• Title/Summary/Keyword: Nitrous oxide ($N_20$)

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Determination of Initial Denitrification in Intact Cores under Various Freshwater Wetland Types

  • Seo, Dong-Cheol;Delaune, R.D.;Lane, Robert R.;Day, John W.
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.1
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    • pp.20-24
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    • 2012
  • Denitrification rate was determined for various freshwater wetland types in the Mississippi River Coastal delta plain. Site 1 and 4 were collected from forested-tupelo dominated wetland, and site 2 and 3 were from floating emergent marsh. The maximum $N_2O$ emission was $7.47mg\;N\;m^{-2}$ for site 1 at day 6 after the addition of nitrate, $6.96mg\;N\;m^{-2}$ for site 2 at day 4, $6.63mg\;N\;m^{-2}$ for site 3 at day 3, and $9.64mg\;N\;m^{-2}$ for site 4 at day 4. The denitrification rate was determined using the acetylene inhibition method $1.24mg\;N\;m^{-2}d^{-1}$ for site 1, $1.93mg\;N\;m^{-2}d^{-1}$ for site 2, $2.24mg\;N\;m^{-2}d^{-1}$ for site 3, and $2.78mg\;N\;m^{-2}d^{-1}$ for site 4. The maximum denitrification rate was in the order of site 4 > site 3 > site 2 > site 1.

Estimation of Greenhouse Gas (GHG) Emissions from Livestock Agriculture in Korea (2011년도 축산부문 온실가스 인벤토리 산정 연구)

  • Yang, Seung-Hak;Choi, Dong-Yoon;Cho, Sung-Back;Hwang, Ok-Hwa;Park, Kyu-Hyun
    • Journal of Animal Environmental Science
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    • v.20 no.4
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    • pp.139-146
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    • 2014
  • This research was conducted to examine the temporal methane ($CH_4$) and nitrous oxide ($N_2O$) emission trends in livestock agriculture from year 1990 to 2011 with Tier 1 national greenhouse gas (GHG) inventory reporting method, which was related to efforts of decreasing GHG emissions and to achievement of voluntary GHG mitigation target. Methane emissions from enteric fermentation were calculated with default $CH_4$ emission factors of IPCC. Methane and $N_2O$ emissions from manure treatment processes were calculated with Tier 1 and mixture of Tier 1 and Tier 2 including $N_2O$ emission factors of manure treatment systems and nitrogen excretion rate of livestock, respectively. According to 2013 National GHG Inventory Monitoring, Reporting, and Verification report, GHG emission fluctuations from enteric fermentation and manure treatment processes were similarto livestock head fluctuation. GHG emissions from enteric fermentation were mainly affected by beef cattle including Hanwoo, while manure treatment processes were affected by various livestock.

Decrease of Interface Trap Density of Deposited Tunneling Layer Using CO2 Gas and Characteristics of Non-volatile Memory for Low Power Consumption (CO2가스를 이용하여 증착된 터널층의 계면포획밀도의 감소와 이를 적용한 저전력비휘발성 메모리 특성)

  • Lee, Sojin;Jang, Kyungsoo;Nguyen, Cam Phu Thi;Kim, Taeyong;Yi, Junsin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.7
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    • pp.394-399
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    • 2016
  • The silicon dioxide ($SiO_2$) was deposited using various gas as oxygen and nitrous oxide ($N_2O$) in nowadays. In order to improve electrical characteristics and the interface state density ($D_{it}$) in low temperature, It was deposited with carbon dioxide ($CO_2$) and silane ($SiH_4$) gas by inductively coupled plasma chemical vapor deposition (ICP-CVD). Each $D_{it}$ of $SiO_2$ using $CO_2$ and $N_2O$ gas was $1.30{\times}10^{10}cm^{-2}{\cdot}eV^{-1}$ and $3.31{\times}10^{10}cm^{-2}{\cdot}eV^{-1}$. It showed $SiO_2$ using $CO_2$ gas was about 2.55 times better than $N_2O$ gas. After 10 years when the thin film was applied to metal/insulator/semiconductor(MIS)-nonvolatile memory(NVM), MIS NVM using $SiO_2$($CO_2$) on tunneling layer had window memory of 2.16 V with 60% retention at bias voltage from +16 V to -19 V. However, MIS NVM applied $SiO_2$($N_2O$) to tunneling layer had 2.48 V with 61% retention at bias voltage from +20 V to -24 V. The results show $SiO_2$ using $CO_2$ decrease the $D_{it}$ and it improves the operating voltage.

Emission Characteristics of Greenhouse Gases (CH4, N2O) in Mechanically Ventilated Swine Farm during Winter Season (겨울철 강제환기식 돈사 내 온실가스 (CH4, N2O) 배출 특성 연구)

  • Park, Junyong;Jung, Minwoong;Jo, Gwanggon;Jang, Yu-Na
    • Journal of The Korean Society of Agricultural Engineers
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    • v.63 no.4
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    • pp.33-41
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    • 2021
  • The emission characteristics and emission factors were determined by measuring the concentration of methane (CH4) and nitrous oxide (N2O), the amount of ventilation, etc. in the two fattening rooms which have the same environment in winter. As a result of monitoring, the average concentration of CH4 and N2O was 20.7-26.7 ppm and 1.4-1.6 ppm. The average temperature inside the room was measured at 20.0-21.4℃, and the average ventilation was 1345.4-1567.3 m3/h. The daily emission of CH4 for the first 30 days showed a constant emission of 3.6-8.2 g/d/m2/pig, but thereafter, the emission increased rapidly. The daily emission of N2O was 0.7-1.3 g/d/m2/pig, showing stable emission during the test period, and relatively insignificant emission compared to the emission of CH4. After repeated test, it was confirmed that there was no significant difference between the two rooms. As a result, the CH4 6. 21 g/d/m2/pig and N2O 1.02 g/d/m2/pig average emission for each room was derived.

Effect of Water Management on Greenhouse Gas Emissions from Rice Paddies Using a Slow-release Fertilizer (완효성 비료를 시용한 논에서의 물관리에 따른 온실가스 배출량 평가)

  • Eun-Bin Jang;Hyun-Chul Jeong;Hyo-Suk Gwon;Hyoung-Seok Lee;Hye-Ran Park;Jong-Mun Lee;Taek-Keun Oh;Sun-Il Lee
    • Korean Journal of Environmental Agriculture
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    • v.42 no.2
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    • pp.112-120
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    • 2023
  • Methane (CH4) and nitrous oxide (N2O) are significant contributors to greenhouse gas (GHG) emissions from rice fields. Mid-summer drainage is a commonly practiced water management technique that reduces CH4 emissions from rice fields. Slow-release fertilizers gradually release nutrients over an extended period and have been shown to reduce N2O emissions. However, the combined effect of slow-release fertilizer and water management on GHG emissions remains unclear. This study compared GHG emissions from a rice paddy subjected to mid-summer drainage for 10 days (control) with that of a rice paddy subjected to prolonged mid-summer drainage for 20 days combined with slow-release fertilizer (W+S). Gas sampling was conducted weekly using a closed chamber method. During the rice cultivation period, cumulative CH4 and N2O emissions were reduced by 12.3% and 16.2%, respectively, in the W+S treatment compared to the control. Moreover, the W+S treatment exhibited a 1.9% increase in grain yield compared to the control. Under experimental conditions, slow-release fertilizers, in combination with prolonged mid-summer drainage, proved to be the optimal approach for achieving high crop yield while reducing GHG emissions. This represents an effective strategy to mitigate GHG emissions from rice paddy fields.

Efficacy of Isoproterenol as a Marker of Epidural Test Dose in Patients Anesthetized with Enflurane (Enflurane 전신마취중 경막외 시험용량의 표식자로서 Isoproterenol의 효율성)

  • Kim, Keon-Sik;Kang, Wha-Ja;Lee, Doo-Ik
    • The Korean Journal of Pain
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    • v.14 no.2
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    • pp.186-192
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    • 2001
  • Background: Epidural test doses containing epinephrine are an incomplete marker for the detection of inadvertent intravascular injection. Therefore, many investigators have attempted to find a more reliable marker as an alternative to epinephrine in adult patients anesthetized with enflurane. The present study was designed to test whether two different simulated intravenous test doses of isoproterenol could be used as a reliable marker for the detection of inadvertent intravascular injection in adult patients anesthetized with $O_2-N_2O$-enflurane. Methods: Forty healthy adult patients were anesthetized with 1% end-tidal enflurane and nitrous oxide after endotracheal intubation and were randomized to one of two groups according to the dose of isoproterenol. Group 1 and 2 (n = 20 each) received 3 ml of 1.5% lidocaine with 3 and 5 g isoproterenol intravenously, respectively, to simulate an intravascularly administered test dose. Heart rate (HR) and systolic blood pressure (SBP) were measured at 20-second intervals for 4 min after injection. Results: Mean maximal HR increases were $24{\pm}17$, $35{\pm}11$ bpm (P < 0.05), mean maximal SBP increases were $14{\pm}8$, $13{\pm}9$ mmHg and mean maximal SBP decreases $20{\pm}11$, $22{\pm}9$ mmHg following the IV injection of 3, $5{\mu}g$ isoproterenol, respectively. The incidence of hypotension was similar in both groups. Isoproterenol 3 and $5{\mu}g$ produced 75%, 100% sensitivity in the HR criteria ($\geq$ 20 bpm increase) and 60%, 70% sensitivity in the SBP criteria ($\geq$ 15 mmHg), respectively. Conclusions: These results indicate that based on the HR response, the epidural test dose containing $5{\mu}g$ isoproterenol to simulate an intravascular administration is a more reliable marker than $3{\mu}g$ isoproterenol in adult healthy patients during enflurane anesthesia.

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A STUDY ON THE CONSCIOUS SEDATIVE EFFECT OF CHLORAL HYDRATE/HYDROXYZINE WITH AND WITHOUT $N_2O-O_2$ (Chloral hydrate와 Hydroxyzine의 경구투여와 $N_2O-O_2$ 병용투여시 진정효과에 관한 연구)

  • Hong, Sung-Joon;Lee, Keung-Ho
    • Journal of the korean academy of Pediatric Dentistry
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    • v.29 no.4
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    • pp.489-497
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    • 2002
  • The purpose of this study was to compare the clinical sedation effect of chloral hydrate and hydroxyzine combination with and without nitrous oxide/oxygen inhalation when young children were sedated for dental treatment. The uncooperative 20 children aged, 21 to 47 months of age(ASA Class I), participated in the study. The author examined 20 children(male 12, female 8). Each patient was assigned to receive chloral hydrate(50mg/kg) and hydroxyzine(25mg). Next appointment, each patient was assigned to receive $N_2O-O_2$, choral hydrate and hydroxyzine. Sleep, crying, movement, and overall behavior response were evaluated, and the sedative effects were evaluated by Houpt's rating scale. Pulse rate and peripheral oxygen saturation were also measured for monitoring the sedated patients during treatment period by pulse oximeter. The result were as follows : 1. In the evaluation of sleep scores, crying scores, and movement scores, chloral $hydrate/hydroxyzine/N_2O-O_2$ combination group was significantly rated high(p<0.05). 2. In the evaluation of overall behavior scores, chloral hydrate/hydroxyzine/$N_2O-O_2$ combination group was significantly rated high(p<0.05). 3. In the evaluation of overall behavior evaluation scores(by Houpt), 93.3% in chloral $hydrate/hydroxyzine/N_2O-O_2$ combination group and 63.3% in chloral hydrate/hydroxyzine combination group were rated "good" or "very good". 4. There was no adverse side effect(i.e. respiratory depression) in both group.

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Effect of Nitrogen Compounds and Organic Carbon Concentrations on $N_2O$ Emission during Denitrification (탈질에서 질소성분 및 유기탄소 농도가 $N_2O$ 배출에 미치는 영향)

  • Kim, Dong-Jin;Kim, Heon-Ki;Kim, Yu-Ri
    • Clean Technology
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    • v.17 no.2
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    • pp.134-141
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    • 2011
  • The effects of the compounds and concentrations of nitrogenous electron acceptor, the ratio of electron donor/electron acceptor (C/N), and the complexity of electron donor on the emission of $N_2O$ during wastewater denitrification were quantitatively investigated in this study. The higher ${NO_3}^-$ and ${NO_2}^-$ concentrations, the more $N_2O$ emission was observed. ${NO_2}^-$ has strong effect on $N_2O$ emission as it emitted morc $N_2O$ than ${NO_3}^-$, 50 mg/L of ${NO_2}^-$-N gave the highest conversion (9.3%) and yield (9.8%) of $N_2O$ while ${NO_3}^-$-N (50 mg/L) gave 5.6% conversion and 11.0% yield. Lower C/N ratio decreases nitrogen removal efficiency, but it increases the conversion of $N_2O$ because of the incomplete denitrification by the limited organic carbon. When real domestic wastewater is used as the electron donor of the denitrification, $N_2O$ emission is reduced to 1/10 of the emission when single carbon (acetate) is used. It is thought that multiple carbon source utilizes many denitrification pathways and it seems to be helpful for the reduction of $N_2O$ emission.

A Study of Denitrification in the Grassland with an Acetylene Inhibition Technic (초지(草地)에서의 아세칠렌 조해법(阻害法)에 의(依)한 탈질(脫窒) 연구(硏究))

  • Jo, Jin-Ki;Choi, Jyung;Park, Woo-Churl
    • Korean Journal of Soil Science and Fertilizer
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    • v.16 no.4
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    • pp.353-357
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    • 1983
  • A field study was conducted for 20 soil columns to investigate the denitrification in the grassland with a method introducing $C_2H_2$ in the denitrifying system. Since acetylene blocked the pathway from $N_2O$ to $N_2$, all the free products of denitrification consisted of nitrous oxide. In this study, denitrification was measured as $N_2O$. Results are as follows. 1. In most of boils examined, denitrification was observed as $N_2O$ when acetylene was introduced into the denitrification system while $N_2O$ was scarcely evolved without acetylene in the system. 2. Denitrification occurred even in the grassland soils when they were saturated with water. Denitrification was nil or negligible without water saturation. 3. Denitrification loss far 3 days incubation(from 13th to 16th day after urea application) was 4.2% in average and 14.2% in maximum. 4. Soil chemical properties such as nitrate nitrogen, nitrite nitrogen, total nitrogen, total carbon and mineralizable carbon did not show clear relationships with denitrificatien, probably since soil chemical properties were analysed for the soils after incubation.

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Kinetics of N2O Decomposition over Fe-TNU-9 Zeolite (Fe-TNU-9 제올라이트 상에서 아산화질소의 분해반응 속도론)

  • Park, Jung-Hyun;Jeon, Seong-Hee;Van Khoa, Nguyen;Shin, Chae-Ho
    • Applied Chemistry for Engineering
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    • v.20 no.4
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    • pp.453-458
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    • 2009
  • Iron-containing TNU-9 zeolites were prepared by aqueous ion exchange in the range of Fe contents 0.6~3.3 wt%. Direct decomposition of $N_2O$ was performed varying $N_2O$ concentrations and reaction temperatures. Fe-TNU-9 zeolites used were characterized using XRD, $N_2$ sorption, SEM/EDX. A 2.7 wt% Fe-TNU-9 zeolite showed high activities and above this contents of Fe the effect of catalytic activity was little dominated. Fe-TNU-9 zeolites after ion exchange conserved their TNU-9 structure although the degree of crystallinity was decreased until ca. 60% in 3.1 wt% Fe-TNU-9 zeolite after ion exchange in 0.01 M Fe solution. The decrease in the degree of crystallinity could be correlated with the decrease of surface area and pore volume. The partial reaction order of $N_2O$ in the decomposition of $N_2O$ was dependent on the reaction temperature from 0.69 at $420^{\circ}C$ to 0.97 at $494^{\circ}C$. The activation energy of $N_2O$ was also dependent on the $N_2O$ concentration and its value is ranged to 34~43 kcal/mol.