• Title/Summary/Keyword: Surface Property

Search Result 3,086, Processing Time 0.035 seconds

Preparation and Characteristics of High Voltage Liquid Silicone Rubber by Modified Cross-linking Agent

  • Jung, Se-Young;Kim, Byung-Kyu
    • Transactions on Electrical and Electronic Materials
    • /
    • v.10 no.1
    • /
    • pp.9-15
    • /
    • 2009
  • There is a growing demand for a high voltage silicone rubber composite with high mechanical property and high electrical property. The effect of modified cross-linking agent on the mechanical, electrical properties, and short-circuit test performance of silicone rubber insulators have been investigated. To use base polymer, the various silicone polymers were prepared by the equilibrium polymerization. Aluminum trihydrate surface was treated by vinyl silane. Liquid silicone rubber nanocomposite was prepared from the compounding of VPMPS, HPDMS, catalyst, and alumina trihydrate modified with 1,3,5-trivinyl-l,3,5-trimethylcyclotrisiloxane. The mechanical property and electrical property for insulation materials were measured, indicating the high tensile strength and the good short-circuit property.

Corrosion Property Evaluation of Copper Alloy Tubes against Sea Water

  • Pang, Beilli;Ong, Sang-Kil;Lee, Hong-Ro
    • Journal of Surface Science and Engineering
    • /
    • v.42 no.6
    • /
    • pp.280-286
    • /
    • 2009
  • In this study, the corrosion property of copper alloy tubes in seawater has been investigated. Three copper alloys of nominal composition Cu-20Zn-2Al(Al-Brass), Cu-30Ni(CN70/30) and Cu-10Ni(CN90/10) were considered. The samples were immersed in 3%NaCl flowing solution at $90^{\circ}C$ for 30, 50 and 80 days. Corrosion rate of copper alloy tubes in 3%NaCl flowing solution was investigated by weight-loss measurements and electrochemical test. The CN70/30 showed lowest corrosion rate among three copper alloy tubes. Because of passive films formation, corrosion rates of three types of copper tubes were decrease with time. Surface characteristics of copper alloy tubes were analyzed by optical micrograph(OM), scanning electronic microscopy (SEM), energy dispersive X-ray analysis(EDAX) and X-ray diffraction patterns(XRD). CN70/30 showed partly pitting problem on the surface owing to high Fe content, even though having high resistant against corrosion. Cracks appeared on the surface of CN90/10 and CN70/30 after more than 50 days immersion, which could be derived from high nickel contents.

The Effects of LaF3 Coating on the Electrochemical Property of Li[Ni0.3Co0.4Mn0.3]O2 Cathode Material

  • Yun, Su-Hyun;Kim, Seuk-Buom;Park, Yong-Joon
    • Bulletin of the Korean Chemical Society
    • /
    • v.30 no.11
    • /
    • pp.2584-2588
    • /
    • 2009
  • The effect of $LaF_3$ coating on the structural and electrochemical properties of $Li[Ni_{0.3}Co_{0.4}Mn_{0.3}]O_{2}$ cathodes was investigated using XRD, SEM, TEM, and a cycler. The coating layer consisted of nano-sized particles attached nonuniformly to the surface of pristine powder. Despite the surface coating treatment, phase difference by $LaF_3$ coating was not detected. The discharge capacities of coated electrodes were a little lower than that of pristine sample at a 1 C rate. However, as the C rate increases, the capacity retention of the coated sample becomes obviously superior to that of the pristine sample. The cyclic performances of the electrodes in the voltage range of 4.8 $\sim$ 3.0 V were also improved by the surface coating. Such enhancement is attributed to the presence of the $LaF_3$ coating layer, which effectively suppressd the reaction between electrodes and electrolytes on the surface of the $Li[Ni_{0.3}Co_{0.4}Mn_{0.3}]O_{2}$ electrode.

An enhancement in wear property of UHMWPE used in joint prosthesis (인공관절에 사용되는 UHMWPE의 내마모성 향상에 관한 연구)

  • Kim, K.T.;Lee, C.W.;Choi, J.B.;Choi, K.
    • Proceedings of the KOSOMBE Conference
    • /
    • v.1996 no.11
    • /
    • pp.3-6
    • /
    • 1996
  • The Ultra-high molecular weight polyethylene (UHMWPE) is exclusivity used as the articulation component with metal or ceramic materials in artificial joint prosthesis because of its good mechanical properties. In the long term however, wear of UHMWPE causes complex problems and hence causes loosening of He prosthesis. In this study, we tried to enhance the wear property of UHMWPE by attaching a hydrophilic graft on the UHMWPE surface and by improving surface hardness without deteriorating the mechanical properties of UHMWPE. This was achieved by ion implantation and by ${\gamma}$-irradiation to the surface in acrylic acid solution and by photo-polymerization in divinylbenzen (DVB), diallysophthalate (DAIP) solution. The wear test was performed by a wear testing machine of ball-on-disk type devised by the authors. The UHMWPE with hydrophlic surface and increased surface hardness developed by above treatments showed less volumetric wear.

  • PDF

Micro-patterning for Biomimetic Functionalization of Surface

  • Jeon, Deok-Jin;Lee, Jun-Yeong;Yeo, Jong-Seok
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.02a
    • /
    • pp.272-273
    • /
    • 2013
  • Some living thingsuse micro- or nano- structures for living in nature. Scientists and engineers made efforts to mimic them, and they succeeded in making new types of applications. They used 'Namib desert beetle' to self-filling device by moisture harvesting and 'lotus leaf' to self-cleaning device by water repelling. 'Namib desert beetle' and lotus leaf have micro-patterns on their surface, which consists of hydrophobic or hydrophilic materials [1]. Moreover, micro-patterns on the surface make self-filling or self-cleaning property enhanced because of the surface roughness. Surface roughness enhances wettability [2]. Micro-pattern is a significant factor to make the surface be functional, so we want to make new types of functional surface by micro-patterning. In this work,we make several functional micro-patterns (radial, line, and dot arrays) using maskless lithography and analyze the characteristics of each micro-pattern. In order to analyze and understand surface characteristics, micro-patterns with varying sizes are investigated. All experiments are proceeded on mr-DWL5 photo resists coated on silicon wafers in same condition. All the experiments have demonstrated good performances about hydrophobic or hydrophilic property corresponding to their material and structural combinations. In radial micro-pattern, although the surface is flat, water drops on hydrophilic radial pattern can be convergent to a middle point and water drops on hydrophobic radial pattern can be divergent from the middle point. In line array micro-pattern, water drops can roll off along only one direction in parallel with the line arrays. Such phenomena might be mainly caused by the local change of surface roughness. From these results, controlling the movement and direction of water drops is made feasible without introducing a slope, which can potentially be used for new types of applications.

  • PDF

Enzymatic Modification of Wool/Polyester Blend Fabrics Using Lipase from Aspergillus Oryzae (리파제에 의한 양모/폴리에스터 혼방직물의 동시 개질)

  • Song, Hyun-Joo;Kim, Hye-Rim;Song, Wha-Soon
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.33 no.7
    • /
    • pp.1121-1127
    • /
    • 2009
  • This study presents an eco-friendly and one-step finishing method for modifying fiber property that reduces fiber damage in wool/polyester blend fabrics. Lipase from aspergillus oryzae is used in this experiment. The enzymatic treatment condition is optimized by measuring the relative activity of lipase depending on pH level, temperature, concentration of lipase, and treatment time. The concentration of $CaCl_2$as an activator is determined by the characteristics including whiteness, water contact angle (WCA), and dyeing property. The modified properties of lipase treated fabrics are tested for pill resistance and surface morphology. The results are described as follows: the optimum condions for lipase treatment constitute a pH level of 8.0, treatment temperature of 40$^{\circ}$$_C$, concentration of lipase at 100% (o.w.f), and a treatment time of 90 minutes. $CaCl_2$helps in raising lipase activation, and the optimum concentration is 50mM. The whiteness, wet ability, and pill resistance of lipase treated fabrics improves as compared to the control. The dyeing property of lipase treated fabrics improved by 53.5% after using the one-bath dyeing method. This means that lipase treatment can save time and cost during the dyeing process since lipase treatment modifies wool and polyester fibers. The surface of lipase treated wool fibers do not exhibit any change, however voids and cracks manifest on the surface of lipase treated polyester fibers.

Functionalization of Electrospun Nano/Micro-fibrous Scaffolds Using Gamma-ray Irradiation (감마선 조사법을 이용한 전기방사 나노/마이크로 섬유 지지체의 표면 기능화)

  • Lim, Jong-Young;Shin, Young Min;Choi, Jong-Bae;Jeong, Jin-Oh;Gwon, Hui-Jeong;Jeong, Sung In;Park, Jong-Seok;Lim, Youn-Mook
    • Journal of Radiation Industry
    • /
    • v.7 no.1
    • /
    • pp.45-49
    • /
    • 2013
  • In tissue engineering application, a fibrous structure of scaffolds has been issued as an alternative system to regulate cell survival and tissue regeneration, and electrospinning technique has been popularly used to generate fibrous meshes or sheets mimicking the structure of native extracellular matrix (ECM). However, recent strategy in the scaffold development is expanded to provide the structural property as well as a biological property of native ECM, a variety of surface modification techniques have been used to introduce biological property. In this study, we developed biomimetic poly(L-lactide-co-${\varepsilon}$-caprolactone) (PLCL) nano- and micro-fibrous scaffolds as a unique platform with structural and biological properties with native ECM using electrospinning method and gamma-ray irradiation. Surface morphology of the scaffolds was observed by scanning electron microscopy, and alteration of surface property was evaluated with toluidine blue O staining, water contact angle measurement and ATR-FTIR analysis.

Sensitivity improvement of $CeO_2$ oxygen sensor by betterment of surface characteristics through chemical mechanical polishing process (CMP 공정을 통한 표면 특성 개선에 의한 $CeO_2$ 산소 센서 감도 향상 연구)

  • Jung, Pan-Gum;Jun, Young-Kil;Ko, Pil-Ju;Kim, Nam-Hoon;Lee, Woo-Sun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2007.11a
    • /
    • pp.65-65
    • /
    • 2007
  • Microstructure and surface roughness of the sensing materials should be improved to use them in advanced sensor applications because the uneven surface roughness degrades the light reflection, pattern resolution, and devices performance. Chemical mechanical polishing (CMP) processing was selected for improving the surface roughness of $CeO_2$ which is one of the well known materials for the oxygen gas sensors. Surface roughness and removal rate of spin coated $CeO_2$ thin films were examined with a change of CMP process parameters such as down force and table speed. The optimized process condition, reflected by the surface roughness with the hillock-free surface as well as the excellent removal rate with the good uniformity, was obtained. The effects of the improved surface roughness on the sensing property of $CeO_2$ thin films were also confirmed. The improved sensitivity of $CeO_2$ thin films for oxygen sensors were obtained after CMP process by the improved surface characteristics. Therefore, we conclude that sensing property of $CeO_2$ thin film is strongly dependent on the surface roughness of $CeO_2$ thin films by using CMP process.

  • PDF

On Crossing Changes for Surface-Knots

  • Al Kharusi, Amal;Yashiro, Tsukasa
    • Kyungpook Mathematical Journal
    • /
    • v.56 no.4
    • /
    • pp.1247-1257
    • /
    • 2016
  • In this paper, we discuss the crossing change operation along exchangeable double curves of a surface-knot diagram. We show that under certain condition, a finite sequence of Roseman moves preserves the property of those exchangeable double curves. As an application for this result, we also define a numerical invariant for a set of surface-knots called du-exchangeable set.

A Study on Fundamental Performance of Epoxy Resin Mortar Mixed Special Cement for Concrete Surface Control (특수시멘트 혼입 에폭시 수지계 콘크리트용 바탕조정재의 기초물성에 관한연구)

  • 최성민;김용현;황원주;오상근
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 1998.10c
    • /
    • pp.145-150
    • /
    • 1998
  • This study deals with the effect on performance of epoxy resign mortar mixed special cement for surface control and maintenance of aging concrete construction. The test of main property of epoxy resign in this study are the evaluation on the adhesive strength between substrate and epoxy resign mortar under the environment of wet or concrete substrate surface. We gained the test results of good adhesive strength over 15 kgf/$\textrm{cm}^2$ under the wet and dry condition of concrete surface.

  • PDF