• 한국전기전자재료학회논문지
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• 제25권3호
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• pp.193-197
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• 2012

$Gd_{1-x}VO_4:{Eu_x}^{3+}$ red phosphors were synthesized with changing the concentration of $Eu^{3+}$ ion by using a solid-state reaction method. The crystal structure, surface morphology, and photoluminescence and photoluminescence excitation properties of the red phosphors were measured by using X-ray diffractometer, field emission-scanning electron microscopy, and florescence spectrometer, respectively. The XRD results showed that the main peak of all the phosphor powders occurs at (200) plane. As for the photoluminescence properties, the maximum excitation spectrum occurred at 306 nm due to the charge transfer band from ${VO_4}^{3-}$ to $Eu^{3+}$ ions and the maximum emission spectrum was the red luminescence peaking at 619 nm when the concentration of $Eu^{3+}$ ion was 0.10 mol.

• Rapid Communication in Photoscience
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• 제3권2호
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• pp.35-37
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• 2014

PEC (photoelectrochemical) water splitting for $O_2/H_2$ production is one of the promising but difficult way to utilize solar energy. Among photocatalytic materials for PEC water oxidation, $BiVO_4$ (Eg = 2.4 eV) has been recently intensively studied since it has various advantageous properties. But its maximum efficiency has not been realized owing to kinetic factors - slow water oxidation at surface & insufficient stability. These problems can be simultaneously solved by application of oxygen evolution catalyst (OEC) such as $CoO_x$, Co-Pi, $IrO_x$ etc. Herein we report the first successful application of $NiFeO_x$ OEC on $BiVO_4$, showing good performance compared to other effective OEC applied on $BiVO_4$ under basic conditions. The enhanced activity of OEC loaded $BiVO_4$ has been supported by the surface charge separation efficiency and electrochemical impedance studies.

• 한국정보과학회:학술대회논문집
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• 한국정보과학회 2003년도 가을 학술발표논문집 Vol.30 No.2 (3)
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• pp.415-417
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• 2003

개방형 네트워크로의 진화는 third­party업체들의 참여를 가능하게 하였고. third­party애플리케이션의 대표적인 예로 VoIP를 들 수 있다. 최근 플랫폼에 중립적이며, 언제 어디서나 손쉽게 접근할 수 있는 Web 서비스의 등장은 많은 개발자들의 흥미를 유발하고 있다. 이에 Parlay Group에서는 개방형 네트워크에서 Web서비스를 지원하기위해 Parlay X API를 제정하였다. 본고에서는 개방형 네트워크에서의 Web서비스 제공을 위한 방법으로 VoIP Web서비스를 구현하여 Parlay X API를 활용하여 보았다.

• 정보처리학회논문지C
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• 제10C권4호
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• pp.501-508
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• 2003

인터넷상에서 음성을 전달하는 VoIP는 일반 고객들뿐만 아니라 기업에서도 기존 PSTN을 대체하는 수단으로써 각광 받고 있다. 현재의 VoIP는 음성 통화를 효율적으로 제공하고 있으나 VoIP 촉진을 위해서는 다양한 부가서비스의 지원이 필요하다. 이를 위해 IETF에서 부가서비스 지원을 위한 CPL(Call Processing Language) 표준을 개발하고 있다. CPL을 사용하기 위해서는 사용자가 CPL 스크립트를 작성한 후 특정한 서버에 스크립트를 저장해야 하며 이를 위해 CPL을 지원하는 클라이언트가 요구된다. 본 논문은 VoIP에서 부가서비스를 지원하기 위한 SIP 기반의 CPL 클라이언트 설계 및 구현에 관하여 기술한다. CPL을 지원하기 위한 클라이언트는 리눅스 2.4.x, C, 그리고 GTK1.2를 이용하여 구현하였다.

• 한국인터넷방송통신학회논문지
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• 제11권2호
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• pp.245-252
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• 2011

VoIP는 IP기반의 네트워크를 통해 음성 통화를 전송하는 Voice over Internet Protocol의 약자로서 최근에는 IP기반으로 음성 이외의 다양한 서비스가 제공되고 있다. 이러한 VoIP서비스의 확대 공급에 따라 VoIP 서비스의 품질관리가 중요한 이슈로 부각되고 있다. 따라서 본 논문에서는 VoIP서비스의 품질관리에 관한 연구를 다룬다. 이를 위하여 본 고에서는 VoIP 기술, 서비스 현황 및 네트워크 구성도를 파악하고 네트워크 사업자 관점이 아닌 고객관점의 VoIP 품질관리를 위한 key quality indicators(KQIs)/key performance indicators(KPIs)를 파악한다. 이를 위하여 일반적인 서비스 품질관리의 개념과 통신관련 서비스 품질관리의 개념에 대해서도 파악한다. 또한 KQIs중 가장 중요하다고 생각되는 품질관리 지표를 선정하여 통계적 품질관리 기법 중 하나인 $\bar{x}$와 R Charts를 이용하여 어떻게 기업에서 품질관리를 할 수 있는지 실제 예를 보여준다.

• 한국재료학회지
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• 제22권2호
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• pp.103-109
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• 2012

Red-emitting $Eu^{3+}$-activated $(Y_{0.95-x}Al_x)VO_4$ (0 < x $\leq$ 0.12) nanophosphors with the particle size of ~30 nm and the high crystallinity have been successfully synthesized by a hydrothermal reaction. In the synthetic process, deionized water as a solvent and ethylene glycol as a capping agent were used. The crystalline phase, particle morphology, and the photoluminescence properties of the excitation spectrum, emission intensity, color coordinates and decay time, of the prepared $(Y_{0.95-x}Al_x)VO_4:Eu^{3+}$ nanophosphors were compared with those of the $YVO_4:Eu^{3+}$. Under 147 nm excitation, $(Y_{0.95-x}Al_x)VO_4$ nanophosphors showed strong red luminescence due to the $^5D_0-^7F_2$ transition of $Eu^{3+}$ at 619 nm. The luminescence intensity of $YVO_4:Eu^{3+}$ enhanced with partial substitution of $Al^{3+}$ for $Y^{3+}$ and the maximum emission intensity was accomplished at the $Al^{3+}$ content of 10 mol%. By the addition of $Al^{3+}$, decay time of the $(Y,Al)VO_4:Eu^{3+}$ nanophosphor was decreased in comparison with that of the $YVO_4:Eu^{3+}$ nanophosphor. Also, the substitution of $Al^{3+}$ for $Y^{3+}$ invited the improvement of color coordinates due to the increase of R/O ratio in emission intensity. For the formation of transparent layer, the red nanophosphors were fabricated to the paste with ethyl celluloses, anhydrous terpineol, ethanol and deionized water. By screen printing method, a transparent red phosphor layer was formed onto a glass substrate from the paste. The transparent red phosphor layer exhibited the red emission at 619 nm under 147 nm excitation and the transmittance of ~80% at 600 nm.

• 한국결정성장학회지
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• 제33권4호
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• pp.132-138
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• 2023

Doped and undoped-BiVO₄ samples with different elements (Li, Mg) and amounts were synthesized with a hydrothermal method. The synthesized samples were characterized using various techniques including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV-Vis diffusion reflectance spectroscopy (UV-Vis DRS), and photoluminescence (PL) spectroscopy. Photocatalytic activity of the samples was evaluated by measuring the degradation of methyl blue (MB) under visible light irradiation. The results indicated that the incorporation of Mg and Li into BiVO₄ caused lattice distortion, the presence of surface hydroxyl groups, a narrower band gap, and a reduced recombination ratio of photo-induced electron-hole pairs. Notably, the photocatalytic activity of Mg5%-Li5% co-doped BiVO₄ sample exhibited a significant improvement compared to that of undoped BiVO₄ sample.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.169.2-169.2
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• 2015

$VO_2$ is a well-known a metal-to-insulator-transition (MIT) material, accompanied with a first order structural phase transition near room temperature. Because of the structural phase transition and the MIT occur near a same temperature, there is an ongoing argument whether the MIT is induced by the structural phase transition. $VO_2$ exhibits a relatively weak anti-oxidization ability and can be oxidized to higher-valence oxides (e.g., $V_4$ $O_7$ or $V_2$ $O_5$) when annealed at a high temperature in an oxygen-rich atmosphere. We fabricated $VO_2$ films on $Al_2$ $O_3$ (0001) substrates using a DC magnetron sputtering deposition process with carefully control the $O_2$ percentage in an atmosphere. X-ray diffraction measurements from the films showed only (0l0) peaks with no extra peaks, indicating b-oriented films. The temperature-dependent local structural properties of $VO_2$ films were investigated by using in-situ X-ray absorption fine structure (XAFS) measurements at the V K edge. XAFS revealed that the structural phase transition was occurred nearly $70^{\circ}C$ for heating process and reproducible. Resistance measurements as a function of temperature (R-T) demonstrated that the resistance of $VO_2$ films was changed by a factor of 4 near $75^{\circ}C$ which was higher than $68^{\circ}C$ reported from a $VO_2$ bulk. We will discuss the MIT of $VO_2$ films, comparing with the local structural properties determined by XAFS measurements.

• 한국진공학회지
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• 제21권2호
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• pp.93-98
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• 2012

고상 반응법을 사용하여 $Sm^{3+}$ 이온의 함량비를 변화시키면서 $Gd_{1-x}VO_4:{Eu_x}^{3+}$ 형광체 분말을 합성하였다. 모든 형광체 시료의 결정 구조는 $24.76^{\circ}$에 중심을 갖는 (200) 주 회절 피크로 구성되는 정방정계이었으며, 결정 입자의 형상은 $Sm^{3+}$ 이온의 함량비가 0.05 mol일 때 구형에 근접하고 균일한 크기 분포를 나타내었다. 발광 특성의 경우에, $Sm^{3+}$ 이온의 함량비에 관계없이 모든 형광체 분말은 파장 565, 603, 645 nm에 피크를 갖는 각각 황색, 주황색, 적색 형광을 보였다. $Sm^{3+}$ 이온의 함량비가 증가함에 따라 흡수 스펙트럼의 세기는 감소하는 경향을 나타내었으며, $Sm^{3+}$ 이온의 함량비가 0.05 mol일 때 최대 흡수와 발광 스펙트럼이 관측되었고, 대칭비의 값은 1.19이었다.

• 대한금속재료학회지
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• 제46권9호
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• pp.604-608
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• 2008

The layered compounds vanadium disulfide($VS_2$) and vanadium dioxide($VO_2$) intercalated with Li are investigated for using the Discrete Variational $(DV)-X{\alpha}$ molecular orbital method. The chemical bonding properties of the atoms were examined by bond overlap population of electronic states. The plot of density of states supports the covalent bonding properties by showing the overlap between the atoms. There is a strong tendency of covalent bonding between V-S and V-O. The intensity of covalent bonding of $VS_2$ is stronger than $VO_2$. The net charge of $LiVO_2$ is higher than that of $LiVS_2$. This results of the calculation of $VO_2$ and $VS_2$ indicate that $(DV)-X{\alpha}$ method can be widely applied in the new practical materials.