• Title/Summary/Keyword: contact effect

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The Graft Polymerization of Acrylic Acid in Vapour Phase onto Poly(ethylene terephthalate) by Cold Plasma Part (I) (저온 Plasma를 이용한 Poly(ethylene terephthalate)에의 Acrylic Acid의 기상 Graft 공중합 반응(I))

  • 천태일;최석철;모상영
    • Textile Coloration and Finishing
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    • v.1 no.1
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    • pp.7-18
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    • 1989
  • The distinguishing characteristic of the glow discharge is that chemical reaction induced by partially ionized gases are limited only to the substrate surface. Most studies have been done on the plasma etching and polymerization. The graft polymerization in vapour phase by cold plasma has been rarely investigated. In this study the system of tub3ar reaction chamber with capacitively coupled electrode of alternative current of 60 Hz was employed for the graft polymerization. The graft polymerization of Acylic Acid(AA) onto the poly (ethylene terephthalate) (PET) was carried out by treatment of PET film and fabric by cold plasma (glow discharge of argon gas), followed by the supply of AA vapour. The graft yield was about 1 wt%. The surface property was determined by contact angle, the surface tension was evaluated by zisman’s plot and equation of surface tension mesurement. The results were as follows: 1. In order to obtain lower contact angle, it was effective to avoid the vicinity of electrodes for a setting position of substrate. 2. Contact angle affected on the monomer pressure and its duration of exposure to the acid vapour. 3. Polymer radical formation was influenced by the changes of the value of current density and plasma treatment time. 4. Total surface tension of plasma grafted PET film increased. With an increase in the carboxylic acid content, the dispersion force decreased, while, the polar force and hydrogen bonding force increased. 5. The contact angle decreased from $75^\circ$ to around $30^\circ$ by plasma grafting. There was no ageing effect on the contact angle after 4 months.

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A Case of Allergic Contact Dermatitis Treated with Korean Medicine (알레르기성 접촉피부염 치험 1례)

  • Kim, Ji-Soo;Park, Soo-Yeon;Choi, Chang-Won;Kim, Kyeong-Soo;Kim, Kyeong-Ok;Wei, Tung-Shuen;Yang, Seung-Joung
    • The Journal of the Society of Korean Medicine Diagnostics
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    • v.19 no.2
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    • pp.115-124
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    • 2015
  • Objective This study is designed to investigate the effect of Korean medical therapy on Allergic contact dermatitis patient. Method This is a case report on a female patient who has been suffering from allergic contact dermatitis. To reduce her symptoms, we provided with internal herbal medicine 3 times a day, acupuncture therapy two time a day and Carbon phototherapy one time a day. Results After series of treatments, the symptoms of allergic contact dermatitis were remarkably improved. SCORAD Index was changed from 77.3 to 13.6. Conclusions This study shows us that Korean medical treatments has remedial values for dermatitis patients. Hence, more studies should be demanded in Korean medicine for elevation of treatment rate.

Effect of Kinematic Motion on Changes in Coefficients of Friction of Porcine Knee Joint Cartilage (기구학적 운동이 돼지 무릎 관절연골의 마찰계수 변화에 미치는 영향)

  • Kim, Hwan;Kim, ChoongYeon;Lee, KwonYong;Kim, DaeJoon;Kim, DoHyung
    • Tribology and Lubricants
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    • v.29 no.1
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    • pp.46-50
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    • 2013
  • In this study, the frictional behaviors of articular cartilage against a Co-Cr alloy in two types of kinematic motions were compared. Cartilage pins were punched from the femoral condyles of porcine knee joints, and Co-Cr alloy disks were machined from orthopedic-grade rods and polished to a surface roughness ($R_a$) of 0.002. Friction tests were conducted by using a pin-on-disk-type tribotester in phosphate buffered saline (PBS) under pressures of 0.5, 1, and 2 MPa. All tests were performed in the repeat pass rotational (ROT) and the linear reciprocal (RCP) sliding motions with the same sliding distance and speed of 50 mm/s. The coefficients of friction of the cartilage against the Co-Cr alloy increased with the sliding time in both kinematic motions for all contact pressures. The maximum coefficients of friction in RCP motion were 1.08, 2.82, and 1.96 times those in ROT motion for contact pressures of 0.5, 1, and 2 MPa, respectively. As the contact pressure increased, the coefficients of friction gradually increased in RCP motion, whereas they decrease and then increased in ROT motion. The interaction between the directional change of the shear stress and the orientation of collagen fiber in the superficial layer of the cartilage could affect the change in the frictional behaviors of the cartilage. A large difference in the coefficients of friction between the two kinematic motions could be interpreted as differences in the directional change of shear stress at the contact surface.

Computerized analysis of occlusal contacts in bruxism patients treated with occlusal splint therapy

  • Gumus, Hasan Onder;Kilinc, Halil Ibrahim;Tuna, Suleyman Hakan;Ozcan, Nihal
    • The Journal of Advanced Prosthodontics
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    • v.5 no.3
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    • pp.256-261
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    • 2013
  • PURPOSE. Occlusal splints are commonly used to prevent tooth wear caused by bruxism. However, the effects of splints on occlusion are still unclear. Although it is rarely alluded in literature, splints can provoke severe occlusal alterations and other complications. This study was aimed to identify differences in the responses of individuals with bruxism and healthy individuals to a full-arch maxillary stabilization splint in terms of occlusal changes. MATERIALS AND METHODS. Occlusal contacts in 20 (5 male, 15 female) bruxism patients and 20 (5 male, 15 female) controls with normal occlusion were evaluated before and after occlusal splint therapy. T-Scan III, a computerized occlusal analysis system, was used to simultaneously measure occlusion and disclusion times as well as left-right and anterior-posterior contact distributions before splint therapy and 3 months after therapy. Wilcoxon and Mann-Whitney U tests were used for statistical analyses (${\alpha}$=.05). RESULTS. No differences were found in the posterior contact of bruxism patients before and after stabilization splint treatment. However, differences in posterior contact were observed between bruxists and normal individuals prior to treatment, and this difference disappeared following treatment. CONCLUSION. The results of this study showed the use of a stabilization splint may not have an effect on occlusion. However, the area of posterior occlusal contact among bruxists was found to be greater than that of normal individuals. According to this study, the clinical use of splints may be harmless.

A Study on the Variation of Electric Contact Resistance Due to Change in Contact Force in a Tin-plated Connector (주석 도금한 커넥터의 접촉 하중의 변화에 의한 전기 접촉저항 변화에 관한 연구)

  • Yu, Hwan-Shin;Oh, Man-Jin;Park, Hyung-Bae
    • Journal of Advanced Navigation Technology
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    • v.18 no.4
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    • pp.381-386
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    • 2014
  • In order to investigate the effect of contact load, which is one of the fretting corrosion factors affecting the electric connector, a coupled fretting corrosion specimens were prepared using a tin-plated brass coupon with a thickness of $3{\mu}m$. Electric resistance of the contact was measured during the fretting corrosion test period. There was increase in resistance with fretting cycles. The change in resistance can be classified by 3 stages. The first stage exhibited low and stable resistance. Second stage showed steady increment of the resistance and third stage showed very high and intermittent resistance. The relationship between the failure cycle (Nf) and contact force (P) can be drawn as; It is possible to draw the prediction equation for the failure cycle of the electric connector corresponding to the very high and intermittent resistance under various environment conditions through the fretting tests under various conditions such as load, displacement, temperature.

CYTOTOXICITY OF RETROGRADE FILLING MATERIALS TESTED BY 51Cr RELEASE, MIT AND LD ACTIVITY (51Cr방출과 MTT 및 LD활성도를 이용한 역충전재의 세포독성에 관한 연구)

  • Choi, La-Young;Im, Mi-Kyung
    • Restorative Dentistry and Endodontics
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    • v.19 no.2
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    • pp.409-428
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    • 1994
  • Endodontic surgery is performed when conventional endodontic therapy fails or is contraindicated. In such cases, retrograde filling materials including amalgam, composite resin, and various cements have been used. Biocompatibilty and margin sealing ability of retrograde filling materials are important for the long term success of endodontic surgery. In vitro cell culture is frequently used as the method of measuring the biocompatibilty of dental materials. The purpose of this study was to evaluate the cytotoxicity of six kinds of retrograde filling materials including newly developed light curing glass ionomer cements. Each material was mixed according to. the manufacture's instruction and evaluated as : freshly mixed, 24-hour after mixing, and 168-hour after mixing respectively. The elution solution was extracted after 24-hour contact with materials using media. Cytotoxicity was evaluated by direct contact, or elution contact. Test results of radiochromium($^{51}Cr$) release, cell viability using tetrazolium dye (3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl dimethyltetrazolium bromide(MTT) test and lactate dehydrogenase(LD) of damaged L929 cells were analyzed. In the $^{51}Cr$ release of direct contact, all experimental retrograde filling materials except amalgam and glass ionomer cement showed increased cytotoxicity compared to control. In the $^{51}Cr$ release of elution solution, the released $^{51}Cr$ was so minimal that it was impossible. to evlauate the cytotoxicity exactly. The elution solutions of glass ionomer cement and IRM showed marked cytotoxicity in MTT test. LD enzyme activity was highest in tests of direct contact with composite, light curing composite, and light curing glass ionomer cement and IRM. Amalgam revealed least cytotoxicity while IRM showed cytotoxicity using all three methods. Composite, light curing composite and light curing glass iomomer cement were cytotoxic in the tests of $^{51}Cr$ release and LD activity. Glass ionomer cement showed cytotoxic effect only in the MTT method. From these results it is suggested that the standardization and optimization of cytotoxicity testing, especially using elution solutions, should be strongly advised.

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Study of Soluble Organic Matter of Livestock Wastewater Treated by Ionized Gas and Coagulation after Ionized Gas (이온화가스와 응집공정을 조합한 축산폐수의 처리시 용존 유기물의 특성에 관한 연구)

  • Lee, Eun-Ju;Chung, Paul-Gene;Kim, Min-Jeong;Hyun, Mi-Hee
    • Journal of Korean Society on Water Environment
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    • v.20 no.6
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    • pp.708-713
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    • 2004
  • This study was performed to investigate the variations of hydrophilic and hydrophobic organic matter fractions in soluble organic matter according to livestock wastewater treatment by ionized gas and coagulation effect to these fractions after ionized gas contact. As a result of experiment, because of ionized gas contact, particle in the surface of livestock wastewater was more smaller and the result was consisted of particle size analysis and the amount of small size was increased. Also, we confirmed that organic matters in livestock wastewater by ionized gas contact were removed. The relation equation between ionized gas contact time(X) and $TCOD_{cr}$(Y) was shown as yscale(y)=3.748-0.431* xscale(X). That between ionized gas contact time(X) and $TCOD_{cr}$(Y) was yscale(y)=3.283-0.463* xscale(X). As respects the HPL(hydrophilic matter)and HPO(hydrophobic matter) fractions of raw in livestock wastewater treatment plant, HPL fraction was 53.2% and HPO fraction was 46.8%. But, HPO fraction according to ionized gas treatment was increased at 30min and after that time, HPL fraction was increased. Also, when we performed coagulation process after ionized gas treatment of raw wastewater, the removal efficiency of organic matter was the highest at 30min of ionized gas treatment because of the variation of HPL and HPO fractions in organic matter by ionized gas. In coagulation process following after ionized gas process, HPO was removed more effective than HPL.

Effects of the Korean Herbal Bathing Candidates on Allergic Contact or Wound Induced Dermatitis Mice Model (알레르기성 접촉 피부염 및 외과적 창상 모델에서 한방 입욕제 원료 처방의 효과)

  • Kim, Jung-Soo;Han, Seung-Heon;Jung, Bo-Kyoung;Park, So-Jung;Kim, Hyung-Woo;Chae, Han;Kwon, Young-Kyu;Kim, Byung-Joo
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.24 no.3
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    • pp.484-489
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    • 2010
  • Allergic contact or wound induced dermatitis are common environmental health issue and seriously affect the patient's quality of life. In now, people are interested in the korean herbal bathing that get better the skin conditions. This study was performed to investigate the effect of korean herbal bathing candidates extract on allergic contact or wound induced dermatitis. ICR mice were divided into four groups: naive, control, experimental group A and B. Control and experimental groups induced allergic contact or wound induced dermatitis by DNFB and TMA. Since then, each experimental group was pasted with corresponding korean herbal bathing extract into the skin. All groups were observed after 5 days. When the korean herbal bathing extract was applied, arbitrary skin wound index and epidermal thickness were significantly decreased compared to that of control. These data suggest that these korean herbal bathing candidates may be an effective therapeutic supplements for the treatment of skin.

Design of an Electron Ohmic-Contact to Improve the Balanced Charge Injection in OLEDs

  • Park, Jin-U;Im, Jong-Tae;Yeom, Geun-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.283-283
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    • 2011
  • The n-doping effect by doping metal carbonate into an electron-injecting organic layer can improve the device performance by the balanced carrier injection because an electron ohmic contact between cathode and an electron-transporting layer, for example, a high current density, a high efficiency, a high luminance, and a low power consumption. In the study, first, we investigated an electron-ohmic property of electron-only device, which has a ITO/$Rb_2CO_3$-doped $C_{60}$/Al structure. Second, we examined the I-V-L characteristics of all-ohmic OLEDs, which are glass/ITO/$MoO_x$-doped NPB (25%, 5 nm)/NPB (63 nm)/$Alq_3$ (32 nm)/$Rb_2CO_3$-doped $C_{60}$(y%, 10 nm)/Al. The $MoO_x$doped NPB and $Rb_2CO_3$-doped fullerene layer were used as the hole-ohmic contact and electron-ohmic contact layer in all-ohmic OLEDs, respectively, Third, the electronic structure of the $Rb_2CO_3$-doped $C_{60}$-doped interfaces were investigated by analyzing photoemission properties, such as x-ray photoemission spectroscopy (XPS), Ultraviolet Photoemission spectroscopy (UPS), and Near-edge x-ray absorption fine structure (NEXAFS) spectroscopy, as a doping concentration at the interfaces of $Rb_2CO_3$-doped fullerene are changed. Finally, the correlation between the device performance in all ohmic devices and the interfacial property of the $Rb_2CO_3$-doped $C_{60}$ thin film was discussed with an energy band diagram.

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A Study on the Super-hydrophobicity of Poly(ethylene terephthalate) Fabric by TiO2 Nano-particles Coating (TiO2 나노입자 코팅에 의한 PET섬유의 초발수성에 관한 연구)

  • Park, Sung-Min;Kwon, Il-Jun;Kim, Ji-Yeon;Kim, Chang-Nam;Yeum, Jeong-Hyun;Yoon, Nam-Sik
    • Textile Coloration and Finishing
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    • v.21 no.1
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    • pp.30-37
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    • 2009
  • Studies on plants such as lotus leaf suggested that dual-scale structure could contribute to super-hydrophobicity. We introduced super-hydrophobicity onto poly(ethylene terephthalate)(PET) fabric with dual-scale structure by assembling $TiO_2$ nano sol. PET fabric was treated with $TiO_2$ sol, water-repellent agent using various parameters such as particle size, concentration. Morphological changes by particle size were observed using field emmission scanning electron microscopy(FE-SEM) and AFM measurement, contact angle measurement equipment. The contact angle of water was about 138.5$^{\circ}$, 125.8$^{\circ}$, 125.5$^{\circ}$ and 108.9$^{\circ}$ for PET fabric coated with 60.2nm, 120.1nm, 200nm and 410.5nm $TiO_2$ particles, compared with about 111.5$^{\circ}$ for PET fabric coated with water repellent. When we mixed particle sizes of 60.2nm and 120.1nm by 7:3 volume ratio, the contact angle of water was about 132.5$^{\circ}$. And we mixed particle sizes of 60.2nm and 200nm by 7:3 volume ratio, the contact angle of water was about 141.8$^{\circ}$. Also we mixed particle sizes of 60.2nm and 410.5nm by 7:3 volume ratio, the best super-hydrophobicity was obtained. In this paper, we fabricated various surface structures to the water-repellent surfaces by using four types of $TiO_2$ nano-particles, and we found that the nanoscale structure was very important for the super-hydrophobicity.