• 제목/요약/키워드: M.P.S.

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순수 물에서 Sodium Dodecylsulfate(SDS)와 Sodium Dodecylbenzenesulfonate(DBS)의 혼합미셀화에 대한 열역학적 고찰 (Thermodynamics on the Mixed Micellization of Sodium Dodecylsulfate(SDS) with Sodium Dodecylbenzenesulfonate(DBS) in Pure Water)

  • 이병환
    • 대한화학회지
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    • 제40권6호
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    • pp.420-426
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    • 1996
  • 순수 물에서 Sodium dodecylsulfate(SDS)와 Sodium dodecylbenzenesulfonate(DBS)로 구성된 혼합계면활성제의 임계미셀농도(CMC) 및 반대이온의 결합상수(${\beta}$)값을 15$^{\circ}C$에서 35$^{\circ}C$까지의 온도범위에서 전도도법으로 측정하였으며, 측정된 CMC 및 ${\beta}$값의 온도에 따른 변화로부터 SDS/DBS 혼합계면활성제의 미셀화에 대한 여러가지 열역학 함수값(${\Delta}C_p,\;{\Delta}G_m^{\circ},\;{\Delta}H_m^{\circ}$${\Delta}S_m^{\circ}$)들을 계산하였다. 측정한 온도범위 내에서 SDS/DBS 혼합계면활성제의 미셀화로 인한 ${\Delta}G_m^{\circ}$${\Delta}C_p$의 값들은 모두 음의 값을 그리고 ${\Delta}S_m^{\circ}$값은 모두 양의 값을 나타내었다. 이러한 열역학 함수값들의 온도 및 몰분율조성(${\alpha}_{SDS}$)에 따른 변화를 이용하여 SDS/DBS 혼합계면활성제의 미셀화를 분석하였다.

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HYPERSTABILITY OF A SUM FORM FUNCTIONAL EQUATION RELATED DISTANCE MEASURES

  • Lee, Young Whan
    • 충청수학회지
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    • 제33권1호
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    • pp.147-156
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    • 2020
  • The functional equation related to a distance measure f(pr, qs) + f(ps, qr) = M(r, s)f(p, q) + M(p, q)f(r, s) can be generalized a sum form functional equation as follows $${\frac{1}{n}}{\sum\limits_{i=0}^{n-1}}f(P{\cdot}{\sigma}_i(Q))=M(Q)f(P)+M(P)f(Q)$$ where f, g is information measures, P and Q are the set of n-array discrete measure, and σi is a permutation for each i = 0, 1, ⋯, n-1. In this paper, we obtain the hyperstability of the above type functional equation.

내염성 효모의 분리 및 세포외 protease의 생산

  • 정승찬;현광욱;김재호;이종수
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2000년도 추계학술발표대회 및 bio-venture fair
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    • pp.559-562
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    • 2000
  • 내염성이며 세포외 protease를 강력하게 생산하는 효모를 재래식 메주효모들과 자연계에서 분리된 내염성 효모들 가운데서 선별하여 Hansenula sp. S-9으로 동정하였다. S-9균주는 $30^{\circ}C$, pH 7.5, 0.5M NaCl을 함유한 배지에서 잘 생육하였고 1.0% beef extract와 1% glucose 및 0.5M NaCl를 함유한 BD배지에서 $30^{\circ}C$로 72시간 배양하였을 때 가장 많은 효소가 생산되었다.

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Real-Time Implementation of Shunt Active Filter P-Q Control Strategy for Mitigation of Harmonics with Different Fuzzy M.F.s

  • Mikkili, Suresh;Panda, Anup Kumar
    • Journal of Power Electronics
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    • 제12권5호
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    • pp.821-829
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    • 2012
  • This research article presents a novel approach based on an instantaneous active and reactive power component (p-q) theory for generating reference currents for shunt active filter (SHAF). Three-phase reference current waveforms generated by proposed scheme are tracked by the three-phase voltage source converter in a hysteresis band control scheme. The performance of the SHAF using the p-q control strategy has been evaluated under various source conditions. The performance of the proposed control strategy has been evaluated in terms of harmonic mitigation and DC link voltage regulation. In order to maintain DC link voltage constant and to generate the compensating reference currents, we have developed Fuzzy logic controller with different (Trapezoidal, Triangular and Gaussian) fuzzy M.F.s. The proposed SHAF with different fuzzy M.F.s is able to eliminate the uncertainty in the system and SHAF gains outstanding compensation abilities. The detailed simulation results using MATLAB/SIMULINK software are presented to support the feasibility of proposed control strategy. To validate the proposed approach, the system is also implemented on a real time digital simulator and adequate results are reported for its verifications.

Phenylmercuric 8-oxyquinolinate의 합성(合成)과 그 살균효과(殺菌效果)에 대하여 (Studies on the synthesis of phenylmercuric 8-oxyquinolinate and its fungicidal effect)

  • 서용택;손청열;이성환
    • Applied Biological Chemistry
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    • 제6권
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    • pp.37-43
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    • 1965
  • Fusarium 균류(菌類)에 의한 식물병해(植物病害)에 대하여 효과(效果)가 크고 또한 식물(植物)의 기공(氣孔)을 축소(縮少)시켜 수분증산량(水分蒸散量)을 감소(減少)시킨다고 알려진 8-hydroxyquinolinesulfate와 새로운 화합물(化合物)인 phenylmercuric 8-oxyquinolinate를 합성(合成)하여 이들의 살균효과(殺菌效果) 및 증산작용억제(蒸散作用抑制) 여부에 대하여 실험(實驗)하였으며 그 결과(結果)를 요약(要約)하면 다음과 같다. 1) Skraup 합성법(合成法)에 의하여 m.p. $74{\sim}75^{\circ}C$의 침상결정(針狀結晶)인 8-hydroxyquinoline을 합성(合成)하였다. 2) 8-Hydroxyquinoline 과 phenylmercuricacetate를 반응(反應)시켜 m.p. $159{\sim}160^{\circ}C$의 황갈색 침상결정(針狀結晶)인 phenylmercuric 8-oxyquinolinate를 합성(合成)하였다. 3) Phenylmercuric 8-oxyquinolinate의 살균효과(殺菌效果)의 크기순서는 다음과 같다. a) Cochliobolus miyabeanus에 대하여 P.M.A. P.M.A. 4) Phenylmercuric 8-oxyquinolinate 용액(溶液)을 양(陽)이온 교환수지(交換樹脂)인 Amberolite IR-120의 원통(圖筒)에 전개(展開)유출(流出)시킨 결과(結果) 수은(水銀)이온부(部)가 완전히 흡착(吸着)되었다. 5) 국화엽(菊花葉)에다 수분증산억제시험(水分蒸散抑制試驗)을 실험(實驗)한 결과(結果) phenylmercuric 8-oxyquinolinate 20ppm에서 가장 증산억제효과(蒸散抑制效果)가 컸다. 6) 이상의 결과(結果)로서 phenylmercuric 8-oxyquinolinate는 우수한 살균효과(殺菌效果)와 동시(同時)에 植街에 대한 증산억제효과(蒸散抑制效果)를 가지고 있다는 것을 알수 있다.

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Q&P와 AM강의 잔류오스테나이트 분율과 안정도에 따른 인장특성 거동 (Effects of Stability and Volume Fraction of Retained Austenite on the Tensile Properties for Q&P and AM Steels)

  • 변상호;오창석;남대근;김영석;강남현;조경목
    • 한국재료학회지
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    • 제19권6호
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    • pp.305-312
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    • 2009
  • The effects of Quenching and Partitioning (Q&P) and Annealed Martensite (AM) heat treatment on the microstructure and tensile properties were investigated for 0.24C-0.5Si-1.5Mn-1Al steels. The Q&P steels were annealed at a single phase ($\gamma$) or a dual phase (${\gamma}+{\alpha}$), followed by quenching to a temperature between $M_s$ and $M_f$. Then, enriching carbon was conducted to stabilize the austenite through the partitioning, followed by water quenching. The AM steels were intercritically annealed at a dual phase (${\gamma}+{\alpha}$) temperature and austempered at $M_s$ and $M_s{\pm}50^{\circ}C$, followed by cooling in oil quenching. The dual phase Q&P steels showed lower tensile strength and yieldyield strength than those of the single phase Q&P steels, and tThe elongation for the dual phase Q&P steel was partitioning 100s higher than that of that for the single phase Q&P steels as the partitioning time was less than 100s up to partitioning 100s. For AM steels, the tensile/yield strength decreased and the total elongation increased as the austempering temperature increased. The stability of the retained austenite controlled the elongation for Q&P steels and the volume fraction of the retained austenite controlled the elongation for AM steels.

Supported Liquid Membrane을 이용한 Short Peptide의 추출 (Extraction of Short Peptide Using Supported Liquid Membranes)

  • 이재흥;박기문
    • 한국축산식품학회지
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    • 제25권3호
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    • pp.340-343
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    • 2005
  • SLM을 이용한 short peptide의 분리를 목적으로 donor phase의 pH 및 acceptor phase의 염농도, membrane의 carrier 농도 차에 따른 peptide의 이동속도를 확인한 결과는 다음과 같다. 즉, pH 7.0 이하에서는 acceptor phase의 NaCl 농도나 carrier 농도에 상관없이 Gly-Tyr의 이동속도는 거의 영향을 끼치지 않았고, pH 7.0 이상에서는 이동속도가 급격히 증가함을 알 수 있었다. 그리고 Aliquat가 $8\%$ 함유된 D-SLM과 $20\%$ 함유된 H-SLM의 경우 Gly-Tyr의 이동속도는 H-SLM이 D-SLM보다 pH 9.0, 0.25 M NaCl 용액에서는 약 3배, pH 8.0, 1.0 M NaCl용액에서는 10배 정도 빠르게 이동하였다. 또한 H-SLM에서 acceptor phase의 NaCl 농도가 1.0 M 인 경우 0.25 M에 비해 10배 정도 이동속도가 빠른 것으로 나타났다. 따라서, short peptide인 Gly-Tyr의 SLM을 이용한 추출에서 donor phase의 pH 7.0 이상, carrier 농도가 높은 H-SLM 사용, acceptor phase의 염 농도가 높을수록 이동속도가 빠른 것으로 나타났다.

Purification and Characterization of 2,3-Dihydroxybiphenyl 1,2- Dioxygenase from Comamonas sp.

  • Lee Na Ri;Kwon Dae Young;Min Kyung Hee
    • 한국미생물학회:학술대회논문집
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    • 한국미생물학회 2001년도 추계학술대회
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    • pp.16-25
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    • 2001
  • A genomic library of biphenyl-degrading strain Comamonas sp. SMN4 was constructed by using the cosmid vector pWE15 and introduced into Escherichia coli. Of 1,000 recombinant clones tested, two clones that expressed 2,3-dihydroxybiphenyl 1,2-dioxygenase activity were found (named pNB 1 and pNB2). From pNB1 clone, subclone pNA210, demonstrated 2,3-dihydroxybiphenyl 1,2-dioxygenase activity, is isolated. 2,3-Dihydroxybiphenyl 1,2-dioxygenase (23DBDO, BphC) is an extradiol-type dioxygenase that involved in third step of biphenyl degradation pathway. The nucleotide sequence of the Comamonas sp. SMN4 gene bphC, which encodes 23DBDO, was cloned into a plasmid pQE30. The His-tagged 23DBDO produced by a recombinant Escherichia coli, SG 13009 (pREP4)(pNPC), and purified with a Ni-nitrilotriacetic acid resin affinity column using the His-bind Qiagen system. The His-tagged 23DBDO construction was active. SDS-PAGE analysis of the purified active 23DBDO gave a single band of 32 kDa; this is in agreement with the size of the bphC coding region. The 23DBDO exhibited maximum activity at pH 9.0. The CD data for the pHs, showed that this enzyme had a typical a-helical folding structures at neutral pHs ranged from pH 4.5 to pH 9.0. This structure maintained up to pH 10.5. However, this high stable folding strucure was converted to unfolded structure in acidic region (pH 2.5) or in high pH (pH 12.0). The result of CD spectra observed with pH effects on 23DBDO activity, suggested that charge transition by pH change have affected change of conformational structure for 23DBDO catalytic reaction. The $K_m$ for 2,3-dihydroxybiphenyl, 3-metylcatechol, 4-methylcatechol and catechol was 11.7 $\mu$M, 24 $\mu$M, 50 mM and 625 $\mu$M.

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Sample Size Determination for the Estimation of Population Density of Marine Benthos on a Tidal Flat and a Subtidal Area, Korea

  • Koh, Chul-Hwan;Kang, Seong-Gil
    • Journal of the korean society of oceanography
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    • 제33권3호
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    • pp.113-122
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    • 1998
  • The requisite numbers of sample replicates for the population study of soft-bottom benthos were estimated from survey data on the Songdo tidal flat and subtidal zone in Youngil Bay, Korea. Large numbers of samples were taken; two-hundred-fifty 0.02 m$^2$ box corers and fifty 0.1m$^2$ van Veen grabs were taken on the Songdo tidal flat and in Youngil Bay, respectively. The effect of sampler size on sampling efforts was investigated by pooling the unit samples in pairs, fours, eights, etc. The requisite number of sample replicates (n$_r$) was determined by sample variance (s$^2$) and mean (m) function (n$_r$:s$^2$/P$^2$m$^2$), at P=0.2 level, in which s$^2$ and m were calculated from the counts of individuals collected. For example, seven samples of 0.02 m$^2$ corer for the intertidal and two samples of 0.1 m$^2$ van Veen grab for subtidal fauna were required to estimate the total density of community. The smaller sampler size was more efficient than larger ones when sampling costs were compared on the basis of the total sampling area. The requisite number of sample replicates was also predicted ($\^{n}$n$_r$) by substituting $\^{s}$$^2$ obtained from the regression of s$^2$ against m using the Taylor's power law ($\^{s}$$^2$:am$^b$). The regression line of survey data on s$^2$ and m plotted on log scale was well fitted to the Taylor's power law (r$^2$${\geq}$0.95, p<;0.001) over the whole range of m. The exponent b was, however, varied when it was estimated from m which was categorized into classes by its scale. The fitted exponent b was large when both density class and the sampler size were large. The number of sample replicates, therefore, could be more significantly estimated, if regression coefficients (a and b) would be calculated from sample variance and mean categorized into density classes.

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LEAST SQUARES SOLUTIONS OF THE MATRIX EQUATION AXB = D OVER GENERALIZED REFLEXIVE X

  • Yuan, Yongxin
    • Journal of applied mathematics & informatics
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    • 제26권3_4호
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    • pp.471-479
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    • 2008
  • Let $R\;{\in}\;C^{m{\times}m}$ and $S\;{\in}\;C^{n{\times}n}$ be nontrivial unitary involutions, i.e., $R^*\;=\;R\;=\;R^{-1}\;{\neq}\;I_m$ and $S^*\;=\;S\;=\;S^{-1}\;{\neq}\;I_m$. We say that $G\;{\in}\;C^{m{\times}n}$ is a generalized reflexive matrix if RGS = G. The set of all m ${\times}$ n generalized reflexive matrices is denoted by $GRC^{m{\times}n}$. In this paper, an efficient method for the least squares solution $X\;{\in}\;GRC^{m{\times}n}$ of the matrix equation AXB = D with arbitrary coefficient matrices $A\;{\in}\;C^{p{\times}m}$, $B\;{\in}\;C^{n{\times}q}$and the right-hand side $D\;{\in}\;C^{p{\times}q}$ is developed based on the canonical correlation decomposition(CCD) and, an explicit formula for the general solution is presented.

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