• Title/Summary/Keyword: Conversion of $CO_2$ to CO

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Interrelationships among pH, pe, Fe++ and Water Soluble Phosphate in Reduced Soil- Water Suspension (환원(還元)된 토양현탁액중(土壤懸濁液中) pH, pe, Fe++ 및 수용성(水溶性) 인산간(燐酸間)의 관계(關係)에 관한 연구)

  • Yoon, Jung-Hui;Hong, Chong-Woon;Huh, Beom-Lyang
    • Korean Journal of Soil Science and Fertilizer
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    • v.15 no.3
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    • pp.162-165
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    • 1982
  • As an approach to the explanation of increased availability of phosphate in reduced wetland soils, the interrelationships among pH, pe, $Fe^{+{+}}$ and water soluble phosphate in reduced soil-water suspension was studied. 1. p.e value of soil incubated for 8 weeks at $30^{\circ}C$ under waterlogged condition was sufficiently low to allow the conversion of strengite to vivianite. 2. The concentration of water soluble $Fe^{+{+}}$ in this system was higher than that is allowable by the solubility of vivianite. 3. From the relationship between pH and the concentration of water soluble $Fe^{+{+}}$, the concentration of water soluble $Fe^{+{+}}$ could be determined with the solubility of $FeCO_3$. 4. No definite relationship between pH and water soluble P was recognized which implied that the concentration of water soluble P in this system could not determined with the solubility of vivianite.

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Optimization of KOGAS DME Process From Demonstration Long-Term Test (KOGAS DME 공정의 실증 시험을 통한 최적화 기술개발)

  • Chung, Jongtae;Cho, Wonjun;Baek, Youngsoon;Lee, Changha
    • Journal of Hydrogen and New Energy
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    • v.23 no.5
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    • pp.559-571
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    • 2012
  • Dimethyl ether (DME) is a new clean fuel as an environmentally-benign energy resource. DME can be manufactured from various energy sources including natural gas, coal, and biomass. In addition to its environmentally friendly properties, DME has similar characteristics to those of LPG. The aim of this article is to represent the development of new DME process with KOGAS's own technologies. KOGAS has investigated and developed new innovative DME synthesis process from synthesis gas in gaseous phase fixed bed reactor. DME has been traditionally produced by the dehydration of methanol which is produced from syngas, a product of natural gas reforming. This traditional process is thus called the two-step method of preparing DME. However, DME can also be manufactured directly from syngas (single-step). The single-step method needs only one reactor for the synthesis of DME, instead of two for the two-step process. It can also alleviate the thermodynamic limitations associated with the synthesis of methanol, by converting the produced methanol into DME, thereby potentially enhancing the overall conversion of syngas into DME. KOGAS had launched the 10 ton/day DME demonstration plant project in 2004 at Incheon KOGAS LNG terminal. In the mid of 2008, KOGAS had finished the construction of this plant and has successively finished the demonstration plant operation. And since 2008, we have established the basic design of commercial plant which can produce 3,000 ton/day DME.

Production of heteropolysaccharide-7 by Beijerinckia indica HS-2001 with continuous culture

  • Yang, Jae-Gyun;Seo, Hyeong-Pil;Sin, Myeong-Gyo;Lee, Jin-U
    • 한국생물공학회:학술대회논문집
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    • 2003.04a
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    • pp.249-252
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    • 2003
  • Maximal production of heteropolysaccharide-7(PS-7) with a batch culture for 48 hr was $10.0\;g/{\ell}$ and its conversion rate from 2% (w/v) glucose to PS-7 was 50%. After substitution of media, production of PS-7 continued and reached its maximal production. The highest productivity occurred when the fresh medium, which contained all ingredients, for the production of PS-7 was substituted. Higher production of PS-7 was maintained at a dilution rate of 0.0125, which was established as the optimal dilution rate for the production of PS-7 by B. indica HS-2001.

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High Purity Hydrogen Generator for Fuel Cell Vehicles (연료전지 자동차 탑재형 고순도 수소생산장치)

  • Han, Jaesung;Lee, Seok-Min
    • Journal of Hydrogen and New Energy
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    • v.12 no.4
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    • pp.277-285
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    • 2001
  • We developed a compact, 10 kWe, purifier-integrated reformer which supplies hydrogen for fuel cell vehicles. Our proprietary technologies regarding hydrogen purification by palladium alloy membrane and catalytic combustion by noble metal coated wire-mesh catalyst were combined with the conventional methanol steam reforming technology, resulting in higher conversion, excellent quality of product hydrogen, and better thermal efficiency than any other systems. In this system, steam reforming, hydrogen purification, and catalytic combustion take place all in a single reactor so that the whole system is compact and easy to operate. The module produces $8.2Nm^3/hr$ of 99.999% or higher purity hydrogen with CO impurity less than 10 ppm, which is equivalent to 10 kWe when PEMFC has 45 % efficiency. Thermal efficiency of the module is 81 % and the power density of the module is 1.6 L/kWe. As the results of experiments, cold-start time has been measured about 20 minutes. Response time of hydrogen production to the change of the feed rate has been within 1 minutes.

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The De-CH4 Characteristics of NGOC for CH4 Reduction of a CNG Bus (CNG 버스의 CH4 저감용 NGOC의 de-CH4 특성)

  • Seo, Choong-Kil;Choi, Byung-Chul
    • Journal of Power System Engineering
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    • v.20 no.4
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    • pp.69-74
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    • 2016
  • Recently, in order to meet the stricter emission regulations, the proportion of after-treatments for vehicle and vessel is increasing gradually. The purpose of this study is to investigate the de-$CH_4$ characteristics of NGOC in front of proposed combined system according to additive catalyst and support ratio. In the case of Pd addition, the de-$CH_4$ performance of 2Pt-2Pd-3MgO/$Al_2O_3$ NGOC was improved by approximately 10 to 20% for the HC components. The de-$CH_4$ performance of 2Pt-2Pd-3Cr-3MgO/$Al_2O_3$ NGOC was higher compared to five kinds of NGOC catalysts, because Cr particle was smaller and dispersion of Pd was increased. The NGOC(Zeolite:$Al_2O_3$(80%:20%)}catalyst according to support ratio, was improved performance at low temperature region on CO and NO conversion rate.

A study on core loss analysis of 1.5V 60A class VRM (1.5V 60A급 VRM의 인덕터 손실 분석에 관한 연구)

  • Jeon, Hyun;Lee, Darl-Woo;Ahn, Tae-Young;Choi, Gwang-Bo
    • Proceedings of the KIPE Conference
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    • 2005.07a
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    • pp.449-451
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    • 2005
  • In this paper, to report the experimental results the core losses of VRM inductor. The VRM, that has a output voltage 1.5V, output current 60A, maximum power of 90W. Experimental results verify, the VRM has a almost same data of fast transient response, a efficiency test with high flux and ferrite inductor. A maximum power conversion efficiency of the experimental VRM was measured at 92% within 0.2% load regulation.

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Synthesis of Acrylic Resins with High-Solids Contents for HS Coatings (하이솔리드 도료용 고 고형분인 아크릴수지의 합성에 관한 연구)

  • Yang, In-Mo;Wu, Jong-Pyo;Park, Hong-Soo;Kim, Seong-Kil
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.4
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    • pp.233-239
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    • 2000
  • To prepare an environmental friendly high-solid coatings an acrylic resin containing 80% of solid content was synthesized by addition polymerization of caprolactone acrylate, n-butyl acrylate, ethyl methacrylate, and 2-hydroxyethyl methacrylate. The conversion was $78{\sim}93%$ and the prepared resin's physical properties are as follows: viscosity, $212{\sim}3424cps: $M_{n}$ $1740{\sim}2400$. There was a trend that viscosity and molecular weight of the resin increased with Tg, but no direct proportionality was observed.

Biogas Reforming through Microwave Receptor Heating (마이크로웨이브 수용체 가열을 통한 바이오가스 개질)

  • Young Nam Chun;June An
    • New & Renewable Energy
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    • v.20 no.1
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    • pp.126-134
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    • 2024
  • Biogas, composed mainly of methane (CH4) and carbon dioxide (CO2), is a renewable gas that can serve as an alternative energy source. In this study, we developed a new microwave reformer and analyzed its reforming characteristics. We observed that higher temperatures of the microwave receptor led to increased reforming efficiency. By supplying appropriate amounts of methane and steam, we could prevent carbon generated from the thermal decomposition reaction of carbon dioxide from depositing on the catalytic active layer, thus avoiding the inhibition of catalytic activity. Hydrogen generation was enhanced when maintaining the biogas ratio and steam supply at adequate levels. Increasing the SiC ratio in the receptor improved the uniformity of temperature distribution and growth rate, resulting in higher conversion rates of the reforming process.

Effects of a Sensory Stimulation on Weight, Stress Hormone and Behavioral State in Premature Infants (감각자극이 미숙아의 체중, 스트레스호르몬 및 행동상태에 미치는 효과)

  • 이군자
    • Journal of Korean Academy of Nursing
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    • v.29 no.2
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    • pp.445-455
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    • 1999
  • This study has been conducted on the nonequivalent control group pretest-posttest design in quasi experimental basis and newly born premature infants from intensive care unit of G Medical University Hospital in Inchon Metropolitan were selected in two groups of 21 infants each. The first group for experimental and the other for control. Data has been collected form October 30, 1997 to August 29, 1998. For the experimental group tactile and kinesthetic stimulation was applied 2 times a day for 10 days(10 : 00~11 : 00 hours in the morning and 17 : 00~18 : 00 in the afternoon). As a weight weighing instrument. electronic indicator scale(Cas Co. korea) was used. To determine urine cortisol concentration level in stress hormone, radio immune assay method was used. And high performance liquid chlomatography was used to determine urine norepinephrine, concentration level To determine behavior status, tools developed by Anderson et at(1990) and remodeled by Kim Hee-Sook(1996) were used. Collected data were analyzed with the SAS program using x$^2$-test, student t-test, repeated measures ANOVA and paired t -test. The result were as follow. 1. As for the daily weight gain. the experimental group showed first change in weight and this group also showed higher weight in the average weight than the control group. Statistically, however, there was no significant factor between the two group. 2. The cortisol concentration in urine showed decrease in the experimental group norepinephrine concentration in urine showed increase in both experimental and control groups. No statistical significance was shown between the two groups. 3. In the aspect of behavior status. the experimental group showed statistical significance by showing inactive in the state of alert and conversion to a positive state than the control group. In conclusion, the sensory stimulation in this study showed a positive aspect through there was no statistical significance in the weight gain and urine stress hormone concentration. In the behavior status, there was statistical significance in the frequency of staying inactive in the state of alert and conversion to a positive state.

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Broadband energy harvester for varied tram vibration frequency using 2-DOF mass-spring-damper system

  • Hamza Umar;Christopher Mullen;Soobum Lee;Jaeyun Lee;Jaehoon Kim
    • Smart Structures and Systems
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    • v.32 no.6
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    • pp.383-391
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    • 2023
  • Energy harvesting in trams may become a prevalent source of passive energy generation due to the high density of vibrational energy, and this may help power structural health monitoring systems for the trams. This paper presents a broadband vibrational energy harvesting device design that utilizes a varied frequency from a tram vehicle using a 2 DOF vibrational system combined with electromagnetic energy conversion. This paper will demonstrate stepwise optimization processes to determine mechanical parameters for frequency tuning to adjust to the trams' operational conditions, and electromagnetic parameters for the whole system design to maximize power output. The initial optimization will determine 5 important design parameters in a 2 DOF vibrational system, namely the masses (m1, m2 (and spring constants (k1, k2, k3). The second step will use these parameters as initial guesses for the second optimization which will maintain the ratios of these parameters and present electrical parameters to maximize the power output from this system. The obtained values indicated a successful demonstration of design optimization as the average power generated increased from 1.475 mW to 17.44 mW (around 12 times).