• Bulletin of the Korean Chemical Society
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• v.27 no.10
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• pp.1613-1617
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• 2006

Optimum analytical conditions for cyclic voltammetry (CV) and square wave (SW) stripping voltammetry were determined using mercury-mixed carbon nanotube paste electrode (PE). The results approached the microgram working ranges of SW: 10.0-80.0 $ugL^{-1}$ and CV: 100-700 $ugL^{-1}$ Cd (II); working conditions of 300-Hz frequency, 100 mV amplitude, 1.6 V accumulation potential, 400 sec accumulation time, and 40 mV increment potential. First, analysis was performed through direct assay of cadmium ions deep into the fishs brain core and plant tissue in real time with a preconcentration time of 400 sec. The relative standard deviation of 10.0 $mgL^{-1}$ Cd (II) observed was 0.064 (n = 12) at optimum conditions. The low detection limit (S/N) was set at 0.6 $ugL^{-1}$ ($5.33{\times}10^{-9}$ M). The methods can be used in direct analysis in vivo or in real-time monitoring of plant tissue.

• Transactions on Electrical and Electronic Materials
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• v.17 no.5
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• pp.252-256
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• 2016

This paper deals the study of a linear MHD pump solution used to eliminate and to avoid the dangers of the mercury appearing through pollution and contamination. The formulation of the magnetohydrodynamic phenomena is derived from Maxwell and Navier-Stokes equations are solved using the finite volume method. Simulation results highlight the performance of the pump such as the electromagnetic force, the velocity, and the pressure, the application of Ansys-Fluent software validation these results.

• Analytical Science and Technology
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• v.5 no.1
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• pp.7-15
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• 1992

Germainium(IV) was determined in perchloate supporting electrolyte solution containing phenylfluorone by hanging mercury drop electrode(HMDE) of Linear Sweep Voltammetry(LSV) and in hydrochloric acid solution by UV-VIS Spectrophotometry. The complex germanium(IV) with phenylfluorone was shown linear calibration curve in the range of $2.5{\sim}80{\mu}g/L$ by LSV and in the range of $10{\sim}300{\mu}g/L$ by UV-VIS Spectrophotometry.

• Analytical Science and Technology
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• v.5 no.1
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• pp.17-24
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• 1992

Germanium(IV) was determinated in perchloric acid supporting electrolyte solution containing catechol derivates 3.4-dihydroxy benzoic acid, 3.4-dihydroxy benzaldehyde, adrenaline by hanging mercury electrode(HMDE) of anodic stripping polarography. And then to apply this experimental method for determination of germanium(IV) in natural samples. Germanium(IV) was determinated $300{\mu}g/L$ in ginseng and $210{\mu}g/L$ in mineral water.

• Proceedings of the KIEE Conference
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• 2005.11a
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• pp.119-121
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• 2005

The problem of lamp life have being solved before electrode-less lamps were developed. But, mercury is using till now. So people are concerned about friendly-environmental lamp, and many researcher hardly study it. In this paper, an ICP lamp which is using Xe gas and Ne gas was designed after optical properties were measured and analyzed. As a result, H-mode properties and penning effect properties were known. Also xenon and neon of properties analyze by spectrum.

• Journal of the Korean Chemical Society
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• v.9 no.2
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• pp.71-74
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• 1965

Reduction of Ti(Ⅳ)-oxalate complex on dropping mercury electrode has been studied as a function of oxalate concentration and of pH varied with HCl. Assuming there are equilibrium $TiO(C_2O_4)_2= \;+\;2H^+\;=\;Ti^{+4}\;+\;2C_2O_4\;=\;+\;H_2O,\;K_4$ in addition to $TiO(C_2O_4)_2\;^=\;=\;TiO^{++}\;+\;2C_2O_4=\;K_2\;Ti(C_2O_4)_2\;^-\;=\;Ti^{+3}\;+\;2C_2O_4=\;K_3$ in the system cathodic wave has been well explained for that pH is higher than 0.5. The equilibrium constants $K_2,\;K_3$ and $K_4$ have been to be $2{\times}10^{-12},\;5{\times}10^{-13}$ and $10^{-11}$, respectively. The reduction of Ti(Ⅳ)-oxalate system is $Ti^{+4}\;+\;e\;{\to}\;Ti^{+3}$ in the concentration of hydrochloric acid, higher than 3M.

• Journal of the Korean Chemical Society
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• v.36 no.6
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• pp.889-893
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• 1992

A very sensitive adsorptive stripping voltammetric method is studied on the gallium-morin complex at a hanging mercury drop electrode (HMDE) in 0.1 M acetate buffer solution. The effects of various analytical conditions are discussed on the reduction peak current of the adsorbed complex on the suface of HMDE. Interferences by other trace metals and surfactant are also discussed. Detection limit is 1.7 nM of gallium with 60 seconds deposition time, and the relative standard deviation (n = 7) at 4 ${\mu}$g/l gallium is 2.8%.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.58 no.12
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• pp.2446-2452
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• 2009

A Ceramic Metal-halide lamp is achieved by adding multiple metals to a basic mercury discharge. Because the vapor pressure of most metals is very much lower than mercury itself, metal-halide salts of the desired metals, having higher vapor pressures, are used to introduce the material into the basic discharge. The metal compounds are usually polyatomic iodides, which vaporize and subsequently dissociate as they diffuse into the bulk plasma. Metals with multiple visible transitions are necessary to achieve high photometric efficiency and good color. Compounds of Sc, Dy, Ho, Tm, Ce, Pr, Yb and Nd are commonly used. The maximum visible efficacy of a Ceramic Metal Halide lamp, under the constant of a white light source, is predicted to be about 450lm/W. This is controlled principally by the chemical fill chosen for a particular lamp. Current these lamps achieve 130lm/W and these life time are the maximum 16,000[hr]. So factors of performance lower are necessary to improve lamp performance. In this paper, we analyzed factors of performance lower by accelerated deterioration test. The lamp was operated with short duration turn-on/turn-off procedure to enhance the effect due to electrode sputtering during lamp ignition. The tested lamp that was operated with a longer turn-on/off(20/20 minutes) showed blackening, changed distance between electrodes and lowered color rendering & color temperature by losses of Dy at 421.18nm, I at 511nm, T1 at 535nm and Na at 588nm compared with the new lamp.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2009.10a
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• pp.153-157
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• 2009

A Highly efficient Mercury-free Flat Fluorescent Lamp (MFFL) with dielectric barrier Xe gas discharge was developed for an alternative of conventional line-type Cold Cathode Fluorescent Lamps (CCFLs) which shows a wide voltage margin and a stable discharge operation for diffuse glow discharge with an application of a auxiliary electrode. Electro-optic characteristics of the MFFL were examined through the changes in ambient temperature, total pressure and Xe partial pressure. the single cell is expanded into a multi-structured configuration to realize a large sized lamp by a simple repetition of the single cells, and a new driving scheme is proposed for an adaptive brightness control using dual auxiliary electrodes and bi-polar drive scheme. In addition, interesting application of this ultra high luminance flat lamp by the optimization of the gas condition and the pattern of the rear phosphor layer is suggested as a good alternative of daylight lamp source

• Proceedings of the KIPE Conference
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• 2008.06a
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• pp.553-555
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• 2008

현재 사용하고 있는 LCD(Liquid Crystal Display) Backlight용 램프는 주로 CCFL(Cold Cathod Fluorescent Lamp)과 EEFL(External Electrode Fluorescent Lamp)이 사용되고 있다. 하지만 이 램프는 수은을 사용하여 RoHS(the Restriction of the use of certain Hazardous Substances in electrical and electronic equipment)규제가 점점 강화되면서 사용이 제한되고 있으며, 이에 따라 수은을 사용하지 않는 램프의 제작이 불가피해지고 있다. 또한 LCD TV는 CRT와 PDP와는 다른 LCD만의 Hold-type 특성과 LC(Liquid Crystal)의 응답속도로 인하여 Motion Blur현상이 나타나는 단점이 있다. 본 논문에서는 RoHS 규제를 만족시키는 무수은 면광원 램프를 구동하기 위한 인버터를 제안한다. 제안한 인버터는 포워드 방식을 사용하여 반도체 소자 및 자기 소자의 수를 줄여서 구동회로가 간단하다. 또한 면광원 램프를 세로방향으로 6블록으로 나누어 스캔구동을 하여 Motion Blur현상을 저감 시켰다. 끝으로 실험을 통하여 제안한 인버터의 유용성을 입증하였다.