• Journal of the Korean Electrochemical Society
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• v.10 no.2
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• pp.126-131
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• 2007

The durability problem of Prussian blue in non-aqueous $Li_+$-based electrolytes has been due to the degradation of the Prussian blue electrode matrix during the insertion/extraction processes by $Li_+$. In this work, we designed and synthesised the Prussian blue without reducing the electrochromic performance in non-aqueous $Li_+$-based electrolytes. Prussian blue was electrodeposited on a glass which has ITO coating, and the coating solution is a mixture solution of $FeCl_3\;and\;K_3Fe(CN)_6$ with deionized water added HCl, KCl, and LiCl, respectively. The durability of Prussian blue was evaluated by an in-situ transmittance measurement during a continuous and pulse potential cycling test, and measured by electroactive layer thickness due to evaluating the degradation.

• Journal of Power Electronics
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• v.13 no.4
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• pp.516-527
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• 2013

This paper presents a new overall system for state-of-available-power (SoAP) prediction for a lithium-ion battery pack. The essential part of this method is based on an adaptive network architecture which utilizes both fuzzy model (FIS) and artificial neural network (ANN) into the framework of adaptive neuro-fuzzy inference system (ANFIS). While battery aging proceeds, the system is capable of delivering accurate power prediction not only for room temperature, but also at lower temperatures at which power prediction is most challenging. Due to design property of ANN, the network parameters are adapted on-line to the current battery states (state-of-charge (SoC), state-of-health (SoH), temperature). SoC is required as an input parameter to SoAP module and high accuracy is crucial for a reliable on-line adaptation. Therefore, a reasonable way to determine the battery state variables is proposed applying a combination of several partly different algorithms. Among other SoC boundary estimation methods, robust extended Kalman filter (REKF) for recalibration of amp hour counters was implemented. ANFIS then achieves the SoAP estimation by means of time forward voltage prognosis (TFVP) before a power pulse occurs. The trade-off between computational cost of batch-learning and accuracy during on-line adaptation was optimized resulting in a real-time system with TFVP absolute error less than 1%. The verification was performed on a software-in-the-loop test bench setup using a 53 Ah lithium-ion cell.

• The Transactions of the Korean Institute of Power Electronics
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• v.21 no.4
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• pp.335-342
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• 2016

This paper proposes an energy storage-assisted, series-connected module-integrated power conversion system that integrates a photovoltaic power conditioner and a charge balancing circuit. In conventional methods, a photovoltaic power conditioner and a cell-balancing circuit are needed for photovoltaic systems with energy storage devices, but they cause a complex configuration and high cost. Moreover, an imbalanced output voltage of the module-integrated converter for PV panels can be a result of partial shading. Partial shading can lead to the fault condition of the boost converter in shaded modules and high voltage stresses on the devices in other modules. To overcome these problems, a bidirectional buck-boost converter with an integrated magnetic device operating for a charge-balancing circuit is proposed. The proposed circuit has multiple secondary rectifiers with inductors sharing a single magnetic core, which works as an inductor for the main bidirectional charger/discharger of the energy storage. The secondary rectifiers operate as a cell-balancing circuit for both energy storage and the series-connected multiple outputs of the module-integrated converter. The operating principle of the cell-balancing power conversion circuit and the power stage design are presented and validated by PSIM simulation for analysis. A hardware prototype with equivalent photovoltaic modules is implemented for verification. The results verify that the modularized photovoltaic power conversion system in the output series with an energy storage successfully works with the proposed low-cost bidirectional buck-boost converter comprising a single magnetic device.

• Journal of Power Electronics
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• v.18 no.2
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• pp.343-355
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• 2018

A wide-voltage-conversion range bidirectional DC-DC converter is proposed in this paper. The topology is comprised of one typical LC energy storage component and a special common grounded asymmetric H-bridge with four active power switches/anti-parallel diodes. The narrow output PWM voltage is generated from the voltage difference between two normal (wider) output PWM voltages from the asymmetric H-bridge with duty cycles close to 0.5. The equivalent switching frequency of the output PWM voltage is double the actual switching frequency, and a wide step-down/step-up ratio range is achieved. A 300W prototype has been constructed to validate the feasibility and effectiveness of the proposed bidirectional converter between the variable low voltage side (24V~48V) and the constant high voltage side (200V). The slave active power switches allow ZVS turn-on and turn-off without requiring any extra hardware. The maximum conversion efficiency is 94.7% in the step-down mode and 93.5% in the step-up mode. Therefore, the proposed bidirectional topology with a common ground is suitable for energy storage systems such as renewable power generation systems and electric vehicles with a hybrid energy source.

• Journal of Electrochemical Science and Technology
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• v.6 no.3
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• pp.75-80
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• 2015

We introduce a new synthesis method to prepare small TiO₂ nanoparticles with a narrow particle size distribution, which is achieved by electron beam (E-beam) irradiation. The effects of E-beam irradiation on the synthesis of TiO₂ nanoparticles and the electrochemical performance of TiO₂ nanoparticles as alternative anode materials for Li-ion batteries are investigated. The TiO₂ nanoparticles induced by E-beam irradiation present better cycling performance and rate capability than the TiO₂ nanoparticles synthesized by normal hydrolysis reaction. The better electrochemical performance is attributed to small particle size and narrow particle size distribution, resulting in the large surface area that provides innumerable reaction sites and short diffusion length for Li⁺ through TiO₂ nanoparticles.

• Journal of Electrical Engineering and Technology
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• v.12 no.6
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• pp.2237-2246
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• 2017

A nonisolated two-phase bidirectional dc-dc converter (NTPBDC) is a very attractive solution for the battery energy storage system (BESS) applications due to the high voltage conversion ratio and the reduced conduction loss of the switching devices. However, a hard-switching based NTPBDC decreases the overall voltage conversion efficiency. To overcome this problem, this paper proposes a novel NTPBDC with zero-voltage-transition (NTPBDC -ZVT). The soft-switching for the boost and buck main switches is achieved by using a resonant cell, which consists of a single resonant inductor and four auxiliary switches. Furthermore, due to the single resonant inductor, the proposed NTPBDC-ZVT has the advantages of simple implementation, reduced size, and low cost. The validity of the proposed NTPBDC-ZVT is verified through experimental results.

• Transactions of the Korean hydrogen and new energy society
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• v.32 no.5
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• pp.388-400
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• 2021

Power to gas (P2G) is one of the energy storage technologies that can increase the storage period and storage capacity compared to the existing battery type. One of P2G technology produces hydrogen by decomposing water from renewable energy (electricity) and the other produces CH4 by reacting hydrogen with CO2. This study is an experimental study to produce CH4 by reacting CO2 of biogas with hydrogen using a 40 wt% Ni-Mg-Al catalyst and a commercial catalyst. Catalyst characteristics were analyzed through H2-TPR, XRD, and XPS instruments of 40% Ni catalyst and commercial catalyst. The effect on the CO2 conversion rate and CH4 selectivity was analyzed, and the activities of a 40% Ni catalyst and a commercial catalyst were compared. As a result of experiment, In the case of a 40 wt% catalyst, the maximum CO2 conversion rate showed 77% at the reaction temperature of 400℃. Meanwhile, the commercial catalyst showed a maximum CO2 conversion rate of 60% at 450℃. When 50% of CO was added to the CO2 methanation reaction, the CO2 conversion rate was increased by about 5%. This is considered to be due to the atmosphere in which the CO reaction can occur without the process of converting to CH4 after forming carbon and CO as intermediates in terms of the CO2 mechanism on the catalyst surface.

• Journal of the Korean Electrochemical Society
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• v.10 no.4
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• pp.252-256
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• 2007

A series of spherical porous carbons were prepared via resorcinol-formaldehyde (RF) sol-gel polymerization in the presence of cationic surfactant (CTAB, cetyltrimethylammonium bromide), wherein the carbon sphere size was controlled by varying the CTAB introduction time after a pre-determined period of addition reaction (termed as "pre-curing"). The sphere size gradually decreases with an increase in the pre-curing time within the range of 30-150 nm. The carbons possess two types of pores; one inside carbon spheres (intra-particle pores) and the other at the interstitial sites made by carbon spheres (inter-particle pores). Of the two, the surface exposed on the former was dominant to determine the electric double-layer capacitor (EDLC) performance of porous carbons. As the intra-particle pores were generated inside RF gel spheres by gasification, the pore diameter was similar for all these carbons, thereby the pore length turned out to be a decisive factor controlling the EDLC performance. The charge-discharge voltage profiles and complex capacitance analysis consistently illustrate that the smaller-sized RF carbons deliver a better rate capability, which must be the direct result of facilitated ion penetration into shorter pores.

• Journal of the Korean Solar Energy Society
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• v.27 no.1
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• pp.75-81
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• 2007

Steam reforming of methane using Xe-arc solar simulator was studied for the application of concentrated solar energy into chemical reaction. The reactor, a volumetric absorber, consisted of a porous ceramic foam disk coated with commercial reforming catalyst. Operating temperature was in the range of $450\;-\;550^{\circ}C$ and the excess steam ratio to methane was from 3.0 to 5.0. At the steady-state condition, the conversion of methane Increased with temperature in the range of 15 % - 30 % and the experimentally determined conversion was found to be close to theoretical equilibrium conversion. It was also found that the CO selectivity slightly decreased with excess steam ratio. Finally, the conversion of methane decreased significantly with space velocity of reactants.

• 한국초전도학회:학술대회논문집
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• v.9
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• pp.305-309
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• 1999

This paper presents an high efficiency energy conversion system for very high-speed flywheel energy storage system using high Tc superconducting bearings. Main configuration of power convertor is designed to replace of the conventional battery with EMB(Electro Mechanical Battery). PMSM(Permanent Magnet Synchronous Motor) using Halbach array is used as the energy conversion system of motor and generator. Some PWM methods for the high frequency inverter is described and the power factor effects to the torque characteristics and efficiency of the motor and generator is analyzed. As the results, it is verified that the inverter output current is well regulated to be in-phase or inverse-phase sinusoidal waveform to have the wide operational range from 2,500rpm to 42,000rpm. Proposed circuit is designed to obtain the very high speed, high efficiency and stable rotational characteristics, and to be applied to1.2r[kW]/65[Wh] system.