• Journal of Conservation Science
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• v.23
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• pp.1-10
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• 2008

Consolidants based on tetraethoxysilane (TEOS) such as alkoxysilanes have been widely used for the consolidation of decaying stone heritages. Low-viscosity alkoxysilanes penetrate inside the decaying stone and polymerize within the porous structure of the decaying stone, significantly increasing the cohesion of the material. However, TEOS-based consolidants suffer from practical drawbacks, such as crack formation of the gel during the drying phase due to the developed capillary force, which is typical for TEOS-based consolidants. We prepared new consolidants TEOS-based consolidants containing flexible (3-glycidoxypropyl)trimethoxysilane (GPTMS) and silica nanoparticles (or polyhedral oligomeric silsesquioxanes (POSS)) in order to reduce capillary force development during gel drying. Since the consolidants should have a good interaction with the component of the stone in order to connect the isolate grains of decaying stone, the adhesion interaction of the developed consolidants on the surface of the granite was macroscopically investigated by the ISO 2409 cross cutting test. The adhesion interaction decreased with the addition of silica nanoparticle and POSS while it increased with the addition of GPTMS in TEOS solution.

• Journal of the Korean association of regional geographers
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• v.16 no.2
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• pp.85-99
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• 2010

This study analyzes the geomorphic environments of river channels and properties of sediments in the Naeseong-River basin, a branch of Nakdong-River. While the area at NU1 located in the uppermost reaches indicates the landscapes with the gravel riverbeds, the sand riverbeds can be seen in the downstream of NU2 whose basin consists mostly of the granite regolith. The downstream of NU2 has the braided channels in the beds and this may be due to the large quantities of sand particles supply to the bed under the favorable geologic and geomorphic conditions, properties of river flowing within the floodplains less resistant to the erosion and great fluctuations of discharges. Whereas the river at NU2 may seem that sand particles are actively eroded during the high water-level periods, the particles may be actively deposited during the periods at NM2 and NL2. Moreover, in the reaches of NU2 to NM1 and NL1 to NL2, the mean grain sizes of sediments increase downstream suggesting the other supplies of coarse sediments from the lower order streams running the steep slopes because the river flows in the areas consisting of the metamorphic rocks rather than the granites and shows the properties of incised meander.

• Journal of Conservation Science
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• v.27 no.2
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• pp.201-209
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• 2011

While consolidants based on tetraethoxysilane (TEOS) have been widely used for the consolidation of decaying stone heritages, TEOS-based consolidants suffer from practical drawbacks, such as crack formation of the gel during the drying phase due to the developed capillary force. We have prepared new TEOS-based consolidants containing flexible (3-glycidoxypropyl) trimethoxysilane (GPTMS) in order to reduce capillary force development during gel drying. In this study, we have prepared TEOS/GPTMS-based consolidants containing ETEOS in order to improve the surface hydrophobisity. The physical properties of the TEOS/GPTMS/ETEOS solution with different hydrolysis were compared with those of the commercial products Wacker OH$^{(R)}$. The contact angle of the surface increased with the addition of the ETEOS, which is higher than that of Wacker OH$^{(R)}$. The sol-gel mechanism was manipulated by the degree of hydrolysis as well as the amount of ETEOS. The properties and the applicability of the developed consolidants for the decayed Korean granites are also investigated.

• The Journal of the Petrological Society of Korea
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• v.15 no.1 s.43
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• pp.39-48
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• 2006

U-Pb ages were determined from the granitic rocks from central and northeastern parts of Yeongnam massif. Porphyritic granite of Seosang-myeon, Hamyang-gun near the boundary with Anui-myeon shows age of $225.4{\pm}4.1Ma$. Foliated granodiorites of Anui-myeon, Hamyang-gun and Sinwon-myeon, Geochang-gun are $195.6{\pm}1.8Ma$ and $194.2{\pm}2.4Ma$ old respectively. Granites from Hari-myeon and Buksang-myeon of Geochang-gun show almost identical ages of $198.4{\pm}2.5Ma$ and $194.6{\pm}2.6Ma$ respectively, while foliated granodiorite of Yeongju shows an age ot $171.3{\pm}2.3Ma$. Combining with previously reported results, Triassic granitoids were emplaced almost identically at ca. 225 Ma throughout the areas of Hamyang and Sangju oi Yeongnam massif and Baengnok, Jeomchon and Goesan of Okcheon metamorphic belt. There were significant gap of non-magmatism before the resume of granitic activities over the large areas of Hamyang-gun, Geochang-gun, Gimcheon-si and Seongju-gun from Triassic-Jurassic boundary to early Jurassic, 200-194 Ma. Igneous activity within the Yeongnam massif of this period has not been reported from the Okcheon belt or Gyeonggi massif and may reflect distinct tectonic environment. Around 170 Ma, when Yeongju granodiorite was emplaced, there were active granitic magamtism throughout the Yeongnam massif, Okcheon belt and also Gyeonggi massif.

• Economic and Environmental Geology
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• v.34 no.1
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• pp.105-117
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• 2001

The characteristics of hydrogeochemistry and fluorine distribution in drinking groundwater from limestone and granite were studied in the Keumsan-Wanju area, where major important fluorite-deposits are distributed. The hydrochemical properties of groundwater from studied area arc commonly characterized as $Ca-HC0_3$ water type. However, some of the groundwater samples collected from Jurassic and Cretaceuus granites belong to $Ca-Na-HC0_3 and Na-HC0_3$ type, respectively. The contamination of drinking groundwater by minewater from the nearby fluorite deposits is not found yet. However, groundwater having high F contents up to 1].4 mgll, which is higher than the drinking water limit, is found from the wells located in Cretaceous granite. The tluorine contents in groundwater generally increase with increasing well depth. The concentrations of F in the groundwater show a positive relationship with the values of Na, $HC0_3, Cl. Si0_2$, pH, whereas a negative relationship with Ca. The positive correlation of F-concentrations to major elements ($Si0_2$, Na, CI) and trace elements (Li, B, Rb) may suggest that the groundwater come from the decomposition of tluoride-bearing silicate minerals within highly differentiated granitic rocks, Therefore, wells for drinking water should not be developed or should be drilled within shallow level in the Cretaceous granite region to reduce the F contents in the groundwater.

• Economic and Environmental Geology
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• v.9 no.1
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• pp.27-43
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• 1976

The flourite in Hwacheon, Hwanggangri and Keumsan district are major fluorite producing areas in Korea. The fluorite deposits of Hwacheon district are wholly fissure filling hydrothermal veins embedded in Precambrian gneiss and schists and Jurassic granites. Also some fluorite deposits are emplaced in felsite whose age is unknown. Emplacement of most fluorite veins of the district are controlled by EW fracture system. Fluorites are generally accompanied to chalcedonic quartz and also kaolinite, montmorillonite, dickite and calcite in parts. Vertical and lateral mineral zonings are not distinct. The fluorite deposits in the Hwanggangri district are wholly embedded in limestone and other calcareous sediments of Paleozoic Yeongweol Group. Most of the fluorite deposits belong to one of two categories which are steeply. dipping veins and gently dipping replacement deposits adjacent to Late Cretaceous(83-90mys) granite bodies. The strikes of fluorite veins of Hwanggangri district mostly occupy the fractures of $N30^{\circ}-40^{\circ}E$ and $N30^{\circ}-40^{\circ}W$ system. Fluorites are accompanied to calcite, milky quartz, chalcedonic quartz, and also montmorillonite, kaolinite in parts. But in some deposits, scheelite, various sulfide minerals and barite are accompanied. Emplacement of fluorite deposits are largely controlled by lithology and structures of this district. In some deposits fluorite veins gradate to scheelite veins and also telescoping of the mineral zones are found in this district. In the Keumsan district, fissure-filled fluorite veins and replacement deposits are mostly emplaced in limestone of Paleozoic Yeongweol Group, late Cretaceous quartz-porphyry, granite and sandstone. Some deposits are emplaced in Precambrian metasediments. Mineralogy and other characteristics of the deposits in this district is similar to those of Hwanggangri district. Fluid inclusion studies reveal the difference of salinities, $CO_2$ contents of ore fluid and temperatures during fluorite mineral deposition in the these districts. In Hwacheon district, ore-fluids were comparatively dilute brine and low $CO_2$ content. Filling temperatures ranges $104^{\circ}C$ to $170^{\circ}C$. In the Chuncheonshinpo mine, most deeply exploited one in this district, salinitles range 0.5-2. 2wt. % NaCl and filling temperatures range from $116^{\circ}C$ to $143^{\circ}C$. In the Hwanggangri district, ore fluids were complex and filling temperature ranges very widly. In the contact metasomatic fluorite deposits, ore fluid were NaCl rich brines with moderate $CO_2$ content and filling temperatures range from $285^{\circ}C$ to above $360^{\circ}C$. Fluids inclusions in tungsten and sulfide minerals bearing fluorite veins show high $CO_2$ content up to 31wt. %. Filling temperature ranges from $101^{\circ}C$ to $310^{\circ}C$. Fluids inclusions In mainly fluorite bearing veins were more dilute brine and low $CO_2$ contents. Filling temperatures range from $95^{\circ}C$ to $312^{\circ}C$. Filling temperature of fluid inclusions of Keumsan district are between $95^{\circ}C$ and $237^{\circ}C$. Data gathered from geologic, mineralogic and fluid inclusion studies reveal that fluorite mineralization in H wacheon district proceeded at low temperature with dilute brine and low $CO_2$ content. In Hwangganri district, fluorite mineralization proceeded by several pulse of chemically distinct ore fluids and formed the mineralogically different type of deposits around cooling granite pluton which emplaced comparatively shallow depth.

• Journal of the Mineralogical Society of Korea
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• v.19 no.4 s.50
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• pp.355-361
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• 2006

Artificially crushed sands occupy approximately 30 percent of the total consumption in South Korea. The demand for the crushed sands is expected to rise in the future. Most manufacturers use granitic rocks to produce the crushed sands. During the manufacturing process, fine fractions (i.e., sludges or particles smaller than 63 microns) are removed through the process of flocculation. The fine fraction occupies about 15% of the total weight. The sludges are comprised of quartz, feldspars, calcite, and various kinds of clay minerals. Non-clay minerals occupy more than 75 percent of the sluges weight, according to the XRD semi-quantification measurement. Micas, kaolinites, chlorite, vermiculite, and smectites occur as minor constituents. The sludges from Jurassic granites contain more kaolinites and $14{\AA}$-types than those from the Cretaceous ones. The chemical analysis clearly shows the difference between the parent rocks and the sludges in chemical compositions. Much of colored components in the sludges was accumulated as the weathering products. Particle size analysis results show that the sludges can be categorized as silt loam in a sand-silt-clay triangular diagram. This result was for her confirmed by the hydraulic conductivity data. In South Korea, the sludges remained after crushed sand production are classified as an industrial waste because of their impermeability, and which is caused by their high silt and clay fractions.

• Economic and Environmental Geology
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• v.37 no.5
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• pp.459-475
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• 2004

The geology of the Kualakulun area in Middle Kalimantan, Indonesia comprises Permian to Carboniferous Pinoh Metamorphic Rocks and Cretaceous Sepauk Plutonics of the Sunda Shield, late Eocene Tanjung Formation, Oligocene Malasan Volcanics, Oligocene to early Miocene Sintang Intrusives and Quaternary alluvium. Sepauk Plutonic rocks are classified as the calc-alkaline series and the S-type granite. Sintang Intrusive rocks are basic-intermediate and intermediate rocks, and consists of basalt, basaltic andesite, basaltic trachyandesite and trachyandesite. The Malasan Volcanics are characterized by intermediate dacitic pyroclasticl and minor lavas and belong to the subalkaline (calc-alkaline and tholeiitic) series. The whole-rock K-Ar ages of the fine-grained biotite granites and medium-grained granitoids were determined to be 100.5-106.5 Ma and 91.9-102.6 Ma, respectively. The whole-rock K-Ar age of the diorite is 89.1 Ma. K-Ar ages of the Malasan Volcanics and Shintang intrusives show 31.5-36.8 Ma and 24.6-34.5 Ma, respectively, and correspond to the Tertiary time.

• The Journal of Engineering Geology
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• v.10 no.2
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• pp.52-74
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• 2000

The basement rock of upper stream of Keum River Valley consists of Precambrian gneiss which is resistant to weathering. That of mid and lower stream valley, however, is mainly composed of Mesozoic granites which are vulnerable to weathering. The upstream part of Geum River Basin is typified by the deeply-incised and steep meandering streams, whereas mid and lower part is characterized by wide floodplain and gently dipping river bottom toward the Yellow Sea. In particular flooding deposits, in which are imprinted a number of repetitions of erosion and sedimentation during the Holocene, are widely distributed in the lower stream of Geum River Basin. For understanding of erosions in the mid and lower stream of Geum River Basin, the rate of erosion of each small basins were estimated by using the data of field survey, erosional experiments and GIS ananlysis. It was revealed that erosion rate appeared highest in granite areas, and overall areas, in this field survey were represented by relatively high erosion rates. By implemeatation of remote sensing and imagery data, the temporal changes of river bed sediments for about last 11 years were successfully monitored. Observed as an important phenomenon is that the river bed has been risen since 1994 when an embankment (Dyke) was constructed in the estuarine river mouth. From the results derived from the detailed river bed topographical map made in this investigation, the sedimentation of the lower river basin is considered to be deposited with about 5 cm/year for the last 11 years. Based on this river bed profile analysis by HEC-6 module, it is predicted that Geum River bed of Ganggyeong area is continuously rising up in general until 2004. Although extraction of a large amount of aggregates from Gongju to Ganggyung areas, the Ganggyung lower stream shows the distinct sedimentation. Therefore, it is interpreted that the active erosions of tributary basins Geum drainage basins can affect general river bed rising changes of Geum River.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.12 no.1
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• pp.111-122
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• 2009

Abatements of TN and ${NO_3}^-$-N in a horizontal subsurface-flow wetland with litter layer on its surface were compared with those without one. The wetland was constructed in 2001 on floodplain of the Gwangju Stream which flows through Gwangju City in Korea. Its dimensions were 29m in length, 9m in width and 0.65m in depth. A bottom layer of 45cm was filled with crushed granites (15~40mm in diameter) and a middle layer of 10cm had pea pebbles. An upper layer of 5cm contained coarse sands. Reeds (Phragmites australis) growing in natural wetlands were transplanted on its surface. Water of the stream was channelled into the wetland by gravity flow and its effluent was discharged back into the stream. Average Litter layer of 12.2cm was formed on its surface in 2007. The layer and above-ground parts of reeds were eliminated in April 2008. Volumes and water quality of influent and effluent of the wetland were analyzed from May to November in 2007 and 2008, respectively. Inflow into the wetland both in 2007 and 2008 averaged approximately 40$m^3$/day and hydraulic residence time both in 2007 and 2008 was about 1.5days. Influent TN concentration in 2007 and 2008 averaged 3.96 and 3.89mg/L, respectively and average influent ${NO_3}^-$-N concentration in 2007 and 2008 was 2.11 and 2.05mg/L, respectively. With a 0.05 significance level, influent concentrations of TN and ${NO_3}^-$-N, temperatures and pH of effluent, and heights and stem numbers of reeds showed no difference between the wetland with litter layer and without one. TN retention in the wetland with litter layer and without one averaged 64,76 and 54.69%, respectively and ${NO_3}^-$-N removal averaged 60.83 and 50.61%, respectively. Both TN and ${NO_3}^-$-N abatement rates in the wetland with litter layer were significantly high (TN abatement: p<0,001, ${NO_3}^-$-N abatement: p=0.001) when compared with those without one. The subsurface-flow wetland having litter layer on its surface was more efficient for TN and ${NO_3}^-$-N removal.