• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.04a
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• pp.233-236
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• 2002

다양한 산업활동에 의하여 발생하는 6가 크롬 (Cr(Ⅵ))은 대표적인 토양 및 지하수 오염물질이다. Cr(Ⅵ)은 3가크롬(Cr(III))로의 환원에 의한 침전반응으로 이동성이 저하된다고 알려져 있다. 본 연구에서는 기존의 고형화/안정화 공정에 환원.분해 반응을 추가한 2가철 기반 분해성 고형화/안정화(Degradative Solidification/Stabilization)공정에 의한 Cr(Ⅵ) 처리 특성을 고찰하였다. 회분식 실험결과 cemen/Fe(II) system내에 Cr(Ⅵ)은 환원반응 뿐만 아니라 cement에 의한 침전에 의해서도 제거됨이 밝혀졌다. Cr(Ⅵ)의 제거속도는 Fe(II)의 반응당량에 비례하는 것으로 보여진 반면, cement/solution ratio에 따른 Cr(Ⅵ) 제거동역학의 차이는 그다지 크지 않았다

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.218-222
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• 2004

Batch slurry experiments were conducted to develop cement/slag/Fe(II) system that could treat hazardous liquid wastes containing halogenated organic solvents. Portland cement in combination with Fe(II) was reported to reductively dechlorinate chlorinated organics in a modified solidification/stabilization process. TCE (trichloroethylene) was used a model halogenated organic solvent. The objectives of this study were to assess the feasibility of using cement and steel converter slag amended with Fe(II) as a low cost abiotic reductive dechlorination and to investigate the kinetics of TCE dechlorination over a wide range of TCE concentration. From the result of screening experiments, cement/slag/Fe(II) system was identified as a potentially effective system to treat halogenated organic solvent. Kinetic studies were carried out to further investigate degradation reaction of TCE NAPL (Non Aqueous Phase Liquids) in cement/slag/Fe(II) systems by using batch slurry reactors. Degradation rate of TCE solution in this system can be explained by pseudo-first-order rate law because the prediction with the rate law is in good agreement with the observed data.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 2002.10a
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• pp.345-348
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• 2002

The dredged soils of rural streams can be treated with cement for recycling. It is very important to know whether the treated soils have achieved some required qualities for further treatments if the soils are mixed with cement. In this study, fall-cone test was used to examine changes in workability and compactibility during an curing time of soil-cement mixture. Test results showed that fall-cone apparatus can be satisfactorily used for this purpose. Although there was some difference of initial curing time and cement contents, the engineering properties of treated soils were little affected.

• Proceedings of the Korea Concrete Institute Conference
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• 2009.05a
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• pp.321-322
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• 2009

when the polluted soil with heavy metal ions was solidified using magnesia-phosphate cement, heavy metal ions were rarely eluted. Furthermore, the results cf SEM-EDS analysis showed that heavy metal ions in polluted soil turns into insoluble solid solution by magnesia-phosphate cement, it come to have the effect to stabilize heavy metals.

• Economic and Environmental Geology
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• v.37 no.1
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• pp.99-106
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• 2004

Pollution reduction and/or control technology becomes one of the pressing post-semiconductor research field to lead an advanced industrial structure. Soil/groundwater remediation techniques may act as a core technology which will create many demands on pollution reduction areas. A plenty numbers of abandoned metal mines were left without any remediation action in Korea, and it may be potential sources of heavy metal and As contamination in the ecosystem. In order to bring this soil contamination to a settlement, the emerging soil/groundwater remediation techniques should be introduced. Main research topics in the United States and Europe move towards the clean remediation technology without any secondary impact and the feasible application of developing technique into the field scale study. With these advantages, several soil/groundwater techniques such as electrokinetic soil processing, permeable reactive barrier, stabilization/solidification, biosorption, soil flushing with biosurfactant, bioleaching and phytoremediation will be summarized in this paper.

• Journal of the Korea institute for structural maintenance and inspection
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• v.8 no.4
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• pp.87-96
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• 2004

As a special concrete, which is a mixture of soil, cement and water, has strength like regular concrete for pavement, soil cement has been used in various field such as pavement and soft soil improvement. The objective of this study was to investigate the characteristic of unconfined compressive strength and time dependent behavior of soil cement that is made from decomposed granite soil or coluvial and inorganic solidification liquid. The results showed that the unconfined compressive strength appears to increase as the amount of cement and curing time increase In addition, the strength seems to decrease with increase of the potion of fine particles(No 200 sieve). The result of XRD indicated that there is Vermiculite, the product of reaction, in the soil cement. The dynamic properties of material, such as shear complex compliance, shear complex modulus, and phase angle could be calculated from the hysteresis loop obtained from the Haversine Creep Tests. Finally, creep behavior was able to be predicted from these dynamic properties.

• Journal of the Korean GEO-environmental Society
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• v.13 no.2
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• pp.59-65
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• 2012

Solidification/Stabilization(S/S) is one of the remediation technologies that have been applied for treating inorganic hazardous wastes. This study investigated the reduction of arsenic concentration of arsenic-contaminated soil using by S/S. The binder plays a role in controlling the mobility and solubility of the contaminants in S/S process, so it is important to determine the optimum binder content. Therefore, this study evaluated the effectiveness of S/S using four different binders(cement, zero valent iron, and monosulfate and ettringite(cement-based synthesized materials) at the binder content ranged between 5%(wt.) and 20%(wt.). The leachability of arsenic in 1 N HCl was different depending on the types of binders: cement(71.41%) > monosulfate(47.45%) > ettringite(46.36%) > ZVI(33.08%) at the binder content of 20%. Additionally, three kinds of a mixture binder were prepared using cement and additives(monosulfate, ettringite, calcium sulfoaluminate(CSA)) and tested for arsenic reduction. The highest arsenic removal capacity was found at the mass ratio of cement to the additive, 4:1 in all experiments using a mixture binder, regardless of the additives types. A mixture binder(cement and additives) resulted in higher arsenic removal relative to the arsenic removal when cement was used alone.

• Journal of the Korea Organic Resources Recycling Association
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• v.28 no.2
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• pp.15-29
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• 2020

The aims of this study is to improve physical properties of the sewage sludge and the process sludge generated in the leachate treatment by mixing the dry fuel, to develop the neutral solidifing agents that reduce oder, and to recycle the sewage and the process sludges as landfill cover materials. The mixing ratio (W/W) of sludges and dry fuel was appropriate at about 1:1, and the mixed materials were shown to be homogeneous at that ratio. We could know that when the sludges were mixed with dry fuel, moisture contents and viscosities are reduced, and air passages are formed between particles and particles. The various mixing tests and odor tests showed that the neutral solidifing agent was effective for the odor reduction. The main ingredient of the solidifing agent is the ash of sewage sludge, enabling it competitive in waste recycling and production costs. The landfill cover, using developed neutral solidification agent, improved physical properties to satisfy the quality standards and to increase the compressive strength. It also proved to reduce the value of complex oder and the usage of solidification agent to 1/3 (3,000 to 1,000) and to 1/8 (50% to 6%), respectively, from the comparative study with alkaline solidified landfill cover. Further research is under way to prove that this can be mixed with general soil to be used as a soil improvement agent for plant cultivation.

• Journal of Environmental Impact Assessment
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• v.21 no.1
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• pp.63-69
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• 2012

Sediment has been increasingly acknowledged as a carrier in water system and an available contamination. For this reason, dredging of sediment in reservoir to remediate water quality and secure storage capacity is conducted annually. However, disposal of numerous dredged sediment is necessary as a secondary problem. Currently, in Korea, dredged sediment is classified as waste to be reclamated or recycled into sandy soil, however, they are still in trouble because of spacial and environmental problem. Therefore, rather than simple disposal or reuse into sandy soil, it is necessary to research on method to manage main cause of pollution and increase the value as a resource. In this study, we intend to develop a recycle technology for numerous dredged sediment produced by dredging in deteriorated reservoirs using solidificator (stabilizer). To achieve this, we will consider utilization of dredged sediment and evaluation of use possibility as natural recycle by analysis the characteristics of soil-solidificator mixture in terms of physicochemical properties and the mixing ratio between sediment and solidificator.

• Proceedings of the Korean Geotechical Society Conference
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• 2004.03b
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• pp.714-721
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• 2004

The purpose of this study is to find out the similitude laws for dissipation velocity of excess pore pressure after liquefaction according to magnitude of input accelerations and height of model soils from the results of impulse load tests. In impulse load tests, model soils were constructed to the height of 25cm, 50cm, and 100cm in acrylic tubes whose inside diameters were 19cm and 38cm respectively, and impulse loads were applied at the bottom of each model soil to liquefy the entire model soil. Excess pore pressure distribution by depth and settlement of soil surface were measured in each test. Dissipation curves of excess pore pressure measured in each tests were simulated by solidification theory, and dissipation velocities of excess pore pressure were determined from the slope of simulated dissipation curves. From the results of impulse load tests, dissipation velocity of excess pore pressure was not affected by magnitude of input acceleration, and from this fact, dissipation process was proved to be different from dynamic phenomenon. However, dissipation velocity of excess pore pressure increased as height of model soil increased and showed little difference as diameter of model soil increased. Therefore, the similitude law for dissipation velocity could be expressed by the similitude law for model height to 0.2 without regard to the diameter of model soil.