• Title/Summary/Keyword: Non-flammable

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Estimation of Flash Points of Flammable Liquid Mixtures with Non-flammable Liquids (난연성액체에 따른 가연성 액체혼합물의 인화점 추산)

  • 이수경;엄종호;하동명;이성민
    • Journal of the Korean Society of Safety
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    • v.7 no.3
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    • pp.53-59
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    • 1992
  • A general theory is developed which enables closed-cup flash points of mixtures of flammable and non-flammable liquid to be estimated from a knowledge of a certain properties of flammability diagram by thermodynamic method. The estimated equations is shown the effect of both the flame inhibiting properties of the vapor of the non-flammable component and the relative volatility of that component. The vapor phase flame inhibition effect results in a even greater elevation of flash points than the rotative volatility of that component. Especially in cases of similar vapor phase flame inhibition of the non-flammable component, the rotative volatility is affected greater elevation of flash points(extinguishing effect).

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Design of Non-flammable Mixed Refrigerant Joule-Thomson Refrigerator for Semiconductor Etching Process (반도체 식각공정을 위한 비가연성 혼합냉매 줄톰슨 냉동기 설계)

  • Lee, Cheonkyu;Kim, Jin Man;Lee, Jung-Gil
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.2
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    • pp.144-149
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    • 2022
  • A cryogenic Mixed Refrigerant Joule-Thomson refrigeration cycle was designed to be applied to the semiconductor etching process with non-flammable constituents. 3-stage cascade refrigerator, single mixed refrigerant Joule-Thomson refrigerator, and 2-stage cascade type mixed refrigerant Joule-Thomson refrigerator are analyzed to figure out the coefficient of performance. Non-flammable mixture of argon(Ar), tetrafluoromethane(R14), trifluoromethane (R23) and octafluoropropane(R218) were utilized to analyze the refrigeration cycle efficiency. The designed refrigeration cycle was adapted to cool down the coolant of HFE7200(Ethoxy-nonafluorobutane, C4F9OC2H5) with certain constraints. Maximum coefficient of performance of the refrigeration system is obtained as 0.289 for the cooling temperature lower than -100℃. The detailed result of the coefficient of performance according to the mixture composition is discussed in this study.

Experimental Investigation of 2kW Class Non-flammable Mixed Refrigerant Joule-Thomson Refrigerator with Cooling Temperature of -100 ℃ for Cryogenic Etching (초저온 식각을 위한 냉각용량 2kW 급 -100 ℃ 비가연성 혼합냉매 줄톰슨 냉각기의 실험적 고찰)

  • Jongmin Eun;Cheonkyu Lee
    • Journal of the Semiconductor & Display Technology
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    • v.23 no.2
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    • pp.6-11
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    • 2024
  • This paper presents the design and experimental analysis of a cryogenic refrigeration system for -100 ℃, primarily intended for semiconductor etching process. The refrigeration system utilizes non-flammable mixed refrigerant Joule-Thomson refrigeration cycle, incorporating a precooling stage to enhance overall performance. The selected refrigerants for the system include R1234yf for the precooling stage, and Ar, R14, R23 and R218 for the main cooling stage of the Joule-Thomson refrigeration cycle. Design results according to the system constraints and experimental results are discussed, including lowest evaporation temperature, compressor isentropic efficiency and overall pressure tendencies. The achieved refrigerant fraction from optimal design is Ar: R14: R23: R218 = 0.15: 0.4: 0.15: 0.3, indicating COP of 0.1118 at the isentropic compressor efficiency of 50%. The experimental result shows the developed system reaches steady state in approximately 3 hours.

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A Study on the Estimation Model of Liquid Evaporation Rate for Classification of Flammable Liquid Explosion Hazardous Area (인화성액체의 폭발위험장소 설정을 위한 증발율 추정 모델 연구)

  • Jung, Yong Jae;Lee, Chang Jun
    • Journal of the Korean Society of Safety
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    • v.33 no.4
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    • pp.21-29
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    • 2018
  • In many companies handling flammable liquids, explosion-proof electrical equipment have been installed according to the Korean Industrial Standards (KS C IEC 60079-10-1). In these standards, hazardous area for explosive gas atmospheres has to be classified by the evaluation of the evaporation rate of flammable liquid leakage. The evaporation rate is an important factor to determine the zones classification and hazardous area distance. However, there is no systematic method or rule for the estimation of evaporation rate in these standards and the first principle equations of a evaporation rate are very difficult. Thus, it is really hard for industrial workplaces to employ these equations. Thus, this problem can trigger inaccurate results for evaluating evaporation range. In this study, empirical models for estimating an evaporation rate of flammable liquid have been developed to tackle this problem. Throughout the sensitivity analysis of the first principle equations, it can be found that main factors for the evaporation rate are wind speed and temperature and empirical models have to be nonlinear. Polynomial regression is employed to build empirical models. Methanol, benzene, para-xylene and toluene are selected as case studies to verify the accuracy of empirical models.

A Study on the Origination of Backcountry Litter in Moaksan Provincial Park (모악산도립공원의 산쓰레기 발생특성)

  • Rho, Jae-Hyun;Huh, Joon
    • Journal of the Korean Institute of Landscape Architecture
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    • v.35 no.5
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    • pp.64-72
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    • 2007
  • This study investigated the types, forms, and origination of litter found along one hiking course in Moaksan Provincial Park, 'Jungin-ri Course'(entrance-ridge-valley-peak). In addition, a survey was conducted to understand hikers' litter control awareness in order to determine possible backcountry litter control measures. The following are the results of this study: 1. For the litter Sequency investigation, 199 recyclable pieces of litter were found on the mid-slope(61.6%), 89 by the entrance(27.6%), 19 in the valley(5.9%) and 16 on the peak(4.9%). A total of 323 pieces of litter were found. Paper materials were the most common, followed by plastic containers such as PET bottles and yogurt containers. Of particular interest, 288 papers and cans were found on the mid-slope(46.9%). By the entrance, more plastics and bottles were found. 2. There were 614 pieces of flammable litter collected and only 19 pieces of non-flammable. Most of the flammable litter, including snack pacts, plastic bags, processed lumber, cigarette butts, tissues, cigarette boxes, and fabric was found on the mid-slope. 3. Very little food waste was found throughout the whole site proving that the policy prohibiting hikers from cooking and eating at the designated sites has been effective. However, food waste is difficult to find because it naturally decays with time. 4. $X^2$-test was used to find different types of litter and their verified origination frequency. It was found that recyclable litter, and food waste took about 1%. In addition, recyclable litter, especially bottles, was found relatively frequently by the entrance. Flammable litter was found most often at the peak. 5. The questionnaire results showed that 48.2% of the respondents "shorten their hiking journey and purchase food outside the entrance" and 29.6% said that they "bring a packed meal from home". Only 8.2% said that they "cook something when an appropriate location is found". At the Jungin-ri course, a few hikers brought their own food to eat or cook, but most hikers purchased something to eat onsite. 6. The results of the question about having experience littering while hiking showed that 19.3% litter and 79.2% do not. Those that responded "yes" gave various reasons for littering. 63.6% claimed, "there are no designated trash containers". 15.9% said they litter subconsciously. Finally, 3.2% insist that they litter "because food naturally decomposes". 7. As a result of the overall satisfaction according to the Likert scale and the analysis with an average of 14 variables, it was found that the average "toxic litter control convenience" was 2.41 with very low satisfaction. Thus, the results indicate the importance of providing appropriate back country litter control facilities.

A study on the Application of Inorganic Reinforced Non-Flammable Molding to Building Exterior (무기계보강 CLC 불연몰딩의 건축물 외벽적용 연구)

  • Kwon, Hae-Won;Gong, Min-Ho;Lee, Chang-Woo;Choi, Byung-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.61-62
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    • 2021
  • Exterior wall molding, which is widely applied as a design element of the exterior wall of domestic apartment, should be applied as a nonflammable or semi-nonflammable material grade according to the rules on standards for evacuation/fire protection structures of buildings. For this reason, stone and AL sheet are mainly used, but stone is expensive and design autonomy is low. Inorganic reinforced CLC nonflammable molding was applied to the exterior wall of the building through tests of nonflammable performance, noise reduction, and installation stability.

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Development and Performance Evaluation of Non-flammable Mineral Foam Board Using Waste Glass (폐유리를 활용한 불연 무기물 발포 보드 개발 및 성능평가)

  • Kim, Hyen-Soo;Choi, Won-Young;Kim, Sang-Heon;Choi, Seung-Hwan;Park, Soon-Don
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.1
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    • pp.17-25
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    • 2020
  • In this study, non-flammable mineral foam board using waste glass that can be produced to standardized specifications were developed and evaluated for the performance. In addition to the physical and mechanical performance, the environmental properties such as insulation, non-combustibility, gas hazard, sound absorption, etc. were tested to verify the use as interior and exterior building materials. Through the structural review, the validity was verified for the application of the office and restaurant building.

The Measurement of Flash Point for Binary Mixtures of 2,2,4-Trimethylpentane, Methylcyclohexane, Ethylbenzene and p-xylene at 101.3 kPa

  • Hwang, In Chan;In, Se Jin
    • Clean Technology
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    • v.26 no.4
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    • pp.279-285
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    • 2020
  • Laboratories and industrial processes typically involve the use of flammable substances. An important property used to estimate fire and explosion risk for a flammable liquid is the flash point. In this study, flash point data at 101.3 kPa were determined using a SETA closed cup flash point tester on the following solvent mixtures: {2,2,4-trimethylpentane + methylcyclohexane}, {2,2,4-trimethylpentane + ethylbenzene}, and {2,2,4-trimethylpentane + p-xylene}. The purpose of this work is to obtain flash point data for binary mixtures of 2,2,4-trimethylpentane with three hydrocarbons (methylcyclohexane, ethylbenzene, and p-xylene), which are representative compounds of the main aromatic hydrocarbon fractions of petroleum. The measured flash points are compared with the predicted values calculated using the GE models' activity coefficient patterns: the Wilson, the Non-Random Two-Liquid (NRTL), and the UNIversal QUAsiChemical (UNIQUAC) models. The non-ideality of the mixture is also considered. The average absolute deviation between the predicted and measured lower flash point s is less than 1.99 K, except when Raoult's law is calculated. In addition, the minimum flash point behavior is not observed in any of the three binary systems. This work's predicted results can be applied to design safe petrochemical processes, such as identifying safe storage conditions for non-ideal solutions containing volatile components.

Analysis of the Response Time of a Photoelectric Spot-Type Smoke Detector Depending on the Type of Fires (화원에 따른 광전식 연기감지기 반응시간 분석)

  • Jee, Seung-Wook
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.27 no.5
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    • pp.89-94
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    • 2013
  • The fire testing performed for smoke detector model approval in Korea tests only one kind of fire smoke. A photoelectric spot-type smoke detector using Mie scattering is affected by the wavelength of light beam and the particle diameter. According to UL (Underwriters Laboratories Inc.) 268 standard, this paper analyze the characteristic of the response for a photoelectric spot-type smoke detector on sale in Korea using various fire smokes. Probability that the response time is included in non-defective range is 100% in paper fire, 90% in wood fire and 75% in flammable liquid fire, 90% in wood fire and 75% in flammable liquid fire. According to the estimation for population mean of the response time choosing a confidence level of 99%, a maximum of 19% for wood fire and that of 38% for flammable liquid fire are defective. As the result of analysis of smoke particle, this paper is found that these results are caused by the smoke particles are wide variations in size or have very black.

A Study on the Properties and Methods of Electrode System for Tapping of Melts (출탕유도전극을 이용한 용융물의 출탕방법 및 특성에 대한 연구)

  • Moon, Young-Pyo;Choi, Jang-Young
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.3
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    • pp.499-503
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    • 2016
  • For safety and economy reasons, hazardous waste including radioactive waste is desired to be converted into stable waste forms with a maximum volume reduction. High temperature melting technology using a plasma torch system can effectively treat even the non-flammable waste as desired. By far, one of the most difficult process for melting the non-flammable waste is a tapping of melts because the melting point of a residual slag in the tapping hole is high and because the viscosity of the melt increases sharply when tapping out. In case of a stationary furnace with a slant tapping port on the side of furnace, a certain amount of melts is left in the tapping hole after tapping out. Because of this, at every end of a melting cycle, the tapping hole needs to be opened by tapping device. The developed tapping device of melts based on both a guide electrode and auxiliary electrode is adequate for the application to discharge of melts except that the consumption of the guide electrode is somewhat faster than expected. Melt is collected in the water cooled vessel.