• Title/Summary/Keyword: Chloride ion attack

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Analysis on Changes in Strength, Chloride Diffusion, and Passed Charges in Normal Concrete Considering Ages and Mix Proportions (재령 및 배합특성을 고려한 보통 콘크리트의 강도, 염화물 확산계수, 통과전하량 변화 분석)

  • Lee, Hack-Soo;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.1
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    • pp.1-7
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    • 2017
  • Concrete behavior in early-age is changing due to hydration reaction with time, and a resistance to chloride attack and strength development are different characterized. In the present work, changing strength and resistance to chloride attack are evaluated with ages from 28 days to 6 months. For the purpose, strength, diffusion coefficient, and passed charge are evaluated for normal concrete with 3 different mix proportions considering 28-day and 6-month curing conditions. With increasing concrete age, the changing ratio of strength falls on the level of 135.3~138.3%, while diffusion coefficient and passed charge shows 41.8%~51.1% and 53.6%~70.0%, respectively. The results of chloride diffusion coefficient and passed charge show relatively similar changing ratios since they are much dependent on the chloride migration velocity in electrical field. The changing ratios in chloride behaviors are evaluated to be much larger than those in compressive strength since the ion transport mechanism is proportional to not porosity but square of porosity.

An Experimental Study on the Shrinkage Properties and Resistance for Chloride Attack of Seaside Construction Concrete added Durability Improvement Agent (내구성개선제가 첨가된 해안 구조물용 콘크리트의 수축특성과 내염해성에 관한 실험적 연구)

  • Kim, Do-Su;Kim, Woo-Jae;Kim, Hyun-Bae;Jung, Sang-Jin
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.11a
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    • pp.151-154
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    • 2006
  • It is generally referred that life cycle of concrete construction is depend on whether durability of concrete is obtained or not. Nevertheless, it has not been yet applied that new material and technology to improve durability of concrete such as seaside concrete construction. In this study, chemical agent which is capable of improving durability added to 2 types seaside concrete mixs and evaluated engineering properties such as slump, air content, setting time and compressive strength. Besides shrinkage crack with an restraint condition and chloride ion penetration tests were executed to measure resistance of concrete added chemical agent and then compared non-added. It was appeared that engineering properties and resistant for chlorides was possible to improved. But resistant for shrinkage crack was not noticeable improvement than non-added. Therefore it is necessary that more consideration and following study to improve durability aspect to shrinkage crack and chlorides resistant.

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Evaluation on the Chloride Ion Diffusion Coefficient of Mortar Depending on Replacement Ratio of Recycled Fine Aggregate (순환잔골재 치환율에 따른 모르타르의 염화물이온확산계수 평가)

  • Lee, Sang-Yun;Yoo, Jae-Chul;Kim, Gyu-Yong;Yoon, Min-Ho;Nam, Jeong-Soo;Choi, Hyeong-Gil
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.6
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    • pp.479-485
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    • 2016
  • This paper presents an experimental study conducted to investigate the effect of recycled fine aggregate (RFA) on the mechanical properties and chloride diffusion behavior of mortar. The test results revealed that the addition of RFA plays an important role in the mechanical properties and pore structures of the investigated mortar specimens as well as chloride diffusion behavior. The mechanical properties such as compressive strength and flexural strength of recycled fine aggregate mortar (RFAM) were gradually decreased as RFA replacement ratio increase. The pore structure of RFAM was examined by permeability tests. The RFAM showed a increment in the permeability according to replacement ratio increase of RFA. But the chloride diffusion coefficient of RFAM was almost same up to 50% replacement ratio of RFA due to a chloride binding phenomenon of RFAM which may compensate the higher permeability of RFAM.

Experimental Study for Evaluation of Chloride Ion Diffusion Characteristics of Concrete Mix for Nuclear Power Plant Water Distribution Structures (원전 취배수 구조물 콘크리트 배합의 염소이온 확산특성 평가를 위한 실험적 연구)

  • Lee, Ho-Jae;Seo, Eun-A
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.5
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    • pp.112-118
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    • 2022
  • In this study, the diffusion characteristics were evaluated using the concrete mix design of nuclear safety-related structures. Among the concrete structures related to nuclear power safety, we selected the composition of intake and drainage structures that are immersed in seawater or located on the tidal platform and evaluated the chloride ion permeation resistance by compressive strength and electrical conductivity and the diffusion characteristics by immersion in salt water. analyzed. Compressive strength was measured on the 1st, 7th, 14th, 28th, 56th, and 91st days until the 91st day, which is the design standard strength of the nuclear power plant concrete structure, and chloride ion permeation resistance was evaluated on the 28th and 91st. After immersing the 28-day concrete specimens in salt water for 28 days, the diffusion coefficient was derived by collecting samples at different depths and analyzing the amount of chloride. As a result, it was found that after 28 days, the long-term strength enhancement effect of the nuclear power plant concrete mix with 20% fly ash replacement was higher than that of concrete using 100% ordinary Portland cement. It was also found that the nuclear power plant concrete mix has higher chloride ion permeation resistance, lower diffusion coefficient, and higher resistance to salt damage than the concrete mix using 100% ordinary Portland cement.

Development of Multidiretion Incoming Salt Collector (다방향 비래염분 포집기 개발 및 포집 정확도 검증)

  • Park, Dong-Cheon;Ahn, Jae-Cheol;Kim, Woo-Jae;Oh, Sang-Gyun;Kim, Hyo-Youl;Kang, Byung-Hi
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.05a
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    • pp.13-14
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    • 2011
  • Reinforced concrete structures are damaged by concrete carbonation, salt attack, and sulfate attack. The evaluation of the amount of chloride ion from the sea is very important to assess the life expectancy of Reinforced Concrete structures. The incoming salt collector which is developed in Japan has been used until the present, Unfortunately, the incoming salt collector has had a bad reputation which is caused by backward wind. The wind from backward causes the reduction of the amount of collected salt in collector's gauze. The collector was developed for excluding the effect of backward wind. The performance of it was verified from analytic and experimental methods.

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Evaluation of Chloride Attack Resistibility of Heavyweight Concrete Using Copper Slag and Magnetite as Aggregate (동슬래그 및 자철석을 골재로 사용한 중량 콘크리트의 회파블록 적용을 위한 염해저항성 평가)

  • Moon, Hoon;Kim, Ji-Hyun;Lee, Jae-Yong;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.6
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    • pp.483-492
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    • 2017
  • Recently, the coastal area has become the popular place for infrastructure development. To provide a beautiful scenary of costal area to nearby facilities without any hinderance, and also to protect those facilities from the sea water overflow, it is necessary to develop a new type of wave dissipating block, which is a turning wave block. It is noticeable that the top of the turning wave block is flat and thus can provide spaces for various purposes. However, the unit weight of the block decreases due to the presence of pipeline that is installed for turning the direction of the waves. In order to mitigate such problem, a heavyweight concrete needs to be used to increase the resistance against tidal waves. The copper slag and magnetite were used as a source of fine and coarse aggregate, respectively. The 28 day compressive strength of concrete incorporating ordinary and heavyweight aggregate did not show significant differences. It should be noted that the chloride ion penetration resistance was evaluated using NT-BUILD 492 rather than ASTM C 1202 method because concrete incorporating magnetite as a coarse aggregate showed excessive current flow by ASTM C 1202 method. According to the results from NT Build 492 method, which uses the penetration depth of chlorine ions to obtain chloride ion diffusivity, the heavyweight concrete incorporating the copper slag and the magnetite showed the best resistance against the chloride ion penetration. Therefore, it is reasonable to say that heavyweight concrete made with copper slag and magnetite can be used for production of turning wave block.

Effect of the Pore Structure of Concrete on the Compressive Strength of Concrete and Chloride Ions Diffusivity into the Concrete

  • Kim, Jin-Cheol;Paeng, Woo-Seon;Moon, Han-Young
    • Journal of the Korea Concrete Institute
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    • v.15 no.2
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    • pp.345-351
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    • 2003
  • The transport characteristics of deleterious ions such as chlorides depend on the pore structures of concrete and are the major factors in the durability of concrete structures in subjected to chloride attack such as in marine environments. In this paper, the effect of the pore structure on compressive strength and chloride diffusivity of concrete was investigated. Six types of concretes were tested. The pore volume of concrete containing mineral admixtures increased in the range of 3∼30nm due to micro filling effect of hydrates of the mineral admixtures. There was a good correlation between the median pore diameter, the pore volume above 50nm and compressive strength of concrete, but there was not a significant correlation between the total pore volume and compressive strength. The relationship between compressive strength and chloride diffusivity were not well correlated, however, pore volume above 50nm were closely related to the chloride diffusion coefficient.

Improvement of Seawater Corrosion Resistance of Concrete Reinforcing Steel Using by Conductive Photocatalyst (전도성 광촉매를 이용한 콘크리트 철근의 염해 내구성 향상에 관한 연구)

  • Bae, Geun-Guk;Bae, Geun-Woo;Ahn, Yong-Sik
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.2
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    • pp.152-159
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    • 2017
  • In marine environment, the durability of concrete and reinforcing steel is known to be deteriorate by the permeation of chloride ion into concrete. In this study the conductive photocatalyst was used to improve the seawater corrosion resistance of the concrete and steel. Mortar and concrete samples were prepared by mixing with various amounts of conductive active carbon and photocatalytic powder($TiO_2$). The compressive strength of concrete was decreased with the increase of the amount of conductive carbon powders. The samples containing conductive carbon and photocatalytic powders showed the superior seawater corrosion resistance compared with the ordinary sample, which was verified by XRF analysis showing the concentration of chloride ion($Cl^-$) of mortars and concretes. The inhibitive effect of photocatalyst against chloride attack was discussed with the diffusion coefficient of chloride ion into mortar and concrete.

Modeling of Chloride Ingress in Reinforced Concrete Structures (철근 콘크리트 구조물의 염소이온 침투 모델)

  • Koo, Hyun-Bon;Kim, Eui-Tae;Lee, Kwang-Myong
    • Journal of the Korea Concrete Institute
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    • v.15 no.1
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    • pp.25-34
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    • 2003
  • The degradation of reinforced concrete (RC) structures due to physical and chemical attacks has been a major issue in construction engineering. Deterioration of RC structures by chloride attack followed by reinforcement corrosion is one of the serious problems. An objective of this study is to develop a form of mathematical model of chloride ingress into concrete. In order to overcome some limits of the previous approaches, a chloride ingress model, consisting of chloride solution intrusion through the capillary pore and chloride ion diffusion through the pore water, was proposed. Moreover, the variability of chloride ion diffusivity due to the degree of hydration of cement, relative humidity in pore, exposure condition, and variation of chloride binding, was considered in the model. In order to verify the proposed model, the results predicted by the proposed model were compared with analysis results of Life-365, a computer program for predicting the service life of reinforced concrete structures exposed to chlorides. In conclusion, the proposed model would be promising to predict the chloride ion profile and to estimate the service life of RC structures.

The Mechanical Properties of Concrete Using Blended Super Low Heat Cement (혼합형 초저발열 시멘트를 사용한 콘크리트의 물성-현수교 앵커리지 콘크리트 대상-)

  • 송용순;강석화;손명수
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.341-344
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    • 1999
  • In the case of the offshore concrete structures like the anchorage block of a suspension bridge of Kwangan Grand Road, there is a need of the concrete which has low heat of hydration and good resistance for sea-water attack. In this study, the blended super low heat cement which satisfies that requirement was developed and several tests were carried out. The concrete using the blended super low heat cement showed lower adiabatic temperature rise than 3$0^{\circ}C$ and good early strength. Also, its passed charge(coulomb) to resist chloride ion penetration was very low.

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