• Polymer(Korea)
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• v.24 no.5
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• pp.599-609
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• 2000

In order to improve the mechanical properties of unsaturated polyester (UPE) resins, the UPE resins with different glycol molar ratios were prepared. The effects of molar ratios of the UPE resins on the curing behaviors and mechanical properties were investigated. The microgel reaction mechanism was employed to characterize the system. It was found that the final conversion increased with increasing NPG molar ratios, and the conversion at the peak of differential scanning calorimetry (DSC) thermogram appeared to decrease with increasing NPG molar ratios. The flexural strength, tensile modulus, water resistance, and infiltration increased with increasing NPG content, but the tensile strength, tensile elongation, and flexural modulus decreased. Among the UPE resins prepared from the glycols with the molar ratios (PG/NPG) of 0.5/0.5, 0.25/0.75, those of laminated composites plates showed better mechanical properties.

• Journal of the Korean Chemical Society
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• v.39 no.1
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• pp.57-65
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• 1995

The electrochemical reduction of methylene blue (MB) in 1.0${\times}$10-2 M KNO3 aqueous solution was investigated by direct current (DC), differential pulse (DP) polarography, cyclic voltammetry (CV) and controlled potential coulometry (CPC). The electrode reduction of melthylene blue was processed CE reaction mechanism by two electrons transfer at the first reversible wave (- 0.18 volts vs. Ag/AgCl). MB was strongly adsorbed on the stationary mercury electrode and the reduction product of conptrolled potential electrolysis was rapidly auto-oxidized in air to the original methylene blue. Upon the basis of interpretation of cyclic voltammogram with pH change, possible CE electrode reaction mechanism was suggested.

• Journal of the Semiconductor & Display Technology
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• v.19 no.1
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• pp.29-35
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• 2020

The cure characteristics of three kinds of naphthalene type epoxy resins(NET-OH, NET-MA, NET-Epoxy) with a 2-methyl imidazole(2MI) catalyst were investigated for preparing sheet epoxy molding compound(SEMC) for wafer level package(WLP) applications, comparing with diglycidyl ether of bisphenol-A(DGEBA) and 1,6-naphthalenediol diglycidyl ether(NE-16) epoxy resin. The cure kinetics of these systems were analyzed by differential scanning calorimetry with an isothermal approach, and the kinetic parameters of all systems were reported in generalized kinetic equations with diffusion effects. The NET-OH epoxy resin represented an n-th order cure mechanism as like NE-16 and DGEBA epoxy resins, however, the NET-MA and NET-Epoxy resins showed an autocatalytic cure mechanism. The NET-OH and NET-Epoxy resins showed higher cure conversion rates than DGEBA and NE-16 epoxy resins, however, the lowest cure conversion rates can be seen in the NET-MA epoxy resin. Although the NETEpoxy and NET-MA epoxy resins represented higher cure reaction conversions comparing with DGEBA and NE-16 resins, the NET-OH showed the lowest cure reaction conversions. It can be figured out by kinetic parameter analysis that the lowest cure conversion rates of the NET-MA epoxy resin are caused by lower collision frequency factor, and the lowest cure reaction conversions of the NET-OH are due to the earlier network structures formation according to lowest critical cure conversion.

• Bulletin of the Korean Chemical Society
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• v.24 no.12
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• pp.1751-1756
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• 2003

An electrochemical study related to the electroreduction of 4-amino-6-methyl-3-thio-1,2,4-triazin-5-one(I), 6-methyl-3-thio-1,2,4-triazin-5-one(II), and 2,4-dimetoxy-6-methyl-1,3,5-triazine(III) in dimethylformamide at glassy carbon electrode has been performed. A variety of electrochemical techniques, such as differential pulse voltammetry (DPV), cyclic voltammetry (CV), chronoamperometry, and coulometry were employed to clarify the mechanism of the electrode process. The compounds I and II with thiol group exhibited similar redox behavior. Both displayed two cathodic peaks, whereas the third compound, III, without thiol group showed only one cathodic peak in the same potential range of the second peak of I and II. The results of this study suggest that in the first step the one electron reduction of thiol produced a disulfide derivative and in the second reduction step the azomethane in the triazine ring was reduced in two electron processes. A reduction mechanism for all three compounds is proposed on this basis. In addition, some numerical constants, such as diffusion constant, transfer coefficient, and rate constant of coupled chemical reaction in the first reduction peak were also reported.

• Proceedings of the Korean Geotechical Society Conference
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• 2009.09a
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• pp.430-440
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• 2009

Top-Base Foundation(TBF) was developed in Japan as a factory made concrete product. It is actively used in 6,000 sites by the end of 1980s in Japan and applied for a domestic patent in 1985. It is a shallow foundation whose effectiveness is proven by many relevant researchers and engineers. TBF was introduced to Korea in 1991 and has been applied mainly to architectural structures to date. Currently, the effectiveness in bearing capacity and settlement of TBF is being underestimated for civil engineering structures. Characteristics of Top-Base Foundation studied in Japan and Korea is known as follows: (1) as concrete part and crushed stone behave together, they perform the function of rigid mat; (2) the conical part and pile part of TBF disperses load by interaction with the crushed stone; (3) by preventing lateral strain and differential settlement on lower ground, it improves bearing capacity and constrains settlement at the same time. In Korea, it is used mostly in clayey soft grounds. The formula of bearing capacity and settlement of TBF suggested in Japan give the values of the underestimated. bearing capacity while its settlement is overestimated in comparison with the values measured from the field loading test. Therefore, in this study, the stress delivery mechanism of Top-Base Foundation developed in Japan and Floating Top Base developed in Korea is investigated through numerical analysis and laboratory model test.

• Journal of the Korean Ceramic Society
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• v.35 no.11
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• pp.1162-1170
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• 1998

Applicability of crystallization kinetics on thermal analysis was investigated for PbO-TiO2-B2O3-BaO glass systems together with theoretical background of kinetics and electron microscopic observations on nu-cleation and crystallization. Kissinger equation can be used on DTA under the assumption that the nucleus density is fixed during DTA runs. Crystallization mechanism affected on the activation energy Ek obtained from powder samples which is used for domination of surface crystallization. Avrami parameter n that was obtained from Ozawa equation represented closely the crystallization mechanisms observed by an electron microscope. The modified Kissinger equation takes into account crystallization mechanism thereby pro-ducing the true activation energy of crystallization.

• Smart Structures and Systems
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• v.24 no.1
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• pp.95-110
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• 2019

The semi-active impact damper (SAID) is proposed to improve the damping efficiency of traditional passive impact dampers. In order to investigate its damping mechanism and vibration control effects on realistic engineering structures, a 20-story nonlinear benchmark building is used as the main structure. The studies on system parameters, including the mass ratio, damping ratio, rigid coefficient, and the intensity of excitation are carried out, and their effects both on linear and nonlinear indexes are evaluated. The damping mechanism is herein further investigated and some suggestions for the design in high-rise buildings are also proposed. To validate the superiority of SAID, an optimal passive particle impact damper ($PID_{opt}$) is also investigated as a control group, in which the parameters of the SAID remain the same, and the optimal parameters of the $PID_{opt}$ are designed by differential evolution algorithm based on a reduced-order model. The numerical simulation shows that the SAID has better control effects than that of the optimized passive particle impact damper, not only for linear indexes (e.g., root mean square response), but also for nonlinear indexes (e.g., component energy consumption and hinge joint curvature).

• Molecules and Cells
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• v.46 no.1
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• pp.57-64
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• 2023

In eukaryotic cells, a key RNA processing step to generate mature mRNA is the coupled reaction for cleavage and polyadenylation (CPA) at the 3' end of individual transcripts. Many transcripts are alternatively polyadenylated (APA) to produce mRNAs with different 3' ends that may either alter protein coding sequence (CDS-APA) or create different lengths of 3'UTR (tandem-APA). As the CPA reaction is intimately associated with transcriptional termination, it has been widely assumed that APA is regulated cotranscriptionally. Isoforms terminated at different regions may have distinct RNA stability under different conditions, thus altering the ratio of APA isoforms. Such differential impacts on different isoforms have been considered as post-transcriptional APA, but strictly speaking, this can only be considered "apparent" APA, as the choice is not made during the CPA reaction. Interestingly, a recent study reveals sequential APA as a new mechanism for post-transcriptional APA. This minireview will focus on this new mechanism to provide insights into various documented regulatory paradigms.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.29 no.8A
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• pp.879-888
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• 2004

In this paper, we propose a real time QoS(Quality of Service) guaranteed transmission mechanism for MPEG video traffic at the congested node in IP based networks. Recent spread of the Internet has increased the demands of a real time multimedia service of the quality, Because the type of Internet services can, however, offer the best effort delivery strategies, it is difficult to treat all the types of traffic with differential COS (Class of Service). Most of all, the hierarchical coding method of MPEG data utilizes the reference frame for the motion prediction. The loss of the reference frames makes QoS of the video traffic degraded because the reference frame bit error causes the consecutive packet loss. Therefore we have studied the real time QoS guaranteed mechanism for video traffic by analyzing the previous methods. Computer simulation results show that the proposed scheme has better performance than the previous one.

• Journal of the Microelectronics and Packaging Society
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• v.13 no.2 s.39
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• pp.15-19
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• 2006

The resistance switching characteristics of amorphous $SiO_2$ and poly-crystalline $TiO_2$ were investigated. Both films exhibit well defined switching characteristics with low and high resistance states. From I-V curve analyses, it was found that the low resistance states of both films obey an ohmic conduction mechanism and the high resistance states show generation of a Schottky potential barrier. Regarding the mechanism for resistance switching of the binary oxide, it is suggested that the generation and annihilation of potential barriers accounts for the changes to the high resistance state and low resistance state, respectively. The device operation characteristic parameters such as reset and set voltages of $TiO_2$ are distinctly smaller than those of $SiO_2$, indicating that the values are related to the dielectric constant.