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DISCRIMINATION BETWEEN VIRGIN OLIVE OILS FROM CRETE AND THE PELOPONESE USING NEAR INFRARED TRANSFLECTANCE SPECTROSCOPY

  • Flynn, Stephen J.;Downey, Gerard
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1520-1520
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    • 2001
  • Food adulteration is a serious consumer fraud and a potentially dangerous practice. Regulatory authorities and food processors require a rapid, non-destructive test to accurately confirm authenticity in a range of food products and raw materials. Olive oil is prime target for adulteration either on the basis of the processing treatments used for its extraction (extra virgin vs virgin vs ordinary oil) or its geographical origin (e.g. Greek vs Italian vs Spanish). As part of an investigation into this problem, some preliminary work focused on the ability of near infrared spectroscopy to discriminate between virgin olive oils from separate regions of the Mediterranean i. e. Crete and the Peloponese. A total of 46 oils were collected: 18 originated in Crete and 28 in the Peloponese. Oils were stored in a temperature-controlled room at 2$0^{\circ}C$ prior to spectral collection at room temperature (15-18$^{\circ}C$). Samples (approximately 0.5$m\ell$) were placed in the centre of the quartz window in a camlock reflectance cell; the gold-plated baking plate was then gently placed into the cell against the glass so as to minimize the formation of air bubbles. The rear of the camlock cell was then screwed into place producing a sample thickness of 0.5mm. Spectra were recorded between 400 and 2498nm at 2nm intervals on a NIR Systems 6500 scanning monochromator. Spectral collection took place over 2-3 days. Data were analysed using both WINISI and The Unscrambler software to investigate the possibility of discriminating between the oils from Crete and the Peloponese. A number of data pre-treatments were used and discriminant models were developed using discriminant PLS (WINISI & Unscrambler) and SIMCA (Unscrambler). Despite the small number of samples involved, a satisfactory discrimination between these two oil types was achieved. Graphical examination of principal component scores for each oil type also holds out the possibility of separating oils from either Crete and the Peloponese on the basis of districts within each region. These preliminary data suggest the potential of near infrared spectroscopy to act as a screening technique for the confirmation of geographic origin of extra virgin olive oils. The sample presentation strategy adopted uses only small volumes of material and produces high quality spectra.

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Evaluation of Mechanical Test Characteristics of Fillet Welding (필릿 용접의 기계적 시험 특성 평가)

  • Cho, Byung-Jun;Lee, Soung-Jun;Rhim, Jong-Guk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.2
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    • pp.535-541
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    • 2020
  • FCAW is used mainly in the welding of carbon steel and alloy steel because it can be welded in all positions and can obtain excellent quality at sites with variable working conditions. Recently, many studies in Korea have estimated the fatigue strength, residual stress, and deformation, and to develop a fillet welding process. On the other hand, there have been few studies of the mechanical properties based on the strength, macro and magnetic particle test results for fillet welding. This study shows the following results through fillet welding, macro testing and strength testing using SM490A (solid-structure rolled steel) for thick plates using SS400 (rolled steel) for the upper plate and FCAW. The hardness test, macro test and magnetic particle test were then conducted. The hardness tests showed that all result values were smaller than the KS B 0893 standard values of 350Hv. The macro-test showed that each type of welded part was in a normal organic state and that there were no internal errors, bubbles, or impurities on the front of the welded part. Therefore, there were no concerns about lamination. The magnetic particle examination showed no problems.

Effect of Microsparged Aeration on Oxygen Transfer Rate and Cell Viability in Mammalian Cell Culture Bioreactor (동물 세포 반응기에서의 초미세 통기법이 산소 전달 속도와 세포 생존율에 미치는 영향)

  • 김정모;장건희;최춘순;김정회
    • Microbiology and Biotechnology Letters
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    • v.29 no.4
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    • pp.240-247
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    • 2001
  • The effect of microsparged aeration in mammalian cell bioreactor on the oxygen transfer rate and cell viability was studied. The microspargers with differ- ent micron-sized pores were used to supply oxygen to the medium. The oxygen transfer coefficients (k$_{L}$a) measured in the bioreactor were markedly increased, which is due to the increase of the contacting area between air bubbles and liquid medium when the pore size of microsparger decreases. When the impellers of two different types (square-pitch marine impeller and $45^{\circ}$ pitched flat blade impeller) were used for agitation, the k$_{L}$a values were slightly higher with the marine impeller than with the blade impeller. The detrimental effect of direct gas sparging with microsparger on mammalian cells was investigated in bubble columns with various air flow rates and different pore sized microspargers. The first-order cell death rate constant ($k_{d}$ /7) was shown to be directly proportional to the air flow rate and inversely proportional to the pore size. During the cultivation of hybridoma cells using microsparger with the pore size of $0.57\mu$m in the mammalian cell culture bioreactor, the continuous sparging caused the cell death and suppressed the cell growth. However, cells grew normally and cell viability was maintained above 90% in the logarithmic phase when the air was intermittently sparked in order to maintain the dissolved oxygen level above 20%.

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A study on skin permeability enhancement of active substances in cosmetics using nanobubble technique (나노버블 기법을 이용한 화장품 내 유효물질의 피부투과성 증가에 관한 연구)

  • Lee, Sung-Joo;Lee, Soon-Hong;Park, Seung-il
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.4
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    • pp.1041-1051
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    • 2020
  • The technology of microbubbles and nanobubbles originated in Japan and Europe is applicable to various applications and its effects are diverse, attracting attention not only from many researchers but also from industry experts. In particular, nanobubbles have the advantage that they can be applied to products in the form of liquids, such as cosmetics, from the study that they can exist for more than several months in water. In this study, it was carried out the production of nanobubbles using bubble encapsulation technique and the experiment of skin permeability enhancement of active substances in cosmetics using nanobubble techniquethree. Nanobubbles were confirmed to affect the skin permeability increase of active substances, and up to 250% increase in skin permeability compared to non-bubbles-free materials(Caffeic acid, at 8 hour). It is expected that research results and industrial ripple effects can be expected not only in the cosmetic field, but also in fields applicable to the improvement of permeability by nanobubble techniques, such as areas related to drug delivery system.

Study on the meaning of Edi-curation in Trans-media era - Based on the comic(webtoon) and publishing content - (트랜스미디어 시대에서 에디큐레이션의 의미에 대한 연구 - 출판 및 만화 콘텐츠를 중심으로 -)

  • Park, Se-Hyeon
    • Cartoon and Animation Studies
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    • s.44
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    • pp.235-261
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    • 2016
  • Media consumers in the context of the Internet and digital media are using the same content to a variety of platforms. As such, the content of various genres is converted to the form of a new content through the process of fusion, combination, transformation, differentiation, reproduction, etc on the basis of digital media. That is referred to as trans-media. In order to create the successful content in trans-media era, it requires the work of Edi-curation. Edi-curation work is the act of editing and adding meaning to the curation work of curators. In that sense, this paper analyzed the definition and meaning for Edi-curation of publishing and comic(webtoon) content in trans-media era. Edi-curation process induces the changing role of consumers and producers of content in the digital media experience. In process of Edi-curation, consumers(producers) will soon lead to a media producer(consumer), namely proconsumer / produser. Diversification of digital platforms and devices, digital 1 person (or SNS) appeared in the media, etc. are also required to Edi-curation of content and comic(webtoon) published in a variety of ways. Depending on the intention of media producers (or consumers), content through the process of replication, montage, disassembly, dismantling, hypertext, compression, and reconstruction births to new content. The work of Edi-curation has the significance that it affects the way the media producers work in creative process, as well as the reading content of the media consumers. In the publishing content, Edi-curation work is the logicality destruction of a chapter or a paragraph, a sentence of colloquialisms, card news, the deformation of the utilization of video and media content. Meanwhile in the comic(webtoon) content, we mention the destruction of cut(frame), the various modifications of speech bubbles, onomatopoeia, and mimetic word.

Photocatalytic Oxidation of Han River Humic Substances and Change of Their Characteristics by $TiO_2/UV$ in a Rotating Photoreactor ($TiO_2/UV$ 회전반응기를 이용한 한강 휴믹물질의 광촉매산화 처리 및 특성 변화)

  • Shin, Jee-Won;Kim, Hyun-Chul;Han, Ihn-Sup
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.10
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    • pp.1129-1135
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    • 2005
  • In this study. the applicability of a rotating reactor for the oxidative removal of aqueous humic substances extracted from the Han River in Seoul, Korea was investigated. As air blowing for proper mixing of $TiO_2$ photocatalyst could inhibit UV-irradiation between a UV lamp and photocatalyst by air bubbles, a rotating reactor with some baffles was used for better UV-irradiation effect in this study. Han River humic substances are different from the other commercial humic substances(e.g., from Aldrich and International Humic Substance Society). Their characteristics were investigated with structural and spectroscopic analyses using FT-IR(Fourier transform-infrared), and $^{13}C$-NMR (nuclear magnetic resonance). The humic substances were extracted by XAD-7HP and treated with $TiO_2$-coated hollow beads under UV-A and UV-C irradiation in order to solve problems of separation and recovery of photocatalyst after reaction. At approximately 5 mg/L of initial TOC concentration, pH 3 and $2.0\;g-TiO_2/L$ dose, photocatalytic oxidation of Han River humic substances showed the optimum removal efficiency. Also, UV-C and UV-A lamps showed similar TOC removal efficiency. However, under UV-C irradiation, Han River humic substances were degraded to smaller compounds and increased the proportion of low molecular weight fractions compared to UV-A.

Preliminary Study on Factor Technology of Selective Catalytic Reduction System in Marine Diesel Engine (선박용 디젤엔진 SCR 시스템 요소 기술에 관한 기초 연구)

  • Park, Yoon-Yong;Song, Ha-Cheol;Ahn, Gi-Ju;Shim, Chun-Sik
    • Journal of Navigation and Port Research
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    • v.40 no.4
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    • pp.173-181
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    • 2016
  • From 2016, controls on reduction of NOx and SOx emissions from the vessels that are operated in the emission control area were tightened. The selectivity catalytic reduction system of the denitrification equipment which NOx among the above controlled materials is very effective and used commercially very much. But it has the disadvantage that CSR is activated at high temperatures. Therefore, the SCR and SCR activation instrument that can react even at low temperatures by using micro-nano bubbles so that the above problems can be minimized were developed. And the computational fluid dynamics technique was used by ANSYS-CFX package to prepare the plan that improves the SCR system's efficiency. Simulation for the viscous flow analysis of the SCR system was executed by applying the Navier-Stokes equation to it as a governing equation. For the SCR system's shape, 3D modeling was done by using CATIA V5. SCR jet nozzle's position was checked by changing it to the intervals of 1/3, 1/2, and 2/3 from the inlet of the vent pipe to compare the SCR system's efficiency. And the number of nozzles was compared and analyzed by simulating 4, 6, and 8 holes to check an effect of the number on the SCR system's efficiency. The simulation result has found that the closer nozzles are to the inlet of the vent pipe and the more nozzles are, the more efficiency is improved.

Effect of Agitation Speed and Air Rate on Separation Efficiency in Fly Ash Flotation (플라이애시 부유선별 과정에서 교반속도와 공기주입량 변화에 따른 영향 연구)

  • Kim, Min Sik;Kang, Heon Chan
    • Resources Recycling
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    • v.27 no.1
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    • pp.45-54
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    • 2018
  • This study aimed to investigate the effects of mechanical factors such as agitation speed and air rate in fly ash flotation. Specifically, we used thermal power plant fly ash with unburned carbon content of 3.4 to 3.7%. The effect of pH, agitation speed, collector dosage, and frother dosage - the key factors of froth flotation - showed unburned carbon recovery and unburned carbon content of 63% and 34%, respectively, when the dosage of safflower oil used as collector was 800 g/ton, pH was 7, agitation speed was 1,200 rpm, and frother dosage was 400 g/ton. The SEM/EDS analysis of fly ash in that case indicated that the spherical fly ash particles lowered the unburned carbon content as they floated with the air bubbles without being dissolved in the unburned carbon or settled in the ore solution. The other experiment of changing the mechanical factors such as agitation speed and air rate resulted in unburned carbon recovery and unburned carbon content of 74% and 67%, respectively, at air rate of 8 L/min and agitation speed of 900 rpm. The recovery and unburned carbon content increased as the low agitation speed and additional air injection decreased the strength of the eddy current in the ore solution and consequently prevented the floating of fine fly ash particles with unburned carbon. In addition, the recovery rate and unburned carbon increased further to 80% and 70%, respectively, showing the best performance when the agitation speed and air rate were lowered to 800 rpm and 6 L/min, respectively.

Changes in the CO2 and amount of mycelium growth of the liquid spawn on Flammulina velutipes (팽나무버섯 액체 종균 배양시 이산화탄소 농도와 균사 생장량 변화)

  • Shim, Kyu-Kwang;Yoo, Young-Jin;Koo, Chang-Duck;Kim, Young-Seok;Kim, Myung-Koon
    • Journal of Mushroom
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    • v.10 no.1
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    • pp.3-8
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    • 2012
  • In this study, to produce Flammulina velutipes mushroom liquid spawn efficiently and effectively the effects of explosive aeration (supplying air with tiny bubbles) of the liquid culture medium on carbon dioxide concentration and residual sugar content in the medium on carbon dioxide concentration and residual sugar contentin the medium were measured. Carbon dioxide concentrations were measured at the outlet of the incubator. On the third day the explosive aeration greatly increased mycelial growth of the liquid spawn, and carbon dioxide concentration also greatly increased but decreased after 5 days. Free sugar contents in the liquid culture consistantly decreased up to 7 days and thereafter was not detected. The weight of the mycelia were maintained similar levels after 3 days. Total nitrogen content in the liquid medium constantly decreased during the 11days of explosive aeration. The content of free sugars in 7 days of culture was the lowest level, thus the inoculum incubated for 6~7 days was thought to be the most effective. Carbon dioxide concentration measurement at the outlet of the container during the liquid spawn incubation required low cost but was efficient to estimate the degree of mycelial growth to be used as a simple indicator.

Radiation Resistance and Fabrication of Carbon Fiber Reinforced Thermoplastic Composites by Electropolymerization (전기중합법에 의한 열가소성 수지 탄소섬유 강화 복합재료의 제조와 내방사선성)

  • Park, Minho;Kim, Minyoung;Kim, Wonho;Cho, Wonjei
    • Applied Chemistry for Engineering
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    • v.8 no.3
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    • pp.489-501
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    • 1997
  • Electropolymerization of 2-vinylnaphthalene (2-VN) and methylmethacrylate (MMA) with high radiation resistance property was conducted on the surfaces of carbon fibers by using a nonaqueous solution of comonomers dissolved in N,N-dimethylformamide containing sodium nitrate as a supporting electrolyte. The fabrication of carbon fiber/2-VN/MMA prepreg was performed electrochemically in 1:1 comonomer solution. Electropolymerization was conduced by changing the current density, initial comonomer concentration, and reaction time. The weight gain on the surface of the carbon fibers was measured by thermogravimetric analyser (TGA). The highest weight gain of 50 wt% was obtained at 600mA/g~800mA/g current density range, but the weight gain was rapidly decreased above 800mA/g current density. The weight gain was increased with the concentration of comonomer, while the concentration of electrolyte had almost no effect on the weight gain. At 300mA/g current density, weight gain rate was increased abruptly to the initial 30 minutes of reaction time. After that the rate was decreased due to the generation of gas bubbles. In order to check the effect of coated polymers on the radiation resistance, morphology changes before and after $\gamma$-ray irradiation was investigated for the composites.

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