• Title/Summary/Keyword: Solution stability

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Influence of Raito of TGA(thioglycolic acid) on CdTe QDs Solution Stability for a Period of Time (CdTe QDs 용액 안정성의 장시간 유지지속을 위한 TGA(thioglycolic acid)의 첨가효과)

  • Kim, Jong-Hwan;Kim, Tae-Hee;Gwoo, Dong-Gun;Kee, Kyung-Bum;Choi, Won-Gyu;Han, Kung-Seok;Ryu, Bong-Ki
    • Korean Journal of Materials Research
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    • v.22 no.9
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    • pp.465-469
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    • 2012
  • This paper focuses on the after synthesis of CdTe quantum dots(QDs) in aqueous solution. CdTe nanoparticles were prepared in aqueous solution using mercaptocarboxylic acid or thioglycolic acid(TGA) as stabilizing agents. QDs emit light smaller than the nano size. The contents of the mercaptocarboxylic acid, and a kind of raw material, were revealed for a period of time. We succeeded in synthesizing a very high quality QDs solution; we discussed how to make QDs better and to keep them stabilized. TGA is known as one of the best stabilizing agents. Many papers have mentioned that TGA is a good stabilizing agent. We dramatically confirmed the state of QDs after the experiments. The QDs solution can be influenced by several factors. Different content of TGA can influence the stability of the CdTe solution. Most papers deal with the synthesis of CdTe, so we decided to discuss the after synthesis process for the stability of the CdTe solution.

Dispersion Characteristics of Zinc Oxide Nanoparticles in Ionic and Non-ionic Isotonic Solution (이온성 및 비이온성 등장액 용매에서 산화아연나노입자의 분산 특성)

  • Choi, Jonghye;Kim, Hyejin;Park, Kwangsik
    • YAKHAK HOEJI
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    • v.57 no.4
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    • pp.282-288
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    • 2013
  • Zinc oxide nanoparticles (ZnONPs) are widely used in a variety of products and cosmetic products including paper, paints, plastics and sunscreen. However, information on the safety of ZnONPs are not enough and many publications suggest possible toxic effects on environmental and human health. Furthermore, physico-chemical characteristics of nanoparticles makes it hard to test toxicity using the test guidelines of chemicals adopted by regulatory bodies. In this study, stability of ZnONPs was investigated using different types of isotonic solution, which is important in the toxicity study of intravenous route. Precipitation, aggregation, size, zeta potential and morphology of ZnONPs were evaluated with different times and concentrations. Precipitation of ZnONPs were observed in ionic isotonic solution including phosphate-buffered saline, Kreb's-Ringer solution, physiological salt solution and cell culture media of DMEM (Dulbecco's Modified Eagle's Medium) with 10% fetal bovine serum. On the other hand, they were stable without precipitation in non-ionic isotonic solution such as 5% glucose and 2% glycerol, respectively, which are biocompatible for intravenous injection. The average size of ZnONPs in 5% glucose and 2% glycerol was stably maintained, which is less than 30 nm and very similar as that in water dispersion of ZnONPs, provided by the manufacturer. The stability was maintained during the experimental period of 5 days and diluted state up to 15,000 ppm. These data suggest that 5% glucose and 2% glycerol solution can be used for the vehicles of ZnONPs in the toxicity study of intravenous injection route.

The Dispersion Stability of $\alpha-Fe_2O_3$ Particulate Soil in the Anionic/Nonionic Mixed Surfactant Solution (음/비이온계 혼합계면활성제 용액에서 $\alpha-Fe_2O_3$ 입자의 분산안정성)

  • 정선영;강인숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.28 no.6
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    • pp.854-861
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    • 2004
  • To estimate dispersion stability of particles in anionic and nonionic surfactant mixed solution, suspending power was examined as functions of duration time of suspension, ionic and nonionic surfactant mixed ratio, surfactant concentration, kinds of electrolyte, ionic strength and mole numbers of oxyethylene additions to nonionic surfactant using $\alpha$-Fe$_2$O$_3$ particle as the model of particulate soil. The suspending power of anionic and nonionic surfactant mixed solution was relatively higher than that of anionic and nonionic surfactant single solution regardless of solution concentration. The suspending power was gradually decreased with increasing duration time of suspension. In the absence of electrolyte, the effect of surfactant concentration on suspending power was small but in solution with electrolyte, suspending power was lowest at 1 % surfactant concentration. With 1${\times}$10$^{-3}$ ionic strength and polyanionic electrolyte in solution, the suspending power was high but effects of oxyethylene mole number to nonionic surfactant on suspending power was small. Generally the suspending power was gradually increased with decreasing the particle size. Hence the suspending power was inversely related to the particle size.

BS-STABILITIES AND $\rho$-STABILITIES FOR FUNCTIONAL DIFFERENCE EQUATIONS WITH INFINITE DELAY

  • Choi, Sung Kyu;Goo, Yoon Hoe;Im, Dong Man;Koo, Namjip
    • Journal of the Chungcheong Mathematical Society
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    • v.25 no.4
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    • pp.753-762
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    • 2012
  • We study the BS-stability and the $\rho$-stability for functional difference equations with infinite delay as a discretization of Murakami and Yoshizawa's results [6] for functional differential equation with infinite delay.

MITTAG-LEFFLER STABILITY OF SYSTEMS OF FRACTIONAL NABLA DIFFERENCE EQUATIONS

  • Eloe, Paul;Jonnalagadda, Jaganmohan
    • Bulletin of the Korean Mathematical Society
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    • v.56 no.4
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    • pp.977-992
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    • 2019
  • Mittag-Leffler stability of nonlinear fractional nabla difference systems is defined and the Lyapunov direct method is employed to provide sufficient conditions for Mittag-Leffler stability of, and in some cases the stability of, the zero solution of a system nonlinear fractional nabla difference equations. For this purpose, we obtain several properties of the exponential and one parameter Mittag-Leffler functions of fractional nabla calculus. Two examples are provided to illustrate the applicability of established results.

EXISTENCE AND STABILITY RESULTS OF GENERALIZED FRACTIONAL INTEGRODIFFERENTIAL EQUATIONS

  • Kausika, C.;Balachandran, K.;Annapoorani, N.;Kim, J.K.
    • Nonlinear Functional Analysis and Applications
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    • v.26 no.4
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    • pp.793-809
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    • 2021
  • This paper gives sufficient conditions to ensure the existence and stability of solutions for generalized nonlinear fractional integrodifferential equations of order α (1 < α < 2). The main theorem asserts the stability results in a weighted Banach space, employing the Krasnoselskii's fixed point technique and the existence of at least one mild solution satisfying the asymptotic stability condition. Two examples are provided to illustrate the theory.

Improved Bias Stress Stability of Solution Processed ITZO/IGZO Dual Active Layer Thin Film Transistor

  • Kim, Jongmin;Cho, Byoungdeog
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.215.2-215.2
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    • 2015
  • We fabricated dual active layer (DAL) thin film transistors (TFTs) with indium tin zinc oxide (ITZO) and indium gallium zinc oxide (IGZO) thin film layers using solution process. The ITZO and IGZO layer were used as the front and back channel, respectively. In order to investigate the bias stress stability of ITZO SAL (single active layer) and ITZO/IGZO DAL TFT, a gate bias stress of 10 V was applied for 1500 s under the dark condition. The SAL TFT composed of ITZO layer shows a poor positive bias stability of ${\delta}VTH$ of 13.7 V, whereas ${\delta}VTH$ of ITZO/IGZO DAL TFT was very small as 2.6 V. In order to find out the evidence of improved bias stress stability, we calculated the total trap density NT near the channel/gate insulator interface. The calculated NT of DAL and SAL TFT were $4.59{\times}10^{11}$ and $2.03{\times}10^{11}cm^{-2}$, respectively. The reason for improved bias stress stability is due to the reduction of defect sites such as pin-hole and pores in the active layer.

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Influence of Various Cyclodextrins on the Stability of Hydrocortisone 17-Butyrate in Aqueous Solution

  • Chun, In-Koo;Kim, Bo-Young
    • Archives of Pharmacal Research
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    • v.15 no.2
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    • pp.176-183
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    • 1992
  • The stabilizing effects of $\alpha$-$\beta$-$\gamma$- and dimethyl-$\beta$-cyclodextrins $(\alpha$-, $\beta$-, $\gamma$- and DM-$\beta-$-CyDs) on the degradation of hydrocortisone 17-butyrate (HC-17B) in aqueous solution was investigated. Hc-17B underwent a facile hydroxide ion-catalyzed rearrangement to the less active 21-butyrate ester by the apparent first-order kinetics, and maximum stability of HC-17B was obtained at around pH 4.0. The stability of HC-17B was increased by inclusion complexation with $\alpha$-, $\gamma$- and DM-$\beta$-CyD in the pH range of 2.0-8.0 examined, whereas $\beta$-CyD accelerated the degradation of HC-17B at the pH higher than 5.0. The effects of ionic strength, solvent, temperature and CyD concentration were also investigated. Stability constants and apparent degradation rate constants of HC-17B-$\gamma$-CyD and HC-17B-DM-$\beta$-CyD complexes were determined kinetically on the basis of 1:1 complexation. The results suggested that the inclusion complexation with $\gamma$-CyD or DM-$\beta$-CyD was most useful means to enhance the stability of the steroid.

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A Study on the Ion Exchange and th Chemical Stability of Na-fluor-tetrasilicic Mica by $H^+$ions (나트륨형불소 4 규소운모의 $H^+$ 이온교환 및 화학적인 안정성에 관한 연구)

  • 송종택
    • Journal of the Korean Ceramic Society
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    • v.22 no.1
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    • pp.35-39
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    • 1985
  • Synthetic mica $NaMg_{2.5}(Si_4O_{10})F_2 (Na-TSM)$ was treated with HCl solution and H-type exchange resin to investigate the chemical stability and the ion exchange by measuring the dissolution of chemical components and the exchanged $H^+$ ion. The replacement of $Na^+$ ion occurred in contact with HCl solution and H-type ion exchange resin at the surface of Na-TSM particles reached $Na^+$ ions at maximum value of 70~80%. $Mg^{2+}$ ion of octahedral layer became to dissolve from the pH2 solution and th amount of it dissolved in-creased almost proportional to $H^+$ ion concentration from around 0.02N $H^+$ ion equilibrium concentration. The crystalline structure of Na-TSM was destructed by dissolution of Mg2+ ion in cncentrated hydrochloric acid solution and resulted silica gel precipitation.

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FEEDBACK CONTROL FOR A TURBIDOSTAT MODEL WITH RATIO-DEPENDENT GROWTH RATE

  • Hu, Xiaoyu;Li, Zuxiong;Xiang, Xingguo
    • Journal of applied mathematics & informatics
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    • v.31 no.3_4
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    • pp.385-398
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    • 2013
  • In this paper, a turbidostat model with ratio-dependent growth rate and impulsive state feedback control is considered. We obtain sufficient conditions of the globally asymptotically stable of the system without impulsive state feedback control. We also obtain that the system with impulsive state feedback control has periodic solution of order one. Sufficient conditions for existence and stability of periodic solution of order one are given. In some cases, it is possible that the system exists periodic solution of order two. Our results show that the control measure is effective and reliable.