• Title/Summary/Keyword: Solution Recirculation

Search Result 54, Processing Time 0.026 seconds

Electro-oxidation Kinetics of Cerium(III) in Nitric Acid Using Divided Electrochemical Cell for Application in the Mediated Electrochemical Oxidation of Phenol

  • Matheswaran, Manickam;Balaji, Subramanian;Chung, Sang-Joon;Moon, Il-Shik
    • Bulletin of the Korean Chemical Society
    • /
    • 제28권8호
    • /
    • pp.1329-1334
    • /
    • 2007
  • The electrochemical oxidation of cerium(III) was carried out using divided and undivided electrochemical cells in nitric acid medium. It was found that divided cell with Nafion 324 as the separator gave good conversion yield with high current efficiency compared to the undivided cell. The efficiency of the divided electrochemical cell was further optimized in terms of cell voltage, temperature, flow rate of solution recirculation, concentrations of Ce(III) and nitric acid. The better conditions for 1 M Ce(III) in 3 M nitric acid were found to be 2.5 V, 363 K and 100 mL/min recirculation flow rate based on the current efficiency under the experimental conditions investigated. The Ce(IV) oxidant produced was used as a mediator for the mineralization of phenol. The mineralization efficiency of the cerium mediated electrochemical oxidation was found rapid and higher compared to the direct electrochemical oxidation based on CO2 evolution under the same conditions.

도로터널에서 제트팬 근처의 재순환유동과 연기 역류현상의 상호작용 분석 (Analysis of Interaction Between Recirculating Flow Near The Jet Fan and The Backlayer of Smoke in a Road Tunnel)

  • 김창균;유진웅;김성준
    • 산업기술연구
    • /
    • 제25권A호
    • /
    • pp.191-201
    • /
    • 2005
  • A numerical analysis was done for a tunnel fire in a 1000m road tunnel. A cartesian coordinate was adopted to make a computational grid sytem which has 448,000 computational cells. A transient flow phenomena in the tunnel was simulated by the commercial code of PHEONICS from the ignition of fire to 600 seconds by the interval of 100 seconds. Total computational time of about 44 hours was required to get a convered solution in each time step. The purpose of this research is to analyze of the backlayering pheonomena and recirculation flow in a tunnel. The compuational results say that the backlayering does not happens near the fire of vehicle in this case because the vehicle fire is located at the outside of recirculation zone of flow ocuured near the jet fan. In this research, onset of backlayering pheonomena could be escaped if jet fan is set 95m in front of the the fire of vehicle.

  • PDF

냉복도 밀폐시스템을 적용한 서버실의 실내온도조건 (Server Room Temperature Condition in Data Center with Cold Aisle Containment System)

  • 정용호;장현재;서장후
    • 설비공학논문집
    • /
    • 제25권2호
    • /
    • pp.79-84
    • /
    • 2013
  • In this study, a cold aisle containment system was proposed among various strategies to reduce the energy waste by recirculation air from the hot aisle. To verify the effectiveness of the cold aisle containment system, a test bed which is similar to an actually existing server room was set up in the Internet Data Center(IDC) building. Comparative experiments, conventional open type cooling system and cold aisle containment system were carried out under actual conditions. The result revealed that the range of inlet temperature of the server system was $20{\sim}25^{\circ}C$ in an existing cooling system and the range of inlet temperature dropped below $20^{\circ}C$ by the cold aisle containment system. After all, cold aisle containment system was proved to be the solution for energy saving cooling system.

대체에너지 DME를 사용하는 직접분사엔진의 배기특성에 미치는 Cooled EGR의 영향 (Effects of Cooled EGR on Exhaust Emission Characteristics of DI DME Engine)

  • 표영덕;남상훈;김강출;김영길;이영재
    • 한국수소및신에너지학회논문집
    • /
    • 제14권2호
    • /
    • pp.138-145
    • /
    • 2003
  • There are high expectations for DME(Dimethyl Ether) as a new alternative fuel for diesel engine. Compared with the conventional diesel engine, nearly zero soot emission and high thermal efficiency have been reported from DME fuelled CI engines. However, higher NOx emission is one of the disadvantages from DME Engines. In the present study, cooled EGR(Exhaust Gas Recirculation) was applied to DME engine modified from conventional Dl diesel engine, and effects of EGR were examined under various EGR temperature. Finally, it was concluded that the cooled EGR is an effective solution to reduce NOx emission from DME engine.

접선류 막분리 시스템에 의한 이눌린 수용액의 분리 동특성 (Dynamic Characteristics for the Separation of Inulin Solution in Membrane Filtrsition System of Tangential Flow)

  • 허병기;배천순이기정목영일
    • KSBB Journal
    • /
    • 제5권1호
    • /
    • pp.69-74
    • /
    • 1990
  • 이눌린, 물 및 알콜로 구성된 용액에서 물과 알콜의 투과플럭스와 막투과 압력, 이눌린 농도, 재순환속도 사이의 함수관계를 millipore사의 랩카\ulcornerV시스템을 사용하여 구명하여 보았다. 본 연구의 결과에 의하면 NMWL이 1000이고 이눌린 농도가 1wt%내지 5wt%, 막투과 압력이 $0.4kgf/\;{\textrm{cm}^2}$내지 $3.2kgf/\;{\textrm{cm}^2}$, 재순환 속도가 4ml/sec인 경우에는 투과플럭스와 막투과 압력 및 이눌린농도 사이의 함수관계가 다음식으로 표현되는 겔분모델로 잘 해석됨을 알 수 있었다. Jv=(0.0022P + 0.0003) lu \frac{3p\;+\;2.1}{C_b}$

  • PDF

Numerical analysis of NOx reduction for compact design in marine urea-SCR system

  • Choi, Cheolyong;Sung, Yonmo;Choi, Gyung Min;Kim, Duck Jool
    • International Journal of Naval Architecture and Ocean Engineering
    • /
    • 제7권6호
    • /
    • pp.1020-1033
    • /
    • 2015
  • In order to design a compact urea selective catalytic reduction system, numerical simulation was conducted by computational fluid dynamics tool. A swirl type static mixer and a mixing chamber were considered as mixing units in the system. It had great influence on flow characteristics and urea decomposition into ammonia. The mixer caused flow recirculation and high level of turbulence intensity, and the chamber increased residence time of urea-water-solution injected. Because of those effects, reaction rates of urea decomposition were enhanced in the region. When those mixing units were combined, it showed the maximum because the recirculation zone was significantly developed. $NH_3$ conversion was maximized in the zone due to widely distributed turbulence intensity and high value of uniformity index. It caused improvement of $NO_x$ reduction efficiency of the system. It was possible to reduce 55% length of the chamber and connecting pipe without decrease of $NO_x$ reduction efficiency.

The corrosion of aluminium alloy and release of intermetallic particles in nuclear reactor emergency core coolant: Implications for clogging of sump strainers

  • Huang, Junlin;Lister, Derek;Uchida, Shunsuke;Liu, Lihui
    • Nuclear Engineering and Technology
    • /
    • 제51권5호
    • /
    • pp.1345-1354
    • /
    • 2019
  • Clogging of sump strainers that filter the recirculation water in containment after a loss-of-coolant accident (LOCA) seriously impedes the continued cooling of nuclear reactor cores. In experiments examining the corrosion of aluminium alloy 6061, a common material in containment equipment, in borated solutions simulating the water chemistry of sump water after a LOCA, we found that Fe-bearing intermetallic particles, which were initially buried in the Al matrix, were progressively exposed as corrosion continued. Their cathodic nature $vis-{\grave{a}}-vis$ the Al matrix provoked continuous trenching around them until they were finally released into the test solution. Such particles released from Al alloy components in a reactor containment after a LOCA will be transported to the sump entrance with the recirculation flow and trapped by the debris bed that typically forms on the strainer surface, potentially aggravating strainer clogging. These Fe-bearing intermetallic particles, many of which had a rod or thin strip-like geometry, were identified to be mainly the cubic phase ${\alpha}_c-Al(Fe,Mn)Si$ with an average size of about $2.15{\mu}m$; 11.5 g of particles with a volume of about $3.2cm^3$ would be released with the dissolution of every 1 kg 6061 aluminium alloy.

제한된 Local Buffer를 가진 FMS의 최적구조 결정에 관한 연구 (A Study on Determining the Optimal Configuration of the FMS with Limited Local Buffers)

  • 정양근;김성식;장동식
    • 대한산업공학회지
    • /
    • 제15권1호
    • /
    • pp.105-116
    • /
    • 1989
  • This study presents an algorithm that determines the optimal configuration of the FMSs with limited local buffers. The algorithm finds the lowest cost configuration, i.e. the number of tools, the number of pallets as well as the number of buffers to be installed in front of each machine in the system. Thus it assures a given production ratio with a minimum cost. In the algorithm, FMSs are considered as the closed queueing network with limited queue length. System performance evaluation is performed using the Block-&-Recirculation model developed by Yao and Buzacott. The algorithm is composed with three steps. The steps are namely i) determination of a lower configuration, ii) derivation of an heuristic solution, and iii) obtaining the optimal solution. The computational efforts required in the algorithm usually lies within the capability of personal computers.

  • PDF

원위치 토양세척 공정의 효율향상을 위한 세제선정과 운전기법 (Selection of Surfactant and Operation Scheme for Improved Efficiency of In-situ Soil Flushing Process)

  • 손봉호;임봉수;어성욱;이병호
    • 한국물환경학회지
    • /
    • 제22권5호
    • /
    • pp.824-830
    • /
    • 2006
  • Several tests were conducted to optimize the design parameters of ln-situ soil flushing processes for diesel contaminated soil. According to the batch extraction test for three anionic surfactants evaluation, Calgonit limiting bubble occurrence was selected for its higher oil cleaning efficiency. After optimum surfactant selection, there were many sets of column flushing test. Over 70% of BTEX was removed in this surfactant dose with 400% of soil volume. In the case of no surfactant addition flushing in column, so called "blank flushing test", BTEX removal rate was 64%. But when we reused the effluent for the cleaning solution, the removal rate was decreased to 46.9%. This result showed reabsorption of oil occurred on the soil. With the addition of Calgonit solution to the diesel contaminated column, BTEX was removed up to 98.9% during the first flushing and 99.4% for the second recirculation flushing. In microcosm tests, diesel contaminated soils were cleaned by both surfactant flushing and biological activities. In anoxic condition, nitrate was used as an electron acceptor while the surfactant and the oil were used an electron donor. BTEX removal efficiency could be achieved up to 80% by biological degradation.

A Review of the Efficacy of Ultraviolet C Irradiation for Decontamination of Pathogenic and Spoilage Microorganisms in Fruit Juices

  • Ahmad Rois Mansur;Hyun Sung Lee;Chang Joo Lee
    • Journal of Microbiology and Biotechnology
    • /
    • 제33권4호
    • /
    • pp.419-429
    • /
    • 2023
  • Ultraviolet C (UV-C, 200-280 nm) light has germicidal properties that inactivate a wide range of pathogenic and spoilage microorganisms. UV-C has been extensively studied as an alternative to thermal decontamination of fruit juices. Recent studies suggest that the efficacy of UV-C irradiation in reducing microorganisms in fruit juices is greatly dependent on the characteristics of the target microorganisms, juice matrices, and parameters of the UV-C treatment procedure, such as equipment and processing. Based on evidence from recent studies, this review describes how the characteristics of target microorganisms (e.g., type of microorganism/strain, acid adaptation, physiological states, single/composite inoculum, spore, etc.) and fruit juice matrices (e.g., UV absorbance, UV transmittance, turbidity, soluble solid content, pH, color, etc.) affect the efficacy of UV-C. We also discuss the influences on UV-C treatment efficacy of parameters, including UV-C light source, reactor conditions (e.g., continuous/batch, size, thickness, volume, diameter, outer case, configuration/arrangement), pumping/flow system conditions (e.g., sample flow rate and pattern, sample residence time, number of cycles), homogenization conditions (e.g., continuous flow/recirculation, stirring, mixing), and cleaning capability of the reactor. The collective facts indicate the immense potential of UV-C irradiation in the fruit juice industry. Existing drawbacks need to be addressed in future studies before the technique is applicable at the industrial scale.