• Title/Summary/Keyword: Energy transfer process

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A Study on the Electrochemical Synthesis of L-DOPA Using Oxidoreductase Enzymes: Optimization of an Electrochemical Process

  • Rahman, Siti Fauziyah;Gobikrishnan, Sriramulu;Indrawan, Natarianto;Park, Seok-Hwan;Park, Jae-Hee;Min, Kyoungseon;Yoo, Young Je;Park, Don-Hee
    • Journal of Microbiology and Biotechnology
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    • v.22 no.10
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    • pp.1446-1451
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    • 2012
  • Levodopa or L-3,4-dihydroxyphenylalanine (L-DOPA) is the precursor of the neurotransmitter dopamine. L-DOPA is a famous treatment for Parkinson's disease symptoms. In this study, electroenzymatic synthesis of L-DOPA was performed in a three-electrode cell, comprising a Ag/AgCl reference electrode, a platinum wire auxiliary electrode, and a glassy carbon working electrode. L-DOPA had an oxidation peak at 376 mV and a reduction peak at -550 mV. The optimum conditions of pH, temperature, and amount of free tyrosinase enzyme were pH 7, $30^{\circ}C$, and 250 IU, respectively. The kinetic constant of the free tyrosinase enzyme was found for both cresolase and catacholase activity to be 0.25 and 0.4 mM, respectively. A cyclic voltammogram was used to investigate the electron transfer rate constant. The mean heterogeneous electron transfer rate ($k_e$) was $5.8{\times}10^{-4}$ cm/s. The results suggest that the electroenzymatic method could be an alternative way to produce L-DOPA without the use of a reducing agent such as ascorbic acid.

Investigation of Dual-Spin Turn and Attitude Acquisition of Satellite (위성의 Dual-Spin Turn 방법 분석 및 자세획득)

  • Seo, Hyeon-Ho
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.34 no.2
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    • pp.36-47
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    • 2006
  • The process of dual spin turn maneuver is introduced for attitude acquisition or recovery from flat spin state of a satellite. The physical principle of momentum transfer during dual spin turn is explained clearly. The case studies of special dual spin turn, in addition to the conventional dual spin turn, that are known as an acceptable cases, are performed to investigate the principle of dual spin turn and to provide a physical insight as well as the solution of dual spin turn. This study is done based on case-study simulation, which includes two-state control scheme composed of open-loop maneuver and energy dissipation device. Furthermore, we investigate the stability for the verification of all control cases after implementing two-stage control. We also provide the simulation scenario of flat spin recovery using dual spin turn method as an example.

Calibration of cylindrical NaI(Tl) gamma-ray detector intended for truncated conical radioactive source

  • Badawi, Mohamed S.;Thabet, Abouzeid A.
    • Nuclear Engineering and Technology
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    • v.54 no.4
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    • pp.1421-1430
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    • 2022
  • The computation of the solid angle and the detector efficiency is considering to be one of the most important factors during the measuring process for the radioactivity, especially the cylindrical γ-ray NaI(Tl) detectors nowadays have applications in several fields such as industry, hazardous for health, the gamma-ray radiation detectors grow to be the main essential instruments in radiation protection sector. In the present work, a generic numerical simulation method (NSM) for calculating the efficiency of the γ-ray spectrometry setup is established. The formulas are suitable for any type of source-to-detector shape and can be valuable to determine the full-energy peak and the total efficiencies and P/T ratio of cylindrical γ-ray NaI(Tl) detector setup concerning the truncated conical radioactive source. This methodology is based on estimate the path length of γ-ray radiation inside the detector active medium, inside the source itself, and the self-attenuation correction factors, which typically use to correct the sample attenuation of the original geometry source. The calculations can be completed in general by using extra reasonable and complicate analytical and numerical techniques than the standard models; especially the effective solid angle, and the detector efficiency have to be calculated in case of the truncated conical radioactive source studied condition. Moreover, the (NSM) can be used for the straight calculations of the γ-ray detector efficiency after the computation of improvement that need in the case of γ-γ coincidence summing (CS). The (NSM) confirmation of the development created by the efficiency transfer method has been achieved by comparing the results of the measuring truncated conical radioactive source with certified nuclide activities with the γ-ray NaI(Tl) detector, and a good agreement was obtained after corrections of (CS). The methodology can be unlimited to find the theoretical efficiencies and modifications equivalent to any geometry by essential sufficiently the physical selective considered situation.

Development of Program for Ignition Temperature and Its Applications (발화온도 산출 프로그램 개발 및 적용)

  • Park, Won-Hee;Cho, Youngmim;Kwon, Tae-Soom
    • Asia-pacific Journal of Multimedia Services Convergent with Art, Humanities, and Sociology
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    • v.7 no.4
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    • pp.243-250
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    • 2017
  • A fire phenomenon of a solid such as wood involves a phenomenon in which solid is heated from the outside and the gas generated through the thermal pyrolysis process of the material is burnt. The thermal pyrolysis phenomenon of the solid is a phenomenon in which the amount of energy incident from the outside, the amount of heat dissipation of the solid material, the heat transfer between the solid material and the surroundings including the amount of heat transfer to the air adjacent to the solid surface, and the fraction of oxygen in the air. In this paper, we calculate the required ignition temperature to simulate the fire phenomenon as simple as possible. By using cone calorimeter, the ignition time was measured by variously controlling the heat flux flowing into the wood specimen by using various wood specimens. The user friendly program is developed for calculation of the ignition temperature. Five different woods such as low density MDF, high density MDF, plywood, douglas fir and PB with various thickness are considered. The ignition temperatures suggested in this paper can be used for fire propagation analysis for woods.

A Study on the Energy Efficient Data Aggregation Method for the Customized Application of Underwater Wireless Sensor Networks (특정 응용을 위한 수중센서네트워크에서 에너지 효율적인 데이터통합 방법 연구)

  • Kim, Sung-Un;Park, Seon-Yeong;Yu, Hyung-Cik
    • Journal of Korea Multimedia Society
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    • v.14 no.11
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    • pp.1438-1449
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    • 2011
  • UWSNs(Underwater Wireless Sensor Networks) need effective modeling fitted to the customized type of application and its covering area. In particular it requires an energy efficient data aggregation method for such customized application. In this paper, we envisage the application oriented model for monitoring the pollution or intrusion detection over a given underwater area. The suggested model is based on the honeycomb array of hexagonal prisms. In this model, the purpose of data aggregation is that the head node of each layer(cluster) receives just one event data arrived firstly and transfer this and its position data to the base station effectively in the manner of energy efficiency and simplicity without duplication. Here if we apply the existent data aggregation methods to this kind of application, the result is far from energy efficiency due to the complexity of the data aggregation process based on the shortest path or multicast tree. In this paper we propose three energy efficient and simple data aggregation methods in the domain of cluster and three in the domain of inter-cluster respectively. Based on the comparative performance analysis of the possible combination pairs in the two domains, we derive the best energy efficient data aggregation method for the suggested application.

Mass Transfer Characteristics during the Osmotic Dehydration Process of Apples (사과의 삼투건조시 물질이동 특성)

  • 윤광섭;최용희
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.25 no.5
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    • pp.824-830
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    • 1996
  • In order to minimize the deterioration of osmotic dried apple quality, the characteristics of mass transfer during osmotic dehydration such as solid gain(SG), weight reduction(WR) and moisture loss(ML) were investigated. Moisture and solid transfer were analyzed by Fick's law. The highest (equation omitted)E value was observed with severe browning at $60^{\circ}C.$ The concentration effect on (equation omitted)E were higher at high temperatures than at low temperatures. SG, WR and ML increased as immersion temperature, sugar concentration and immersion time increased. Higher concentration of sucrose led to more sucrose absorption resulting increase in SG. Diffusion coefficients of moisture increased with immersion temperature and sugar concentration. As concentration increased, diffusion coefficients of solids increased at $20^{\circ}C$ while it decreased at $40^{\circ}C$ and $60^{\circ}C.$ Arrhenius equation was appropriately explain the effect of temperature on diffusion coefficients. Moisture and solid diffusion showed high activation energy in 20 。Brix solution, compared with in 40 and 60 。Brix.

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Effect of Process Gas and Burner Gas Temperature on Reaction and Thermal Deformation Characteristics in a Steam Reformer (증기 개질기의 반응 및 열변형 특성에 미치는 공정가스와 버너가스 온도의 영향)

  • Han, Jun Hee;Kim, Ji Yoon;Lee, Jung Hee;Lee, Seong Hyuk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.9
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    • pp.126-132
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    • 2016
  • This study numerically investigates the characteristics of chemical reactions and thermal deformation in a steam reformer. These phenomena are significantly affected by the high-temperature burner gas and the process gas conditions. Because the high temperature of the burner gas ranges from 800 to 1000 K, the reformer tubes undergo substantial thermal deformation, eventually resulting in structural failure. Thus, it is necessary to understand the characteristics of the reaction and thermal deformation under the operating conditions to evaluate the reformer tubes for sustainable, stable operation. Extensive numerical simulations were carried out using commercial CFD code (ANSYS FLUENT/MECHANICA Ver. 13.0) while considering three-dimensional turbulent flows and combined heat transfer including conduction, convection, and radiation. Structural analysis considering conjugated heat transfer between solid tubes and fluid flows was conducted using the Fluid-Solid Interaction (FSI) method. The results show that when the injection temperature of the process gas and burner gas decreased, the hydrogen production rate decreased significantly, and thermal deformation decreased by at least 15 to 20%.

Research and Development Trend of Carrier Selective Energy Contact Solar Cells (전하선택형 태양전지의 연구개발 동향)

  • Cho, Eun-Chel;Cho, Young Hyun;Yi, Junsin
    • Current Photovoltaic Research
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    • v.6 no.2
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    • pp.43-48
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    • 2018
  • The traditional silicon heterojunction solar cells consist of intrinsic amorphous silicon to prevent recombination of the silicon surface and doped amorphous silicon to transport the photo-generated electrons and holes to the electrode. Back contact solar cells with silicon heterojunction exhibit very high open-circuit voltages, but the complexity of the process due to form the emitter and base at the backside must be addressed. In order to solve this problem, the structure, manufacturing method, and new materials enabling the carrier selective contact (CSC) solar cell capable of achieving high efficiency without using a complicated structure have recently been actively developed. CSC solar cells minimize carrier recombination on metal contacts and effectively transfer charge. The CSC structure allows very low levels of recombination current (eg, Jo < 9fA/cm2), thereby achieves high open-circuit voltage and high efficiency. This paper summarizes the core technology of CSC solar cell, which has been spotlighted as the next generation technology, and is aiming to speed up the research and development in this field.

Preparation of Porous TiO2 Thin Films by Poly(vinyl chloride)-graft-poly(N-vinyl pyrrolidone) and Their Applications to Dye-sensitized Solar Cells

  • Yeon, Seung-Hyeon;Patel, Rajkumar;Koh, Jong-Kwan;Ahn, Sung-Hoon;Kim, Jong-Hak
    • Journal of the Korean Electrochemical Society
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    • v.14 no.2
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    • pp.83-91
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    • 2011
  • Mesoporous titanium dioxide ($TiO_2$) thin films were prepared using poly(vinyl chloride)-graft-poly(N-vinyl pyrrolidone) (PVC-g-PVP) as a templating agent via sol-gel process. Grafting of PVC chains from PVC backbone was done by atom transfer radical polymerization (ATRP) technique. The successful grafting of PVP to synthesize PVC-g-PVP was checked by fourier-transform infrared spectroscopy (FT-IR) and gel permeation chromatography (GPC). The carbonyl group interaction of PVC-g-PVP graft copolymer with $TiO_2$ was confirmed by FT-IR. The porous morphologies of the $TiO_2$ films genereated after calcination at $450^{\circ}C$ was characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The mesoporous $TiO_2$ films with 580 nm in thickness were used as a photoelectrode for solid state dye sensitized solar cell (DSSC) and showed an energy conversion efficiency of 1.05% at 100 $mW/cm^2$.

Unsteady Analysis of the Conduction-Dominated Three-Dimensional Close-Contact Melting (열전도가 주도적인 삼차원 접촉융해에 대한 비정상 해석)

  • Yoo, Hoseon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.8
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    • pp.945-956
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    • 1999
  • This work reports a set of approximate analytical solutions describing the initial transient process of close-contact melting between a rectangular parallelepiped solid and a flat plate on which either constant temperature or constant heat flux is imposed. Not only relative motion of the solid block tangential to the heating plate, but also the density difference between the solid and liquid phase is incorporated in the model. The thin film approximation reduces the force balance between the solid weight and liquid pressure, and the energy balance at the melting front into a simultaneous ordinary differential equation system. The normalized model equations admit compactly expressed analytical solutions which include the already approved two-dimensional solutions as a subset. In particular, the normalized liquid film thickness is independent of all pertinent parameters, thereby facilitating to define the transition period of close-contact melting. A unique behavior of the solid descending velocity due to the density difference is also resolved by the present solution. A new geometric function which alone represents the three-dimensional effect is introduced, and its properties are clarified. One of the representative results is that heat transfer is at least enhanced at the expense of the increase in friction as the cross-sectional shape deviates from the square under the same contact area.