Journal of the Korean Electrochemical Society (전기화학회지)

The Korean Electrochemical Society (한국전기화학회)
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Electrochromic Properties of Li+-Modified Prussian Blue

리튬이온이 첨가된 프루시안 블루의 전기변색 특성 연구

  • Yoo, Sung-Jong (School of Chemical and Biological Engineering & Research Center for Energy Conversion and Storage, Seoul National University) ;
  • Lim, Ju-Wan (School of Chemical and Biological Engineering & Research Center for Energy Conversion and Storage, Seoul National University) ;
  • Park, Sun-Ha (School of Chemical and Biological Engineering & Research Center for Energy Conversion and Storage, Seoul National University) ;
  • Won, Ho-Youn (Hanwha Chemical R&D Center) ;
  • Sung, Yung-Eun (School of Chemical and Biological Engineering & Research Center for Energy Conversion and Storage, Seoul National University)
  • 유성종 (서울대학교 화학생물공학부) ;
  • 임주완 (서울대학교 화학생물공학부) ;
  • 박선하 (서울대학교 화학생물공학부) ;
  • 원호연 (한화석유화학 중앙연구소) ;
  • 성영은 (서울대학교 화학생물공학부)
  • Published : 2007.05.28
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Abstract

The durability problem of Prussian blue in non-aqueous $Li_+$-based electrolytes has been due to the degradation of the Prussian blue electrode matrix during the insertion/extraction processes by $Li_+$. In this work, we designed and synthesised the Prussian blue without reducing the electrochromic performance in non-aqueous $Li_+$-based electrolytes. Prussian blue was electrodeposited on a glass which has ITO coating, and the coating solution is a mixture solution of $FeCl_3\;and\;K_3Fe(CN)_6$ with deionized water added HCl, KCl, and LiCl, respectively. The durability of Prussian blue was evaluated by an in-situ transmittance measurement during a continuous and pulse potential cycling test, and measured by electroactive layer thickness due to evaluating the degradation.

[ $Li_+$ ]를 기반으로 하는 비수용액 전해질에서 Prussian blue가 degradation이 없이 구동할 수 있도록 소재를 design하고 제조하여 전기화학적 변색특성을 연구하였다. Prussian blue는 ITO가 코팅되어 있는 유리판위에 일정전류-전착법으로 코팅을 했고, 이 때 사용된 코팅 용액은 $FeCl_3,\;K_3Fe(CN)_6$을 deionized water에 녹이고, HCl, KCl, LiCl을 각각 넣었다. 전기화학적 변색특성을 비교하기 위해 continuous와 pulse potential cycle 하는 동안 transmittance 변화를 in-situ He-Ne laser를 이용하여 측정하였고, electroactive layer thickness를 통해 degradation된 정도를 실험하였다.

Keywords

References

  1. C. G Granqvist, 'Handbook of Inorganic Electrochromic Materials', Elsevier, Amsterdam, (1995)
  2. P. J. Gellings and H. J. M. Bouwmeester, C. G. Granqvist (Eds.), 'The CRC Handbook of Solid State Electrochemistry', CRC press, Boca Raton, (1997)
  3. P. R. Somani and S. Radhakrishnan, 'Electrochromic materials and devices: present and future' Mater. Chem. Phys., 77, 117 (2003) https://doi.org/10.1016/S0254-0584(01)00575-2
  4. U. Bach, D. Corr, D. Lupo, F. Pichot, and M. Ryan, 'Nanomaterials-based electrochromics for paper-quality displays' Adv. Mater., 14, 845 (2002) https://doi.org/10.1002/1521-4095(20020605)14:11<845::AID-ADMA845>3.0.CO;2-8
  5. D. Corr, U. Bach, D. Fay, M. Kinsella, C. McAtamney, F. O' Reilly, S. N. Rao, and N. Stobie, 'Coloured electrochromic 'paper-quality' displays based on modified mesoporous electrodes' Solid State Ionics, 165, 315 (2003) https://doi.org/10.1016/j.ssi.2003.08.054
  6. R. J. Mortimer, 'Organic electrochromic materials' Electrochim. Acta, 44, 2971 (1999) https://doi.org/10.1016/S0013-4686(99)00046-8
  7. K.-S. Ahn, Y.-C. Nah, K.-Y. Cho, S.-S. Shin, J.-K. Park, and Y.-E. Sung, 'All-solid-state electrochromic device composed of $WO_{3}$ and $Ni(OH)_{2}$ with a $Ta_{2}O_{5}$ protective layer' Appl. Phy. Lett., 81, 3930 (2002) https://doi.org/10.1063/1.1522478
  8. S. K. Deb, 'Optical and photoelectric properties and color centers in thin-films of tungsten oxide' Philos. Mag., 27, 801 (1973) https://doi.org/10.1080/14786437308227562
  9. C. G. Granqvist, 'Electrochromic tungsten oxide films: Review of progress 1993-1998' Sol. Energy Mater. Sol. Cells, 60, 201 (2000) https://doi.org/10.1016/S0927-0248(99)00088-4
  10. C. G. Granqvist, E. Avendano, and A. Azens, 'Electrochrornic coatings and devices: survey of some recent advances' Thin Solid Films, 442, 201 (2003) https://doi.org/10.1016/S0040-6090(03)00983-0
  11. V. D. Neff, 'Electrochemical oxidation and reduction of thin films of Prussian blue' J. Electrochem. Soc., 125, 886 (1978) https://doi.org/10.1149/1.2131575
  12. H. Kellawi and D. R. Rosseinsky, 'Electrochemical bichromic behaviour of ferric ferrocyanide (Prussian Blue) in thin film redox processes' J. Electroanal. Chem., 131, 373 (1982) https://doi.org/10.1016/0022-0728(82)87089-7
  13. R. J. Mortimer and D. R. Rosseinsky, 'Electrochemical polychromicity in iron hexacyanoferrate films, and a new films form of ferric ferricyanide' J. Electroanal. Chem., 151, 133 (1983) https://doi.org/10.1016/S0022-0728(83)80429-X
  14. H. J. Buser, D. Schwarzenbach, W. Petter, and A. Ludi, 'The crystal structure of Prussian Blue: $Fe_{4}\left[Fe(CN)_{6}_\right]_{3}$.$xH_{2}O$' Inorg. Chem., 16, 2704 (1977) https://doi.org/10.1021/ic50177a008
  15. F. Herren, P. Fischer, A. Ludi, and W. Haelg, 'Neutron diffraction study of Prussian Blue, $Fe_{4}\left[Fe(CN)_{6}_\right]_{3}$.$xH_{2}O$. Location of water molecules and long-range magnetic order' Inorg. Chem., 19, 956 (1980) https://doi.org/10.1021/ic50206a032
  16. T. Ikeshoji and T. Iwasaki, 'In situ x-ray diffraction measurement of Prussian blue modified electrode' Inorg. Chem., 27, 1123 (1988) https://doi.org/10.1021/ic00280a002
  17. N. Leventis and Y. C. Chung, 'Thin-layer type electrochemistry and stability studies of Prussian blue films in non-aqueous electrolytes' J. Electrochem. Soc., 138, L21 (1991) https://doi.org/10.1149/1.2085999
  18. N. Leventis and Y. C. Chung, 'Poly(3-methylthiophene) Prussian blue-a new composite electrochromic material' J. Mater. Chem., 2, 289 (1992) https://doi.org/10.1039/jm9920200289
  19. M. A. Habib and S. P. Maheswari, 'Effect of temperature on a complementary $WO_{3}$-Prussian blue electrochromic system' J. Electrochem. Soc., 139, 2155 (1992) https://doi.org/10.1149/1.2221194
  20. M. K. Carpenter and R. S. Conell. 'A single-film electrochromic device' J. Electrochem. Soc., 137, 2464 (1990) https://doi.org/10.1149/1.2086962
  21. I. M. Kodintsev, G. A. Kokarev, V. A. Kolesnikov, and S. M. Sokolova, 'Electrochromism of films of $WO_{3}$ in acetonitrile solutions of electrolytes' Sov. Electrochem., 19, 1024 (1983)
  22. S. J. Yoo, J. W. Lim, and Y.-E. Sung, 'Improved electrochromic devices with an inorganic solid electrolyte protective layer' Sol. Energy Mater. Sol. Cells, 90, 477 (2006) https://doi.org/10.1016/j.solmat.2005.04.033
  23. K. Itaya, T. Ataka, and S. Toshima, 'Spectroelectrochemistry and electrochemical preparation method of Prussian blue modified electrodes' J. Am. Chem. Soc., 104, 4767 (1982) https://doi.org/10.1021/ja00382a006
  24. L. M. Siperko and T. Kuwana, 'Electrochemical and spectroscopic studies of metal hexacynometalate films' J. Electrochem. Soc., 130, 396 (1983) https://doi.org/10.1149/1.2119718
  25. J. J. Garcia-Jareo, J. J. Navarro, A. F. Roig, H. Scholl, and F. Vicente, 'Impedance analysis of Prussian blue films deposited on ITO electrodes' Electrochim. Acta, 40, 1113 (1995) https://doi.org/10.1016/0013-4686(95)00017-9

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