• Title/Summary/Keyword: Metal doping.

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EFFECTS OF Co-DOPING LEVEL ON THE MICROSTRUCTURAL AND FERROMAGNETIC PROPERTIES OF LIQUID-DELIVERY METALORGANIC-CHEMICAL-VAPOR-DEPOSITED $Ti_{1-x}Co_xO_2$ THIN FILMS

  • Seong, N.J.;Seong, S.G.
    • Proceedings of the Korean Magnestics Society Conference
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    • 2002.12a
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    • pp.42-43
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    • 2002
  • Spintronics is a rapidly expanding research area because of recent developments in the physics of spin-dependent phenomena. For use as spintronic materials, dilute magnetic semiconductors (DMS) are of considerable interest as spin injectors for spintronic devices.$^{[1]}$ Many researchers have studied DMS, in which transition metal atoms are introduced into the lattice, thus inserting local magnetic moments into the lattice. (omitted)

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High Hydrogen Capacity and Reversibility of K-Decorated Silicon Materials

  • Park, Min-Hee;Ryu, Seol;Han, Young-Kyu;Lee, Yoon-Sup
    • Bulletin of the Korean Chemical Society
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    • v.33 no.5
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    • pp.1719-1721
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    • 2012
  • We have investigated the $H_2$ adsorption structures and binding energies of the metal (M)-doped (M = Li, Na, K, Mg, and Al) silicon complexes, $M-Si_{19}H_{11}$ and $M-Si_{24}H_{12}$, using density functional calculations. Alkali metals are preferred as doping elements because the Mg-Si and Al-$H_2$ interactions are weak. The maximum numbers of $H_2$ molecules that can be adsorbed are four and five for M=Li and K, respectively. We propose that the K-decorated silicon material might be an effective hydrogen storage material with high hydrogen capacity and high reversibility.

Hydrogen Evolution Properties of Alanate-based Hydrogen Storage Materials (알라네이트 계 수소 저장 물질의 수소 방출 특성)

  • JEONG, HEONDO
    • Journal of Hydrogen and New Energy
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    • v.28 no.4
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    • pp.361-368
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    • 2017
  • Alanate-based materials, which were known to have high hydrogen storage capacity, were synthesized by mechanochemically metathesis reaction of metal chloride and sodium alanate without solvent. XRD patterns of synthesized materials showed that metathesis reaction of cations between metal chloride and sodium alanate was progressed favorably without any solvent. Magnesium alanate showed that 3.2 wt.% of hydrogen was evolved by the thermal decomposition. The addition of a small amount of Ti to the magnesium alanate greatly reduced hydrogen evolution temperature. Also, Ti doped magnesium alanate had a good regeneration property. Both the calcium and lithium-magnesium alanate showed the lower starting temperature of the two step hydrogen evolution and fast kinetics for the hydrogen evolution.

First-Principles Study of Magnetic Interactions between Transition Metal Ions in ZnO (ZnO내 전이 금속 불순물의 자기적 특성에 관한 제일원리 연구)

  • Lee, Eun-Cheol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.6
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    • pp.444-448
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    • 2010
  • Based on first-principles calculations, we study the magnetic properties of Co, Ni, Fe, V, and Mn impurities in ZnO. The stabilities of the ferromagnetic state and the magnetic moment of each impurity largely depend on the amount of doped electron or hole. For lightly doped n-type ZnO, it is found that the doping of Ni ions is the most effective for inducing ferromagnetism, while Fe ions show the most stable ferromagnetic couplings for heavily doped n-type samples. The characteristics of the magnetic interactions of Co ions are similar with those of Fe ions, but Co ions require much larger amount of doped electron than Fe ions to show the ferromagnetic couplings. The ferromagnetic coupling between Mn and V ions is unstable in n-type conditions.

The Resistive Switching Characteristics of Au-NiO-Au Segmented Nanowires Synthesized by Electrochemical Deposition

  • Lee, Sae-Eun;Kim, Dong-Uk;Yu, Bong-Yeong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.29.1-29.1
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    • 2011
  • ReRAM은 metal-oxide-metal구조로 차세대 비활성 메모리를 대체하기 위하여 연구되어왔다. ReRAM은 낮은 전력 소모와 다른 두 저항상태 사이의 높은 scalability를 갖는 장점이 있지만 높은 reset전류와 일정하지 않은 저항 값을 갖고 있어 실용화에 어려움을 겪고 있다. 저항변화현상의 메커니즘은 일반적으로 일정 전압이 가해 졌을 때, MIM 구조의 산화물 내에서 필라멘트가 형성되었다 파괴되는 것으로 알려져 있다. 저항스위칭 메모리의 작동능력을 증진시키기 위해서는, oxide층의 두께조절, 산화층과 electrode 사이의 계면 특성 연구가 필요하다. 본 연구에서는, 전기화학증착법을 이용하여 Au-NiO-Au segmented 나노와이어 구조를 만들었다. 전기화학증착 방법을 이용하면 에칭 손상없이 간단하게 나노 구조체를 형성 할 수 있고, 나노 사이즈로 제작된 산화층이 전도성 필라멘트가 형성되는 영역을 제한하여 reset전류를 줄일 수 있는 장점이 있다. 또한 열처리 과정에서 Au가 NiO부분에 diffusion되는 현상을 이용하여 doping에 따른 switching 변화 특성도 관찰하였다.

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A Study on the Low Temperature(45$0^{\circ}C$) Poly-Si TFT Fabricated on the Glass Substrate by Metal-Induced Lateral Crystallization (MILC) (금속 유도 측면 결정화에 의해 유리기판 위에 제작된 저온(45$0^{\circ}C$) 다결정 박막 트랜지스터에 관한 연구)

  • 김태경;인태형;이병일;주승기
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.5
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    • pp.48-53
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    • 1998
  • Poly-Si TFT's could be fabricated on glass substrates by metal induced lateral crystallization (MILC) method at 450.deg. C. Channel area of the poly-Si TFT's was laterally crystallized from source and drain areas, where a thn nickel film was deposited. Dopants activation for the formation of source and drain region could be achieved by thermal annealing at 450.deg. C after the ion mass doping of phosphorus. The field effect mobility of thus formed N-channel poly-Si TFT's was 76cm$^{2}$/Vs, and the on/off current ratio was higher than 7E6.

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Investigation of Junction-less Tunneling Field Effect Transistor (JL-TFET) with Floating Gate

  • Ali, Asif;Seo, Dongsun;Cho, Il Hwan
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.17 no.1
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    • pp.156-161
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    • 2017
  • This work presents a novel structure for junction-less tunneling field effect transistor (JL-TFET) with a floating gate over the source region. Introduction of floating gate instead of fixed metal gate removes the limitation of fabrication process suitability. The proposed device is based on a heavily n-type-doped Si-channel junction-less field effect transistor (JLFET). A floating gate over source region and a control-gate with optimized metal work-function over channel region is used to make device work like a tunnel field effect transistor (TFET). The proposed device has exhibited excellent ID-VGS characteristics, ION/IOFF ratio, a point subthreshold slope (SS), and average SS for optimized device parameters. Electron charge stored in floating gate, isolation oxide layer and body doping concentration are optimized. The proposed JL-TFET can be a promising candidate for switching performances.

Hole Transfer Layer p-doped with a Metal Oxide for Low Voltage Operation of OLEDs

  • Shin, Won-Ju;Lee, Je-Yun;Kim, Jae-Chang;Yoon, Tae-Hoon;Kim, Tae-Shick;Song, Ok-Keun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.435-438
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    • 2007
  • $V_{2}O_{5}$ was tested as a p-dopant for lower operating voltage and higher stability of OLEDs. Low voltage and high stability were achieved using this doping layer. It can be separated to bulk and interface contributions and the latter is a more dominant factor both of operation voltage and stability.

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Structure Modeling of 100 V Class Super-junction Trench MOSFET with Specific Low On-resistance

  • Lho, Young Hwan
    • Journal of IKEEE
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    • v.17 no.2
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    • pp.129-134
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    • 2013
  • For the conventional power metal-oxide semiconductor field-effect transistor (MOSFET) device structure, there exists a tradeoff relationship between specific on-resistance ($R_{ON.SP}$) and breakdown voltage ($V_{BR}$). In order to overcome the tradeoff relationship, a uniform super-junction (SJ) trench metal-oxide semiconductor field-effect transistor (TMOSFET) structure is studied and designed. The structure modeling considering doping concentrations is performed, and the distributions at breakdown voltages and the electric fields in a SJ TMOSFET are analyzed. The simulations are successfully optimized by the using of the SILVACO TCAD 2D device simulator, Atlas. In this paper, the specific on-resistance of the SJ TMOSFET is successfully obtained 0.96 $m{\Omega}{\cdot}cm^2$, which is of lesser value than the required one of 1.2 $m{\Omega}{\cdot}cm^2$ at the class of 100 V and 100 A for BLDC motor.

Optical Properties of Ag/Chalcogenides Thin Films Exposed to Laser (레이저 광 노출에 따른 Ag/칼코게나이드 박막의 광학적인 특성)

  • 김종기;박정일;정흥배;이현용
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.561-565
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    • 1999
  • We measured the optical properties in Ag/chalcogenide films with the exposure of 325nm-Held laser In addition we have investigated the Ag doping mechanism as considering the changes of Ag-concentration distribution and optical energy gap ( $E_{op}$ ) with Photon-dose. The "windows" characteristics of Ag thin film occur around the wavelength of 325 nm and the Ag is evaluated to be transparent, without an absorption, in the region. While the $E_{op}$ of S $b_2$ $S_3$ thin film was changed largely by an exposure of HeNe laser(632.8 nm) an exposure of HeCd laser resulted in relatively small variation of $E_{op}$ . Therefore it is thought that photon absorption at the metal layer plays an important role in Ag photodoping.on at the metal layer plays an important role in Ag photodoping.

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