• Title/Summary/Keyword: Solute

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Dynamics of Carbon Sequestered in Concentric Layers of Soil Macroaggregates

  • Park, Eun-Jin;Smucker, Alvin J.M.
    • The Korean Journal of Ecology
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    • v.28 no.4
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    • pp.181-188
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    • 2005
  • Methods used to study carbon sequestration by soil aggregates have often excluded the concentric spatial variability and other dynamic processes that contribute to resource accessibility and solute transport within aggregates. We investigated the spatial gradients of carbon (C) and nitrogen (N) from the exterior to interior layers within macroaggregates, $6.3\sim9.5$ mm, sampled from conventional tillage (CT) and no tillage (NT) sites of a Hoytville silt clay loam. Spatial gradients in C accumulation within macroaggregates were related to the differences in C dynamics by determining the sizes and the turnover rates of fast C and slow C pools in the concentric layers of aggregates. Aggregate exteriors contained more labile C and were characterized by greater C mineralization rates than their interiors in both management systems. In contrast, C in the interior layers of aggregates was more resistant in both systems. These results indicated the spatial differentiation of C dynamics within macroaggregates, i.e., exterior layers as a reactive site and interior layers as a protective site. Greater total C distribution in the exterior layers of NT aggregates indicated more influx of C from the macropores in interaggregate space than C. mineralization (net gain of C), whereas lower C distribution within the exterior layers of CT aggregates indicated net loss of C by greater C mineralization than C influx. We found total C increased approximately 1.6-fold by the conversion of CT soils to NT management systems for a period of 36 years. Differences in total accumulation and the spatial distribution of C within aggregates affected by management were attributed to the differences in aggregate stability and pore networks controlling the spatial heterogeneities of resource availability and microbial activity within aggregates.

What Do We Learn from Two-Dimensional Raman Spectra by Varying the Polarization Conditions?

  • Ma, Ao;Stratt, Richard M.
    • Bulletin of the Korean Chemical Society
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    • v.24 no.8
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    • pp.1126-1134
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    • 2003
  • The signals obtained from the $5^{th}$-order (two-dimensional) Raman spectrum of a liquid can depend dramatically on the polarizations of the various light beams, but to date there has been no evidence presented that different polarization conditions probe any fundamentally different aspects of liquid dynamics. In order to explore the molecular significance of polarization we have carried out a molecular dynamics simulation of the $5^{th}$-order spectrum of a dilute solution of CS₂ in liquid Xe, perhaps the simplest system capable of displaying a full range of polarization dependencies. By focusing on the 5 distinct rotational invariants revealed by the different polarizations and by comparing our results with those from liquid Xe, a liquid whose spectrum has no significant polarization dependence, we discovered that the polarization experiments do, in fact, yield valuable microscopic information. With different linear combinations of the experimental response functions one can separate the part of the signal derived from the purely interaction-induced part of the many-body polarizability from the portion with the largest contributions from single-molecule polarizabilities. This division does not directly address the underlying liquid dynamics, but it significantly simplifies the interpretation of the theoretical calculations which do address this issue. We find that the different linear combinations differ as well in whether they exhibit nodal lines. Despite the absence of nodes with the atomic liquid Xe, observing the resilience of our solution's nodes when we artificially remove the anisotropy of our solute leads us to conclude that there is no direct connection between nodes and specifically molecular degrees of freedom.

A Study on Middle School Students' Understanding of Dissolution (중학생들의 용해 현상 이해에 대한 연구)

  • Kang, Dae Hun;Paik, Seoung Hey;Park, Kuk Tae
    • Journal of the Korean Chemical Society
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    • v.45 no.1
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    • pp.83-89
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    • 2001
  • This study was to examine middle school students' understanding of dissolution. More than 75% students understood that dissolution was caused by small particles' filling the space between large particles due to the difference of size among particles. Some other students responded that solute disappeared or was absorbed in a solvent as the result of dissolution. Besides, they didn't know that space between particles was the reason of the volume's decreasing after the process of dissolution. Instead, they explained that space between particles caused dissolution. And they hardly understood the fact that solutes affect solubility. Students'misunderstanding about the concept of dissolution resulted from the lack of the explanation on the right concept of dissolution in science textbooks and the inappropriate use of the dissolution model by teachers. In conclusion, we need the appropriate explanation in middle school science textbooks that consider the students'level and the development of the appropriate model that demonstrates dissolution in the perspective of particles.

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Determination of Loxoprofen Adsorption Isotherms by Frontal Analysis and Pulse Input Method (Frontal Analysis와 Pulse Input Method를 이용한 Loxoprofen의 등온흡착식 결정)

  • Lee, Eun;Park, Joon-Sub;Kim, In-Ho
    • KSBB Journal
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    • v.21 no.5
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    • pp.371-375
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    • 2006
  • Frontal analysis(FA) and Pulsed input method(PIM) have been frequently utilized to measure isotherm of single solute, as well as non-competitive isotherms of two solutes in chromatography(1). FA and PIM were used in this study as complementary methods to measure adsorption isotherms of loxoprofen racemate in HPLC. Prior to FA and PIM experiments, measurements of loxoprofen solubility were made at hexane/ethanol=50/50, 80/20, 95/5(v/v) with acetic acid(0.5%) for adjusting pH. The last composition(95/5) of hexane/ethanol allows us to separate loxoprofen racemate into two forms(retentate, extract). PIM and FA were used to determine the isotherms of re-and ex-loxoprofen.

A Dye Tracer Study of Infiltration Pattern in a Residual Soil Developed from Granite (화강암 기원 잔적토양에서 염료추적자의 침투 유형에 관한 연구)

  • 전철민;김재곤;이진수;김탁현
    • Economic and Environmental Geology
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    • v.37 no.4
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    • pp.383-389
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    • 2004
  • Understanding flow pattern of water and solute in subsurface is essential for the reduction and prevention of contamination of soil and groundwater and for the investigation and remediation of contaminated site. The objective of this study is to examine the infiltration pattern in a soil developed from the Jurassic granite using (Brilliant Blue FCF $C_{37}H_{34}N_{2}Na_{2}O_{9}S_{3}$), the nonfluorescent and nontoxic food dye. All image processing was conducted using geographic image processing software, ER Mapper, Version 6.2. The dye coverage was determined by counting the stained pixels in the photographs (80${\times}$80cm, 80TEX>${\times}$5cm) for the vertical and horizontal view. A homogeneous matrix flow occurred in the A horizon with weak, medium granular structure and fingering at the interface of finer-textured A horizon and coarser-textured C horizon. Pegmatitic vein originated from the granite and plant root in C horizon induced preferential flow.

Prediction of Water Activity for Gelatinized Model Foods (모형식품의 수분활성도 예측)

  • Jung, Seung-Hyeon;Chang, Kyu-Seob;Park, Young-Deok
    • Korean Journal of Food Science and Technology
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    • v.25 no.2
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    • pp.94-97
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    • 1993
  • This study was to predict water activity of gelatinized model foods containing moisture, protein and starch with different concentration of humectants such as sodium chlorife and sucrose. The water activity of each samples were determinded by electrical hygrometry. The degree of lowering water activity in model foods with humectant solutions was following order as NaCl>sucrose. Model food $P_2S_1$ was predominant in depression of water activity by humectants than other model foods. The multiple regression equations between water activity and different humectants concentration, compositions and solution ratio of model foods were obtained and $R^2$ values were higher than 0.91.

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Effects of Hwangryunhaedok-tang plus Yukmijihwang-tang add Chogudeung on Blood Pressure and Renal Function in Spontaneously Hypertensive Rats (황연해독탕 합 육미지황탕 가 조구등이 자발적 고혈압 백서의 혈압 및 현장 기능에 미치는 영향)

  • Sohn Eun Jin;Kang Dae Gill;Lee An Sook;Kim Bok Hae;Lee Ho Sub
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.16 no.2
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    • pp.359-364
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    • 2002
  • The present study examined the effects of water extract of Hwangruynhaedoktang plus Yukmijihwangtang add Chogudeung (HYC) on the blood pressure and renal function in spontaneously hypertensive rats (SHR). The HYC water extract blocked increase of systolic blood pressure (SBP) in SHR. The urinary volume (UV), sodium (UNaV), potassium (UkV), and chloride (UclV) excretions were significantly increased in SHR administered with high dose of water extract of HYC, but urinary osmolality was not changed. The creatinine clearance (Ccr), which is index of glomerular filtration rate (GFR), was increased by administration of HYC, while solute-free water reabsorption (TcH2O) was not changed. Taken together, these results suggest that the depressor effects of HYC, at least in part, caused by diuretic effect due to increase of glomerular filtration rate.

Effect of Acanthopanacis cortex Water Extract on Renal Function in Ischemia/Reperfusion-lnduced Acute Renal Failure Rats (오가피(五加皮) 물추출물이 허혈-재관류로 유발된 급성 신부전에 미치는 영향)

  • Lee, An-Sook;Kang, Dae-Gil;Kim, Eun-Ju;Yang, Sun-Nye;Uhm, Jae-Yeon;An, Jun-Seok;Lee, Ho-Sub
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.21 no.5
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    • pp.1201-1209
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    • 2007
  • The present study was designed to examine whether water extract of Acanthopanacis cortex(AC) has an effect on renal functional parameters in association with the expression of aquaporin 2 (AQP-2) and heme oxygenase-1 (HO-1) in the ischemia/reperfusion induced acute renal failure (ARF) rats. Polyuria caused by down-regulation of renal AQP 2 in the ischemia-induced ARF rats was markedly restored by administration of AC (200 mg/kg, p.o.) with restoring expression of AQP 2 in the kidney. Administration of AC lowered the renal expression of HO-1, which was upregulated in rats with ischemia/reperfusion-induced ARF. The renal functional parameters including creatinine clearance, urinary sodium excretion, urinary osmolality, and solute-free reabsorption were also markedly restored in ischemia-ARF rats by administration of AC. Histological study also showed that renal damages in the ARF rats were abrogated by administration of AC. Taken together, the present data indicate that AC ameliorates renal defects in rats with ischemia/reperfusion-induced ARF.

Effect of Al Addition on the Precipitation Behavior of a Binary Mg-Zn Alloy

  • Kim, Ye-Lim;Tezuka, Hiroyasu;Kobayashi, Equo;Sato, Tatsuo
    • Korean Journal of Materials Research
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    • v.22 no.3
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    • pp.111-117
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    • 2012
  • The effect of Al addition on the precipitation behavior of a binary Mg-Zn alloy was investigated based on the changes in the morphology, distribution and element concentration of precipitates formed during aging treatment. The as-cast Mg-6.0 mass%Zn (Mg-6Zn) and Mg-6.0 mass%Zn-3.0 mass%Al (Al-added) were homogenized at 613 K for 48 h and at 673 K for 12 h; they were then solid solution treated at 673 K for 0.5 h and 1 h, respectively. The Mg-6Zn and Al-added alloys were aged at 403 K and 433 K. The peak hardness of the Al-added alloy was higher than that of the Mg-6Zn alloy at each aging temperature. Rod-like, plate-like, blocky, and lath-like precipitates were observed in the Al-added alloy aged at 433 K for 230.4 ks, although the rod-like and plate-like precipitates were observed in the TEM microstructure of the Mg-6Zn alloy aged at 433 K for 360 ks. Moreover, the precipitates in the Al-added alloy were refined and densely distributed compared with those in the Mg-6Zn alloy. The Cliff-Lorimer plots obtained by the EDS analysis of the rod-like ${\beta}_1^'$ and plate-like ${\beta}_2^'$ phases in the Al-added alloy peak aged at 433 K for 230.4 ks were examined. It was confirmed that the ${\beta}_2^'$ phases had higher concentration of solute Al atom than was present in the ${\beta}_1^'$ phases, indicating that the properties of precipitates can be changed by Al addition.

Growth and solute pattern of Suaeda maritima and Suaeda asparagoides in an abandoned salt field

  • Choi, Sung-Chul;Lim, Sung-Hwan;Kim, Sang-Hun;Choi, Deok-Gyun;Kim, Jong-Guk;Choo, Yeon-Sik
    • Journal of Ecology and Environment
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    • v.35 no.4
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    • pp.351-358
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    • 2012
  • To investigate the environmental adaptation and ecophysiological characteristics of Suaeda maritima and S. asparagoides under saline conditions, plant growth and density were analyzed according to environmental changes of habitats. The total ion content of soil decreased with time, which was caused by the predominance of exchangeable $Na^+$ and $Cl^-$ in the upper layers. The population of S. maritima was more densely distributed in the region with higher ion contents of $Cl^-$, $Mg^{2+}$, $K^+$ and $Na^+$ than the population of S. asparagoides. Both species were showed a decreased population density according to increases in plant growth. Under the conditions of a salt field, S. maritima and S. asparagoides contained high inorganic ions to maintain low water potential, but low water soluble carbohydrate contents. In the case of free amino acid, S. maritima showed an especially high proline content, and contained rather large amounts of free amino acids, whereas S. asparagoides did not. Both species showed high inorganic ion contents in the leaves, which might be a mechanism of avoiding the ionic toxicity by diluting the accumulated ionic concentration with a high ratio of water content to dry weight. This result suggests that S. maritima seems to adapt to saline conditions by accumulating proline in addition to inorganic ions. S. asparagoides seems to adapt by osmoregulation processes, using inorganic ions rather than free amino acids.