• Title/Summary/Keyword: bond model

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A Study on the Development of Forced Carbonation Reforming Technology for Recycled Aggregates (순환골재의 강제 탄산화 개질 기술 개발을 위한 기초적 연구)

  • Lim, Myung-Kwan;Park, Won-Jun;Lee, Huck;Kim, Do-Yun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.05a
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    • pp.207-208
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    • 2016
  • The most important things for the production of recycled aggregates are saving energy, suppressing the generation of by-product fine particles and sustaining the performance of concrete. As solutions, this study proposes this technology of improving the performance of recycled aggregates through forced carbonation.1) It is to stimulate and carbonate the bond paste part that causes the deterioration of recycled aggregates. Particularly, the purpose of this technology is to fill and chemically stabilize pores inside the bond paste, further improving the quality of recycled aggregates with a decreased absorption rate and an enhanced aggregate strength. Ultimately, it is possible to obtain a carbonation model, depending on the paste ratio and particle-size distribution of recycled aggregates. Moreover, by calculating the optimum carbonation period through the verification of this carbonation model, it is possible to examine how much the strength is improved by the reformation of recycled aggregated.

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P56 LCK Inhibitor Identification by Pharmacophore Modelling and Molecular Docking

  • Bharatham, Nagakumar;Bharatham, Kavitha;Lee, Keun-Woo
    • Bulletin of the Korean Chemical Society
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    • v.28 no.2
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    • pp.200-206
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    • 2007
  • Pharmacophore models for lymphocyte-specific protein tyrosine kinase (P56 LCK) were developed using CATALYST HypoGen with a training set comprising of 25 different P56 LCK inhibitors. The best quantitative pharmacophore hypothesis comprises of one hydrogen bond acceptor, one hydrogen bond donor, one hydrophobic aliphatic and one ring aromatic features with correlation coefficient of 0.941, root mean square deviation (RMSD) of 0.933 and cost difference (null cost-total cost) of 66.23. The pharmacophore model was validated by two methods and the validated model was further used to search databases for new compounds with good estimated LCK inhibitory activity. These compounds were evaluated for their binding properties at the active site by molecular docking studies using GOLD software. The compounds with good estimated activity and docking scores were evaluated for physiological properties based on Lipinski's rules. Finally 68 compounds satisfied all the properties required to be a successful inhibitor candidate.

Modeling shear behavior of reinforced concrete beams strengthened with externally bonded CFRP sheets

  • Khan, Umais;Al-Osta, Mohammed A.;Ibrahim, A.
    • Structural Engineering and Mechanics
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    • v.61 no.1
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    • pp.125-142
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    • 2017
  • Extensive research work has been performed on shear strengthening of reinforced concrete (RC) beams retrofitted with externally bonded carbon fiber reinforced polymer (CFRP) in form of strips. However, most of this research work is experimental and very scarce studies are available on numerical modelling of such beams due to truly challenging nature of modelling concrete shear cracking and interfacial interaction between components of such beams. This paper presents an appropriate model for RC beam and to simulate its cracking without numerical computational difficulties, convergence and solution degradation problems. Modelling of steel and CFRP and their interfacial interaction with concrete are discussed. Finally, commercially available non-linear finite element software ABAQUS is used to validate the developed finite element model with key tests performed on full scale T-beams with and without CFRP retrofitting, taken from previous extensive research work. The modelling parameters for bonding behavior of CFRP with special anchors are also proposed. The results presented in this research work illustrate that appropriate modelling of bond behavior of all the three types of interfaces is important in order to correctly simulate the shear behavior of RC beams strengthened with CFRP.

Rotor dynamic analysis of a tidal turbine considering fluid-structure interaction under shear flow and waves

  • Lass, Andre;Schilling, Matti;Kumar, Jitendra;Wurm, Frank-Hendrik
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.11 no.1
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    • pp.154-164
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    • 2019
  • A rotor dynamic analysis is mandatory for stability and design optimization of submerged propellers and turbines. An accurate simulation requires a proper consideration of fluid-induced reaction forces. This paper presents a bi-directional coupling of a bond graph method solver and an unsteady vortex lattice method solver where the former is used to model the rotor dynamics of the power train and the latter is used to predict transient hydrodynamic forces. Due to solver coupling, determination of hydrodynamic coefficients is obsolete and added mass effects are considered automatically. Additionally, power grid and structural faults like grid fluctuations, eccentricity or failure could be investigated using the same model. In this research work a fast, time resolved dynamic simulation of the complete power train is conducted. As an example, the rotor dynamics of a tidal stream turbine is investigated under two inflow conditions: I - shear flow, II - shear flow + water waves.

A Study on the Impact of Business Cycle on Corporate Credit Spreads (글로벌 회사채 스프레드에 대한 경기요인 영향력 분석: 기업 신용스프레드에 대한 경기사이클의 설명력 추정을 중심으로)

  • Jae-Yong Choi
    • Asia-Pacific Journal of Business
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    • v.14 no.3
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    • pp.221-240
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    • 2023
  • Purpose - This paper investigates how business cycle impacts on corporate credit spreads since global financial crisis. Furthermore, it tests how the impact changes by the phase of the cycle. Design/methodology/approach - This study collected dataset from Barclays Global Aggregate Bond Index through the Bloomberg. It conducted multi-regression analysis by projecting business cycle using Hodrick-Prescott filtering and various cyclical variables, while ran dynamic analysis of 5-variable Vector Error Correction Model to confirm the robustness of the test. Findings - First, it proves to be statistically significant that corporate credit spreads have moved countercyclicaly since the crisis. Second, It indicates that the corporate credit spread's countercyclicality to the macroeconomic changes works symmetrically by the phase of the cycle. Third, the VECM supports that business cycle's impact on the spreads maintains more sustainably than other explanatory variable does in the model. Research implications or Originality - It becomes more appealing to accurately measure the real economic impact on corporate credit spreads as the interaction between credit and business cycle deepens. The economic impact on the spreads works symmetrically by boom and bust, which implies that the market stress could impact as another negative driver during the bust. Finally, the business cycle's sustainable impact on the spreads supports the fact that the economic recovery is the key driver for the resilience of credit cycle.

Contagion in Global Bond Markets

  • Sang-Kuck CHUNG;Vasila Shukhratovna ABDULLAEVA;Sun-Jae MOON
    • The Journal of Economics, Marketing and Management
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    • v.12 no.4
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    • pp.27-36
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    • 2024
  • Purpose: The paper analyzes for detecting unexpected shocks such as global financial crisis and COVID-19 pandemic, and contagion between countries by capturing in the mean-shift, variance-covariance-shift, and skewness-coskewness-shift parameters of interest rates. Research design, data and methodology: A flexible multivariate model of interest rates is provided by allowing for regime switching and a joint skewed normal distribution. The model is applying to the structural breaks of crisis and contagion between the US and the selected global bond markets during the global financial crisis and COVID-19 pandemic, respectively. Inspection of the moment statistics weakly suggests a flight to safety to the US during the global financial crisis and to Canada during the COVID-19 pandemic. Results: The results indicate that risk averse investors had a higher risk appetite for the US and Canada assets during the crisis regimes, compared to their counterparts. Conclusions: The results show that coskewness contagion dominates correlation contagion, and coskewness contagion is significant for the Korea and Japan-US pairs for the global financial crisis and the Euro-US pair for the COVID-19 pandemic. All channels of structural breaks of crisis and contagion are significant when considered jointly, reinforcing the need to consider contagion and structural breaks during crises in a multivariate setting.

Corporate Bond Rating Using Various Multiclass Support Vector Machines (다양한 다분류 SVM을 적용한 기업채권평가)

  • Ahn, Hyun-Chul;Kim, Kyoung-Jae
    • Asia pacific journal of information systems
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    • v.19 no.2
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    • pp.157-178
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    • 2009
  • Corporate credit rating is a very important factor in the market for corporate debt. Information concerning corporate operations is often disseminated to market participants through the changes in credit ratings that are published by professional rating agencies, such as Standard and Poor's (S&P) and Moody's Investor Service. Since these agencies generally require a large fee for the service, and the periodically provided ratings sometimes do not reflect the default risk of the company at the time, it may be advantageous for bond-market participants to be able to classify credit ratings before the agencies actually publish them. As a result, it is very important for companies (especially, financial companies) to develop a proper model of credit rating. From a technical perspective, the credit rating constitutes a typical, multiclass, classification problem because rating agencies generally have ten or more categories of ratings. For example, S&P's ratings range from AAA for the highest-quality bonds to D for the lowest-quality bonds. The professional rating agencies emphasize the importance of analysts' subjective judgments in the determination of credit ratings. However, in practice, a mathematical model that uses the financial variables of companies plays an important role in determining credit ratings, since it is convenient to apply and cost efficient. These financial variables include the ratios that represent a company's leverage status, liquidity status, and profitability status. Several statistical and artificial intelligence (AI) techniques have been applied as tools for predicting credit ratings. Among them, artificial neural networks are most prevalent in the area of finance because of their broad applicability to many business problems and their preeminent ability to adapt. However, artificial neural networks also have many defects, including the difficulty in determining the values of the control parameters and the number of processing elements in the layer as well as the risk of over-fitting. Of late, because of their robustness and high accuracy, support vector machines (SVMs) have become popular as a solution for problems with generating accurate prediction. An SVM's solution may be globally optimal because SVMs seek to minimize structural risk. On the other hand, artificial neural network models may tend to find locally optimal solutions because they seek to minimize empirical risk. In addition, no parameters need to be tuned in SVMs, barring the upper bound for non-separable cases in linear SVMs. Since SVMs were originally devised for binary classification, however they are not intrinsically geared for multiclass classifications as in credit ratings. Thus, researchers have tried to extend the original SVM to multiclass classification. Hitherto, a variety of techniques to extend standard SVMs to multiclass SVMs (MSVMs) has been proposed in the literature Only a few types of MSVM are, however, tested using prior studies that apply MSVMs to credit ratings studies. In this study, we examined six different techniques of MSVMs: (1) One-Against-One, (2) One-Against-AIL (3) DAGSVM, (4) ECOC, (5) Method of Weston and Watkins, and (6) Method of Crammer and Singer. In addition, we examined the prediction accuracy of some modified version of conventional MSVM techniques. To find the most appropriate technique of MSVMs for corporate bond rating, we applied all the techniques of MSVMs to a real-world case of credit rating in Korea. The best application is in corporate bond rating, which is the most frequently studied area of credit rating for specific debt issues or other financial obligations. For our study the research data were collected from National Information and Credit Evaluation, Inc., a major bond-rating company in Korea. The data set is comprised of the bond-ratings for the year 2002 and various financial variables for 1,295 companies from the manufacturing industry in Korea. We compared the results of these techniques with one another, and with those of traditional methods for credit ratings, such as multiple discriminant analysis (MDA), multinomial logistic regression (MLOGIT), and artificial neural networks (ANNs). As a result, we found that DAGSVM with an ordered list was the best approach for the prediction of bond rating. In addition, we found that the modified version of ECOC approach can yield higher prediction accuracy for the cases showing clear patterns.

Nonlinear Analysis of RC Beams Considering Fixed-End Rotation due to Bond-Slip (부착슬립에 의한 강체변형을 고려한 철근콘크리트 보의 비선형해석)

  • Kwak Hyo-Gyoung;Kim Sun-Pil
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2005.04a
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    • pp.456-463
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    • 2005
  • An analytical procedure to analyze reinforced concrete (RC) beams subject to monotonic loadings is proposed on the basis of the moment-curvature relations of RC sections. Unlike previous analytical models which result the overestimation of stiffnesses and underestimation of structural deformations induced from ignoring the shear deformation and assuming perfect-bond condition between steel and concrete, the proposed relation considers the rigid-body-motion due to anchorage slip at the fixed end. The advantages of the proposed relation, compared with the previous numerical models, are on the promotion in effectiveness of analysis and reflection of influencing factors which must be considered in nonlinear analysis of RC beam by taking into account the nonlinear effects into the simplifying moment-curvature relation. Finally, correlation studies between analytical and experimental results are conducted to establish the applicability of the proposed model to the nonlinear analysis of RC structures.

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ONIOM and Its Applications to Material Chemistry and Catalyses

  • Morokuma, Keiji
    • Bulletin of the Korean Chemical Society
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    • v.24 no.6
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    • pp.797-801
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    • 2003
  • One of the largest challenges for quantum chemistry today is to obtain accurate results for large complex molecular systems, and a variety of approaches have been proposed recently toward this goal. We have developed the ONIOM method, an onion skin-like multi-level method, combining different levels of quantum chemical methods as well as molecular mechanics method. We have been applying the method to many different large systems, including thermochemistry, homogeneous catalysis, stereoselectivity in organic synthesis, solution chemistry, fullerenes and nanochemistry, and biomolecular systems. The method has recently been combined with the polarizable continuum model (ONIOM-PCM), and was also extended for molecular dynamics simulation of solution (ONIOM-XS). In the present article the recent progress in various applications of ONIOM and other electronic structure methods to problems of homogeneous catalyses and nanochemistry is reviewed. Topics include 1. bond energies in large molecular systems, 2. organometallic reactions and homogeneous catalysis, 3. structure, reactivity and bond energies of large organic molecules including fullerenes and nanotubes, and 4. biomolecular structure and enzymatic reaction mechanisms.

Shift-transient characteristics of an automatic transmission (자동변속기의 변속과도특성 해석)

  • Chang, Hyo-Whan;Jun, Yoon-Sik
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.22 no.3
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    • pp.654-662
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    • 1998
  • Shift quality of an automatic transmission in a vehicle is mainly affected by transient pressures in the hydraulic system during shifting. In this study, dynamic modelings of the hydraulic system and the power train of an automatic transmission are made systematically by a bond-graph method. The dynamic characteristics of the line pressures and clutch/brake pressures during shiftings are investigated by simulations and verified by experiments. The effects of clutch/brake pressures on the shift torque are also investigated through driving simulation.