• Transactions of the Korean hydrogen and new energy society
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• v.19 no.2
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• pp.103-110
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• 2008

The most failure mode of PEM fuel cell is gas crossover caused by pinhole formation in MEAs. The degradation phenomena of MEA with pinholes were evaluated in various accelerated operation condition, such as OCV, low humidity and high partial pressure of oxygen. The performances of MEA with pinholes were almost same before and after normal 144 hours operation($70^{\circ}C$, $640mA/cm^2$, 65%RH $H_2/air$). The results of accelerated operation showed that OCV and low humidity condition more deteriorated MEA than gas crossover owing to pinholes. When oxygen was used as cathode gas, the pinholes of MEA were enlarged due to heat of combustion reaction on Pt catalyst of electrodes. This combustion reaction occurred at pinholes near gas inlet and resulted in local MEA failure.

• Journal of the Korean Institute of Gas
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• v.27 no.3
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• pp.123-133
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• 2023

Commercial hydrogen fuel cell vehicles are charged by compressing gaseous hydrogen to high pressure and storing it in a storage tank in the vehicle. This process causes the temperature of the gas to rise, to ensure the safety to storage tanks, the temperature is limited. Therefore, a heat transfer model is needed to explain this temperature rise. The heat transfer model includes the convective heat transfer phenomenon, and accurate estimation is required. In this study, the convective heat transfer coefficient in the hydrogen fueling process was calculated and compared using various correlation equations considering physical phenomena. The hydrogen fueling process was classified into the fueling line from the dispenser to the tank inlet and the storage tank in the vehicle, and the convective heat transfer coefficients were estimated according to process parameters such as mass flow rate, diameter, temperature and pressure. As a result, in the case of the inside of the filling line, the convective heat transfer coefficient was about 1000 times larger than that of the inside of the storage tank, and in the case of the outside of the filling line, the convective heat transfer coefficient was about 3 times larger than that of the outside of the storage tank. Finally, as a result of a comprehensive analysis of convective heat transfer coefficients in each process, it was found that outside the storage tank was lowest in the entire hydrogen fueling process, thus dominated the heat transfer phenomenon.

• Journal of the Korean Society of Safety
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• v.19 no.4 s.68
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• pp.150-154
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• 2004

Gas explosion characteristics of hydrogen and liquefied petroleum gas(LPG) were measured in 6L cylindrical vessel, and experiment for explosion to fire transition phenomena of the gases were carried out using the 270L vessel. Explosion characteristics were measured using the stain type pressure transducer and explosion to fire transition phenomena was analyzed with the hish-speed camera. Base on the experiment, it was found that explosion pressure was most high slightly above the stoichiometric concentration, and explosion pressure rise rate and flame propagation velocity were proportional to the combustion velocity. And we find that those kind of explosion characteristics affect the explosion-to-fire transition, in addition, explosion flame temperature, flame residence time, are important parameters in explosion-to-fire transition.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2006.09a
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• pp.3-12
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• 2006

The main feature of these total technologies is that we can constitute the optimum treatment scheme fitting to the property of wastes, amount of wastes and energy requirement. For high moisture content wastes or biomass resources, high pressure steam process (MMCS) for crush, dry and deodorize wastes to produce high quality fertilizer of fuel is most appropriate. For dry or semi-dry solid wastes, the STAR-MEET system can be applied to produce low-BTU gases for power generation using duel fueled diesel engines of Stirling engines, and the REPRES and HyPR-MEET systems can be applied to produce hydrogen rich medium-BTU gas. For waste plastics and oils, liquefaction technology is best fit to produce light oil or kerosene equivalent fuel oils. These total technologies are completely different from the existent waste treatment technologies based on land-filling or incineration, and are expected to disseminate all over the world in the near future.

• Journal of the Korean Institute of Gas
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• v.16 no.6
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• pp.87-101
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• 2012

In gas industries, the potential risks of serious accidents have been increased due to high technology application and process complexities. Especially, in case of gas-related accidents, the extent of demage is out of control since gas plants handle and produce combustible, flammable, explosive and toxic materials in large amounts. The characteristics of this kind of disaster is that accident frequency is low, while the impact of damage is high, extending to the neighboring residents, environment and related industries as well as employees involved. The hydrogen gases treated important things and it used the basic material of chemical plants and industries. Since 2000, this gas stood in the spotlight the substitution energy for reduction of the global warming in particular however it need to compress high pressure(more than 150 bar.g) and store by using the special cylinders due to their low molecular weight. And this gas led to many times the fire and explosion due to leak of it. To reduce these kinds of risks and accidents, it is necessary to improve the new safety management system through a risk management after technically evaluating potential hazards in this process. This study is to carry out the quantitative risk assesment for hydrogen filling plant which are very dangerous(fire and explosive) and using a basic materials of general industries. As a results of this risk assessment, identified the elements important for safety(EIS) and suggested the practical management tools and verified the reliability of this risk assessment model through case study of accident.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2006.05a
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• pp.262-262
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• 2006

The characteristics of Brown gas was experimentally studied in view of efficiency and flame propagation. For this study, the Brown gas stack with 7 cells was manufactured following the Brown gas related patents and reports. All measuring equipments were re-tested and calibrated by Korea Laboratory Accreditation Scheme (KOLAS) certified laboratories. Since the amount of produced gas is most crucial in determining the efficiency, we adopted two gas collecting methods such as bottle trap method and wet gas meter method. The energy efficiency of our own fabricated stack was measured to be 75%, which is comparable to general alkaline water electrolysis efficiency. In order to analyze the flame propagation characteristics of Brown gas, we measured the flame propagation pressure, velocity, and shape by using strain type pressure sensor, optical sensor, and high speed camera in conjunction with Schliren system, respectively. From the experimental results, it was found that the flame propagation behavior of Brown gas was almost the same as that of hydrogen and oxygen mixture gas in 2:1 molar ratio. Moreover, from the high speed camera analysis, we concluded that Brown gas flame exhibits explosion behavior as does mixture gas ($H_{2}:O_{2}=2:1$).

• Transactions of the Korean hydrogen and new energy society
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• v.25 no.1
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• pp.97-104
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• 2014

In a coal gasifier for IGCC, hot syngas leaving the gasifier at about 1550oC is rapidly quenched by cold syngas recycled from the gas cleaning process. This study investigated the flow and heat transfer characteristics in the gas quench system of a commercial IGCC process plant under different operating pressures. As the operating pressure increased from 30 bar to 50 bar, the reduced gas velocity shortened the hot syngas core. The hot fly slag particles were retained within the core more effectively, and the heat transfer became more intensive around the hot gas core under higher pressures. Despite the high particle concentrations, the wall erosion by particle impaction was estimated not significant. However, large particles became more stagnant in the transfer duct due to the reduced gas velocity and drag force under higher pressures.

• Journal of the Korean Institute of Gas
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• v.27 no.4
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• pp.85-91
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• 2023

In this study, an experimental study was conducted on the flame behavior, combustion dynamics, and NOx emission characteristics for hydrogen co-firing with the EV burner which is the first stage combustor of GT24. It was confirmed that as the hydrogen co-firing rate increases, the NOx emission increases. This change was elucidate to be the result of a combination of changes in penetration depth due to changes in fuel density, reduction in fuel mixing due to changes in flame position due to increased flame propagation speed, and oscillation of fuel mixedness due to combustion instability. Through pressurization tests in the range of 1.3 to 3.1 bar, NOx emission characteristics under high-pressure operating conditions were predicted, and based on this, the hydrogen co-firing limits of the EV burner was evaluated.

• Journal of the Korean Institute of Gas
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• v.22 no.6
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• pp.52-58
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• 2018

In reliability based design and assessment (RBDA) methodology, reliability targets are used to ensure that safety levels are met relevant limit states in the stage of design and maintenance. The target reliability for flammable gas pipelines have not been developed yet in Korea. Instead of the reliability targets, the tolerable criteria for risk measures such as societal and individual risk have been applied in pipeline risk management. This paper introduces the procedures to develop the target reliability using tolerable risk criteria for societal and individual risk which can be enforced for high pressure natural gas pipelines in quantitative risk assessment. In addition, we propose the target reliability for natural gas and hydrogen gas transmission pipelines by the procedures.

• Corrosion Science and Technology
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• v.6 no.3
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• pp.112-119
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• 2007

This paper presents the importance of corrosion control and protection technology with a real case study of heater tube rupture damaged by High temperature H2S-H2 corrosion in the refinery. The heater was operated at the Hydrocracking unit and the operation temperature and pressure was $340^{\circ}C$ and $18kg/cm^{3}$ respectively. Top side of the convection tube was thinned by high temperature hydrogen sulfide and hydrogen gas as a uniform corrosion and finally ruptured under operation pressure. Damaged area (Convection tube zone) was blocked by protection wall, so it was impossible to inspect with conventional nondestructive examination. Instead the elbow area which is out of the protection wall was inspected regularly to evaluate the corrosion rate of convection tube indirectly. However the operation temperature and the phase of the process stream was different between inside the chamber and outside the chamber. As a result, it caused severe corrosion to the horizontal convection tube inside the chamber comparing to the elbow outside the chamber. Finally convection tube was corroded more rapidly than the elbow and ruptured after 13 years operation. Because of the rupture, the heater was totally burned and the operation was stopped for 3 months until it has been reconstructed. To prevent this kind of corrosion problem and accident, corrosion control should be strengthened and protection technology should be improved.