• Title/Summary/Keyword: CIO2

Search Result 78, Processing Time 0.02 seconds

Electrochamical Properties of $LiFePO_4$ Electrodes for Lithium Polymer Battery (리튬 폴리머 전지 $LiFePO_4$의 전기화학적 특성)

  • Kong, Ming-Zhe;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2005.05b
    • /
    • pp.5-9
    • /
    • 2005
  • $LiFePO_4$ is a potential candidate for the cathode material of the lithium polymer batteries. $LiFePO_4$ cathode active materials were synthesized by coating on the $LiFePO_4$ was tried using $TiO_2$ and corbon in oreder to increase cyclic performance and electronic conductivity. Highly dispersed on the particles enhances the electronic conductivity and increases the capacity. For lithium polymer battery applications, $LiFePO_4$/SPE/Li and $LiFePO_4$-$TiO_2$/SPE/Li 'cells were characterized electrochemically by cyclic volatammetry and charge/discharge cycling. The $LiFePO_4$-carbon-$TiO_2$ cathode in PVDF-PC-EC-$LiCIO_4$ electrolyte showed high capacity at high current density.

  • PDF

Electrochemical Behavior of Vanadium Trungsten Oxide Thin Films Deposited by Sputtering (스퍼터링으로 증착한 바나듐 텅스텐 산화물 박막의 전기화학적 거동)

  • 박영신;이병일;주승기
    • Journal of the Korean institute of surface engineering
    • /
    • v.30 no.2
    • /
    • pp.121-127
    • /
    • 1997
  • Vanadium tungsten oxide thin films were formed by RF magnetron sputtering and the effects of tungsten addition on the crystallinity and on the electrochemical behavior were investigated. X-ray analysis revealed that amorphized films could be obtained by tungase addition. In order to investigate the electrochemical behavior of the vanadium tungsten oxide films, electrochemical insertion and extraction of lithium were out in 1m $LiCIO_4$-PC-DME electrolyte using litium metal as a counter electrode. When the tungsten was added to the $V_2O_5$ films, cycling reversibility was considerably improved. Electrochemical test showed the cell capacity of about $70\mu\;Ah/\textrm{cm}^2-\mu\textrm{m}$ when the amount of additive tungseten reached 30 atomic percent. No appreciable degradation of the cell capacity could be observed after hundred cycles of insertion and extration od Li.

  • PDF

A Study on the Evaluation of SME's Information Infrastucture (중소기업 정보인프라 진단에 관한 연구)

  • Sung, Tae-Kyung;Chu, Seok-Jin;Kim, Joong-Han;Kim, Jae-Kyeong
    • Asia pacific journal of information systems
    • /
    • v.7 no.2
    • /
    • pp.199-223
    • /
    • 1997
  • The purpose of this study is to identify the components of SME's information infrastructure through literature review, empirically investigate the components, and develop a model for SME's information infrastructure. The fact that SME's are having difficulties in building their own information infrastructure due to the limitation of capital investment, technology, and manpower is the main motive for the study The survey questionnaires were distributed to CEO's and users of 3W SME's and intensive interviews were cornea out to CIO's and information services personnel to further investigate H/W and S/W components of Information Infrastructure. The study results show that there seems to be five main factors for SME's information infrastructure. They are: (1) Informatization Capacity, (2) Software and Network, (3) Management Recognition and Utilization, (4) Hardware, and (5) Alignment between Users and Information Services.

  • PDF

Open Trade Technical Model using ebXML for FTA with China and Korea

  • Jung, Yong Gyu;Kang, Min Soo;Jung, Ga-Woon;Cha, Kwang Seung;Chong, Agatha
    • International Journal of Advanced Culture Technology
    • /
    • v.2 no.1
    • /
    • pp.25-29
    • /
    • 2014
  • China and South Korea have effectively reached a free trade agreement. The deal now faces legal and parliament reviews in the two countries. We need to discuss the recommendations on XML conversion with UN / CEFACT electronic documents. To solve this problem of interworking between these standards, Two kinds of translation rules is proposed for exchanging to UN / CEFACT Tag smoothly. For development and distribution of electronic documents to be conformed to international standards, it is enough to have the role of international activities continue to supply part of the domestic industry and the trends in participation and international standard. Our principal focus is on facilitating national and international transactions, through the simplification and harmonization of processes, procedures and information flows, and so contributing to the growth of global commerce. The agreement with South Korea will be China's ninth bilateral FTA.

New Mechanism for the Reaction of Thianthrene Cation Radical Perchlorate with tert-Butyl Peroxide

  • Park, Bo-Kyung;Sohn, Chang-Kook;Lee, Wang-Keun
    • Bulletin of the Korean Chemical Society
    • /
    • v.23 no.1
    • /
    • pp.103-106
    • /
    • 2002
  • A new reaction mechanism is proposed for the reaction of thianthrene cation radical perchlorate $(Th^{+{\cdot}}CIO_4^-}$ and tert-butyl peroxide in acetonitrile at room temperature on the basis of experimental and theoretical results. Rapid C-O bond rupture instead of O-O bond cleavage was observed by a good peroxy radical trapping agent, thianthrene cation radical. Products were N-tert-butyl acetamide, thianthrene 5-oxide (ThO), thianthrene 5,5-dioxide $(SSO_2)$, and thianthrene (Th). Thianthrene 5,10-dioxide (SOSO) was not obtained. A comparative computational study of the cation radical of tert-butyl peroxide is made by using B3LYP and CBS-4. The computational results are helpful to explain the reaction mechanism.

Effects of Seed Pre-treatment on Field Germination of Zanthoxylum piperitum DC. (초피나무 종자의 전처리가 포장에서의 출아에 미치는 영향)

  • 김인재;김민자;남상영;박재호;이철희;김홍식
    • Korean Journal of Plant Resources
    • /
    • v.16 no.2
    • /
    • pp.141-146
    • /
    • 2003
  • To improve the percentage of field germination of Zanthoxytum piperitum DC., storage in ground(control) and several chemicals as treatments was investigated. Germination percentage was 30.3 and 22.7% in GA$_3$(100 ppm) and NaCIO(10%), respectively compared with 17.3% in storage in ground without treatments. Germination percentage reached maximum between 26 and 33 days after seeding and then increased slowly. Top/Root ratio was the highest at storage in ground after the treatment of GA$_3$ 100ppm.

Dielectric Properties in Composite of Ion-Conductive Polymer and PZT Particles (이온전도성 고분자와 PZT미립자 복합체의 유전특성)

  • Park Sang-Ho;Kang Dae-Ha
    • The Transactions of the Korean Institute of Electrical Engineers C
    • /
    • v.55 no.2
    • /
    • pp.61-67
    • /
    • 2006
  • Dielectric and conductive frequency spectra in 0.01 Hz-13 MHz range have been measured for the composite consisting of PZT inclusions dispersed in $LiCIO_{4}$-doped polyerhylene oxide(Li_PEO) matrix with various volume fractions. The dielectric and conductive spectra of the composites revealed the relaxations related with electrode polarization and interfacial polarization. The observed spectra were reproduced using the empirical dielectric function and we could obtain various parameters related to the above two kinds of polarizations and dicussed about the parameters.

A Study on Adoption of Inter-Organizational Systems (IOS) (기업의 조직간 정보시스템(IOS)의 도입에 관한 연구)

  • Kim, Jun-Woo;An, Sang-Ho
    • Journal of Information Technology Applications and Management
    • /
    • v.12 no.2
    • /
    • pp.63-77
    • /
    • 2005
  • With the progress of IT, the strategic use of information systems (IS) has been applied to the inter-organization business areas, that is called Inter-organization Systems (IOS). Previous IT diffusion researches or IT adoption researches have been focused to newly emerged IT but confined into individual organization. However, IOS such as internet relates with between organizations. In this sense, this research has analysed the IT diffusion factors affected by IOS based on the previous studies of IT adoption. This study employed a research model using the factors of adopting IOS in organization, and conducted an empirical research with questionaries with top domestic 80 firms. And the finding is that the factors of the CIO support, business partners and an industry community have significance but other factors such as the size of firm, the degree of IS maturity, the degree of firm centrality, the complexity or suitability of IOS does not.

  • PDF

Reduction of Microbial Load on Radish (Raphanus sativus L.) Seeds by Aqueous Chlorine Dioxide and Hot Water Treatments (이산화염소수 및 열수처리에 따른 무(Raphanus sativus L.) 새싹 종자의 미생물 제어 효과)

  • Park, Kee-Jai;Lim, Jeong-Ho;Kim, Ji-Hye;Jeong, Jin-Woong;Jo, Jin-Ho;Jeong, Seong-Woong
    • Food Science and Preservation
    • /
    • v.14 no.5
    • /
    • pp.487-491
    • /
    • 2007
  • This study was conducted to investigate the effect of treatment with squeous chlorine dioxide and hot water on the germination of radish (Raphanus sativus L.) seeds, and reduction of microbial load on the seeds. Increases in treatment and the concentration of aqueous chlorine dioxide in water resulted in increasing reductions in the counts of total aerobic microbes. Seeds treated with aqueous chlorine dioxide (100 ppm/20min, 200ppm/20min) showed about a 10-fold decrease in microbial loads. Germination of seeds was not adversely affected by any treatment tested, although the germination rate of seeds in the group treated at $55^{\circ}C$ for 20 min was reduced by 10% compared to that of control. Combined treatment with hot water and aqueous chlorine dioxide yielded better out comes in both microbial reduction and seed germination rate than did single treatments. A combined treatment with 100 ppm aqueous chlorine dioxide and hot water($45^{\circ}C$ or $50^{\circ}C$) resulted in about a 100-fold decrease in microbial load whereas germination rate showed only a slight increase to $97.0{\sim}97.7%$. Total aerobic microbial counts in radish seeds were decreased by aqueous chlorine dioxide and hot water treatment in the order. aqueous $CIO_2$+ hot water > aqueous $CIO_2$ > chlorinated water > hot water > control.

Degradation of the Chlorothalonil by Functional Zeolite-KCIO3 Complex (기능성 Zeolite-KCIO3 복합체에 의한 Chlorothalonil의 분해)

  • Choi, Choong-Lyeal;Park, Man;Lee, Dong-Hoon;Lee, Byung-Mook;Rhee, In-Koo;Choi, Jyung;Kim, Jang-Eok
    • Korean Journal of Environmental Agriculture
    • /
    • v.23 no.2
    • /
    • pp.111-116
    • /
    • 2004
  • Salt occlusion in Zeolite is a unique phenomenon that takes place only when the salt size is similar to the window size of host zeolite. $KCIO_3$-occluded Zeolite, as an environment-friendly oxidant, has a high potential for effective removal of various organic pollutants. This study was carried to investigate the characteristics and the removal kinetics of fungicide chlorothalonil by zeolite-$KCIO_3$ complex. About 10% of $KCIO_3$ was occluded in zeolite pores synthesized by salt-thermal method from fly ash, although the occlusion amount was relatively less compared to that of nitrate salts. By occlusion with $KCIO_3$, no remarkable changes were found in X-ray diffraction patterns of cancrinite, whereas some decrease of overall peak intensities was found with those of sodalite. Different releasing kinetics of $CIO_3^-$ ion were observed in distilled water and soil solution from zeolite-$KCIO_3$ complex. Two reactions, hydration and diffusion, seem to be related with the release of $KCIO_3$. Therefore, the release isotherm of $CIO_3^-$ ion well fitted to the power function model which indicate the release was made by hydration and diffusion. The removal of chlorothalonil by zeolite and $KCIO_3$ reached at reaction equilibrium within 6 hours by 18% and 47% respectively. However, the chlorothalonil removal by the zeolite-$KCIO_3$ complex increased slowly and steadily up to 92% in 96 hours. These findings suggested that zeolite-$KCIO_3$ complex could be applied for effective removal of organic contaminants in the soil and aqueous environment.