• 제목/요약/키워드: Fe-Co alloy

검색결과 335건 처리시간 0.024초

Nd 치환 RE-TM 막의 자기 및 자기광학적 특성 (Magnetic and Magneto-optical Characteristics for Nd-RE-TM Amorphous Alloy Films)

  • 이정구;최영준;임은식;이세광;김순광
    • 한국자기학회지
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    • 제4권3호
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    • pp.244-248
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    • 1994
  • NdTbFeCo 합금막 및 NdTbFeCo/TbFeCo 이층막에 대한 자기광학 Kerr 회전각(${\theta}_{k}$)의 파장의존성 및 자기적 특성을 조사하였다. FeCo의 조성을 일정하게 유지하고 NdTbFeCo 합금막에서 Tb의 일부를 Nd로 치환한 결과, Nd 조성이 증가할 수록 400 nm의 파장영역에서 ${\theta}_{k}$는 증대되었으나, 보자력과 각형비가 급격히 감소하였다. NdTbFeCo 막이 단파장에서 큰 ${\theta}_{k}$를 나타냄에도 불구하고 보자력이 작아 단파장용 광자기기록 매체로서 응용가능성이 희박할 것으로 생각되어, 보자력이 큰 TbFeCo 막과 교환결합 이층막을 제작하였다. 제작된 시료중 $Nd_{16.9}Tb_{15.2}Fe_{50.4}Co_{17.5}(150\;{\AA})/Tb_{21.1}Fe_{65.0}Co_{13.9}(300\;{\AA})$ 교환결합 이층막이 6.0 KOe의 보자력과 500 nm에서 $0.32^{\circ}$${\theta}_{k}$를 나타내었다.

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치과보철용 자석재료의 전기화학적 안정성 개선효과 (IMPROVEMENT EFFECTS OF ELECTROCHEMICAL STABILITY OF MAGNETIC MATERIALS FOR PROSTHETIC DENTISTRY)

  • 곽종하;오상호;최한철;정재헌
    • 대한치과보철학회지
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    • 제44권5호
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    • pp.628-641
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    • 2006
  • Statement of problem: Dental magnetic materials have been applied to removable prosthetic appliances, maxillofacial prostheses, obturator and dental implant but they still have some problems such as low corrosion resistance in oral environments. Purpose: To increase the corrosion resistance of dental magnetic materials, surfaces of Sm-Co and Nd-Fe-B based magnetic materials were plated with TiN and sealed with stainless steels. Materials and methods : Surfaces of Sm-Co and Nd-Fe-B based magnetic materials were plated with TiN and sealed with stainless steels, and then three kinds of electrochemical corrosion test were performed in 0.9% NaCl solution; potentiodynamic, potentiostatic, and electrochemical impedance test. From this study, corrosion behavior, amount of elements released, mean average surface roughness values, the changing of retention force, and magnetic force values were measured comparing with control group of non-coated magnetic materials. Results: The values of surface roughness of TiN coated Sm-Co and TiN coated Nd-Fe-B based magnetic materials were lower than those of non coated Sm-Co and Nd-Fe-B alloy. From results of potentiodynamic test, the passive current density of TiN coated Sm-Co alloy were smaller than those of TiN coated Nd-Fe-B alloy and non coated alloys in 0.9% NaCl solution. From results of potentiostatic and electrochemical impedance test, the surface stability of the TiN coated Sm-Co alloy was more drastically increased than that of the TiN coated Nd-Fe-B alloy and non-coated alloy. The retention and magnetic force after and before corrosion test did not change in the case of TiN coated magnetic alloy sealed with stainless steel. Conclusion: It is considered that the corrosion problem and improvement for surface stability of dental magnetic materials could be solved by ion plating with TiN on the surface of dental magnetic materials and by sealing with stainless steels.

스퍼터링 방법으로 성장한 코발트크롬철망간니켈 고엔트로피 질산화물 박막의 구조특성 (Structural Characterization of CoCrFeMnNi High Entropy Alloy Oxynitride Thin Film Grown by Sputtering)

  • 이정국;홍순구
    • 한국재료학회지
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    • 제28권10호
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    • pp.595-600
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    • 2018
  • This study investigates the microstructural properties of CoCrFeMnNi high entropy alloy (HEA) oxynitride thin film. The HEA oxynitride thin film is grown by the magnetron sputtering method using nitrogen and oxygen gases. The grown CoCrFeMnNi HEA film shows a microstructure with nanocrystalline regions of 5~20 nm in the amorphous region, which is confirmed by high-resolution transmission electron microscopy (HR-TEM). From the TEM electron diffraction pattern analysis crystal structure is determined to be a face centered cubic (FCC) structure with a lattice constant of 0.491 nm, which is larger than that of CoCrFeMnNi HEA. The HEA oxynitride film shows a single phase in which constituting elements are distributed homogeneously as confirmed by element mapping using a Cs-corrected scanning TEM (STEM). Mechanical properties of the CoCrFeMnNi HEA oxynitride thin film are addressed by a nano indentation method, and a hardness of 8.13 GPa and a Young's modulus of 157.3 GPa are obtained. The observed high hardness value is thought to be the result of hardening due to the nanocrystalline microstructure.

Texture Study in HDDR-treated Nd-Fe-B-type Particles

  • Kim, Jung-Hwan;Kwon, H.W.
    • Journal of Magnetics
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    • 제10권4호
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    • pp.152-156
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    • 2005
  • Effects of the disproportionating hydrogen pressure and alloy composition on the texture in the HDDR-treated Nd-Fe-B particles were examined using the $Nd_{12.6}Fe_{81.4}B_6$ and $Nd_{12.6}Fe_{68.7}B_6Co_{11.0}Ga_{1.0}Zr_{0.l}$ alloys. Disproportionation kinetics of the $Nd_2Fe_{14}B$ phase in the Nd-Fe-B alloy was retarded significantly by the addition of Co, Ga and Zr. The retarded disproportionation kinetics of the $Nd_2Fe_{14}B$ phase ensured a wider processing win­dow in terms of disproportionating hydrogen pressure for achieving a texture in the HDDR-treated Nd-Fe-B alloy particles.

AIM 및 ESR 법에 의해 제조한 Fe-29Ni-17Co 합금의 조직 및 성질 (Structure and Properties of Fe-29Ni-17Co Alloy Manufactured by Air Induction Melting and Electro-Slag Remelting)

  • 이정근;김문현;주대헌;김명호
    • 한국주조공학회지
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    • 제22권4호
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    • pp.160-166
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    • 2002
  • The structure and properties of Fe-29Ni-17Co alloy which had been melted using induction furnace in air atmosphere and than electroslag-remelted were investigated. The oxygen content was reduced to 0.03% when the ingot was refined from $0.09{\sim}0.12%$ of that air melted. The amounts of spheroidal oxides inclusions and gas porosities of ingot were markedly reduced by the ESR process. CTE of ESR ingot contained small amount of oxides and porosities was found to be lower than that of AIM ingot, and tensile properties of ESR ingot and plate were found to be superior than that of AIM ingot and plate.

고잔류자화 $\alpha$-Fe기 Nd-Fe-B 초미세결정립 합금의 자기특성 (Magnetic Properties of $\alpha$-Fe Based Nd-Fe-B Nanocrystalline with High Remanence)

  • 조용수;김윤배;박우식;김창석;김택기
    • 한국자기학회지
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    • 제5권1호
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    • pp.38-41
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    • 1995
  • $\alpha$-Fe를 주상으로 하는 새로운 Nd-Fe-B계 합금을 개발하기 위하여 Nd 함유량을 4at.%로 고정시킨 Nd-Fe-B 초미세결정립합금의 제조 및 자기특성이 조사되었다. 급속응고법으로 제조된 $Nd_{4}Fe_{85.5}B_{10.5}$ 비정질합금은 결정화하여 $\alpha$-Fe 기지상에 $Nd_{2}Fe_{14}B$이 형성되나 자기특성${_{i}H_{c}=95.5kA/m(1.2kOe),\;Br=1.2T}$은 열화된다. Nb 및 Cu를 첨가한 $Nd_{4}Fe_{82}B_{10}Nb_{3}Cu_{1}$ 합금은 $\alpha$-Fe 결정립미세화(<30nm)로 보자력이 207kA/m(2.6 kOe)로 증가하나 잔류자화는 개선되지 않았다. 이 합금조성에 8at.% Co 첨가는 결정립을 더욱 미세화시키며 자기특성을 개선 시킨다. 최적열처리조건에서 $Nd_{4}Fe_{74}Co_{8}B_{10}Nb_{3}Cu_{1}$ 합금의 잔류자화, 보자력 및 최대에너지적이 각각 1.34 T, 219 kA/m (2.75kOe) 및 $95.5kJ/m^{3}$(12MGOe) 이다.

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Co1-xFex와 Co1-xMnx 강자성 전이 합금 박막의 자기 모멘트와 터널 접합에 의한 스핀 편극치의 상관관계 연구 (The correlation between Spin Polarized Tunneling and Magnetic Moment in Co-Mn and Co-Fe Alloy Films)

  • 최등장;장은영;이년종;김태희
    • 한국자기학회지
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    • 제17권5호
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    • pp.194-197
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    • 2007
  • 극초진공 하에서 제작한 다양한 전이자성합금 박막에 대해 (Co-Fe, Co-Mn) 그 자기적 특성과 함께 Meservey-Tedrow 방식으로 측정한 스핀 편극치를 비교 분석 하였다. 약 20 nm 두께의 제작된 시료들은 표면 효과가 우세하리라는 기대와는 반대로 거의 벌크와 유사한 자기적 특성을 보였다. CoFe 또는 NiFe의 경우와는 달리 CoMn 경우 즉 강자성과 반자성 금속의 합금의 경우, 그 스핀 편극치가 그 자기모멘트에 의존하는 경향을 관찰 하였다. 이는 페르미 에너지 준위에서 터널링 현상에 대해 중요한 역할을 하는 sp-편력전자들과 고립되어 있는 d-전자 간의 교환상호작용(exchange interaction)에 의한 영향으로 이해할 수 있다.

고강도 저열팽창 인바합금에 있어서 CO 첨가의 영향 (Effects of Co Addition in High Strength and Low Thermal Expansion Invar Alloy)

  • 김봉서;조영암;유경재;권해웅;이희웅;김병걸
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 D
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    • pp.1901-1903
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    • 1999
  • To investigate invar alloy as a core material for increased capacity over-head transmission line which have high strength and low thermal expansion coefficient, hardness and thermal expansion coefficient of Fe-Ni-Co alloy have been studied. It is necessary that invar alloy have low thermal expansion coefficient and high strength for increased capacity over-head transmission line. In this paper. we tried to find out the effect of Ni and Co which has ferromagnetic properties and high saturation magnetization. It was found that Ni decrease thermal expansion coefficient and hardness, Co decrease thermal expansion coefficient but increase hardness in Fe-xNi-Co system. In Fe-(29-x)Ni-Co system, the material has no low thermal expansion properties substituting Co instead of Ni in concentration range of $1\sim7$%Co.

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CoFeSiB 아몰퍼스합금 자기리본 변위센서 개발에 관한 연구 (A Study on Development of the Displacement Sensor of CoFeSiB Amorphous Alloy Magnetic Ribbon)

  • 강재덕;신용진
    • 한국전기전자재료학회논문지
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    • 제14권2호
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    • pp.163-168
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    • 2001
  • This dissertation describes the development of a sensor for measuring microscopic displacement where we use CoFeSiB amorphous alloy magnetic ribbon having near zero magnetostrictive properties. For the development of the sensor, we first fabricate amorphous alloy magnetic ribbon, and then investigate its physical and magnetic properties. Finally, its possibility of practical application as a displacement sensor is discussed. The experimental samples were made of near zero magnetostrictive (Co$\_$0.94/Fe$\_$0.06/)$\_$9/Si$_2$B$\_$19/ alloy which were fabricated by a rapid liquid quenching method. As a results, we got amorphous alloy magnetic ribbons of 12㎛ in thickness, 10 mm in length, and 2.5 m in width. It was found that the crystallization temperature and the Curie temperature are around 451$\^{C}$ and around 441$\^{C}$ respectively. We couldn't observe any noticeable change of the impedance frequency of 10MHz, but observed the impedance change of 3.76 %/Oe at 100 MHz. The inductance was nearly stable over the frequency range of 1∼10 MHz, In addition, it was observed that the variation of the inductance and the impedance were linear within the displacement ranges of 20∼60㎛. As the results of the experiments, it is suggested that the displacement sensor which is fabricated by using amorphous alloy magnetic ribbon of (Co$\_$0.04/Fe$\_$0.06/)$\_$79/Si$_2$B$\_$19/ compound, can be used as a sensor to detect microscopic displacement.

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Gd effect on microstructure and properties of the Modified-690 alloy for function structure integrated thermal neutron shielding

  • Cheng Zhang;Jie Pan;Zixie Wang;Zhaoyu Wu;Qiliang Mei;Qianxue Ding;Jing Gao;Xueshan Xiao
    • Nuclear Engineering and Technology
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    • 제55권5호
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    • pp.1541-1558
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    • 2023
  • The new Modified-690Gd alloy, namely as Ni-30Cr-(10-x) Fe-xGd (x = 0.5, 1.0, 1.5,2.0, 3.0 wt%) for function structure integrated thermal neutron shielding has been prepared and characterized. The Modified-690Gd alloy was mainly composed of γ austenite matrix and (Ni, Cr, Fe)5Gd precipitated along grain boundaries. The new Modified-690Gd alloy had great mechanical properties, which had the tensile strength exceeding 620 MPa and the elongation being above 50%. Meanwhile, this alloy had excellent weldability and good corrosion resistance in boric acid. The new Modified-690Gd alloy is expected to be a kind of high efficiency thermal neutron shielding materials.