• 제목/요약/키워드: Particle assembly

검색결과 134건 처리시간 0.021초

물 위에 사는 곤충의 부양과 가라앉음에 관한 연구 (Study on the Floating and Sinking of Insects Living on Water)

  • 이덕규;김호영
    • 대한기계학회논문집B
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    • 제30권10호
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    • pp.982-986
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    • 2006
  • It is well known that the surface tension forces can make a particle denser than water float when the size of the particle is of the order of 1 mm. This is deeply related to the basic mechanism enabling small insects to wander around on the pond surface and also to a newly emerging technology of self-assembly using capillary forces. For the quantitative understanding of this effect, we experimentally study the maximum density of a cylinder that can float on water and how fast the cylinder sinks when the density exceeds the maximum value. We compare our experimental results with the theoretical prediction and find good agreement between them.

Magnetic Behaviors of Isolated Fe-Co-Ni Nanoparticles in a Random Arrangement

  • Yang, Choong Jin;Kim, Kyung Soo;Wu, Jianmin
    • Journal of Magnetics
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    • 제6권3호
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    • pp.94-100
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    • 2001
  • Fe-Co-Ni particles with an average size of 45 and 135 nm are characterized in terms of magnetic phase transformation and magnetic properties at room temperature. BCC structure of Fe-Co-Ni spherical particles can be synthesized from Fe-Co-Ni-Al-Cu precursor films by heating at 600-80$0^{\circ}C$ for the phase separation of Fe-Co rich Fe-Co-Ni particles, followed by a post heating at $600^{\circ}C$ for 5 hours. The average size of nanoparticles was directly determined by the thickness of precursor films. Exchange interactive hysteresis was observed for the nano-composite (Fe-Co-Ni)+(Fe-Ni-Al) films resulting from the short exchange interface between ferromagnetic Fe-Co-Ni particles surrounded by almost papramagnetic Ni-Al-Fe matrix. Arraying the isolated Fe-Co-Ni nano-particles in a random arrangement on $Al_2O_3$substrate the particle assembly showed a behavior of dipole interactive ferromagnetic clusters depending on their volume and inter-particle distance.

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Poly(vinyl alcohol) block의 신디오탁틱이 Poly(vinyl alcohol-b-styrene)의 micelle형성에 미치는 영향 (Influence of the Syndiotacticity of Poly(vinyl alcohol) block on the formation of micelles for Poly(vinyl alcohol-b-styrene))

  • 이광화;조창기
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 봄 학술발표회 논문집
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    • pp.291-292
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    • 2003
  • Amphiphilic block copolymer는 self-assembly특성을 가지고 있기 때문에 선택된 용매 속에서 nanoscale-domain 즉 micelle을 형성할 수 있다. 이러한 특성은 기타 불용성 물질을 가용화하고 colloidal particle을 안정화시키거나 micro-emulsion을 형성할 수 있어 pharmaceutics, drug delivery system등 영역, 그리고 emulsion stabilizer, thickener, dispersion agent등으로 사용될 수 있다. (중략)

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에어로졸 공정에 의한 Graphene-$TiO_2$ 복합체 제조 및 염료감응 태양전지 특성평가 (Preparation of graphene-$TiO_2$ composite by aerosol process and it's characterization for dye-sensitized solar cell)

  • 조은희;김선경;장희동;장한권;노기민;김태오
    • 한국입자에어로졸학회지
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    • 제9권2호
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    • pp.51-57
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    • 2013
  • A graphene(GR)-$TiO_2$ composite was synthesized from colloidal mixture of graphene oxide(GO) nanosheets and $TiO_2$ nanoparticles by an aerosol assisted self-assembly. The morphology, specific surface area and pore size of asprepared GR-$TiO_2$ composite were characterized by FE-SEM, BET, and BJH respectively. The shape of GR-$TiO_2$ composite was spherical. The average particle size was 0.5-1 ${\mu}m$ in diameter and the pore diameter ranged 20-50 nm. Photovoltaic characteristics of a mixture of the GR-$TiO_2$ and $TiO_2$ nanoparticles were measured by a solar simulator under simulated solar light. The highest photoelectric conversion efficiency of the mixture photoanode was 5.1%, which was higher than that of $TiO_2$ photoanode.

On the Particle Swarm Optimization of cask shielding design for a prototype Sodium-cooled Fast Reactor

  • Lim, Dong-Won;Lee, Cheol-Woo;Lim, Jae-Yong;Hartanto, Donny
    • Nuclear Engineering and Technology
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    • 제51권1호
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    • pp.284-292
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    • 2019
  • For the continuous operation of a nuclear reactor, burnt fuel needs to be replaced with fresh fuel, where appropriate (ex-vessel) fuel handling is required. Particularly for the Sodium-cooled Fast Reactor (SFR) refueling, its process has unique challenges due to liquid sodium coolant. The ex-vessel spent fuel transportation should concern several design features such as the radiation shielding, decay-heat removal, and inert space separated from air. This paper proposes a new design optimization methodology of cask shielding to transport the spent fuel assembly in a prototype SFR for the first time. The Particle Swarm Optimization (PSO) algorithm had been applied to design trade-offs between shielding and cask weight. The cask is designed as a double-cylinder structure to block an inert sodium region from the air-cooling space. The PSO process yielded the optimum shielding thickness of 26 cm, considering the weight as well. To confirm the shielding performance, the radiation dose of spent fuel removed at its peak burnup and after 1-year cooling was calculated. Two different fuel positions located during transportation were also investigated to consider a functional disorder in a cask drive system. This study concludes the current cask design in normal operations is satisfactory in accordance with regulatory rules.

PFC를 이용한 콘크리트기둥의 발파모델링 (Blast Modeling of Concrete Column Using PFC)

  • 최병희;양형식;류창하
    • 화약ㆍ발파
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    • 제23권1호
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    • pp.47-54
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    • 2005
  • 본 연구에서는 $PFC^{3D}$를 사용하여 시멘트 모르타르와 굵은 골재로 이루어진 콘크리트 기둥의 발파과정에서 나타나는 폭발과 파괴현상을 모사하여 보았다. 폭원모델링 과정에서는 공내입자들의 반경을 팽창/수축시키는 기법을 통해 공벽입자들에 접촉력의 형태로 폭발압력을 부여하는 방법을 사용하였다. 현장 발파실험에서는 철근콘크리트 기둥을 대상으로 초안폭약을 사용하여 발파하고 그 파괴거동을 고속카메라를 이용하여 관찰하였다. 모사과정에서는 철근의 규격과 입자요소의 크기에 따른 해석시간을 고려하여 모르타르와 굵은 골재로 이루어진 콘크리트 기둥을 대상으로 제안된 폭원모델링 기법을 적용하여 해석을 실시하였다. 해석결과 나타난 저항선의 이동속도는 $17\~24\;m/s$로서 실험치 $14\~18\; m/s$를 약간 상회하고 있으나 제안된 폭원모델링 기법을 사용한다면 암석이나 기타 재료들에 대한 발파과정에서 나타는 파괴거동을 수치적으로 보다 유사하게 모사할 수 있을 것으로 판단된다.

주형법으로 제조된 Gd2O3:Eu3+ 적색 형광체의 나노입자 분산 및 형상제어 (Dispersion and Shape Control on Nanoparticles of Gd2O3:Eu3+ Red Phosphor Prepared by Template Method)

  • 박정민;반세민;정경열;최병기;강광중;김대성
    • 한국재료학회지
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    • 제27권10호
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    • pp.534-543
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    • 2017
  • $Gd_2O_3:Eu^{3+}$ red phosphors were prepared by template method from crystalline cellulose impregnated by metal salt. The crystallite size and photoluminescence(PL) property of $Gd_2O_3:Eu^{3+}$ red phosphors were controlled by varying the calcination temperature and $Eu^{3+}$ mol ratio. The nano dispersion of $Gd_2O_3:Eu^{3+}$ was also conducted with a bead mill wet process. Dependent on the time of bead milling, $Gd_2O_3:Eu^{3+}$ nanosol of around 100 nm (median particle size : $D_{50}$) was produced. As the bead milling process proceeded, the luminescent efficiency decreased due to the low crystallinity of the $Gd_2O_3:Eu^{3+}$ nanoparticles. In spite of the low PL property of $Gd_2O_3:Eu^{3+}$ nanosol, it was observed that the photoluminescent property was recovered after re-calcination. In addition, in the dispersed nanosol treated at $85^{\circ}C$, a self assembly phenomenon between particles appeared, and the particles changed from spherical to rod-shaped. These results indicate that particle growth occurs due to mutual assembly of $Gd(OH)_3$ particles, which is the hydration of $Gd_2O_3$ particles, in aqueous solvent at $85^{\circ}C$.

MEA 제조 방법에 따른 직접 메탄올 연료전지의 성능저하 현상 평가 (Effect of MEA fabrication on the performance degradation of DMFC)

  • 조윤환;조용훈;박현서;원호연;성영은
    • 신재생에너지
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    • 제3권1호
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    • pp.60-67
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    • 2007
  • Catalyst coated membrane [CCM] type and catalyst coated substrate [CCS] type of membrane electrode assembly [MEA] were manufactured and evaluated their performance. Degradation test were conducted to find the difference of long term stability in two types of MEA and the factor for performance degradation problem occurred. Performance degradation test of single cell in two different types of MEA were carried out when current density was $200mA/cm^{2}$. The degradation test had proceeded for 230 hours and performance degradation was checked by I-V curve and impedance measurement at regular intervals. Also, MEA before/after operation and changes of catalyst layer were characterized by SEM, TEM, and XRD. Maximum power density of CCM type was higher than that of CCS type. Meanwhile, an increase of particle size of catalyst and an increase of impedance resistance after long term operation were observed. In the case of using CCM type MEA, the performance was deteriorated 38% of initial performance. In the case of using CCS type MEA, the performance was deteriorated 43% of initial performance. In consideration of difference of initial performance, performance of CCM type is higher than that of CCS type but both types had similar problems during degradation test.

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Improving the Neutronic Characteristics of a Boiling Water Reactor by Using Uranium Zirconium Hydride Fuel Instead of Uranium Dioxide Fuel

  • Galahom, Ahmed Abdelghafar
    • Nuclear Engineering and Technology
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    • 제48권3호
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    • pp.751-757
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    • 2016
  • The present work discusses two different models of boiling water reactor (BWR) bundle to compare the neutronic characteristics of uranium dioxide ($UO_2$) and uranium zirconium hydride ($UZrH_{1.6}$) fuel. Each bundle consists of four assemblies. The BWR assembly fueled with $UO_2$ contains $8{\times}8$ fuel rods while that fueled with $UZrH_{1.6}$ contains $9{\times}9$ fuel rods. The Monte Carlo N-Particle Transport code, based on the Mont Carlo method, is used to design three dimensional models for BWR fuel bundles at typical operating temperatures and pressure conditions. These models are used to determine the multiplication factor, pin-by-pin power distribution, axial power distribution, thermal neutron flux distribution, and axial thermal neutron flux. The moderator and coolant (water) are permitted to boil within the BWR core forming steam bubbles, so it is important to calculate the reactivity effect of voiding at different values. It is found that the hydride fuel bundle design can be simplified by eliminating water rods and replacing the control blade with control rods. $UZrH_{1.6}$ fuel improves the performance of the BWR in different ways such as increasing the energy extracted per fuel assembly, reducing the uranium ore, and reducing the plutonium accumulated in the BWR through burnup.