• Journal of Energy Engineering
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• v.27 no.4
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• pp.80-85
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• 2018

Usable capacity is one of the most important parameters for evaluating the performance of an adsorbent for $CO_2$ capture from flue gas streams. In the pressure swing adsorption (PSA) process, the usable capacity is calculated as the difference between the quantity adsorbed in flue gas at high pressure (ca. 20 bar) and the quantity adsorbed at lower purge pressure (ca. 2 bar). In this paper, two stereo-types of metal-organic framework (MOF) were evaluated as an promising adsorbent for $CO_2$ capture: flexible structured MOF (MIL-53) and MOF possessing strong binding sites (MOF-74). The results showed that a total $CO_2$ capture capacity is strongly related to the specific surface area and heat of adsorption, revealing high uptake in MOF-74. However, the usable capacity was more pronounced in MIL-53 due to a structural transition.

• Nuclear Engineering and Technology
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• v.56 no.1
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• pp.106-113
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• 2024

Understanding the tritium release and retention behavior of candidate tritium breeder materials is crucial for breeder blanket design. Recently, a melt spraying process was developed to prepare Li₄SiO₄ pebbles, which were subsequently subjected to the in-pile tritium production and extraction platform in China Mianyang Research Reactor (CMRR) to investigate their in-situ tritium release behavior and irradiation performance. The results demonstrate that HT is the main tritium release form, and adding hydrogen to the purge gas reduces tritium retention while increasing the HT percent in the purge gas. Post-irradiation experiments reveal that the irradiated pebbles darken in color and their grains swell, but the mechanical properties remain largely unchanged. It is concluded that the tritium residence time of Li₄SiO₄ made by melt spraying method at 467 ℃ is approximately 23.34 h. High-density Li₄SiO₄ pebbles exhibit tritium release at relatively low temperatures (<600 ℃) that is mainly controlled by bulk diffusion. The diffusion coefficient at 525 ℃ and 550 ℃ is 1.19 × 10^-11 cm²/s and 5.34 × 10^-11 cm²/s, respectively, with corresponding tritium residence times of 21.3 hours and 4.7 hours.

• Journal of the Korean Institute of Gas
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• v.20 no.6
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• pp.37-42
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• 2016

The purpose of this paper is to study for the emission gas control of passenger car. The first example, the PCSV never open when operating condition, but it opened by causing malfunction because of trouble. As a result, the purge gas entered into surge tank, a mount of fuel was displayed with excessive supply on tester. Therefore, it certified the bad-condition of the engine when idling by decreasing of fuel injection quantity from engine ECU. The second example, the hose activating a EGR valve didn't supply the vacuum pressure because of assembling the other part. Thus, it knew the bad-condition of engine that the EGR valve would not work normally by leaking with the other port. The third example, as the rear oxygen sensor of two sensor were fault-installing by changing the sensor of other a car it could not detect of oxygen quantity. Finally, it found the phenomenon of abruptly decreasing vehicle speed when braking a car. Therefore, the system including with emission control has to drastically manage by maximizing condition to role decreasing the emission gas.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.11a
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• pp.130-133
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• 2009

The sequence of the propellant supply is very important for the reliable and safe operation of a LRE combustion test. So combustion performance tests were performed to find an optimum test sequence by changing supply time of propellants and purge gas in the moment of ignition and extinction. The liquid rocket engine consisted of a catalytic ignitor and six swirl-coaxial injectors which used hydrogen peroxide and kerosene. Conclusively, an optimum sequence was found for stable combustion in the moment of ignition and extinction.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2001.04a
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• pp.231-234
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• 2001

OBD-II regulations are already effective in many countries. The California Air Resources Board(CARB) first issued regulations in 1985 for the 1988 model year, known as OBD-I, and required the vehicle's engine management computer to warn the driver by means of a dash-mounted light if a malfunction occurred in either the oxygen sensor, the exhaust gas recirculation(EGR) valve or the evaporative emission system purge solenoid, and to store information on troubles that have no recurrent characteristics. This paper presents two methods of wireless monitoring OBD signal, which is one of the ECU output for self diagnostic measurement. RF module is used to monitor ECU's Self diagnostic signal remotely. Two kinds of measurement systems which are based on micro-controller(80C196KC) for portable detection and PC for sever are considered for receiving the RF signal. Therefore, possibility of real-time monitoring of ECU's self diagnostic signal remotely is verified on this paper.

• Carbon letters
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• v.2 no.1
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• pp.44-54
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• 2001

The characteristics of adsorption and desorption of benzene and toluene were investigated at a fixed bed packed with the activated carbon and activated carbon fiber. Through breakthrough experiments under various feed concentration conditions, it was found that the slope of mass transfer zone and the tailing in the breakthrough curves were different from the feed conditions due to different heats of adsorption. In hot nitrogen desorption, the regeneration time and mass transfer zone of the toluene desorption curve were longer than those of the benzene desorption curve because of the difference in adsorption affinity. With an increase in the regeneration temperature, the height of roll-up and the sharpness of desorption curves increased but the regeneration times decreased. The adsorption capacities of the activated carbon and activated carbon fiber after three-time thermal regenerations decreased about 25% and 37% for benzene and 18% and 25% for toluene, respectively. To investigate the effect of the regeneration temperature on the energetic efficiency, the characteristic desorption temperatures of toluene and benzene were investigated by calculating purge gas consumption and temperature.

• Journal of Environmental Science International
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• v.7 no.5
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• pp.615-622
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• 1998

The volatile organic compounds(VOCs) emitted from raw garlic and Kimchee were analyzed with thermal desorption or purge ＆ trap/gas chromatography/mass selective detection method. Very offensive compounds such as methyl allyl sulfide, dimethyl sulfide, dimethyl disulfide, diallyl sulfide, methyl allyl disulfide, diallyl disulfide and dimethyl trisulfide were detected, and among them, dimethyl disulfide and dimethyl trisulfide were confirmed to be generated during the precocity of Kimchee or emitted from the stuff of Kimchee other than the garlic. Malodorous compounds emitted from the garlic or Kimchee were detected in the breath of a Korean and the refregirator keeping Kimchee. It was confirmed that the disufides emitted from the garlic or Kimchee were major components of offensive odor in the alveolar air and the refregirator. It was clarfied that heat process is very effective to reduce odorous VOCs in garlic or Kimchee.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.234.2-234.2
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• 2014

Organic light emitting diode (OLED) is considered as the next generation flat panel displays due to its advantages of low power consumption, fast response time, broad viewing angle and flexibility. For the flexible application, it is essential to develop thin film encapsulation (TFE) to protect oxidation of organic materials from oxidative species such as oxygen and water vapor [1]. In many TFE research, the inorganic film by atomic layer deposition (ALD) process demonstrated a good barrier property. However, extremely low throughput of ALD process is considered as a major weakness for industrial application. Recently, there has been developed a high throughput ALD, called 'spatial ALD' [2]. In spatial ALD, the precursors and reactant gases are supplied continuously in same chamber, but they are separated physically using a purge gas streams to prevent mixing of the precursors and reactant gases. In this study, the $Al_2O_3$ thin film was deposited by spatial ALD process. We characterized various process variables in the spatial ALD such as temperature, scanning speed, and chemical compositions. Water vapor transmission rate (WVTR) was determined by calcium resistance test and less than $10-^3g/m^2{\cdot}day$ was achieved. The samples were analyzed by x-ray photoelectron spectroscopy (XPS) and field emission scanning electron microscope (FE-SEM).

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.155.2-155.2
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• 2014

Plasma Enhanced Atomic Layer Deposition(PEALD)와 Atomic Layer Deposition(ALD) Techniques는 '정확한 두께 조절' 및 '우수한 균일도'를 가지는 신뢰할 수 있는 진공 기술이다. 본 연구에서는 다공성 구조를 가지는 기판을 대상으로 PEALD와 ALD Techniques을 이용한 $Al_2O_3$ 형성 공정의 증착 특성을 비교하였다. 각 공정은 공통적으로 Tris-Methyl-Aluminium(TMA)을 첫번째 전구체로 사용하였고 purge gas로는 Nitrogen를 사용하였다. 그리고 두번째 전구체로 PEALD 공정에서는 Oxygen Plasma를 사용하였고 ALD 공정에서는 Water를 사용하였다. 복잡한 다공성 구조를 가지는 기판은 $TiO_2$ Nano-Particle paste과 colloidal Silver paste를 소결시켜 제작하여 사용하였다. 각 공정의 차이점을 비교하기 위해서 배기단에 Capacitor Diaphram Gauge(CDG)와 Residual Gas Analyzer(RGA)를 통해서 압력과 잔류 가스를 모니터하였다. 그리고 각 공정을 통해서 porous한 Nano-Particles Network에 형성된 $Al_2O_3$막의 특성을 비교하기 위해서 FE-SEM과 EDX를 통해서 관찰하였다. 또한 좀 더 자세한 비교 분석을 위해서 $Al_2O_3$ 막이 형성된 porous한 Nano-Particles Networks의 각 각의 particles들을 분산시켜 TEM과 AFM를 통해서 관찰하였다. 나아가 전기적 물성의 차이점을 비교하기 위해서 IV 및 CV를 측정하였다. 위의 일련의 비교 실험을 통해서 'PEALD과 ALD을 이용한 다공성 기판의 증착 특성'에 대하여 고찰하였다.

• Food Science of Animal Resources
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• v.21 no.3
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• pp.235-245
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• 2001

This study was conducted to evaluate the usefulness of Second-Heat-Seal film(SHS) as an alternative material to PVDC/EVA shrink film(VSP) being currently used by domestic meat packer for vacuum-packaging of fresh meat. The samples from pork loin and beef striploin and round were stored at 2$^{circ}C$ for 5 weeks and measured for the changes of microbial counts, color, pH, volatile basic nitrogen(VBN), purge loss and sensory parameters. The pork loins packed with SHS showed higher spermine contents during the whole storage period at 2$^{circ}C$, and lower counts in total microbes and lactic acid bacteria after 28 days storage at 2$^{circ}C$ than those packed with SHS tended to be lower than those packed with VSP over the storage time. Nevertheless, no significant differences were observed between two packaging treatments in the other quality parameters evaluated. It is therefore concluded that SHS film might have a possibility to substitute for VSP film for vacuum-packaging of fresh meat at least from a materials point of view.