• 한국표면공학회지
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• 제26권2호
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• pp.87-107
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• 1993

The grain size of the final products of WC-Co and WC-Ni composite powders is dependent on the size of the starting material and the conditions employed for the reduction and carburization. APT-Co and -Ni com-plex salts were prepared by the substitution reaction between ammonium ions in APT and the metal ions in Co(NO3)2 and Ni(NO3)2 solutions of different concentrations(0.1 to 0.7M) at $50^{\circ}C$ and the grain sizes of the com-plex salts was $0.54~0.76\mu\textrm{m}$. The complex which calcined the complex salts at $700^{\circ}$~80$0^{\circ}C$ for 60min. were 0.2~0.5$\mu\textrm{m}$. W-Co($5.92^{\circ}C$) and -Ni(6.95%) powders which reduced the complex oxides with H2d atmo-sphere(flow rate;600cc/min.) at $700^{\circ}$~$800^{\circ}C$ for 60min. were $0.5~0.6\mu\textrm{m}$. The mean grain sizes of WC-Co and WC-Ni composite powders which carburized both complex metals of W-Co and W-Ni at $800^{\circ}C$ for 60min. were $0.5~0.6\mu\textrm{m}$, and take place the coarsening of the grain above $800^{\circ}C$ and the optmium ratio of C3H8 and H2 was 0.2 for the control of the free carbon. The effect of Co contents on the particle sizes decreased from 0.4 to $0.25\mu\textrm{m}$ with increasing the content from 2.0 to 7.6w%. The activation energies on the reductions of oxides and the formations of carbides were as follows ; W-Co : Q = 8.7 kcal/mole, W-Ni : Q = 8.1 kcal/mole, WC-Co pow-der : Q = 17.8 kcal/mole, WC-Ni powder : Q = 16.6 kcal/mole.

• 한국전기전자재료학회논문지
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• 제27권2호
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• pp.85-90
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• 2014

Ag paste has been used in the front electrode of the Si-solar cell. It is composed by Ag powder, glass frit, binder, solvent and dispersant. The role of the binder and the solvent is to make a flow and a printing property. However, it was not enough to report the printing properties with the variation of binder in the controled viscosity. In this study, we selected 3 kinds of typical binder which were used as binder for the paste in the industry, such as Ethyl cellulose, Hydroxypropyl cellulose and Acrylic. Ag pastes using these were prepared, controled viscosity and printed on the SiNx coated Si wafer. In the 'A paste' used Acrylic binder, printed hight was highest and 'H paste' used Hydroxypropyl cellulose binder was lowest. Because 'H paste' was high viscosity due to the molecular weight, the solvent was added in the paste to control the viscosity. Therefore, the content of solid was lower in 'H paste'. The relative pattern width which is related to the spreading of paste was the best in the case of 'H paste' and 'EH paste' at $30^{\circ}C$. It is thought that the optimization of the relative pattern width is possible for a paste by the controling shear thinning phenomenon. In the case of 'A paste', though printing hight was best, the pattern width was dependant on the temperature.

• Korean Chemical Engineering Research
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• 제46권4호
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• pp.701-706
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• 2008

이송식 아크 열플라즈마를 이용하여 벌크상태의 니켈을 증발시킨 후 급속한 냉각과정을 거쳐 니켈 나노입자를 합성하였다. 플라즈마에 의해 질소가 용이하게 해리되어 용융된 니켈속으로 용해되고 과포화된 질소원자는 질소 분자로 가스화반응을 하여 반응열을 발산하는데 그 반응열에 의해 다량의 니켈증기가 생성된다. 생성된 니켈증기는 희석가스와 냉각가스를 이용하여 나노 입자 크기의 니켈분말로 제조된다. 희석가스 유량이 증가할수록 입자크기는 감소하였으며 그 분포경향이 작은 크기에서 좁게 나타났다. 평균입자크기는 희석가스 유량이 250 l/min에서 202 nm로 분석되었으며 모든 입자는 250 nm 이하 크기에서 존재함을 확인하였다.

• 한국전기전자재료학회논문지
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• 제29권3호
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• pp.168-174
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• 2016

A conductive oxide-based sapphire glass indium tin oxide/metal electrode and the optical coating, through patterning process was studied in excellent optical properties and integrated touch panel has a high strength. Indium tin oxide conductive oxides of the sapphire glass to 0.3 A at DC magnetron sputtering method of 10 min, gas flow Ar 10 Sccm Ar, $O_2$ 1.0 Sccm the formation conditions of the thin film after annealing at $550^{\circ}C$ for 30min was achieved through a 86% transmittance. In addition, the coating 130 nm hollow silica sol-gel was to improve the optical transmittance of the indium tin oxide to 91%. For the measurement by the modeling hollow silica sol by Macleod simulation and calculated the average values of silica part to the presence or absence in analogy to actual. Refractive index value and the actual value of the material on the simulation the transmittance difference is it does not completely match the air region similar to the actual value (transmission) could be confirmed that the measurement is set to a value of between 5 nm and 10 nm.

• 한국세라믹학회지
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• 제45권4호
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• pp.232-237
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• 2008

As the single chamber SOFC(SC-SOFC) showed higher prospect on reducing the operation temperature as well as offering higher design flexibility of SOFCs, lots of concerns have been given to investigate the catalytic activity of perovskite-type oxide in mixed fuel and oxidant conditions. Hence we thoroughly investigated the catalytic property of various perovskite-type oxides such as $La_{0.8}Sr_{0.2}MnO_3(LSM),\;La_{0.6}Sr_{0.4}CoO_3(LSC),\;La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3(LSCF),\;Sm_{0.5}Sr_{0.5}CoO_3(SSC),\;and\;Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}(BSCF)$ under the partial oxidation condition of methane which used to be given for SC-SOFC operation. In this study, powder form of each perovskite oxides whose surface areas were controlled to be equal, were investigated as functions of methane to oxygen ratios and reactor temperature. XRD, BET and SEM were employed to characterize the crystalline phase, surface area and microstructure of prepared powders before and after the catalytic oxidation. According to the gas phase analysis with flow-through type reactor and gas chromatography system, LSC, SSC, and LSCF showed higher catalytic activity at fairly lower temperature around $400^{\circ}C{\sim}450^{\circ}C$ whereas LSM and BSCF could be activated at much higher temperature above $600^{\circ}C$.

• 자원리싸이클링
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• 제14권6호
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• pp.37-43
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• 2005

페리튬이온전지로부터 회수된 코발트와 리튬 침출액으로부터 화염분부열분해법에 의하여 $LiCoO_{2}$ 나노분말을 제조하였다. 리튬 및 코발트 성분을 함유하는 전극물질은 열처리 및 기계적 처리에 의해 그 농도를 증가 시켰다. 리튬이온전지 양극물질을 질산으로 용해한 다음 침출액중 Li과 Co의 당량비가 1.0 되도록 $LiNO_{3}$로 조절하여 화염분무열분해용 전구체를 제조하었다. 화염분무열분해법에 의해 제조된 $LiCoO_{2}$ 분말의 평균입자크기는 전구체의 몰 농도가 증가하면서 증가되었으며, 화염온도 역시 입자의 크기를 증가시켰다. 변수실험 결과 $11{\~}35nm$ 크기의 결정형 $LiCoO_{2}$ 나노분말을 제조할 수 있었다 또한 나노 $LiCoO_{2}$의 전극재료로서의 가능성을 확인하기 위하여 충방전 특성 평가와 같은 전기화학적 분석을 수행하였다.

• 한국산학기술학회논문지
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• 제15권5호
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• pp.2587-2593
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• 2014

세라믹 사출공정(CIM)은 산업 분야 전반에 걸쳐 널리 사용되고 있는 공정 중 하나로, 점차 의료용 전자기기의 부품 등으로 확대 적용되고 있다. 본 연구에서는 FEM 해석을 통해 CIM의 공정변수가 제품의 품질에 미치는 영향을 분석했다. 단순평판 형상의 해석결과를 기초로 구멍이 있는 형상, 모서리부가 둥근 형상 및 측벽 구조가 있는 형상 등과 비교 분석했다. 구멍이 있는 형상의 경우, 구멍 주변에 밀도분포가 고르지 못하며 용접선(weld-line)과 같은 결함이 발생할 수 있음을 예측할 수 있었다. 반면 제품의 모서리부 반경이 크면 성형성 및 유동성이 좋아지는 것을 확인했다. 따라서 CIM 공정변수 뿐만 아니라 제품의 형상변수도 고려해야 한다. 해석결과 온도, 초기분율, 속도 등의 공정변수는 제품의 품질 향상을 위한 중요한 설계 변수가 될 수 있음을 확인할 수 있었다.

• 자원리싸이클링
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• 제17권1호
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• pp.29-37
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• 2008

최근 국 내외에서 폐유리의 발생량이 증가하고 있으며 대부분의 폐유리량은 재활용 및 재생산으로 활용되고 있다. 하지만 재활용되지 못한 폐유리는 매립되어 2차적인 환경문제를 야기 시키고 있는 실정이다. 폐유리 미분말의 5% 혼합에 따라 페이스트 평균점도(레올로지)는 22.3% 감소하였으며, 모르타르의 플로우 및 재령 28일 압축강도는 약 1.5%및 6%감소하였다. 또한 굳지 않은 자기 충전 콘크리트의 폐유리 미분말 혼합률이 증가할수록 유동성은 증가하였으며 압축강도는 감소하였다. 자기충전 콘크리트의 JSCE 2등급 규정에 만족하는 유동성 및 적정 압축 강도를 고려한다면, 폐유리 미분말의 최적 혼합률 20%를 찾을 수 있었다.

• Advances in concrete construction
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• 제11권4호
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• pp.335-345
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• 2021

It is known from the literature that there are relatively few studies on the engineering properties of ultra-high performance concrete (UHPC) in early age. In fact, in order to ensure the safety of UHPC during construction and sufficient durability and long-term performance, it is necessary to explore the early behavior of UHPC. The test parameters (test control factors) investigated included the percentage of cement replaced by silica fume (SF), the percentage of cement replaced by ultra-fine silica powder (SFP), the amount of steel fiber (volume percent), and the amount of polypropylene fiber (volume percentage). The engineering properties of UHPC in the fresh mixing stage and at the age of 7 days were investigated. These properties include freshly mixed properties (slump, slump flow, and unit weight) and hardened mechanical properties (compressive strength, elastic modulus, flexural strength, and splitting tensile strength). Moreover, the effects of the experimental factors on the performance of the tested UHPC were evaluated by range analysis and variance analysis. The experiment results showed that the compressive strength of the C8 mix at the age of 7 days was highest of 111.5 MPa, and the compressive strength of the C1 mix at the age of 28 days was the highest of 128.1 MPa. In addition, the 28-day compressive strength in each experimental group increased by 13%-34% compared to the 7-day compressive strength. In terms of hardened mechanical properties, the performance of each experimental group was superior to that of the control group (without fiber and without additional binder materials), with considerable improvement, and the experimental group did not produce explosive or brittle damage after the test. Further, the flexural test process found that all test specimens exhibited deflection-hardening behavior, resulting in continued to increase carrying capacity after the first crack.

• 한국식품영양학회지
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• 제32권2호
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• pp.148-154
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• 2019

The aim of this study was to select compounds for the standardization of fermented Kalopanax pictus Nakai (KP-F), to develop the analysis method using HPLC-PDA and to perform method validation. KP-F is a fermented powder developed to improve the original physiological activities and create a new functionality. Eleutheroside E, Acanthoside B, and Syringaresinol were selected as the standard compounds and developed our own method for simultaneous analysis. The analyte was isolated using C18 column with a gradient elution of 0.05 M phosphoric acid in water and methanol as the mobile phase at a flow rate of 1 mL/min and detected at 210 nm. As a result, all standard compounds showed good linearity with an $R^2$ (coefficient of correlation) of 1.000 and for the limit of detection range of $0.710{\sim}0.831{\mu}g/mL$, and the limit of quantification as $2.150{\sim}2.520{\mu}g/mL$. The precision was RSD (%) of less than 4.80%, while the accuracy was 4.70%>RSD (%) for the range 102.44~110.48%. In conclusion, the developed analysis method is suitable for the detection of Eleutheroside E, Acanthoside B, and Syringaresinol in KP-F.