• Journal of the Korean Electrochemical Society
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• v.25 no.1
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• pp.1-12
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• 2022

Lithium metal is the most promising anode for next-generation lithium-ion batteries due to its lowest reduction potential (-3.04 V vs. SHE) and high specific capacity (3860 mAh/g). However, the dendritic formation under high charging current density remains one of main technical barriers to be used for commercial rechargeable batteries. To address these issues, tremendous research to suppress lithium dendrite formation have been conducted through new electrolyte formulation, robust protection layer, shape-controlled lithium metal, separator modification, etc. However, Li/Li symmetric cell test is always a starting or essential step to demonstrate better lithium dendrite formation behavior with lower overpotential and longer cycle life without careful analysis. Thus, this review summarizes overpotential behaviors of Li/Li symmetric cells along with theoretical explanations like initial peaking or later arcing. Also, we categorize various overpotential data depending on research approaches and discuss them based on peaking and arcing behaviors. Thus, this review will be very helpful for researchers in lithium metal to analyze their overpotential behaviors.

• Applied Chemistry for Engineering
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• v.34 no.4
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• pp.331-346
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• 2023

Recently, green processes that can be directly used in an energy-efficient and electrified society to achieve carbon neutrality are attracting attention. Existing heat and pressure-based desalination technologies that consume tremendous amounts of energy are no exception, and the growth of next-generation electrochemical-based desalination technologies is remarkable. One of the most representative electrochemical desalination technologies is electrochemical ion separation (EIONS) technology, which includes capacitive desalination (CDI) and battery desalination (BD) technology. In the research field of EIONS, various system applications have been developed to improve system performance, such as capacity and cyclability. However, it is very difficult to understand the meaning and novelty of these applications immediately because there are only a few papers that summarize the research background for domestic readers. Therefore, in this review paper, we aim to describe the technological advances and individual characteristics of each system in clear and specific detail about the latest EIONS research. The driving principle, research background, and strengths and weaknesses of each EIONS system are explained in order. In addition, this paper concluded by suggesting the future development and research direction of EIONS. Researchers who are just beginning out in EIONS research can also benefit from this study because it will help them understand the research trend.

• Journal of Convergence for Information Technology
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• v.12 no.2
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• pp.134-141
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• 2022

To improve the performance of aluminum-air batteries, it is very important to understand the effect of electrolytes on the electrochemical properties of electrodes. In this study, the effects of electrolyte cations on the electrochemical redox reactions proceeding at the negative and positive electrodes were investigated using electrolytes having the same anion but different cations such as NaCl, LiCl, CaCl₂, and ZnCl₂. It was confirmed by discharge test, scanning electron microscopy and X-ray diffraction analysis that electrolyte cations affect the discharge potential and specific capacity of the electrode. Precipitates were formed on the surface of the positive electrode by Ca²⁺ and Zn²⁺ ions, resulting in degradation of the performance of the positive electrode. In addition, Ca²⁺ ions passivated the negative electrode and accelerated the performance degradation. This suggests that the positive ions of the electrolyte have different effects on the electrochemical performance of the positive and negative electrodes.

• Journal of Popular Narrative
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• v.25 no.2
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• pp.169-216
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• 2019

This study proposes the concept of Bachchin's Chronotope as a tool for analyzing coevolution between the genre of the epic and society. Bachchin says through the concept of chronotope, literary works are on the foundation on which the axs of time and space intersect, and the literary works standsuch intersections are always conversing with social and historical chronotopes and mutually penetrating. Thus, finding and analyzing chronotope in literary works and extended things such as films and dramas reveals how chronotope and chronotope of a society have created specific social realities through a process of resonance. To make analytical use of this concept, we proposed a "cronotope drama analysis method" and concretely analyzed the genre of Korean medical dramas. The naturalized categories of health care, health, and disease are socially constructed entities, and the analysis of public works that has a significant impact on this process of social construction is essential but was underperformed. According to the analysis, the Korean medical drama's "Chronotope" has evolved using "Chronotope of the school" and "Chronotope of the secret chamber". At this time, the genre of Chronotope was expanding spatially and converging in time. In other words, the influence of structures and systems within the genre has grown, and the capacity of individual actors has decreased. This change in chronotope was interpreted as resonating with the social reality of neo-liberalistic spatial expansion and simultaneous production. The neo-liberalistic trend that dominates Korean society has embraced the category of health care and was further influencing the chronotope of drama text. It can also be inferred that the popular understanding of health care produced by the medical drama genre has taken a break in the process of forming a social reality of health care again.

• Journal of the Korea Organic Resources Recycling Association
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• v.31 no.2
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• pp.63-71
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• 2023

Increased nitrogen in the water system has become an important environmental problem around the world, as it causes eutrophication, algae bloom, and red tide, destroys the water system, and undermines water's self-purification. The most common form of nitrogen in the water system is ammonium ion (NH₄⁺), and the largest portion of ammonium ions comes from wastewater. NH₄⁺ is a major contributor to eutrophication, which calls for appropriate treatment and measures for ammonium removal. This study produced biochar by applying Sorghum × drummondii, a type of biomass with a great growth profile, analyzed the adsorption capacity of Sorghum × drummondii biochar produced from the changing carbonization temperature condition of 200 to 400℃ in the ammonium ion range of 10 to 100 ppm, and used the results to evaluate its potential as an adsorbent. Carbonization decomposed the chemical structure of Sorghum × drummondii and increased the content of carbon and fixed carbon in the biochar. The biochar's pH and electrical conductivity showed high adsorption potential for cations due to electrical conductivity as its pH and electrical conductivity increased along with higher carbonization temperature. Based on the results of an adsorption experiment, the biochar showed 54.5% and 17.4% in the maximum and minimum NH₄-N removal efficiency as the concentration of NH₄-N increased, and higher carbonization temperature facilitated the adsorption of pollutants due to the biochar's increased pores and specific surface area and subsequently improved NH₄-N removal efficiency. FT-IR analysis showed that the overall surface functional groups decreased due to high temperature from carbonization.

• ALGAE
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• v.38 no.2
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• pp.141-150
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• 2023

Light quality is a common environmental factor which influences the metabolism of biochemical substances in algae and leads to the response of algal growth and development. Pyropia yezoensis is a kind of economic macroalgae that naturally grows in the intertidal zone where the light environment changes dramatically. In the present study, P. yezoensis thalli were treated under white light (control) and monochromatic lights with primary colors (blue, green, and red) for 14 days to explore their physiological response to light quality. During the first 3 days of treatment, P. yezoensis grew faster under blue light than other light qualities. In the next 11 days, it showed better adaptation to green light, with higher growth rate and photosynthetic capacity (reflected by a higher rETR_max = 61.58 and E_k = 237.78). A higher non-photochemical quenching was observed in the treatment of red light than others for 14 days. Furthermore, the response of P. yezoensis to light quality also results in the difference of photosynthetic pigment contents. The monochromatic light could reduce the synthesis of all pigments, but the reduction degree was different, which may relate to the spectral absorption characteristics of pigments. It was speculated that P. yezoensis adapted to a specific or changing light environments by regulating the synthesis of pigments to achieve the best use of light energy in photosynthesis and premium growth and metabolism.

• Journal of Korea Entertainment Industry Association
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• v.13 no.5
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• pp.247-262
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• 2019

This study involved the effects of home-visit program with cognitive-stimulating activities on cognitive function and memory self-efficacy of an elderly with dementia special rating(5rates). The study was conducted from February 11 to April 26, 2019 using a 65-year old woman residing in G Metropolitan City. The individual subject study used an A-B-A design. The subject performed activities that required thinking and resolving in order to stimulate both her body and cognition. The activities chosen were easily accessible to those having a form of mild dementia, rates 5 dementia special rating, and repetitively stimulated the subject's intellectual capacity in an attempt to increase her degraded cognitive functioning. Specifically, the activities exercised both short-term memory and recollection using familiar letters, numbers, and bodily movements frequently encountered in daily life. The program positively affected the subject's memory and concentration. In addition, the program was found to be feasible for home use by those with mild dementia, obviating the need to travel to a location like a welfare center. The author presents specific activities for stimulating cognition that can effectively intervene to positively influence the cognitive functioning and memory of those with rates 5 dementia special rating.

• Journal of Internet of Things and Convergence
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• v.9 no.6
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• pp.23-28
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• 2023

Windows operating system generates various logs with timestamps. Timestamp tampering is an act of anti-forensics in which a suspect manipulates the timestamps of data related to a crime to conceal traces, making it difficult for analysts to reconstruct the situation of the incident. This can delay investigations or lead to the failure of obtaining crucial digital evidence. Therefore, various techniques have been developed to detect timestamp tampering. However, there is a limitation in detection if a suspect is aware of timestamp patterns and manipulates timestamps skillfully or alters system artifacts used in timestamp tampering detection. In this paper, a method is designed to detect changes in timestamps, even if a suspect alters the timestamp of a file on a storage device, it is challenging to do so with precision beyond millisecond order. In the proposed detection method, the first step involves verifying the timestamp of a file suspected of tampering to determine its write time. Subsequently, the confirmed time is compared with the file size recorded within that time, taking into consideration the performance of the storage device. Finally, the total capacity of files written at a specific time is calculated, and this is compared with the maximum input and output performance of the storage device to detect any potential file tampering.

• Applied Chemistry for Engineering
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• v.34 no.5
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• pp.529-533
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• 2023

The fundamental electrochemical properties and adsorption capabilities of the carbonized product derived from coffee grounds, a prevalent form of lignocellulose abundantly generated in our daily lives, have been extensively investigated. The structure and morphology of the resultant carbonized product, obtained through a carbonization process conducted at a relatively low temperature of 600 ℃, were meticulously examined using a scanning electron microscope. Raman spectroscopy measurements yielded a relative crystallinity (D/G ratio) of the carbon product of 0.64. Electrical measurements revealed a linear ohmic relationship within the carbonized product. Furthermore, the viability of utilizing this carbonized material as an anode in lithium-ion batteries was evaluated through half-cell charge/discharge experiments, demonstrating an initial specific capacity of 520 mAh/g. Additionally, the adsorption performance of the carbon material towards a representative dye molecule was assessed via UV spectroscopy analyses. Supplementary experiments corroborated the material's ability to adsorb a distinct model molecule characterized by differing surface polarity, achieved through surface modification. This article presents pivotal findings that hold substantial implications for forthcoming research endeavors centered around the recycling of lignocellulose waste.

• Applied Chemistry for Engineering
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• v.35 no.1
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• pp.23-28
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• 2024

Cesium is a potential toxic contaminant due to its high solubility, which allows it to easily penetrate the human body and potentially induce cancer or DNA mutations. In this study, oxygen functional groups were introduced on activated carbons (ACs) by ozone treatment to enhance the cesium adsorption capacity. As the ozone treatment time increased, the oxygen content on the ACs surface increased. Subsequently, the electrostatic interaction between ACs and cesium enhanced, resulting in higher cesium ion adsorption efficiency across all samples. In particular, the sample treated with ozone for 7 minutes at an internal ozone concentration of 50000 ppm had roughly 12% greater oxygen functional group content and the highest cesium removal effectiveness (97.6%). Meanwhile, samples treated for 5 minutes showed a 0.3% cesium removal rate difference compared to those treated for 7 minutes, which was caused by the surface chemical similarity of the two samples due to the reactive characteristics of ozone gas. However, the cesium adsorption performance of ozonated activated carbon seems to be mainly influenced by the amount of oxygen functional groups introduced to the surface, although the specific surface area and pore structure of the activated carbon are also important.