• Title/Summary/Keyword: colloids

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Chemical Characteristics and Water Dispersible Colloid Content of Jeju Citrus Orchard Soils (제주도 감귤원 토양의 화학적 특성과 물 분산성 콜로이드 함량)

  • Oh, Sang-Sil;Chung, Jong-Bae;Hyun, Hae-Nam
    • Korean Journal of Environmental Agriculture
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    • v.21 no.2
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    • pp.130-135
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    • 2002
  • Water-dispersible colloids are suspected to facilitate transport of contaminants to groundwater. This study evaluated some soil chemical properties in relation to the stability of colloids in soils of Jeju citrus orchards. Thirty surface soil samples were collected, and pH, organic matter content oxalate-extractable Al and Fe contents, and water-dispersible colloid content were measured. In soils of higher pH, water-dispersible colloid contents were higher. The stability of colloids was found to be significantly promoted at pH above 5$\sim$6. Since organic matter can act as a flocculant organic matter content significantly enhanced the colloid stability. In soils of less than 5% organic C, water-dispersible colloid content was expected to be significantly higher. In soils of higher oxalate-extractable Al and Fe contents, colloids remaining in suspension were lower. This indicated that amorphous oxides and hydroxides play important stabilizing roles in soil structure and can stabilize soil clay against dispersion. Therefore in soils of higher pH, lower organic matter, and lower amorphous clay minerals, the stability of water-dispersible colloids and the potential of colloid-mediated transport of organic chemicals to groundwater could be higher.

Liquid crystal ferroelectric colloids; non-synthetic method of adjusting properties

  • Reznikov, Yuriy;Buchnev, Olexander;Li, Fenghua;West, John
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.163-166
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    • 2006
  • We found dramatic changes of the properties of LCs by dispersing ferroelectric nanoparticles. Specifically, ferroparticles greatly increase the nematic-isotropic transition temperature, birefringence and dielectric anisotropy of the LC. Ferroelectric nanoparticles/LCs colloids offer a simple and effective means to precisely control the physical properties of LC materials and optimize them for display applications.

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Preparation of ZnO Thin Film by Electrophoretic Deposition(EPD)

  • Jun, Byung-Sei
    • Journal of the Korean Ceramic Society
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    • v.49 no.1
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    • pp.78-83
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    • 2012
  • The electrophoretic deposition(EPD) of ZnO nano-sized colloids is investigated by changing the colloid number concentration, applied force, and deposition time. The change of the colloid size in a suspension was examined by the different colloid number concentrations (N = $3.98{\times}10^{15}$, N = $3.98{\times}10^{14}$, and N = $3.98{\times}10^{13}$) with an increase of the deposition time and applied forces. Deposition behavior was investigated by changing the applied fields (from DC 5 V to 50 V) and the deposition time (5 min to 25 min). The surface microstructures of the as-deposited films were investigated by SEM. The dried films were sintered from $850^{\circ}C$ to $1,050^{\circ}C$ for 2 h and then the microstructures were also explored by SEM. The agglomeration rate was enhanced by increasing the colloid number concentration of colloids. Colloid number concentration in a suspension must be rapidly decreased at higher values of the electric field. ZnO nano-sized colloids had the highest zeta potential value of over -28 mV in methanol. A homogeneous microstructure was obtained at colloid number concentration of N = $3.98{\times}10^{13}$, applied DC field of 5 V/cm and 15 min of deposition time at an electrode distance of 1.5 cm. Under these conditions, the deposited films were sintered at $850^{\circ}C$ and $1,050^{\circ}C$ for 2 h. The results show a typical pore-free surface morphology of a uniform thickness of 400 nm under these experimental conditions.

Evaluating Effects of Membrane Filter Pore Sizes on Determination of Dissolved Concentrations of Major Elements in Groundwater and Surface Water Near Nakdong River (낙동강변 지하수 및 지표수의 주요원소 용존 농도 결정에 대한 막필터 공극 크기의 영향 분석)

  • Kim, Bo-A;Koh, Dong-Chan;Ha, Kyoochul
    • Journal of Soil and Groundwater Environment
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    • v.20 no.4
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    • pp.31-40
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    • 2015
  • Various types of inorganic and organic colloids are present in natural water including groundwater. Previous studies showed that Fe, Mn and Al are colloid-forming elements and dissolved concentrations can be erroneous for these elements if water samples are not properly filtered. Dissolved concentrations of elements including Ca, Na, Mg, K, Fe, Mn, Si and Al in groundwater from alluvial and bedrock aquifers, and surface water near Nakdong River were determined to evaluate effects of colloids on dissolved concentrations in natural water samples using various pore sizes of filters. Groundwater is mostly anoxic and have elevated concentrations of Fe and Mn, which provides a unique opportunity to observe the effects of colloids on dissolved concentrations of colloid-forming elements. Membrane filters with four kinds of pore sizes of 1000 nm, 450 nm, 100 nm, and 15 nm were used for filtration of water samples. Concentrations of dissolved concentrations in each filtrate did not show significant differences from 1000 nm to 100 nm. However, concentrations of all elements considered were decreased in the filtrates obtained using 15 nm pore size filters by 10 to 15% compared to those using 450 nm except for bedrock groundwater. Al in surface water showed a distinct linear decrease with the decrease of filter pore sizes. These results showed that 100 nm pore size had little effect to remove colloidal particles in alluvial groundwater and surface water in our study. In contrast, significant concentration decreases in 15 nm pore size filtrates indicate that the presence of 15 to 100 nm colloidal particles may affect determination of dissolved concentrations of elements in natural water.

Microstructure and shear modulus in concentrated dispersions of bidisperse charged spherical colloids

  • Chun, Myung-Suk;Lee, Sangwoo;Lee, Tae-Seok;Cho, Jae-Seol
    • Korea-Australia Rheology Journal
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    • v.16 no.1
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    • pp.17-26
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    • 2004
  • We examine rigorous computations on microstructural as well as rheological properties of concentrated dispersions of bidisperse colloids. The NVT Monte Carlo simulation is applied to obtain the radial distribution function for the concentrated system. The long-range electrostatic interactions between dissimilar spherical colloids are determined using the singularity method, which provides explicit solutions to the linearized electrostatic field. The increasing trend of osmotic pressure with increasing total particle concentration is reduced as the concentration ratio between large and small particles is increased. From the estimation of total structure factor, we observe the strong correlations developed between dissimilar spheres. As the particle concentration increases at a given ionic strength, the magnitude of the first peak in structure factors increases and also moves to higher wave number values. The increase of electrostatic interaction between same charged particles caused by the Debye screening effect provides an increase in both the osmotic pressure and the shear modulus. The higher volume fraction ratio providing larger interparticle spacing yields decreasing high frequency limit of the shear modulus, due to decreasing the particle interaction energy.

Apoptotic Effects of Eugenol-loaded Nanoemulsions in Human Colon and Liver Cancer Cell Lines

  • Majeed, Hamid;Antoniou, John;Fang, Zhong
    • Asian Pacific Journal of Cancer Prevention
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    • v.15 no.21
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    • pp.9159-9164
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    • 2014
  • Background: In this study eugenol (EU) loaded nanoemulsions (NEs) emulsified with modified starch were prepared and their apoptotic potential against liver and colon cancer cells was examined in comparison with bulk EU. Materials and Methods: We prepared stable EU loaded NEs whcih were characterized by dynamic light scattering, centrifugation and gas chromatography. Furthermore, cell viability was determined using MTT assay, and apoptosis and cell cycle analysess by flow cytometry. Results: HB8065 (liver) and HTB37 (colon) cells when treated with EU:CA NEs demonstrated greater apoptotic cells percentages as evidenced by microscopic images and flow cytometric evaluations. It was observed that EU and EU:CA NE induced apoptosis in both cell lines via reactive oxygen species (ROS) generation. Conclusions: The present study demonstrated that ROS plays a critical role in EU and EU:CA NE induced apoptosis in HB8065 and HTB37 cells. This is the first report on the antiproliferative mechanisms of EU loaded NE.

An Experimental Study on the Sorption Properties of Uranium(VI) onto Bentonite Colloids (벤토나이트 콜로이드에 대한 우라늄(VI) 수착특성에 대한 실험적 연구)

  • Baik Min-Hoon;Cho Won-Jin;Hahn Pil-Soo
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.239-247
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    • 2005
  • In this study, an experimental study on the sorption properties of uranium(VI) onto bentonite colloids generated from a domestic calcium bentonite (called as Gyeongju bentonite). Gyeongju bentonite has been considered as a potential candidate buffer material in the Korean disposal concept for high-level radioactive wastes. The size and concentration of the bentonite colloids used in the sorption experiment were measured by a filtration method. The result showed that the concentration of the synthesized bentonite colloid suspension was 5100ppm and the size of the most of bentonite colloids(over $98\%$) was in the range of 200-450nm in diameter. The amount of uranium lost by the sorption onto bottle walls, by precipitation, and by ultrafiltration or colloid formation was analyzed by carrying out some blank tests. The loss of uranium by the ultrafiltration was significant in the lower ionic strength(i.e., in the case of 0.001M $NaClO_4$) due to the cationic sorption effect onto the ultrafilter by a surface charge reversion. The distribution coefficient (or pseudo-colloid formation constant) for the sorption of uranium(VI) onto bentonite colloids was $10^4^{\sim}10^6$ mL/g depending upon pH and the distribution coefficient was highest in the neutral pH around 6.5.

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DA-7911, $^{188}Rhenium-tin$ Colloid, as a New Therapeutic Agent of Rheumatoid Arthritis

  • Shin, Chang-Yell;Son, Miwon;Ko, Jun-Il;Jung, Mi-Young;Lee, In-Ki;Kim, Soon-Hoe;Kim, Won-Bae;Jeong, Jae-Min;Song, Yeong-Wook
    • Archives of Pharmacal Research
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    • v.26 no.2
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    • pp.168-172
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    • 2003
  • Radiation synovectomy is one of the most useful methods for treating patients with refractory synovitis because of its convenience, long-term effects, repeatability and the avoidance of surgery. In this study, we investigated the toxicity, stability and biodistribution of a rhenium-188 ($^{188}$Re)-tin colloid to evaluate its suitability as a synovectomy agent. Twenty four hours after injecting the $^{188}$Re-tin colloids (74 KBq/0.1 mL) into the tail vein of ICR mice, most of the $^{188}$Retin colloidal particles was found in the lungs. In addition, there were no particle size changes at either room temperature or at $37^{\circ}C$ after injecting the $^{188}$Re-tin colloids in human plasma and synovial fluid. In vitro stability tests showed that the $^{188}$Re-tin colloid remained in a colloidal form without a critical size variation over a 2-day period. We investigated the leakage of $^{188}$Retin colloids from the intraarticular injection site with gamma counting in New Zealand white rabbits. The $^{188}$Re-tin colloids (55.5 MBq/0.15 mL) were injected at the cavum articular and the mean retention percentage of the $^{188}$Re-tin colloid was 98.7% for 1 day at the injection site, which suggests that there was neither change in the particle size nor leakage at the injection sites. In the biodistribution study with the SD rats, the liver showed the highest radioactivity (0.0427% ID/organ) except for the injected knees (99.49%). In the SD rats, mild toxicities including the skin or a synovium inflammation were observed as a result of a radioactivity of 15 mCi/kg at the intraarticular injection site. However, there was no systemic toxicity. In the Ovalbumin (OVA)-induced arthritic rabbits, the $^{188}$Re-tin colloid improved the macroscopic, the histological score and reduced the knee joint diameter when compared to the arthritic control. In conclusion, a $^{188}$Re-tin-colloid is considered as a strong candidate for radiation synovectomy with a superior efficacy and safety.

Characteristics of Volcanic Ash Soils (화산회토(火山灰土)의 특성(特性)에 관(關)하여)

  • Shin, Yong Hwa;Kim, Hyong Ok
    • Korean Journal of Soil Science and Fertilizer
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    • v.8 no.3
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    • pp.113-119
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    • 1975
  • Volcanic Ash Soils are widely distributed in Jeju island, and constitute the important upland soils which are either presently being cultivated or are suitable for reclaiming. The characteristics of Volcanic Ash Soils according to data made available by previous studies in Jeju and the outside of the country are as following: The most conspicuous mineralogical property is the presence of amorphous mineral colloids. The colloids have large and highly reactive surface to which the common physical and chemical properties are related. Soils are low in bulk density and higher both in porosity and permeability. Accumulation of humus in the upper part of soil is found in great quantity. Cation exchange capacity is high mainly due to high humus content, but the absorbing intensity of ammonium and potassium is weaker than that of crystalline clays. The phosphate absorption coefficient is extremely high and deficiency of minor element may occur both crops and animals. Soils are densely populated with actinomycetes and anaerobic bacteria. Nitrification and activity of urease are distinctly stronger than that of non-Volcanic Ash Soils.

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