• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.4
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• pp.435-442
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• 2022

In this study, the density of KS L 5110 was compared with that of gas pycnometer and electronic densimeter for efficient density management of cement, blast furnace slag powder and fly ash. Correlation and usability according to the test method were reviewed, and based on the results of the experiment, the availability of alternative test methods was analyzed. As a result of the density test according to test methods, the density of cement, blast furnace slag powder and fly ash tended to decrease in the order of gas pycnometer, KS L 5110 and electronic densimeter. Because the volume range of the sample to be evaluated is different depending on test methods. The coefficient of determination R² was in the range of 0.71 to 0.93, and the correlation according to test methods showed a relatively good correlation. If correction is applied through correlation, it is analyzed that alternative test methods can be used. As a result of the usability review considering the test procedure, measurement time and coefficient of variation, the gas pycnometer had the simplest test procedure and good reliability. In addition, it is expected that the reproducibility between the testers is relatively high because the skill is not greatly required.

• Journal of the Korean Institute of Intelligent Systems
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• v.23 no.4
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• pp.292-297
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• 2013

In this paper, unusual waveform detection algorithm based on Refractory Period in arrhythmia ECG signal is proposed. Most of arrhythmia ECG signals consist of unusual waveforms with average 10% rate. Thus tremendous benefit can be obtained in terms of time and cost by providing unusual waveform samples reduced more than 90% to medical staffs who have to monitor and analyze for a long time. The proposed algorithm detects the R-peak using the features of R wave and variable refractory period. For the detected R-peak, unusual waveforms are found using means and standard deviation of electric potential and kurtosis of the R-peaks which are not included in unusual waveform. The proposed algorithm was applied to all records of the MIT-BIH arrhythmia database and showed more than average 90% of compression ratio.

• Analytical Science and Technology
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• v.11 no.6
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• pp.469-473
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• 1998

The gasoline brands can be determined by gas chromatography. However, determining from the differences in chromatograms is sometimes ambiguous because the gasoline composition is becoming similar from refinery to refinery due to stringent regulations for the protection of the atmospheric environment. To determine the gasoline brands of five refineries in Korea, we have obtained and compared IR spectra of polymeric dispersants which are added to gasoline at several hundreds of ppm levels. Since the deposit control additives used by the five refineries in Korea are different from one another, it is possible to determine the gasoline brands by comparing their IR spectra. A strong and broad C-O stretch absorption peak appears at $1,096cm^{-1}$ for the additives used by A, B, and C refineries, which renders an easy differentiation of the additives from those of D and E refineries. The differentiation of all five gasoline brands are possible due to the characteristic vibrations present in each additive.

• The Journal of the Acoustical Society of Korea
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• v.42 no.4
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• pp.298-303
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• 2023

This study aimed to investigate the clinical utility of voiced sentence tasks for voice evaluation. To this end, we analyzed the correlation between perturbation-based acoustic measurements [jitter percent (jitter), shimmer percent (shimmer), Noise to Harmonic Ratio (NHR)] using sustained vowel phonation, and cepstrum-based acoustic measurements [Cepstral Peak Prominence (CPP), Low/High spectral ratio (L/H ratio)] using voiced sentences. As a result of analyzing data collected from 65 patients with voice disorders, there was a significant correlation between the CPP and jitter (r = -.624, p = .000), shimmer (r = -.530, p = .000), NHR (r = -.469, p = .000).This suggests that the cepstrum measurement of voiced sentences can be used as an alternative to the analysis limitations of the pathological voice such as not possible perturbation-based acoustic measurement, and result difference according to the analysis section.

• Applied Chemistry for Engineering
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• v.24 no.5
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• pp.476-482
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• 2013

In this work, the effects of electrochemical oxidation of carbon fiber surfaces on mechanical interfacial properties of carbon fibers-reinforced polarized-polypropylene matrix composites were studied with various current densities during the treatments. Surface properties of the fibers before and after treatments were observed by SEM, AFM, XPS, and contact angle measurements. Mechanical interfacial properties of the composites were measured in terms of critical stress intensity factor ($K_{IC}$). From the results it was found that $O_{1s}$ peaks of the fiber surfaces were strengthened after electrochemical oxidation which led to the enhancement of surface free energy of the fiber, resulting in good mechanical performance of the composites. It can be concluded that electrochemical oxidation of the carbon fiber surfaces can control the interfacial adhesion between the carbon fibers and polarized-polypropylene in this composites system.

• Journal of Food Hygiene and Safety
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• v.35 no.3
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• pp.225-233
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• 2020

By the standards and specifications for hygiene products, three test methods for formaldehyde are specified for each item type of hygiene product. After derivatization using acetylacetone and 2,4-dinitrophenylhydrazine (2,4-DNPH), formaldehyde is analyzed by spectrophotometer and high-performance liquid chromatography (HPLC). Validation of the three test methods was performed on tissue, diaper lining and waterproof layer, and panty liner products. The results of linearity (R²), limit of detection (LOD), limit of quantification (LOQ), recovery rate (%) and reproducibility (%), showed that all three methods are suitable for analyzing formaldehyde in hygiene products. After derivatization with 2,4-DNPH and cetylacetone, formaldehyde was analyzed at 0, 3, 6, 9, 24 and 48 hours by HPLC. Formaldehyde derivatized with 2,4-DNPH showed no statistically significant change in formaldehyde peak area over time (P>0.05). But, acetylacetone-derivatizated formaldehyde showed a negative correlation coefficient (r) over time (P<0.01). We investigated the residual amounts of formaldehyde in 205 hygiene products distributed in Busan. Among 74 disposable diaper products tested, 73 had low concentrations of formaldehyde (0.13-29.87 mg/kg). Moreover, formaldehyde was not detected in any of 78 tissue, 27 disposable paper towel, 12 disposable dishcloth, 7 paper cup, one brand of paper straw and 6 disposable napkin products.

• Polymer(Korea)
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• v.29 no.1
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• pp.87-90
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• 2005

In this study, we have examined the exfoliation behavior of layered clay during in-situ polymeriztion with styrene by using real-time XRD analysis. The 4C1 beam line at the Pohang Accelerator Laboratory (PAL) was used for this study. Different exfoliation behaviors have been shown to depend on the cation exchange capacity (CEC) of clay and the chemical structure of organic modifiers. For 10A-MMT and 15A-MMT having high CEC, no peak shifts were observed on real-time XRD analysis during polymerization. However, 2$\theta$ for 25A-MMT and VDAC-MMT, each having low CEC’s as well as aromatic benzene moieties and vinyl groups, respectively, decreased as polymerization time increased.

• Journal of the Korean Chemical Society
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• v.46 no.1
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• pp.19-25
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• 2002

We measured the variations of potentials and current densities for several polymers. The results were carefully examined to identify various factors such as temperature and pH to influence the potential and rate. The Tafel slope for anodic dissolution was determined by the polarization effect under these conditions. The optimum conditions were established for each case. The second anodic current density peak and maximum current density were designated as the relative polarization sensitivity $(I_r/I_f)$. The mass-transfer coefficient value $({\alpha})$ was determined by the Tafel slope for anodic dissolution on the basis of the polarization effect under optimum conditions.

• Applied Chemistry for Engineering
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• v.19 no.3
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• pp.322-325
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• 2008

3,3-Dimethyl-1-butene ($C_6H_{12}$) monomer was deposited using a plasma-enhanced chemical vapor deposition (PECVD) instrument. The more the R.F. power/pressure ratio in FT-IR spectrum, the less the hydrogen quantity and the dangling bond in amorphous carbon films observed so that the mechanical property of the films are improved related to the density. Also, with the increase D peak in Raman spectrum is increased and the ring structure's films are produced. According to these results, hardness and modulus are 12 GPa and 85 GPa, respectively. The refractive index (n) and extinction coefficients (k) of the deposited films are increased with the increase in a power/pressure ratio.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.32 no.6
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• pp.239-245
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• 2022

Reduced graphene oxide (rGO) has attracted many attention and applications due to its excellent electrochemical ability. Therefore, standardization of rGO through structural and thermal analysis facilitates quality improvement and management, enabling users to increase efficiency and reduce relevant costs. For rGO and graphene-related materials, it is very important to determine the number of layers and define the resulting difference in physical properties. In this study, 3~4 layers of rGO-1 and 9~10 layers of rGO-2 were obtained from graphene oxide (GO) through a hydrazine reduction process. For the prepared rGOs, X-ray diffraction (XRD) pattern obtained a diffraction peak at 2θ≈25° related to (002) reflection was used to calculate the layer numbers by determining interlayer distance and FWHM value. To reduce the angular uncertainty, XRD data analysis was performed with angle correction using standard reference materials for X-ray powder diffraction analysis. Precise interlayer distance and number of layers were determined using OriginLab and open-source XRD diffraction analysis programs using the angle-corrected diffraction data. TG-DSC thermal analysis was performed to further standardize the physical properties of rGO samples.