• 제목/요약/키워드: Degradation rate

검색결과 2,410건 처리시간 0.033초

역상마이셀에 의한 나노크기 이산화티탄의 제조 및 브로메이트 광분해 특성 (A Photocatalytic Degradation of Bromate over Nanosized Titanium Dioxide Prepared by Reverse Micelle)

  • 이만식;홍성수;박홍재;정영언;박원우
    • 한국환경과학회지
    • /
    • 제11권9호
    • /
    • pp.987-992
    • /
    • 2002
  • Nanosized titania sol has been produced by the controlled hydrolysis of titanium tetraisopropoxide(TTIP) in sodium bis(2-ethylhexyl)sulfosuccinate(AOT) reverse micelles. The physical properties, such as crystallite size and crystallinity according to R ratio have been investigated by FT-IR, XRD and UV-DRS. In addition, the photocatalytic degradation of bromate has been studied by using batch reactor in the presence of UV light in order to compare the photocatalytic activity of prepared nanosized titania. It is shown that the anatase structure appears in the 300~$600^{\circ}C$ calcination temperature range and the formation of anatase into rutile starts above $700^{\circ}C$. The crystallite size increases with increasing R ratio. In the photocatalytic degradation of bromate, the photocatalytic decomposition of bromate shows the decomposition rate increases with decreasing initial concentration of bromate and with increasing intensity of light.

Characteristics of Nitrobenzene Degradation by Mycobacterium chelonae Strain NB01

  • Oh, Young-Sook;Lee, Youn-Hee;Lee, Jung-Hyun;Choi, Sung-Chan
    • Journal of Microbiology and Biotechnology
    • /
    • 제13권2호
    • /
    • pp.309-312
    • /
    • 2003
  • A bacterial strain NB01, isolated from wastewater, was found to utilize nitrobenzene (NB) as the sole source of nitrogen, carbon, and energy. The strain was classified as a member of a high G+C Gram-positive group and identified as Mycobacterium chelonae based on an analysis of its 16S rRNA gene sequence. The strain grew on NB with a concomitant release of about 63% of the total available nitrogen as ammonia, suggesting a reductive degradation mechanism. The optimal pH and temperature for degradation were PH 7.0-8.0 and $30^{\circ}C$, respectively. The cell growth was retarded at NB concentrations above 1.8 mM. The degradation of NB followed Michaelis-Menten kinetics within the tolerance range, and the $K_m$ and maximum specific removal rate for NB were 0.33 mM and $11.04\;h^{-1}$, respectively.

활성슬러지 고정화 비드를 이용한 페놀 분해에 관한 연구

  • 김선일
    • 한국생물공학회:학술대회논문집
    • /
    • 한국생물공학회 2002년도 생물공학의 동향 (X)
    • /
    • pp.431-434
    • /
    • 2002
  • 단일균이나 활성슬러지를 이용하여 폐수를 처리하고자 할 때 폐수의 pH 가 단일균이나 활성 슬러지의 최적 pH 에 적합하지 아니한 경우에는 미생물을 고정화하여 희망하는 pH에서 최대의 분해활성을 나타내도록 최적 pH를 어느정도 변화시킬 수 있으며, 기존의 활성슬러지법 보다는 활성 슬러지를 고정화하여 처리하는 것이 높은 부하에서도 제거 효율이 높기 때문에 반응조의 콤펙트화가 가능할 것으로 사료된다.

  • PDF

Application of Vegetation Indices for Forest Degradation Using Landsat TM Data

  • Kim, Choen;Joung, Khang-Ho
    • 대한원격탐사학회:학술대회논문집
    • /
    • 대한원격탐사학회 1998년도 Proceedings of International Symposium on Remote Sensing
    • /
    • pp.192-197
    • /
    • 1998
  • This paper demonstrates that it is feasible to evaluate forest degradation and to detect deforestation in the 8156$km^2$ study area affected by expand farming using vegetation indices derived from Landsat TM data. The NDVI-growing stock relation was applied on th Landsat TM data and a 3 second grid DEM, whose coverages could improve the assessment of forest degradation and also estimate the rate of change of forest cover area depending on elevation intervals. The strength of the relationship between the ratio of the greenness and brightness indices and forest degradation conditions would have been more interesting in the deforested areas which were converted to crop farming land.

  • PDF

Hot-carrier 효과로 인한 MOSFET의 성능저하 및 동작수명 측정 (Hot-carrier Induced MOSFET Degradation and its Lifetime Measurement)

  • 김천수;김광수;김여환;김보우;이진효
    • 대한전자공학회논문지
    • /
    • 제25권2호
    • /
    • pp.182-187
    • /
    • 1988
  • Hot carrier induced device degradation characteristics under DC bias stress have been investigated in n-MOSFETs with channel length of 1.2,1.8 um, and compared with those of LDD structure device with same channel length. Based on these results, the device lifetime in normal operating bias(Vgs=Vds=5V) is evaluated. The lifetimes of conventional and LDD n-MOSFET with channel length of 1.2 um are estimated about for 17 days and for 12 years, respectively. The degradation rate of LDD n-MOSFET under the same stress is the lowest at n-region implnatation dose of 2.5E15 cm-\ulcorner while the substrate current is the lowest at the dose of 1E13cm-\ulcorner Thses results show that the device degradation characteristics are basic measurement parameter to find optimum process conditions in LDD devices and evaluate a reliability of sub-micron device.

  • PDF

디젤오염 지하수 정화를 위한 공기주입정화법 칼럼 실험 (Bio Sparging Column Experiment for Remediation of Diesel Contaminated Groundwater)

  • 장순웅;이시진;송정훈;권수열
    • 한국환경과학회지
    • /
    • 제13권12호
    • /
    • pp.1059-1065
    • /
    • 2004
  • Bio sparging experiments were conducted in a laboratory column to investigate the potential removal of diesel contaminated groundwater. The objectives in this study were (a) to determine the extent of diesel degradation in laboratory columns under supplement of nutrient; (b) to determine the effect of variation of air flow in the removal of diesel and (c) to evaluate the potential enhancement of diesel degradation as a function of temperature. Our results showed that the nutrient supplement and higher air flow greatly enhanced diesel degradation. However, the variation of water temperature examined slightly increased degradation rate of diesel fuel.

Impact of Dissolved Wastewater Constituents on Laccase-Catalyzed Treatment of Bisphenol A

  • Kim, Young-Jin
    • 한국환경보건학회지
    • /
    • 제30권2호
    • /
    • pp.161-166
    • /
    • 2004
  • The impact of dissolved wastewater constituents on the treatment of synthetic bisphenol A (BPA) solutions was investigated under a variety of reaction conditions. The laccase enzyme from Trametes vesicolor was used for the BPA treatment. The constituents studied included various inorganic salts, organic compounds and heavy metal ions. BPA degradation was inhibited by sulfate, thiosulfate, sulfide, nitrite, and cyanide ions at 25 mg/$\ell$, 100mg/$\ell$, 25 mg/$\ell$ 150 mg/$\ell$, and 2.5 mg/$\ell$, respectively. However, the inhibitive effects of sulfide and sulfite on BPA degradation were diminished by additional aeration to oxidize them. Formaldehyde significantly reduced the rate of BPA degradation at 1.0% among organic compounds studied. Among heavy metal ions tested, Fe(II) substantially suppressed BPA removal at 1 mM. MgCl$_2$ and CaCl$_2$ exhibited great inhibition of BPA degradation at 25mM.

Te-Se 칼코게나이드박막의 열화에 관한 연구 (A study on the degradation of Te-Se chalcogenide thin films)

  • 정홍배;이영종;김영호;이중기;송준석
    • E2M - 전기 전자와 첨단 소재
    • /
    • 제1권1호
    • /
    • pp.62-69
    • /
    • 1988
  • Te-thin films were highly proper material for optical recording media, but has the demerit of short archival life time due to the unstability to humidity. In order to restrain the degradation, Te$_{100-x}$Se$_{x}$ alloys adding Se stable for the humidity were fabricated. Primarily, to measure the degradation rate with varing the composition of Se to x=5, 10, 14, 25 at.% at Te$_{100-x}$ Se$_{x}$, the change of light transmittance was used in various temperature-humidity environments. As the results, it was showed that Se$_{86}$Te$_{14}$ thin was the most proper composition for the improvement of degradation restraint.int.int.

  • PDF

변성기의 몰딩 재료용 에폭시복합체의 열화 특성 (The Characteristics of Degradation in Epoxy Composites for Molding Materials of PT)

  • 박건호
    • 한국컴퓨터정보학회:학술대회논문집
    • /
    • 한국컴퓨터정보학회 2011년도 제44차 하계학술발표논문집 19권2호
    • /
    • pp.351-354
    • /
    • 2011
  • The electrical degradation phenomena of epoxy composites to be used as a molding material for transformers were studied. The electrets were first manufactured by applying high voltages to five kinds of specimens given a mixing rate, and then TSC(Thermally Stimulated Current) values at the temperature range of $-160{\sim}200[^{\circ}C]$ were measured from a series of experiments. The behaviour of carrier and its origin in epoxy composites were examined, respectively. And various effects of electrical degradation on epoxy composites were also discussed in this study.

  • PDF

Ultrasonic Degradation of Endocrine Disrupting Compounds in Seawater and Brackish Water

  • Park, So-Young;Park, Jong-Sung;Lee, Ha-Yoon;Heo, Ji-Yong;Yoon, Yeo-Min;Choi, Kyung-Ho;Her, Nam-Guk
    • Environmental Engineering Research
    • /
    • 제16권3호
    • /
    • pp.137-148
    • /
    • 2011
  • In this study, a series of experiments was conducted on the relative degradation of commonly known endocrine-disrupting compounds such as bisphenol A (BPA) and $17{\alpha}$-ethinyl estradiol (EE2) in a single-component aqueous solution using 28 and 580 kHz ultrasonic reactors. The experiments were conducted with three different types of model water: deionized water (DI), synthetic brackish water (SBW), and synthetic seawater (SSW) at pH 4, 7.5, and 11 in the presence of inert glass beads and humic acids. Significantly higher sonochemical degradation (93-97% for BPA) occurred at 580 kHz than at 28 kHz (43-61% for BPA), regardless of water type. A slightly higher degradation was observed for EE2 compared to that of BPA. The degradation rate of BPA and EE2 in DI water, SBW, and SSW after 30 min of ultrasound irradiation at 580 kHz increased slightly with the increase in pH from 4 (0.073-0.091 $min^{-1}$ for BPA and 0.081-0.094 $min^{-1}$ for EE2) to 7.5 (0.087-0.114 $min^{-1}$ for BPA and 0.092-0.124 $min^{-1}$ for EE2). In contrast, significant degradation was observed at pH 11 (0.149-0.221 $min^{-1}$ for BPA and 0.147-0.228 $min^{-1}$ for EE2). For the given frequencies of 28 and 580 kHz, the degradation rate increased in the presence of glass beads (0.1 mm and 25 g) for both BPA and EE2: 0.018-0.107 $min^{-1}$ without beads and 0.052-0.142 $min^{-1}$ with beads for BPA; 0.021-0.111 $min^{-1}$ without beads and 0.054-0.136 $min^{-1}$ with beads for EE2. A slight increase in degradation of both BPA and EE2 was found as the concentration of dissolved organic carbon (DOC, humic acids) increased in both SBW and SSW: 0.107-0.115 $min^{-1}$ in SBW and 0.087-0.101 $min^{-1}$ in SSW for BPA; 0.111-0.111 $min^{-1}$ in SWB and 0.092-0.105 $min^{-1}$ in SSW for EE2. After 30 min of sonicating the humic acid solution, DOC removal varied depending on the water type: 27% (3 mg $L^{-1}$) and 7% (10 mg $L^{-1}$) in SBW and 7% (3 mg $L^{-1}$) and 4% (10 mg $L^{-1}$) in SSW.