• Applied Science and Convergence Technology
• /
• 제24권6호
• /
• pp.228-231
• /
• 2015

We investigated the adsorption structures and the initial growth mode of ultra-thin Al films on a W(110) surface at a high temperature. When Al atoms were adsorbed on the W(110) at the substrate temperature of 1100 K and with coverage of 0.5ML, Al atoms formed a p($2{\times}1$) double-domain structure. When the coverage was 1.0 ML, the double domain of a hexagonal structure (fcc(111) face) rotated ${\pm}5^{\circ}$ from the [100] direction of the W(110) surface and another distorted hexagonal structure were found. Low-energy electron diffraction results along with ion scattering spectroscopy results showed that the Al atoms followed the Volmer-Weber growth mode at a high temperature.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2009년도 제38회 동계학술대회 초록집
• /
• pp.369-369
• /
• 2010

Adsorption and ordering of methionine molecules on Ge(100) surface have been studied using high resolution photoemission spectroscopy and low-energy electron diffraction (LEED) to investigate the adsorption structure as a function of coverage. Analysis of C 1s, S 2p, N 1s, and O 1s core levels reveals quite different according to methionine coverage. We found that the relative population of the two types of thiolates induces a structural change in the ordering from $2\;{\times}\;1$ to $1\;{\times}\;1$. Such an unusual evolution of the methionine adsorption on the Ge(100) surface is discussed in relation to chemical reactions and possible molecular rearrangement on the surface.

• Bulletin of the Korean Chemical Society
• /
• 제16권2호
• /
• pp.143-148
• /
• 1995

Ketene (CH2CO) adsorption on Ag(111) has been studied in ultrahigh vacuum using electron energy loss spectroscopy and temperature programmed desorption. Ketene adsorbs molecularly on Ag(111) at temperatures below 126 K. The coverage increases linearly with exposure until saturation. No multilayer formation and no shift in desorption temperature with coverage were observed, indicating a lack of attractive interaction between adsorbate molecules. The desorption activation energy is estimated to be 7.8 kcal/mol by assuming first order kinetics and a pre-exponential factor of 1013 sec-1. The adsorption geometry of ketene on the surface is determined from the relative intensities of the vibrational energy loss peaks. The CCO axis of CH2CO is found to be almost parallel to (∼4°away from) the surface and the molecular plane is almost perpendicular to the surface (∼3°tilt).

• 한국환경복원기술학회지
• /
• 제8권6호
• /
• pp.34-44
• /
• 2005

The objective of this study is to analyze the thermal properties of various green roof type. The experimental districts, have different soil thickness, soil type, the existence of module and the different kinds of vegetation, had installed. A measurement was conducted in Seoul University to investigate the thermal impacts of rooftop greening. The measurement point of temperature were 30, located in soil surface, middle of the soil layer, under the module, hard surface and soffit surface of each experimental district. The experimental investigation lasted from 6th August to 29th August, a total of 24 days. The results showed that green roof can contribute thermal benefits by soil and vegetation and reduce building energy consumption by a role of insulation. It's also better to make soil thickness over 20cm and various vegetation that should be more effective. The district installed only soil also could be effective for reducing the temperature of roof surface. Therefore, the increase of soil thickness and various vegetation could reduce more temperature of roof surface and building energy consumption. Also, it's helpful to reduce temperature that plant coverage rate be raised.

• 한국지하수토양환경학회:학술대회논문집
• /
• 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
• /
• pp.37-47
• /
• 2004

In Korea, over three hundreds of the coal mines were closed or abandoned due to the depression of the mining industry since the late 1980s. Many of them locate in the steep mountain valleys and the coal mine wastes had been disposed without a proper treatment From these mines, enormous amounts of coal mine overburdens have been abandoned in the slopes and the ample amounts of acid mine drainage (AMD) from either portal or overburdens have been discharging directly to the streams, causing the detrimental effects on soil and water qualities. Objectives of this research were to reclaim the coal mine overburdens using the lime waste cake from the soda ash production by stabilizing the overburden slopes, introducing the vegetation alleviate the environmental problems caused by the closed coal mines. The percentages of the grass distribution ratio (%) and the surface coverage ($\textrm{cm}^2$) in each treatment plot were determined during June to August after seed spraying grasses such as orchard grass (Dactylis glomerata L), Kentucky Bluegrass (Poa pratensis L.) and Eulalia (Miscanthus sinensis Anderss) at the end of May. The grasses covered only 15.5 % of the coal overburden plot at the early stage but the coverage was increased with time to 33% in August. Growth of such grasses was enhanced with the combined treatments of lime waste and topsoil resulting in the increased surface coverage by the grasses. The Increment of the surface coverage from June to August was higher with lime waste treatments. The distribution percentages and surface coverage were highest when the lime wastes were treated at 25 % of the lime requirement. This might be related with the high salt contents in the hire wastes. Results demonstrated that the amounts of lime wastes at 25% of the lime requirement were sufficient for neutralizing the acidic coal overburden and introducing the re-vegetation. Either layering between the coal waste and topsoil or mixing with coal overburdens could be adopted as the lime waste treatment method. The combined treatment of lime wastes and topsoil was recommended for re-vegetation in the coal overburden slopes. The lime wastes from the soda ash production might have a potential to be recycled for the reclamation of the abandoned coal mines to alleviate the environmental problems associated with coal mine waste.

• Journal of Astronomy and Space Sciences
• /
• 제36권4호
• /
• pp.225-234
• /
• 2019

We explore the associations between the total sunspot area, solar north-south asymmetry, and Southern Oscillation Index and the physical characteristics of clouds by calculating normalized cross-correlations, motivated by the idea that the galactic cosmic ray influx modulated by solar activity may cause changes in cloud coverage, and in turn the Earth's climate. Unlike previous studies based on the relative difference, we have employed cloud data as a whole time-series without detrending. We found that the coverage of high-level and low-level cloud is at a maximum when the solar north-south asymmetry is close to the minimum, and one or two years after the solar north-south asymmetry is at a maximum, respectively. The global surface air temperature is at a maximum five years after the solar north-south asymmetry is at a maximum, and the optical depth is at a minimum when the solar north-south asymmetry is at a maximum. We also found that during the descending period of solar activity, the coverage of low-level cloud is at a maximum, and global surface air temperature and cloud optical depth are at a minimum, and that the total column water vapor is at a maximum one or two years after the solar maximum.

• Bulletin of the Korean Chemical Society
• /
• 제28권12호
• /
• pp.2442-2444
• /
• 2007

CO adsorbates on the surface of Pt supported on carbon catalysts (Pt/C) were investigated by CO stripping voltammetry. Three types of CO adsorbed samples were prepared: by methanol dehydrogenation only (COm), by CO gas bubbling only (COg), and by methanol dehydrogenation followed by CO gas bubbling (COm+g). Our coverage data show that CO gas can be adsorbed on Pt/C catalyst already saturated with CO adsorbates by methanol dehydrogenation. The COm+g sample showed the properties of both COm as well as COg samples in terms of the potential although the CO adsorbed by dehydrogenation was completely exchanged with CO in the electrolyte solution. Therefore, the oxidation pathways of CO on Pt/C were observed to depend on the initial adsorption conditions of CO more strongly than on the CO coverage. Our results imply that an initial CO poisoning condition in fuel cell operation is an important factor to determine the difficulty in removing the adsorbed CO and confirm that the properties of the adsorbed CO do not change even with chemical replacement with CO in different conditions. In addition, our results indicate a low CO surface mobility on the Pt in an electrolyte solution.

• 한국소음진동공학회:학술대회논문집
• /
• 한국소음진동공학회 2008년도 춘계학술대회논문집
• /
• pp.21-24
• /
• 2008

This study proposes a optimized shape of diffuser profile through investigating the scattering and diffusion characteristics of diffusers. The scattering coefficient according to ISO 17497-1 evaluates uniformity of reverberant sound field of late reflections, while the diffusion coefficient according to AES-4id-2001 evaluates polar response of early reflections. Thus both scattering and diffusion characteristics should contribute to design shape of diffusers to maximize physical performance. To find out design method, the previous results on hemisphere diffusers are reviewed. The frequency characteristics of scattering coefficients depended on the structural height of the diffusers, while amount of scattering coefficients depended on the surface coverage density of the diffusers. However absorptive properties also increased with augment of surface coverage density, thus optimum coverage density should be considered. For the directional diffuser, three types of 2D-diffusers are proposed; semicylinder of h=5mm, semi-truncated cone of h=5-25mm and semicylinder of h=25mm. As results, diffusers with the maximum height of 25mm show the highest scattering coefficients, while diffuser of h=5mm shows high scattering coefficients only at the high-frequency bands. Diffusion coefficient will be investigated for diffusive properties of the early reflection.

• 한국자동차공학회논문집
• /
• 제14권3호
• /
• pp.125-132
• /
• 2006

Transient kinetics of $NH_3$ adsorption/desorption and of SCR(selective catalytic reduction) of NO with $NH_3$ were studied over vanadium based catalysts, such as $V_2O_5/TiO_2$ and $V_2O_5-WO_3/TiO_2$. In the present catalytic reaction process, NO adsorption is neglected while $NH_3$ is strongly chemisorbed on the catalytic surface. Accordingly, it is ruled out the possibility of a reaction between strongly adsorbed $NH_3$ and NO species in line with the hypothesis of an Eley-Rideal mechanism. The present kinetic model assumes; (1) non-activated $NH_3$ adsorption, (2) Temkin-type $NH_3$ coverage dependence of the desorption energy, (3) non-linear dependence of the SCR reaction rate on the $NH_3$ surface coverage. Thus, the surface heterogeneity for adsorption/desorption of $NH_3$ is taken into account in this model. The present study extends the pure chemical kinetic model based on a powdered-phase catalytic system to the chemico-physical one applicable to a realistic monolith reactor.

• Applied Science and Convergence Technology
• /
• 제23권5호
• /
• pp.201-210
• /
• 2014

The influence of electron irradiation and hydrogen adsorption on the electronic structure of the $SrTiO_3$ (001) surface was investigated by ultraviolet photoemission spectroscopy (UPS). Upon electron irradiation of the surface, UPS revealed an electronic state within the band gap (in-gap state: IGS) with the surface kept at $1{\times}1$. This is considered to originate from oxygen vacancies at the topmost surface formed by electron-stimulated desorption of oxygen. Electron irradiation also caused a downward shift of the valence band maximum indicating downward band-bending and formation of a conductive layer on the surface. With oxygen dosage on the electron-irradiated surface, on the other hand, the IGS intensity was decreased along with upward band-bending, which points to disappearance of the conductive layer. The results indicate that electron irradiation and oxygen dosage allow us to control the surface electronic structure between semiconducting (nearly-vacancy free: NVF) and metallic (oxygen de cient: OD) regimes by changing the density of the oxygen vacancy. When the NVF surface was exposed to atomic hydrogen, in-gap states were induced along with downward band bending. The hydrogen saturation coverage was evaluated to be $3.1{\pm}0.8{\times}10^{14}cm^{-2}$ with nuclear reaction analysis. From the IGS intensity and H coverage, we argue that H is positively charged as $H^{{\sim}0:3+}$ on the NVF surface. On the OD surface, on the other hand, the IGS intensity due to oxygen vacancies was found to decrease to half the initial value with molecular hydrogen dosage. H is expected to be negatively charged as $H^-$ on the OD surface by occupying the oxygen vacancy site.