the single crystal is 4 cm. As a result of this study, 15 mol% of CaO has the best crystallinity.