• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.5-5
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• 2011

The research and development of hybrid electric vehicle (HEV), plug-in hybrid electric vehicle (PHEV) and electric vehicle (EV) are intensified due to the energy crisis and environmental concerns. In order to meet the challenging requirements of powering HEV, PHEV and EV, the current lithium battery technology needs to be significantly improved in terms of the cost, safety, power and energy density, as well as the calendar and cycle life. One new technology being developed is the utilization of composite cathode by mixing two different types of insertion compounds [e.g., spinel $LiMn_2O_4$ and layered $LiMO_2$ (M=Ni, Co, and Mn)]. Recently, some studies on mixing two different types of cathode materials to make a composite cathode have been reported, which were aimed at reducing cost and improving self-discharge. Numata et al. reported that when stored in a sealed can together with electrolyte at $80^{\circ}C$ for 10 days, the concentrations of both HF and $Mn^{2+}$ were lower in the can containing $LiMn_2O_4$ blended with $LiNi_{0.8}Co_{0.2}O_2$ than that containing $LiMn_2O_4$ only. That reports clearly showed that this blending technique can prevent the decline in capacity caused by cycling or storage at elevated temperatures. However, not much work has been reported on the charge-discharge characteristics and related structural phase transitions for these composite cathodes. In this presentation, we will report our in situ x-ray diffraction studies on this mixed composite cathode material during charge-discharge cycling. The mixed cathodes were incorporated into in situ XRD cells with a Li foil anode, a Celgard separator, and a 1M $LiPF_6$ electrolyte in a 1 : 1 EC : DMC solvent (LP 30 from EM Industries, Inc.). For in situ XRD cell, Mylar windows were used as has been described in detail elsewhere. All of these in situ XRD spectra were collected on beam line X18A at National Synchrotron Light Source (NSLS) at Brookhaven National Laboratory using two different detectors. One is a conventional scintillation detector with data collection at 0.02 degree in two theta angle for each step. The other is a wide angle position sensitive detector (PSD). The wavelengths used were 1.1950 ${\AA}$ for the scintillation detector and 0.9999 A for the PSD. The newly installed PSD at beam line X18A of NSLS can collect XRD patterns as short as a few minutes covering $90^{\circ}$ of two theta angles simultaneously with good signal to noise ratio. It significantly reduced the data collection time for each scan, giving us a great advantage in studying the phase transition in real time. The two theta angles of all the XRD spectra presented in this paper have been recalculated and converted to corresponding angles for ${\lambda}=1.54\;{\AA}$, which is the wavelength of conventional x-ray tube source with Cu-$k{\alpha}$ radiation, for easy comparison with data in other literatures. The structural changes of the composite cathode made by mixing spinel $LiMn_2O_4$ and layered $Li-Ni_{1/3}Co_{1/3}Mn_{1/3}O_2$ in 1 : 1 wt% in both Li-half and Li-ion cells during charge/discharge are studied by in situ XRD. During the first charge up to ~5.2 V vs. $Li/Li^+$, the in situ XRD spectra for the composite cathode in the Li-half cell track the structural changes of each component. At the early stage of charge, the lithium extraction takes place in the $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ component only. When the cell voltage reaches at ~4.0 V vs. $Li/Li^+$, lithium extraction from the spinel $LiMn_2O_4$ component starts and becomes the major contributor for the cell capacity due to the higher rate capability of $LiMn_2O_4$. When the voltage passed 4.3 V, the major structural changes are from the $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ component, while the $LiMn_2O_4$ component is almost unchanged. In the Li-ion cell using a MCMB anode and a composite cathode cycled between 2.5 V and 4.2 V, the structural changes are dominated by the spinel $LiMn_2O_4$ component, with much less changes in the layered $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ component, comparing with the Li-half cell results. These results give us valuable information about the structural changes relating to the contributions of each individual component to the cell capacity at certain charge/discharge state, which are helpful in designing and optimizing the composite cathode using spinel- and layered-type materials for Li-ion battery research. More detailed discussion will be presented at the meeting.

• Journal of Korea Society of Industrial Information Systems
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• v.29 no.1
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• pp.31-48
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• 2024

The domestic automotive industry must consider a strategic shift from traditional automotive component manufacturing to align with future trends such as connectivity, autonomous driving, sharing, and electrification. This research conducted topic modeling on R&D projects in the future automotive sector funded by the Ministry of Trade, Industry, and Energy from 2013 to 2021. We found that topics such as sensors, communication, driver assistance technology, and battery and power technology remained consistently prominent throughout the entire period. Conversely, topics like high-strength lightweight chassis were observed only in the first period, while topics like AI, big data, and hydrogen fuel cells gained increasing importance in the second and third periods. Furthermore, this research analyzed the areas of concentrated investment for each period based on topic-specific government investment amounts and investment growth rates.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.20 no.12
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• pp.2235-2242
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• 2016

The electric power system based on fuel cell is applied in various forms to the ship and offshore plants. In particular, a research on the hybrid power system of the fuel cell combined with battery in connection topology has been researched actively. Fuel cell-based hybrid ship has not been carried out research, it is not carried out research in the integrated monitoring system. In this paper, we developed an integrated monitoring system to increase the convenience and stability for the hybrid fuel-cell ship operator. Research into integrated monitoring system based on GUI (Graphic User Interface), in consideration of the stability of the user convenience and ship operations, and developed communication and hardwired signal with the main equipment of the ship, to see in realtime state of the ship. The collected ship operation data is stored and it can be seen after the ship operating.

• Journal of the Korean Society of Industry Convergence
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• v.27 no.1
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• pp.63-70
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• 2024

Lithium-ion batteries (LIB) are widely used in various sectors, such as transportation (e.g., electric vehicles (EV)) and energy (e.g., energy storage facilities) due to their high energy density, broad operating temperature (-20 ℃ ~ 60 ℃), and high capacities. LIBs are powerful but fragile on external factors, including pressure, physical damage, overheating, and overcharging, that cause thermal runaway causing fires and explosions. During a LIB fire, a large amount of oxygen is generated from the decomposition of ionogenic materials. A water fire extinguisher that helps with cooling and suffocating must be essentially required at the same time. In fact, however, it is difficult to suppress LIB fires in the case of EVs because a LIB is installed with a battery pack housing that interrupts direct extinguishing by water. Thus, this study aims to investigate effective fire extinguishing measurements for LIB fires by using an EV. Relevant documents, including research articles and reports, were reviewed to identify effective ways of LIBs fire extinguishing. A real-scale fire experiment generating thermal runaway was carried out to figure out the combustion characteristics of EVs. This study revealed that the most effective fire extinguishing measurements for LIB fires are applying fire blankets and water tanks. However, there is still a lack of adequate regulation and guidelines for LIB fire extinguishment. Taking this into account, developing functional fire extinguishment measurements and available regulatory instruments is an urgent issue to secure the safety of firefighters and citizens.

• Journal of the Korea Organic Resources Recycling Association
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• v.30 no.4
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• pp.59-66
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• 2022

Lithium-ion batteries have greatly expanded along with the mobile phone market, and as the electric vehicle business is activated in earnest, they will attract many people's attention even afterwards. Until now, many people have attracted attention to the recovery of valuable metals inside lithium-ion batteries, but graphite, which is mainly used as an anode material, is also worth recycling. Therefore, in order to recover graphite with high purity and valuable metals, graphite that can be used as an anode material of a secondary battery may be generated again through a regeneration process of purifying and separating graphite from a waste lithium-ion battery and recovering electrical characteristics of graphite. This paper describes the process of converting waste graphite into regenerated graphite and the environmental and economic effects of regenerated graphite.

• Economic and Environmental Geology
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• v.55 no.6
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• pp.661-669
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• 2022

The need for miniaturization, high efficiency, and green energy resources as an energy storage device through the development of various electronic device has emerged. Accordingly, nanomaterials with excellent electrochemical properties, such as graphene and graphene hybrids, are attracting attention as promising materials. In particular, in the electric vehicle industry, cost reduction of secondary batteries is a key factor that can determine the spread of related industries, and it is most important to analyze R&D trends for battery material technology and respond to future technological development directions. Therefore, in this study, we tried to suggest a direction for R&D activities in the future by analyzing patent trends for graphene anode material technology for secondary batteries and deriving implications. As a result, in the case of anode material technology, the proportion of foreigners in the US and European patent markets was higher than in the Korean and Japanese patent markets, which means that the US and European marketability is high. In addition, Japanese applicants are filing high-level applications not only in the Japanese patent market but also in other countries suggests that Japan is leading the technology in this field. Lastly, the proportion of research institutes in the patent market of Korea and the US remains high compared to that of Japan and Europe, indicating that the commercialization of technology is still slow in those countries. Therefore research institutes and companies in Korea will have to establish their own strategies for developing and securing materials using the results of patent trends in major countries and major companies analyzed in this study.

• Journal of Digital Convergence
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• v.12 no.11
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• pp.289-298
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• 2014

Recently, the traditional paradigm in railroad technology is changing as more efficient and cost-effective electric vehicle (EV) technologies have emerged. The original concept of PRT (Personal Rapid Transit) proposed in the past has come to be regarded as unrealistic, but its feasibility is improving through the utilization of an EV platform. In particular, battery-powered vehicles pose difficult technical challenges in attempts to achieve reliable and efficient operation. However, based on the inductive power transfer (IPT) technology, the fast charging of supercapacitors with high energy density can contribute to overcoming this technical challenge and promote the transition to electric-powered ground transportation by improving the appearance of cities. This study discusses the development process of a power supply system for PRT, including concept design, numerical analysis, and device manufacturing, along with performance predictions and evaluations. In terms of results, the system was found to meet the performance requirements for power supply modules on a test-bed.

• Transactions of the Korean Society of Automotive Engineers
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• v.20 no.6
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• pp.46-51
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• 2012

Fuel Cell Hybrid Vehicles (FCHVs) have become a major topic of interest in the automotive industry owing to recent energy supply and environmental problems. Several types of power management strategies have been developed to improve the fuel economy of FCHVs including optimal control strategy based on optimal control theory, rule-based strategy, and equivalent consumption minimization strategy (ECMS). The ECMS is applied in this study. This strategy is based on the heuristic concept that the usage of the electric energy can be exchanged to equivalent fuel consumption. This strategy is known as one of the promising solutions for real-time control of hybrid vehicles. The ECMS for an FCHV is introduced in this paper as well as the equivalent fuel consumption parameter. The relationship between the battery final state of charge (SOC) and the fuel consumption while changing the equivalent fuel consumption parameter is obtained for three different driving cycles. The function of the equivalent fuel consumption parameter is also discussed.

• The Journal of the Korea institute of electronic communication sciences
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• v.5 no.6
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• pp.575-580
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• 2010

The research which sees the wild animals back with the system for the penetration prevention, when the wild animals approaches with the infrared ray sensor which composes a proposed system to use radiation department and the solar heat which occur and to make lead in the spiral which informs a guard to application of power department and back the edge where uses the battery of the application of power department which supplies all the member and the outside minute electric current to do in order to maximize a warning utterance or a luminous effect, an utterance department and the light for a prevention and about the system which restrains the wild animals is a thing. The proposed system which sees the express highway and the national road, with region degree establishes back the same wild animals appears and disappears frequently a day and night and between in circumference and goes without question appears and disappears the penetration of the wild animals which prevents and the animal the vehicle and prevents the damage which collides, joins in and driver and is the ecosystem of natural environment protects preserves.

• Journal of IKEEE
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• v.22 no.3
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• pp.630-637
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• 2018

To supply a high voltage to an inverter, a motor control unit (MCU) generally employs a front-end boost converter. Because it generates a high output voltage, the converter needs an output capacitor, which has a high working voltage resulted in cost increasing. To solve this problem, we present a bidirectional dc-to-dc converter, which can decrease a working voltage of the output capacitor. Basic characteristic of the proposed converter is similar to a conventional boost converter. A difference comes from the structure of the output terminal connecting an output capacitor and an input battery in series. Owing to this circuit configuration, the working voltage of the output capacitor becomes lower than that of a conventional boost converter. After theoretical analysis, we carry out simulations and experiments to verify the validity and performance comparing with a conventional boost converter.